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Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

Spot friction welding (SFW) is a cost-effective spot joining technology for aluminum sheets compared with resistance spot welding (RSW) [1]. In this study, coated mild steel was spot friction welded to 6000 series aluminum using a tool with shoulder diameter of 10 mm and welding conditions of 1500-2000 rpm and time of 5 s. Testing showed that tensile shear strength increased as the solidus temperature of the coating on the steel decreased. Microstructure characterizations of steel/Al joint interfaces showed that zinc from the coatings was incorporated into the stir nuggets and that intermetallic phases may have formed but not in continuous layers. Some Al-Zn oxides that appeared to be amorphous were also found in the joint interfaces.

Gas-pressurized space suits are highly resistive to astronaut movement, and this resistance has been previously explained by volume and/or structural effects. This study proposed that an additional effect, pressure effects due to compressing/expanding the internal gas during joint articulation, also inhibits mobility. EMU elbow torque components were quantified through hypobaric testing. Structural effects dominated at low joint angles, and volume effects were found to be the primary torque component at higher angles. Pressure effects were found to be significant only at high joint angles (increased flexion), contributing up to 8.8% of the total torque. These effects are predicted to increase for larger, multi-axis joints. An active regulator system was developed to mitigate pressure effects, and was found to be capable of mitigating repeated pressure spikes caused by volume changes.

A new monitoring system predicts the progression of welding temperature fields during resistance spot welding. The system captures welding voltages and currents to predict contact diameters and simulate temperature fields. The system accurately predicts fusion lines and heat-affected zones. Accuracy holds even for electrode tips used for a few thousand welds of zinc coated steels.

Effects of split injection, with a relatively short time interval between the two sprays, on the spray development process, and the air entrainment into the spray, were investigated by using laser induced fluorescence and particle image velocimetry (LIF-PIV) techniques. The velocities of the spray and the ambient air were measured. The cumulative mass of the ambient air entrained into the spray was calculated by using the entrainment velocity normal to the spray boundary. The vortex structure of the spray, formed around the leading edge of the spray, showed a true rotating flow motion at low ambient pressures of 0.1 MPa, whereas at 0.4 MPa, it was not a true rotating flow, but a phenomenon of the small droplets separating from the leading edge of the spray and falling behind, due to air resistance. The development processes of the 2nd spray were considerably different from that of the 1st spray because the 2nd spray was injected into the flow fields formed by the 1st spray.

For both notchback-type and fastback-type models, it has been found that critical geometries which increase the aerodynamic drag exist, and the time-averaged wake patterns basically consist of an arch vortex behind the rear window and trailing vortices in the wake. The unsteady characteristics of the wake seem to be directly related to aerodynamic drag. However, the unsteady characteristics of these wake patterns for notchback and fastback cars were not clear. The purpose of present paper is to clarify these phenomena. We try to analyze experimentally the unsteady characteristics by measuring the velocity fluctuations in the wake, the pressure fluctuations on the trunk deck and the drag-force fluctuations acting on the model. At the same time, the analysis of the numerical simulation was made by using the same numerical model as the experimental model. The computed flow visualization behind the rear window showed a fluctuating arch vortex.

As a demand for vehicles of higher functionality grows, automakers and material suppliers are devoting increasing efforts to develop technologies for greater safety, lighter weight, higher corrosion resistance, and enhanced quietness. The resin-sandwiched vibration damping steel sheet (VDSS), developed as a highly functional material for reducing vehicle vibration and noise, has been used for oil pans1) and compartment partitions2). First applied for a structural dash panel of the new Mazda 929, a Zn-Ni electroplated VDSS which allows direct electric welding has contributed to greater weight reduction as well as improved quietness.

Long-haul and other heavy-duty trucks, presently almost entirely powered by diesel fuel, face challenges meeting worldwide needs for greatly reducing nitrogen oxide (NOx) emissions. Dual-fuel gasoline-alcohol engines could potentially provide a means to cost-effectively meet this need at large scale in the relatively near term. They could also provide reductions in greenhouse gas emissions. These spark ignition (SI) flexible fuel engines can provide operation over a wide fuel range from mainly gasoline use to 100% alcohol use. The alcohol can be ethanol or methanol. Use of stoichiometric operation and a three-way catalytic converter can reduce NOx by around 90% relative to emissions from diesel engines with state of the art exhaust treatment.

A method was studied for simultaneous zinc phosphating on aluminum and steel surfaces to obtain high corrosion resistance on aluminum surfaces, which conventional phosphatic processing could not provide with sufficient corrosion resistance. Since aluminum is protected by an oxide film on its surface, it has poor processability with zinc phosphating solutions applied to steel. An appropriate quantity of fluoride was therefore added to improve processing, and the coating film, aluminum composition and surface conditions were optimized to suppress filiform corrosion, which is characterized by string-like blisters of paint film starting from a paint defect. In addition, in view of the actual production environment, the corrosion resistance of the ground area made for readjustment after stamping was studied for the optimization of the processing solution.

In order to investigate the corrosion resistance of organic composite-coated steel sheets ( OCS ) in a real automotive environment, many kinds of corrosion tests were performed on test pieces and real automotive doors. Tests with a corrosive solution including iron rust were introduced to simulate the real corrosive environment of automotive doors. The relationship between the components of OCS and the corrosion resistance in the rust-including tests was examined. In addition, electrochemical studies were performed. Results indicate OCS has much better corrosion resistance than plated steel sheets with heavier coating weight in all tests. OCS shows excellent corrosion resistance in rust-free corrosive solution, however, some types of OCS do have corrosion concerns in rust-including tests. It became clear that these OCS types have an organic coating with lower cross-linking.

A study of a direct-injection stratified-charge system (DISC), as applied to a rotary engine (RE) for motor vehicle usage, was undertaken. The goals of this study were improved fuel consumption and reduced exhaust emissions. These goals were thought feasible due to the high thermal efficiency associated with the DISC-RE. This was the first application of this technology to a motor vehicle engine. Stable ignition and ideal stratification systems were developed by means of numerical calculations, air-fuel mixture measurements, and actual engine tests. The use of DISC resulted in significantly improved fuel consumption and reduced exhaust emissions. The use of an exhaust gas recirculating system was studied and found to be beneficial in NOx reduction.

A large quantity of recirculated exhaust gas is used to reduce NOx emissions and improve fuel economy at the same time. The effect of exhaust gas recirculation (EGR) was investigated under the stoichiometric and lean operating conditions and compared with the effect of lean operation without EGR. A mixture injected SI engine that has a mechanically driven mixture injection valve installed was prepared. In this engine, it is possible to charge combustible mixture independently from combustion air and recirculated exhaust gas introduced from intake port in order to stratify the mixture. The effect of the EGR ratio on NOx emissions and fuel consumption was measured under the stoichiometric and lean operating conditions. Due to the mixture distribution controlled by the mixture injection, a large quantity of recirculated exhaust gas could be introduced into the combustion chamber under the stoichiometric air/fuel ratio. The limit of EGR ratio was 48 %.

The development of a cycle simulation model for the jet ignition prechamber stratified charge engine is described. Given the engine geometry, load, speed, air-fuel ratios and pressures and temperatures in the two intakes, flow ratio and a suitable combustion model, the cycle simulation predicts engine indicated efficiency and NO emissions. The relative importance of the parameters required to define the combustion model are then determined, and values for ignition delay and burn angle are obtained by matching predicted and measured pressure-time curves. The variation in combustion parameters with engine operating variables is then examined. Predicted and measured NO emissions are compared, and found to be in reasonable agreement over a wide range of engine operation. The relative contribution of the prechamber NO to total exhaust NO is then examined, and in the absence of EGR, found to be the major source of NO for overall air-fuel ratios leaner than 22:1.

A linearized lumped parameter heat balance model was developed and is discussed for the general case of resistance welding to see the effects of each parameter on the lobe shape. The parameters include material properties, geometry of electrodes and work piece, weld time and current, and electrical and thermal contact characteristics. These are then related to heat dissipation in the electrodes and the work piece. The results indicate that the ratio of thermal conductivity and heat capacity to electrical resistivity is a characteristic number which is representative of the ease of spot weldability of a given material. The increases in thermal conductivity and heat capacity of the sheet metal increase the lobe width while increases in electrical resistivity decrease the lobe width. Inconsistencies in the weldability of thin sheets and the wider lobe width at long welding times can both be explained by the heat dissipation characteristics.

An all-ceramic swirl chamber has been developed which meets the 1987 U.S. particulate emission standard for LDV. The all ceramic construction raises combustion temperature to reduce particulate emission to the necessary level. But particulate reduction led to two-fold increase in NOx. This problem was coped with by applying EGR and fuel injection timing control. As a result NOx has been cut to the same level as with a base engine and particulate has been further reduced.

The substantial part of the drag of an automobile is the pressure drag. Therefore, the car must be designed as it produces minimum pressure drag. The present paper describes effects of geometrical configuration of the rear part of a car on the aerodynamic drag. Experiments were made on 1/5 scale models of fastback and notchback design. For the fastback car the drag depends heavily on the angle of a rear window. At a certain critical angle the drag shows a sharp peak. This peak drag can be reduced drastically by the tapering of plan form of the rear geometry. For the notch-back design some combination of the angle of rear window and height of trunk deck shows similar maximum in the drag. Methods of avoiding the large drag were also found. Our experiment was extended to the measurement of structure of wake by hot wire anemometers and total pressure tubes. The correlation between the wake structure and drag was clarified by the consideration of vorticity and circulation.

The use of hydrogen as a fuel supplement for lean-burn engines at higher compression ratios has been studied extensively in recent years, with good promise of performance and efficiency gains. With the advances in reformer technology, the use of a gaseous fuel stock, comprising of substantially higher fractions of hydrogen and other flammable reformate species, could provide additional improvements. This paper presents the performance and emission characteristics of a gas mixture of equal volumes of hydrogen, CO, and methane. It has recently been reported that this gas mixture can be produced by reforming of ethanol at comparatively low temperature, around 300C. Experiments were performed on a 1.8-liter passenger-car Nissan engine modified for single-cylinder operation. Special pistons were made so that compression ratios ranging from CR= 9.5 to 17 could be used. The lean limit was extended beyond twice stoichiometric (up to lambda=2.2).

The Cu-zeolite (CuZ) SCR catalyst enables higher NOx conversion efficiency in part because it can store a significant amount of NH3. “NH3 storage control”, where diesel exhaust fluid (DEF) is dosed in accord with a target NH3 loading, is widely used with CuZ catalysts to achieve very high efficiency. The NH3 loading actually achieved on the catalyst is currently estimated through a stoichiometric calculation. With future high-capacity CuZ catalyst designs, it is likely that the accuracy of this NH3 loading estimate will become limiting for NOx conversion efficiency. Therefore, a direct measurement of NH3 loading is needed; RF sensing enables this. Relative to RF sensing of soot in a DPF (which is in commercial production), RF sensing of NH3 adsorbed on CuZ is more challenging. Therefore, more attention must be paid to the “microwave resonance cavity” created within the SCR assembly. The objective of this study was to develop design guidelines to enable and enhance RF sensing.

Internal combustion engines for plug-in hybrid heavy duty trucks, especially long haul trucks, could play an important role in facilitating use of battery power. Power from a low carbon electricity source could thereby be employed without an unattractive vehicle cost increase or range limitation. The ideal engine should be powered by a widely available affordable liquid fuel, should minimize air pollutant emissions, and should provide lower greenhouse gas emissions. Diesel engines could fall short in meeting these objectives, especially because of high emissions. In this paper we analyze the potential for a flex fuel gasoline-alcohol engine approach for a series hybrid powertrain. In this approach the engine would provide comparable (or possibly greater) efficiency than a diesel engine while also providing 90 around lower NOx emissions than present cleanest diesel engine vehicles. Ethanol or methanol would be employed to increase knock resistance.