Search Results

Honda diesel engine vehicles that go on the market in 2018 will be equipped with a newly developed silver (Ag)-type catalyzed diesel particulate filter (cDPF). Ag has high particulate matter (PM) oxidation performance, but conventional catalyst-carrying methods cause weak contact property between PM and Ag; therefore, the newly Ag-type cDPF was developed on the concept of enhancing the property of contact between PM and the catalyst to realize contact property enhancement at the macro, meso, and nano scales. As a result, the newly developed catalyst showed an enhancement of T90 performance by a factor of approximately 2 relative to the conventional Ag-type catalyst in fresh condition. Durability in the environment of an automobile in use was examined through hydrothermal aging, lean-rich (L/R) aging, sulfur (S) poisoning, and ash deposition. The results have confirmed that hydrothermal aging is the greatest factor in deterioration.

A new concept for trapping NOx and HC during cold start, the NOx Trap Three-Way Catalyst (N-TWC), is proposed. N-TWC adsorbs NOx at room temperature, and upon reaching activation temperature under suitable air-fuel ratio conditions, it reduces the adsorbed NOx. This allows a reduction in NOx emissions during cold start. N-TWC's reduction mechanism relies on NOx adsorption sites which are shown to be highly dispersed palladium on acid sites in the zeolite. Testing on an actual vehicle equipped with N-TWC confirmed that N-TWC is able to reduce emissions of NOx and HC during cold start, which is a challenge for conventional TWCs.

In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For diesel engines, reducing NOX emissions is a difficult technical challenge.[1],[2],[3],[4]. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows the effective reduction of NOX. However, in order to realize cleaner emission gases, precise engine control in response to the state of the exhaust aftertreatment system is essential.

The new shape ceria-based support material for a lean NOx trap catalyst (LNT) was developed and its catalytic characteristics were investigated. It has a unique shape that each fine particle of raw material is formed into hollow sphere. Samples of platinum loaded powder catalysts were obtained with either the hollow sphere ceria-based material or two kinds of the conventional shape one, and their catalytic activities were evaluated with the synthetic gas. The aged powder catalyst using the hollow sphere ceria-based material had higher CO oxidation performance at low temperature as compared to the conventional shape one with the same composition. The characterization results indicated that the hollow sphere ceria-based material had high thermal stability.

In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For lean-burn diesel engines, since it is not possible to use three-way catalytic converters, reducing NOX emissions is a difficult technical challenge. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows more efficient reduction of NOX than its conventional counterparts. However, an appropriate switching control between lean and rich mixture conditions along with compensation for catalyst deterioration was necessary.

A newly developed three-way catalyst (TWC) has excellent thermal durability with an ultra low amount of platinum group metals (PGM). The performance of the new catalyst is similar to that of a conventional TWC but with only 1/10 of the typical PGM loading. In the conventional TWC, the PGM particles are simply deposited on the surface of the support material; the particles sinter during thermal aging, resulting in significant thermal deterioration. The new developed catalyst contains small nano-sized PGM particles with a unique microstructure and support materials. With this material, the PGM particles remain at the single nano size after high temperature aging.

Just as CO2 reduction is required of four wheeled vehicles for environmental protection, similar environmental concerns drive the development of motorcycle oil technology. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Mr. Ito and his co-authors1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods:JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).

The variable intake and exhaust control valve system for the in-line four-cylinder motorcycle engine was developed for realization of high engine power in all the engine speed ranges. Both the variable intake and exhaust control valves are operated by one servomotor. For high engine speeds, the exhaust collector pipe design for merging of each exhaust gas flow at 180 degrees phase difference is used. For mid engine speeds, the design for merging of each exhaust gas flow at 360 degrees phase difference is used. Two modes are provided to the intake control, and three modes are provided to the exhaust control. Along with exhaust-gas treatment systems such as the catalyst and air-injection system, high engine performance with optimum driveability and reduced emission are realized.

When the alkali metal-supported catalyst was treated at 830°C, the NOx conversion decreased because the alkali metals in the catalyst layer gradually moved to the cordierite honeycomb layer and reacted with the cordierite elements. This phenomena decreased to be added the basic metal oxide (α) in the catalyst layer. The improved catalyst with α 2 showed higher performance than the conventional catalyst in the model gas test. Moreover, the emission values of NOx, HC, and CO were 50% or less than Japanese domestic regulation values even after 830°C×60h heat treatment in a vehicle test.

A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.

For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.

Lean-burn is an effective means of reducing CO2 emissions. To date, Homogenous Lean Charge Spark Ignition (HLSI) combustion, which lowers emissions of both CO2 and NOx, has been studied. Although HLSI realizes lower emission, it is a major challenge for lean-burn engines to meet SULEV regulations, so we have developed a new aftertreatment system for HLSI engines. It consists of three types of catalysts that have different functions, as well as special engine control methods. As the first stage in achieving SULEV emissions, this study focused on enhancing performance under lean conditions. HLSI engine exhaust gases contain high concentrations of hydrocarbons, including a large amount of paraffin, which are difficult to purify, rather than low concentrations of NOx. Therefore, the key point in low emissions is to purify not only NOx, but also high concentrations of paraffin at the same time.

Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).

Into the early-part of the next century, automotive emission standards are becoming stricter around the world. The electrically-heated catalyst (EHC) is well known as an effective technology for the reduction of cold-start hydrocarbon emissions without a significant increase in back pressure. Our extruded, alternator powered EHC (APEHC) manufactured with a unique canning method and equipped with a reliable, water proof electrode has demonstrated excellent durability and reliability, as stated in our previous SAE paper (#960340). The APEHC system discussed in this paper has achieved the Ultra-Low-Emission Vehicle (ULEV) standards, after 100,000 miles of fleet testing, without any failure. This is the final milestone in addressing the EHC as a realistic-production technology for ULEV. With the ability to meet ULEV/Stage III emission targets without a significant increase in back pressure, the EHC will be applied to an especially high performance vehicle with a large displacement engine.

The reduction of NOx in exhaust gas has been a major challenge in diesel engine development. For the NOx reduction issues, a new Lean NOx Catalyst (LNC) aftertreatment system has been developed by Honda. A feature of the LNC system is the method that is used to reduce NOx through an NH₃-Selective Catalytic Reduction (NH₃-SCR). In an LNC system NOx is adsorbed at lean conditions, then converted to NH₃ at rich conditions and subsequently reduced in the next lean phase. In recent years, as the efficiency of the diesel engine has improved, the exhaust gas temperatures have been reduced gradually. Therefore, the aftertreatment system needs to be able to purify NOx at lower temperatures. The development of a new LNC which has a high activity at low temperature has been carried out. For the improvement of the LNC three material improvements were developed. The first of these was the development of a NOx adsorbent which is matching the targeted exhaust gas temperatures.

This emission reduction technique has been researched on motorcycles equipped with a four-cylinder, liquid-cooled engine of 1100cm3 displacement in order to comply with the EURO-3 emission regulation. The EURO-3 emission regulation will be enforced in Europe beginning in year 2006. Compared to the EURO-2 regulation, reduction of cold-start HC and reduction of NOx from the extra-urban driving cycle are the main issues for EURO-3 compliance. The hydrocarbon reduction during cold-starting was achieved by the method of early catalyst activation using a combination of an Idle Air Control Valve system (IACV), ignition-retard, and atomization of fuel spray. In the extra-urban driving cycle, the fine controlled air-fuel ratio reduced. In addition, optimization of the number of three-way catalyst cells and their capacity also reduced NOx. Moreover, power loss decline caused by increased exhaust resistance due to increasing the catalyst size was avoided by optimizing the catalyst location.

Thermal effects on three-way catalysts and deterioration characteristics were studied. Aging atmosphere (oxidizing or reducing) and temperature contributed to catalyst performance deterioration. Catalysts sharply lost their activities under oxidizing conditions at an aging temperature of 900°C and above. Thermal degradation was found due mainly to the decrease in the surface area of alumina coated on the substrate and the increase in the size of cerium oxide (CeO2) crystal particle, an oxgen storage component (OSC). Also observed was a close correlation between the alumina surface area loss and the volume loss of micro pores with their radius less than 100 Å. Tests demonstrated that the catalyst thermal degradation can be reduced if the alumina micro pore volume loss and the CeO2 crystal particle size increase are restrained.

The two liter DOHC-VTEC engine developed for the Honda S2000 produces 179kW (240HP, which is 120HP per liter). It is the highest output power among all naturally aspirated two liter engines ever mass-produced. It also achieves an exhaust emission level within National LEV standards. The new engine utilizes a redesigned VTEC cylinder head, in which MIM (metal injection molding) rocker arms are used. The new cylinder block with a ladder frame structure for its lower part, a newly developed camshaft drive chain and gear system and a metal honeycomb catalyst with an air pump start-up system are also utilized.

Recently, much research has been carried out on secondary O2 feedback which performs control based on the output from a secondary O2 sensor (HEGO sensor). In this research it has been found that, regardless of catalyst aging conditions, the HEGO sensor output indicates 0.6 V when the catalyst reduction rate is maintained at the optimum level. Therefore, based on this relationship, we designed an accurate secondary O2 feedback with the aim of reducing emissions by stabilizing the HEGO sensor output to 0.6 V. In order to realize this control, it was necessary to solve the three problems of nonlinear catalyst characteristics, dead time characteristics, and changes in dynamic characteristics due to catalyst aging conditions. Therefore, these problems were solved using the modeling approach of robust control and a new robust adaptive control named Prediction and Identification Type Sliding Mode Control.

Development is proceeding on catalysts which separate the NOx in lean exhaust gas by adsorption and then reduce the adsorbed NOx in combustion exhaust gas with the stoichiometric or a slightly richer air fuel ratio, as well as exhaust conversion technology that uses these catalysts. Amidst this research it has been found that catalysts containing mixed metal oxides exhibit superior NOx adsorption performance, so the authors prepared a mixed metal oxide catalyst by adding precious metals and promoters, etc. The resulting catalyst has high heat resistance and also offers excellent SOx durability. These properties were presumed to be due to an adsorbent including the mixed metal oxide, and the relation between the physical properties and NOx conversion properties of the catalyst was investigated.