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The authors developed, for use in diesel engines, ceramic tappets cast in aluminum alloy that drastically improved wear resistance and valve train dynamics. The ceramic tappets consist of two parts: a ceramic head, which contacts the cam and push rod, and a tappet body made of aluminum alloy. Concerning the ceramic, silicon nitride was the best material of the three ceramics evaluated in the tests and the sliding surface, in contact with the cam and push rod, was left unground. As for the aluminum alloy, hyper-eutectic aluminum-silicon alloy with a controlled pro-eutectic silicon size was selected. A reliability analysis using the finite-element method (FEM) was also made on the structure of the ceramic tappet for enhanced durability and reliability. The combination of this tappet and a cam made of hardened ductile cast iron, hardened steel, or chilled cast iron, respectively exhibits excellent wear resistance.

To evaluate various Diesel Particulate Filter (DPF) efficiently, accelerated tests are one of effective methods. In this study, a simulator composed by diesel fuel burners is proposed for fundamental DPF evaluations. Firstly particle size distribution measurement, chemical composition and thermal analysis were carried out for the particulate matter (PM) generated by the simulator with several combustion conditions. The PMs generated by specific conditions showed similar characteristics to PMs of a diesel engine. Through these investigations, mechanism of PM particle growth was discussed. Secondly diversified DPFs were subjected to accelerated pressure drop and filtration efficiency tests. Features of DPFs could be clarified by the accelerated tests. In addition, the correlation between DPF pressure drop performance and PM characteristics was discussed. Thirdly regeneration performance of the simulator's PM was investigated.

The Inlet-Membrane DPF which has a small pore size membrane formed on the inlet side of the body wall has been developed as a next generation diesel particulate filter (DPF). It simultaneously realizes low pressure drop, small pressure drop hysteresis, high robustness and high filtration efficiency. The low pressure drop improves fuel economy. The small pressure drop hysteresis has the potential to extend the regeneration interval since the linear relationship between the pressure drop and accumulated soot mass improves the accuracy of the soot mass detection by means of the pressure drop values. The Inlet-Membrane DPF's high robustness also extends the regeneration interval resulting in improved fuel economy and a lower risk of oil dilution while its high filtration efficiency reduces PM emissions. The concept of the Inlet-Membrane DPF was confirmed using disc type filters in 2008 and its performances was evaluated using full block samples in 2009.

A newly developed small-sized IES (inductive energy storage) circuit with a semiconductor switch at turn-off action was successfully applied to an ignition system. This IES circuit can generate repetitive nanosecond pulse discharges. An ignition system using repetitive nanosecond pulse discharges was investigated as an alternative to conventional spark ignition systems in the previous papers. Experiments were conducted using constant volume chamber for CH₄ and C₃H₈-air mixtures. The ignition system using repetitive nanosecond pulse discharges was found to improve the inflammability of lean combustible mixtures, such as extended flammability limits, shorted ignition delay time, with increasing the number of pulses for CH₄ and C₃H₈-air mixtures under various conditions. The mechanisms for improving the inflammability were discussed and the effectiveness of IES circuit under EGR condition was also verified.

The objective of this study is to explain the physical and chemical mechanisms involved in the operation of a catalyzed diesel particulate filter. The study emphasizes on the coupling between reaction and diffusion phenomena (with emphasis on NO2 “back-diffusion”), based on modeling and experimental data obtained on the engine dynamometer. The study is facilitated by a novel multi-dimensional mathematical model able to predict both reaction and diffusion phenomena in the filter channels and through the soot layer and wall. The model is thus able to predict the species concentration gradients in the inlet/outlet channels, in the soot layer and wall, taking into account the effect of NO2 back diffusion. The model is validated versus engine dyno measurements. Two sets of measurements are employed corresponding to low-temperature “controlled” regenerations as well as high-temperature “uncontrolled” conditions.

Combustion phenomena in the regeneration of a diesel particulate filter (DPF) were clarified through a visualization experiment, using a half-cylindrical wall-flow DPF covered by a quartz glass plate. At a constant oxygen concentration (8.5% and 10% in the current study) of a working gas used for regeneration, in the cases of large particulate masses and high working gas temperatures, the particulate matter trapped on the filter surface is burned in a narrow reaction zone which can be observed as a high brightness zone moving slowly toward the downstream side. Just after the reaction zone passes, a sharp temperature peak is detected and there remains no particulate matter on the filter surface. Furthermore, the particulate matter is ignited first around the middle of the DPF, and then, the reaction zone propagates toward both the upstream and the downstream sides.

Ammonia Selective Catalytic Reduction (SCR) is adapted for a variety of applications to control nitrogen oxides (NOx) in diesel engine exhaust. The most commonly used catalyst for SCR in established markets is Cu-Zeolite (CuZ) due to excellent NOx conversion and thermal durability. However, most applications in emerging markets and certain applications in established markets utilize vanadia SCR. The operating temperature is typically maintained below 550°C to avoid vanadium sublimation due to active regeneration of the diesel particulate filter (DPF), or some OEMs may eliminate the DPF because they can achieve particulate matter (PM) standard with engine tuning. Further improvement of vanadia SCR durability and NOx conversion at low exhaust gas temperatures will be required in consideration of future emission standards.

Ammonia Selective Catalytic Reduction (SCR) is a key emission control component utilized in diesel engine applications for NOx reduction. There are several types of SCR catalyst currently in the market: Cu-Zeolite, Fe-Zeolite and Vanadia. Diesel vehicle and engine manufacturers down select their production SCR catalyst primarily based on vehicle exhaust gas temperature operation, ammonia dosing strategy, fuel quality, packaging envelope and cost. For Vanadia SCR, the operating temperature is normally controlled below 550oC to avoid vanadium sublimation. In emerging markets, the Vanadia SCR is typically installed alone or downstream of the DOC with low exhaust gas temperature exposure. Vanadia SCR is also utilized in some European applications with passive DPF soot regeneration. However, further improvement of Vanadia SCR NOx conversion at low exhaust gas temperatures will be required to meet future emission regulations (i.e.: HDD Phase 2 GHG).

Honeycomb substrates are widely used to reduce harmful emissions from gasoline engines and are exposed to numerous thermal shocks during their lifetime making thermal shock resistance one of the key factors in designing honeycomb substrates. More stringent emission regulations will require the honeycomb substrates to be lighter in weight to improve light-off performance and to have better thermal shock resistance than conventional honeycomb substrates to handle higher expected temperature gradients. Thermal shock resistance is generally evaluated on a substrate by evaluating the thermal strain caused by temperature gradients inside the substrate during durability testing [1,2]. During the test, a heated substrate is cooled at a surface face to generate temperature gradients while the temperature inside the honeycomb substrate is monitored by multiple thermocouples.

The development of diesel powered passenger cars is driven by the enhanced emission legislation. To fulfill the future emission limits there is a need for advanced aftertreatment devices. A comprehensive study was carried out focusing on the improvement of the DOC as one part of these systems, concerning high HC/CO conversion rates, low temperature light-off behaviour and high temperature aging stability, respectively. The first part of this study was published in [1]. Further evaluations using a high temperature DPF aging were carried out for the introduced systems. Again the substrate geometry and the catalytic coating were varied. The results from engine as well as vehicle tests show advantages in a highly systematic context by changing either geometrical or chemical factors. These results enable further improvement for the design of the exhaust system to pass the demanding emission legislation for high performance diesel powered passenger cars.

This paper describes the design and operation of the multi-layered zirconia heated exhaust gas oxygen sensor having small-sized and sheet-shaped sensing element. This sensor uses an electrode modified with a rhodium catalyst and heater by means of the thick-film technique. This modification of an electrode's composition and construction affects the reaction on unburned components in exhaust gas as well as the sensor performance. By the addition of a rhodium catalyst, the zirconia exhaust gas oxygen sensor shows acute sensitivity and faster response properties in the transient state on emission component(NOx) generation, in such a way that these sensors show better emission control properties for reduction of NOx emission in current emission control systems. The addition of a rhodium catalyst reduces the green effect of sensor properties, and no significant change of emission control properties is observed after 50,000 equivalent miles using the engine dynamometer durability test.

Silicon nitride (SN) valves promise significant reductions in weight and inertial force for valve trains because they are only two-fifths the weight of equivalent metal versions. This study evaluates how the higher engine speeds and lower valve spring loads that they permit contribute to higher engine output and greater fuel economy. It also evaluates their reliability in the presence of valve bounce and other adverse conditions that ceramic valves normally fail to withstand. For this purpose, material studies, actual engine tests and finite element method (FEM) analysis were conducted. Long-term durability tests revealed that SN valves are capable of providing the necessary resistance to breakage.

For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.

The present paper describes the results of a joint development program focussing on a system approach to meet the EURO IV emission standards for an upper class passenger car equipped with a newly developed high displacement gasoline engine. Based on the well known catalyst systems of recent V6- and V8-engines for the EURO III emission standards with a combination of close coupled catalysts and underfloor catalysts, the specific boundary conditions of an engine with an even larger engine displacement had to be considered. These boundary conditions consist of the space requirements in the engine compartment, the power/torque requirements and the cost requirements for the complete aftertreatment system. Theoretical studies and computer modeling showed essential improvements in catalyst performance by introducing thin wall substrates with low thermal inertia as well as high cell densities with increased geometric surface area.

Selective catalyst reduction (SCR) using cordierite honeycomb substrate is generally used as a DeNOx catalyst for diesel engines exhaust in both on-road and commercial off-highway vehicles to meet today’s worldwide emission regulations. Worldwide NOx emission regulations will become stricter, as represented by CARB2027 and EuroVII. Technologies which can achieve further lower NOx emissions are required. Recently, several technologies, like increased SCR catalyst loading amount on honeycomb substrates, and additional SCR catalyst volume in positions closer to the engine are being considered to achieve ultra-low NOx emissions. However, undesirable pressure drop increase and enlarging after treatment systems will be caused by adopting these technologies. Therefore, optimization of the material and honeycomb cell structure for SCR is inevitable to achieve ultra-low NOx emissions, while minimizing any system drawbacks.

Today the Ammonia Selective Catalytic Reduction (SCR) system with good NOx conversion is the emission technology of choice for diesel engines globally. High NOx conversion SCR systems combined with optimized engine calibration not only address the stringent NOx emission limits which have been introduced or are being considered for later this decade, but also reduce CO2 emissions required by government regulations and the increase in fuel economy required by end-users. Reducing the packaging envelope of today's SCR systems, while retaining or improving NOx conversion and pressure drop, is a key customer demand. High SCR loadings ensure high NOx conversion at very low temperatures. To meet this performance requirement, a High Porosity Substrate which minimizes the pressure drop impact, was introduced in SAE Paper 2012-01-1079 [1], [2], [3].

Fleet average SULEV30 emissions over FTP-75 must be met under full implementation of US Tier 3/LEV III emission regulation in 2025. The majority of SULEV30 certified 2021 model year vehicles are equipped with ≤ 2L displacement engines and some models adopt hybrid powertrain systems. Pickup trucks account for > 20% of passenger vehicles in the US. They could represent a quick route to meet fleet average SULEV30 targets. The newest pickup truck models are typically ULEV50 or ULEV70 certified. To reach SULEV30 or lower emission category, total tailpipe emissions must be reduced by more than 40%. Improvement of cold start emission is essential because over 70% of regulated emission is emitted during the first 60 seconds of a drive cycle with current engine and aftertreatment technology. High porosity (HP) ceramic substrate is designed to reduce thermal mass and time required to reach three-way catalyst (TWC) active temperature compared to conventional ceramic substrates.

The LEV II and SULEV/PZEV emission standards legislated by the US EPA and the Californian ARB will require continuous reduction in the vehicles' emission over the next several years. Similar requirements are under discussion in the European Union (EU) in the EU Stage V program. These future emission standards will require a more efficient after treatment device that exhibits high activity and excellent durabilty over an extended lifetime. The present study summarizes the findings of a joint development program targeting such demanding future emission challenges, which can only be met by a close and intensive co-operation of the individual expert teams. The use of active systems, e.g. HC-adsorber or electrically heated light-off catalysts, was not considered in this study. The following parameters were investigated in detail: The development of a high-tech three-way catalyst technology is described being tailored for applications on ultra thin wall ceramic substrates (UTWS).

Thermal shock performance parameters to assure Ultra Thin Wall (UTW) substrate durability for close-coupled (CC) converter operating conditions have been defined through testing and FEM modeling. Propane burner tests simulating the engine exhaust conditions were performed and coordinated with FEM stress analysis. For the stress analysis, a newly developed Macro-Micro Thermal Stress Analysis method was employed. Validation of the Macro-Micro Thermal Stress Analysis method was made through comparing FEM analysis results with the electric furnace and the burner tests results. A thermal fatigue life prediction method taking into account variation in material strength, fatigue degradation and effective volume was developed. In the verification tests, crack generation stresses were predicted within a 20 % margin of error.

Development of the ultra thin wall ceramic catalytic substrate is necessary to meet increasingly strict emissions regulations. The cell walls need to be thinner in order to improve the warm-up characteristics related to the reduction of emissions and to lower the back pressure. However, the thinner the wall thickness, the smaller the mechanical strength of the substrate becomes. For substrates with 2.5mil wall thickness, we densified a conventional material with 35% porosity to less than 30%[1] to improve erosion resistance. Furthermore, for substrates less than 2.5mil wall thickness, a denser material and strengthened end surface is necessary to protect against erosion. In addition to that, we think that a reinforced periphery is necessary for isostatic strength. In this paper, we evaluated the effect of a densified material, strengthened end surface, and a reinforced periphery.