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Journal Article

Characterization of Hydrocarbon Emissions from Gasoline Direct-Injection Compression Ignition Engine Operating on a Higher Reactivity Gasoline Fuel

2017-03-28
2017-01-0747
Low temperature combustion engine technologies are being investigated for high efficiency and low emissions. However, such engine technologies often produce higher engine-out hydrocarbon (HC) and carbon monoxide (CO) emissions, and their operating range is limited by the fuel properties. In this study, two different fuels, a US market gasoline containing 10% ethanol (RON 92 E10) and a higher reactivity gasoline (RON 80 E0), were compared on Delphi’s second generation Gasoline Direct-Injection Compression Ignition (Gen 2.0 GDCI) multi-cylinder engine. The engine was evaluated at three operating points ranging from a light load condition (800 rpm/2 bar IMEPg) to medium load conditions (1500 rpm/6 bar and 2000 rpm/10 bar IMEPg). The engine was equipped with two oxidation catalysts, between which was located the exhaust gas recirculation (EGR) inlet. Samples were taken at engine-out, between the catalysts, and at tailpipe locations.
Technical Paper

Physical Properties of Bio-Diesel and Implications for Use of Bio-Diesel in Diesel Engines

2007-10-29
2007-01-4030
In this study we identify components of a typical biodiesel fuel and estimate both their individual and mixed thermo-physical and transport properties. We then use the estimated mixture properties in computational simulations to gauge the extent to which combustion is modified when biodiesel is substituted for conventional diesel fuel. Our simulation studies included both conventional diesel combustion (DI) and premixed charge compression ignition (PCCI). Preliminary results indicate that biodiesel ignition is significantly delayed due to slower liquid evaporation, with the effects being more pronounced for DI than PCCI. The lower vapor pressure and higher liquid heat capacity of biodiesel are two key contributors to this slower rate of evaporation. Other physical properties are more similar between the two fuels, and their impacts are not clearly evident in the present study.
Technical Paper

Emission Performance of Low Cetane Naphtha as Drop-In Fuel on a Multi-Cylinder Heavy-Duty Diesel Engine and Aftertreatment System

2017-03-28
2017-01-1000
Greenhouse gas regulations and global economic growth are expected to drive a future demand shift towards diesel fuel in the transportation sector. This may create a market opportunity for cost-effective fuels in the light distillate range if they can be burned as efficiently and cleanly as diesel fuel. In this study, the emission performance of a low cetane number, low research octane number naphtha (CN 34, RON 56) was examined on a production 6-cylinder heavy-duty on-highway truck engine and aftertreatment system. Using only production hardware, both the engine-out and tailpipe emissions were examined during the heavy-duty emission testing cycles using naphtha and ultra-low-sulfur diesel (ULSD) fuels. Without any modifications to the hardware and software, the tailpipe emissions were comparable when using either naphtha or ULSD on the heavy duty test cycles.
Technical Paper

1D Model of a Copper Exchanged Small Pore Zeolite Catalyst Based on Transient SCR Protocol

2013-04-08
2013-01-1578
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.
Technical Paper

On the Use of Thermodynamic Modeling for Predicting Cycle-to-Cycle Variations in a SI Engine under Lean Conditions

2005-10-24
2005-01-3802
We propose a procedure by which a two-zone thermodynamic model combined with a flame propagation sub-model can used for predicting the cycle-to-cycle variations of combustion in a spark ignition (SI) engine operating at very lean and high exhaust gas residual conditions. Under such conditions, the variations have been shown to consist of both deterministic and stochastic components. The deterministic component is inherent to the non-linear nature of the combustion efficiency variation with equivalence ratio (or dilution level) while the stochastic component results primarily from noise associated with the parameters (that are inevitable in a mechanical system) that affect combustion. Since the overall dynamics of the instabilities are driven by the low order deterministic component, if a model can be made to capture this component, the stochastic component is easily modeled by adding noise to the parameters.
Technical Paper

Characterization of Particulate Matter Emissions from Heavy-Duty Partially Premixed Compression Ignition with Gasoline-Range Fuels

2019-04-02
2019-01-1185
In this study, the compression ratio of a commercial 15L heavy-duty diesel engine was lowered and a split injection strategy was developed to promote partially premixed compression ignition (PPCI) combustion. Various low reactivity gasoline-range fuels were compared with ultra-low-sulfur diesel fuel (ULSD) for steady-state engine performance and emissions. Specially, particulate matter (PM) emissions were examined for their mass, size and number concentrations, and further characterized by organic/elemental carbon analysis, chemical speciation and thermogravimetric analysis. As more fuel-efficient PPCI combustion was promoted, a slight reduction in fuel consumption was observed for all gasoline-range fuels, which also had higher heating values than ULSD. Since mixing-controlled combustion dominated the latter part of the combustion process, hydrocarbon (HC) and carbon monoxide (CO) emissions were only slightly increased with the gasoline-range fuels.
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