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In diesel engines the optimization of engine-out emissions, combustion noise and fuel consumption requires the experimental investigation of the effects of different injection strategies as well as of a large number of engine operating variables, such as scheduling of pilot and after pulses, rail pressure, EGR rate and swirl level. Due to the high number of testing conditions involved full factorial approaches are not viable, whereas Design of Experiment techniques have demonstrated to be a valid methodology. However, the results obtained with such techniques require a subsequent critical analysis, so as to investigate the cause and effect relationships between the set of engine operating variables and the combustion process characteristics that affect pollutant formation, noise of combustion and engine efficiency.

The aim of this work is to analyze particle number and size distribution from a small displacement Euro 5 common rail automotive diesel engine, equipped with a close coupled aftertreatment system, featuring a DOC and a DPF integrated in a single canning. In particular the effects of different combustion processes on PM characteristics were investigated, by comparing measurements made both under normal operating condition and under DPF regeneration mode. Exhaust gas was sampled at engine outlet, at DOC outlet and at DPF outlet, in order to fully characterize PM emissions through the whole exhaust line. After a two stage dilution system, sampled gas was analyzed by means of a TSI 3080 SMPS, in the range from 6 to 240 nm. Particle number and size distribution were evaluated at part load operating conditions, representative of urban driving.

The use of Ducted Fuel Injection (DFI) for attenuating soot formation throughout mixing-controlled diesel combustion has been demonstrated impressively effective both experimentally and numerically. However, the last research studies have highlighted the need for tailored engine calibration and duct geometry optimization for the full exploitation of the technology potential. Nevertheless, the research gap on the response of DFI combustion to the main engine operating parameters has still to be fully covered. Previous research analysis has been focused on numerical soot-targeted duct geometry optimization in constant-volume vessel conditions. Starting from the optimized duct design, the herein study aims to analyze the influence of several engine operating parameters (i.e. rail pressure, air density, oxygen concentration) on DFI combustion, having free spray results as a reference.

A real-time mean-value engine model for the simulation of the HRR (heat release rate), in-cylinder pressure, brake torque and pollutant emissions, including NOx and soot, has been developed, calibrated and assessed at both steady-state and transient conditions for a Euro 6 1.6L GM diesel engine. The chemical energy release has been simulated using an improved version of a previously developed model that is based on the accumulated fuel mass approach. The in-cylinder pressure has been evaluated on the basis of the inversion of a single-zone model, using the net energy release as input. The latter quantity was derived starting from the simulated chemical energy release, and evaluating the heat transfer of the charge with the walls. NOx and soot emissions were simulated on the basis of semi-empirical correlations that take into account the in-cylinder thermodynamic properties, the chemical energy release and the main engine parameters.

The present paper illustrates an investigation about the potentialities of injection rate shaping coupled with an after injection. A pilot shot can either be absent or present before the rate-shaped boot injection. The experimental tests have been performed on a partial PCCI Euro 5 diesel engine endowed with direct-acting piezoelectric injectors. Starting from optimized triple pilot-main-after injection strategies, boot injection was implemented by maintaining the direct-acting piezo injector needle open at part lift. The results of two steady state working conditions have been presented in terms of engine-out emissions, combustion noise and brake specific fuel consumption. In addition, in-cylinder analyses of the pressure, heat-release rate, temperature and emissions have been evaluated. Considering the in-cylinder pressure traces and the heat release rate curves, the injection rate shaping proved to influence combustion in the absence of a pilot injection to a great extent.

The present work describes an existing transient, non-isothermal 1D+1D particulate filter model to capture the impact of different types of particulate matter (PM) on filtration and regeneration. PM classes of arbitrary characteristics (size, composition etc.) are transported and filtered following standard mechanisms. PM deposit populations of arbitrary composition and contact states are used to describe regeneration on a micro-kinetical level. The transport class and deposit population are linked by introducing a splitting deposit matrix. Filtration and regeneration modes are compared to experimental data from literature and a brief numerical assessment on the filtration model is performed. The filter model as part of an exhaust line is used in a concept study on different coating variants. The same exhaust line model is connected to an engine thermodynamic and vehicle model. This system model is run through a random drive cycle in office simulation.

La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts towards the simultaneous oxidation of soot and CO was evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367 °C and the half conversion of CO reached at 141 °C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.

The fuel injection plays a crucial role in determining the mixture formation process in Gasoline Direct Injection (GDI) engines. Pollutant emissions, and soot emissions in particular, as well as phenomena affecting engine reliability, such as oil dilution and injector coking, are deeply influenced by the injection system features, such as injector geometric characteristics (such as injector type, injector position and targeting within the combustion chamber) and operating characteristics (such as injection pressure, injection phasing, etc.). In this paper, a new CFD methodology is presented, allowing a preliminary assessment of the mixture formation quality in terms of expected soot emissions, oil dilution and injector coking risks for different injection systems (such as for instance multihole or swirl injectors) and different injection strategies, from the early stages of a new engine design.

The Particle Measurement Programme (PMP) developed an exhaust particle number measurement protocol that has been adopted by current light duty vehicle emission regulations in Europe. This includes thermal treatment of the exhaust aerosol to isolate solid particles only and a number counting device with a lower cutpoint of 23 nm to avoid measurement of smaller particles that may affect the repeatability of the measurement. In this paper, we examine a potential alternative to the PMP system, where the thermal treatment is replaced by a catalytic stripper (CS). This offers oxidation and not just evaporation of the volatile components. Alternative sampling systems, either fulfilling the PMP recommendations or utilizing a CS, have been explored in terms of their volatile particle removal efficiency. Tests have been conducted on diesel exhaust, diesel equipped with DPF and gasoline direct injection emissions.

This paper describes the findings of a design, simulation and test study into how to reduce particulate number (Pn) emissions in order to meet EU6c legislative limits. The objective of the study was to evaluate the Pn potential of a modern 6-cylinder engine with respect to hardware and calibration when fitted to a full size SUV. Having understood this capability, to redesign the combustion system and optimise the calibration in order to meet an engineering target value of 3×1011 Pn #/km using the NEDC drive cycle. The design and simulation tasks were conducted by JLR with support from AVL. The calibration and all of the vehicle testing was conducted by AVL, in Graz. Extensive design and CFD work was conducted to refine the inlet port, piston crown and injector spray pattern in order to reduce surface wetting and improve air to fuel mixing homogeneity. The design and CFD steps are detailed along with the results compared to target.

A set of manganese oxide catalysts was synthesized and doped with Cu and/or Fe by means of the citric acid sol-gel preparation method. The samples were studied by means of several characterization techniques: field-emission scanning electron microscopy (FESEM), X-ray powder diffraction (XRD), N2-physisorption at -196 °C, H2 and soot temperature-programmed reduction (H2-TPR, soot-TPR) and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the prepared catalysts was investigated in the oxidation of a probe VOC molecule (propylene) and carbon soot singularly and simultaneously. The catalytic performances were studied as well assuring a content of 5 vol.% of water in the gaseous reactive mix. The investigations evidenced that the best soot catalytic oxidation rates occurred over the Mn2O3 sample, while the copper-doped manganese oxide (i.e. the MnCu15) showed the best performance in the decomposition of propylene.

The European Emissions Stage 5b standard for diesel passenger cars regulates particulate matter to 0.0045 g/km and non-volatile part/km greater than 23 nm size to 6.0x10₁₁ as determined by the PMP procedure that uses a heated evaporation tube to remove semi-volatile material. Measurement artifacts associated with the evaporation tube technique prevents reliable extension of the method to a lower size range. Catalytic stripper (CS) technology removes possible sources of these artifacts by effectively removing all hydrocarbons and sulfuric acid in the gas phase in order to avoid any chemical reactions or re-nucleation that may cause measurement complications. The performance of a miniature CS was evaluated and experimental results showed solid particle penetration was 50% at 10.5 nm. The sulfate storage capacity integrated into the CS enabled it to chemically remove sulfuric acid vapor rather than rely on dilution to prevent nucleation.

Particulate emission reduction has long been a challenge for diesel engines as the diesel diffusion combustion process can generate high levels of soot which is one of the main constituents of particulate matter. Gasoline engines use a pre-mixed combustion process which produces negligible levels of soot, so particulate emissions have not been an issue for gasoline engines, particularly with modern port fuel injected (PFI) engines which provide excellent mixture quality. Future European and US emissions standards will include more stringent particulate limits for gasoline engines to protect against increases in airborne particulate levels due to the more widespread use of gasoline direct injection (GDI). While GDI engines are typically more efficient than PFI engines, they emit higher particulate levels, but still meet the current particulate standards.

Nano-structured perovskite-type oxides catalysts La1-xAxFe1-yByO3 (where A = Na, K, Rb and B = Cu), prepared by the Solution Combustion Synthesis (SCS) method and characterized by BET, XRD, FESEM, AAS and catalytic activity tests in microreactors and engine bench, proved to be effective in the simultaneous removal of soot and NO, the two prevalent pollutants in diesel exhaust gases in the temperature range 350-450°C. The best compromise between soot and nitrogen oxide abatement was shown by La-K-Cu-FeO3 catalyst which displayed the highest catalytic activity towards carbon combustion and the highest NO conversion activity.

Automotive cabin filters of the “combo” type are intended to remove both aerosols and gaseous contaminants from air entering the climate control system. We analyze the performance of two filters of this type, using published values for the concentration of gaseous contaminants found in highway and street traffic. Using existing expressions for the performance of activated carbons, including the effects of contaminant concentration, flow rate and carbon bed depth, we calculate retentivity and breakthrough time for benzene and carbon tetrachloride at street-level concentrations. The calculated factors are compared to published test data on similar filters.

Future legislations claim further reduction of all restricted emissions as well as the limitation of soot emissions in diesel engines. Special alternative diesel fuels that do not contain aromatic compounds, therefore, promise great potential for further reduction of HC, CO and particulate emissions. During a research project carried out at the Institute for Powertrains and Automotive Technology at the Vienna University of Technology, the potential of alternative diesel fuels was investigated using a state-of-the-art diesel engine with common rail direct injection. The testing took part using an engine test rig as well as on the chassis dynamometer test bench to demonstrate the emission levels in real life conditions. As real biofuel, pure HVO (Hydrogenated Vegetable Oil) was investigated and additionally in different blends with fossil diesel fuel.

The DEXA Cluster consisted of three closely interlinked projects. In 2003 the DEXA Cluster concluded by demonstrating the successful development of critical technologies for Diesel exhaust particulate after-treatment, without adverse effects on NOx emissions and maintaining the fuel economy advantages of the Diesel engine well beyond the EURO IV (2000) emission standards horizon. In the present paper the most important results of the DEXA Cluster projects in the demonstration of advanced particulate control technologies, the development of a simulation toolkit for the design of diesel exhaust after-treatment systems and the development of novel particulate characterization methodologies, are presented. The motivation for the DEXA Cluster research was to increase the market competitiveness of diesel engine powertrains for passenger cars worldwide, and to accelerate the adoption of particulate control technology.

The influence of pilot injection timing and quantity on soot, NOx, combustion noise and bsfc has been analyzed on a passenger car DI Diesel engine prototype equipped with a common rail fuel injection system. The investigated engine operating points were 1500/5, 2000/2, 2500/8 rpm/bar, which are quite typical of EC driving cycles. For each of these operating conditions, the pilot injection quantity was varied by up to 15% of the total injected quantity and the pilot injection timing was varied between 32° and 1° crank angle degrees. The principal combustion characteristics were determined on the basis of the heat release, and a thorough statistical analysis was performed to infer the correlation between the combustion parameters and soot and NOx emissions.

Experimental work was carried out on a small displacement Euro 5 automotive diesel engine alternatively fuelled with ultra low sulphur diesel (ULSD) and with two blends (30% vol.) of ULSD and of two different fatty acid methyl esters (FAME) obtained from both rapeseed methyl ester (RME) and jatropha methyl ester (JME) in order to evaluate the effects of different fuel compositions on particle number (PN) emissions. Particulate matter (PM) emissions for each fuel were characterized in terms of number and mass size distributions by means of two stage dilutions system coupled with a scanning mobility particle sizer (SMPS). Measurements were performed at three different sampling points along the exhaust system: at engine-out, downstream of the diesel oxidation catalyst (DOC) and downstream of the diesel particulate filter (DPF). Thus, it was possible to evaluate both the effects of combustion and after-treatment efficiencies on each of the tested fuels.

This study presents a methodology to predict particle number (PN) generation on a naturally aspirated 4-cylinder gasoline engine with port fuel injection (PFI) from wall wetting, employing numerical CFD simulation and fuel film analysis. Various engine parameters concerning spray pattern, injection timing, intake valve timing, as well as engine load/speed were varied and their impact on wall film and PN was evaluated. The engine, which was driven at wide open throttle (WOT), was equipped with soot particle sampling technology and optical access to the combustion chamber of cylinder 1 in order to visualise non-premixed combustion. High-speed imaging revealed a notable presence of diffusion flames, which were typically initiated between the valve seats and cylinder head. Their size was found to match qualitatively with particulate number measurements. A validated CFD model was employed to simulate spray propagation, film transport and droplet impingement.