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The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Multiple-injection strategies are widely used in DI diesel engines. However, the interaction of the injection pulses is not yet fully understood. In this work, a split injection into a combustion vessel is studied by multiple optical imaging diagnostics. The vessel provides quiescent high-temperature, high-pressure ambient conditions. A common-rail injector which is equipped with a three-hole nozzle is used. The spray is visualized by Mie scattering. First and second stage of ignition are probed by formaldehyde laser-induced fluorescence (LIF) and OH* chemiluminescence imaging, respectively. In addition formation of soot is characterized by both laser-induced incandescence (LII) and natural luminosity imaging, showing that low-sooting conditions are established. These qualitative diagnostics yield ensemble-averaged, two-dimensional, time-resolved distributions of the corresponding quantities.

The most challenging part of the engine combustion development is the reduction of pollutants (e.g. CO, THC, NOx, soot, etc.) and CO2 emissions. In order to achieve this goal, new combustion techniques are required, which enable a clean and efficient combustion. For compression ignition engines, combustion rate shaping, which manipulates the injected fuel mass to control the in-cylinder pressure trace and the combustion rate itself, turned out to be a promising opportunity. One possibility to enable this technology is the usage of specially developed rate shaping injectors, which can control the injection rate continuously. A feasible solution with series injectors is the usage of multiple injections to control the injection rate and, therefore, the combustion rate. For the control of the combustion profile, a detailed injector model is required for predicting the amount of injected fuel. Simplified 0D models can easily predict single injection rates with low deviation.

With Post Euro 6 emission standards in discussion, stricter particulate number (PN) targets as well as a decreased PN cut-off size from 23 to 10 nm are expected. Sub-23 nm particulates are considered particularly harmful to human health, but are not yet taken into account in the current vehicle certification process. Not considering sub-23 nm particulates during the development process could lead to significant additional efforts for Original Equipment Manufacturers (OEM) to comply with future Post Euro 6 PN emission limits. It is therefore essential to increase knowledge about the formation and filtration of particulates below 23 nm. In the present study, a holistic Gasoline Particulate Filter (GPF) characterization has been carried out on an engine test bench under varying boundary conditions and on a burner bench with a novel ash loading methodology.

A new approach is presented to modelling wall heat transfer in the exhaust port and manifold within 1D gas exchange simulation to ensure a precise calculation of thermal exhaust enthalpy. One of the principal characteristics of this approach is the partition of the exhaust process in a blow-down and a push-out phase. In addition to the split in two phases, the exhaust system is divided into several sections to consider changes in heat transfer characteristics downstream the exhaust valves. Principally, the convective heat transfer is described by the characteristic numbers of Nusselt, Reynolds and Prandtl. However, the phase individual correlation coefficients are derived from 3D CFD investigations of the flow in the exhaust system combined with Low-Re turbulence modelling. Furthermore, heat losses on the valve and the seat ring surfaces are considered by an empirical model approach.

The influence of two oxygenated tailor-made fuels on soot formation and oxidation in an optical single cylinder research diesel engine has been studied. For the investigation a planar laser-induced incandescence (PLII) measurement technique was applied to the engine in order to detect and evaluate the planar soot distribution for the two bio fuels within a laser light sheet. Furthermore the OH* chemiluminescence and broad band soot luminosity was visualized by high speed imaging to compare the ignition and combustion behavior of tested fuels: Two C8 oxygenates, di-n-butylether (DNBE) and 1-octanol. Both fuels have the same molecular formula but differ in their molecular structure. DNBE ignites fast and burns mostly diffusive while 1-octanol has a low cetane number and therefore it has a longer ignition delay but a more homogeneous mixture at time of ignition. The two bio fuels were finally compared to conventional diesel fuel.

Exhaust aftertreatment systems must function sufficiently over the full useful life of a vehicle. In Europe this is currently defined as 160.000 km. With the introduction of Euro 7 it is expected that the required mileage will be extended to 240.000 km. This will then be consistent with the US legislation. In order to quantify the emission impact of exhaust system degradation, an Euro 7 exhaust aftertreatment system is aged by different accelerated approaches: application of the Standard Bench Cycle, the ZDAKW cycle, a novel ash loading method and borderline aging. The results depict the impact of oil ash on the oxygen storage capacity. For tailpipe emissions, the maximum peak temperatures are the dominant aging factor. The cold start performance is effected by both, thermal degradation and ash accumulation. An evaluation of this emission increase requires appropriate benchmarks.

Subject of this work is a simulation model for PCCI combustion that can be used in closed-loop control development. A detailed multi-zone chemistry model for the high-pressure part of the engine cycle is extended by a mean value model accounting for the gas exchange losses. The resulting model is capable of describing PCCI combustion with stationary excactness. It is at the same time very economic with respect to computational costs. The model is further extended by identified system dynamics influencing the stationary inputs. For this, a Wiener model is set up that uses the stationary model as a nonlinear system representation. In this way, a dynamic nonlinear model for the representation of the controlled plant Diesel engine is created.

Within a public founded project test cell investigations were undertaken to identify parameters which predominantly influence the development of critical deposits in injection nozzles. A medium-duty diesel engine was operated in two different coking cycles with a zinc-free lubricant. One of the cycles is dominated by rated power, while the second includes a wide area of the operation range. During the experiments the temperatures at the nozzle tip, the geometries of the nozzle orifice and fuel properties were varied. For a detailed analysis of the deposits methods of electron microscopy were deployed. In the course of the project optical access to all areas in the nozzle was achieved. The experiments were evaluated by means of the monitoring of power output and fuel flow at rated power. The usage of a SEM (scanning electron microscope) and a TEM (transmission electron microscope) revealed images of the deposits with a magnification of up to 160 000.

Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” (TMFB) at the RWTH Aachen University, two novel biogenic fuels, namely 1-octanol and its isomer dibutyl ether (DBE), were identified and extensively analyzed in respect of their suitability for combustion in a Diesel engine. Both biofuels feature very different properties, especially regarding their ignitability. In previous works of the research cluster, promising synthesis routes with excellent yields for both fuels were found, using lignocellulosic biomass as source material. Both fuels were investigated as pure components in optical and thermodynamic single cylinder engines (SCE). For 1-octanol at lower part load, almost no soot emission could be measured, while with DBE the soot emissions were only about a quarter of that with conventional Diesel fuel. At high part load (2400 min-1, 14.8 bar IMEP), the soot reduction of 1-octanol was more than 50% and for DBE more than 80 % respectively.

In order to thoroughly investigate and improve the path from biofuel production to combustion, the Cluster of Excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Since then, a variety of fuel candidates have been investigated. In particular, 2-methyl tetrahydrofurane (2-MTHF) has shown excellent performance w.r.t. the particulate (PM) / NOx trade-off [1]. Unfortunately, the long ignition delay results in increased HC-, CO- and noise emissions. To overcome this problem, the addition of di-n-butylether (DNBE, CN ∼ 100) to 2-MTHF was analyzed. By blending these two in different volumetric shares, the effects of the different mixture formation and combustion characteristics, especially on the HC-, CO- and noise emissions, have been carefully analyzed. In addition, the overall emission performance has been compared to EN590 diesel.

The influence of different fuels and injection pressures on the flame lift-off length (LOL), as well as the combustion structure under quiescent conditions in a heated high-pressure vessel were experimentally investigated using OH chemiluminescence measurements. This data was used to validate the newly developed G-equation coupled with MRIF (G-MRIF) model, which was designed to describe the lifted Diesel combustion process. The achieved results are very promising and could be used as a tool to apply this combustion mode into Diesel engines. Furthermore these measurements were used to validate the approach of a new combustion model, which was developed using former OH chemiluminescence measurements by the authors. Based on this approach the LOL is mainly determined by auto-ignition and therefore highly dependent on the cetane number. This model is presented in more detail within this work.

In Common-Rail DI Diesel Engines, multiple injection strategies are considered as one of the methodologies to achieve optimum performance and emission reduction. However, multiple injections open a whole new horizon of parameters which affect the combustion process. These parameters include the number of injection events, the duration between the starts of each injection event, the splitting of the total fuel mass on the different injection events, etc. In the present work, the influence of the number of injection events and the influence of the duration between the starts of each injection event on emission levels are investigated. Combustion and pollutant formation were experimentally investigated in a Common-Rail DI Diesel engine. The engine was operated at conventional part-load conditions with 2000 rpm, no external EGR, and an injected fuel mass of 15 mg/cycle.

In Common-Rail DI Diesel Engines, a low combustion temperature process is considered as one of the most important possibilities to achieve very small emissions and optimum performance. To reduce NOx and Soot strongly, it is necessary to achieve a homogenization of the mixture in order to avoid the higher local temperatures which are responsible for the NOx formation [1]. Through the homogenization it is also possible to obtain a stoichiometric air-fuel ratio in order to significantly reduce the Soot emissions. One way to achieve this homogeneous condition is to start injection very early together with the use of higher EGR rates. The direct effect of these conditions cause a longer ignition delay (this is the time between start of the injection and auto-ignition during physical and chemical sub processes such as fuel atomization, evaporation, fuel air mixing and chemical pre-reactions take place) so that the mixture formation has more time to achieve a homogeneous state.

So far, the effect of injection rate shaping on the diesel combustion in small-bore DI diesel engines has not been extensively investigated, especially at high part load conditions with high EGR rates. The benefit of injection rate shaping is already verified for heavy duty engines at high load conditions with and without EGR. For this investigation, single cylinder engine investigations were conducted at the VKA / RWTH Aachen University. In order to meet the future NOx legislation limits like US-Tier2Bin5 it is crucial to reduce NOx especially at the high load points of the certification cycles, as FTP75 or US06. For the single cylinder investigations two part load points were chosen, which have relevance for the mentioned certification cycles. The experimental work focuses on different rate shapes as rectangular (Common-Rail type), ramp and boot shape at high EGR rates.

One of the basic topics in the design of new injection systems for DI Diesel engines is to decrease the soot emissions. A promising approach to minimize soot production are nozzles with clustered holes. A basic idea of the Cluster Configuration (CC) nozzles is to prevent a fuel rich area in the center of the flame where most of the soot is produced, and to minimize the overall soot formation in this way. For this purpose each hole of a standard nozzle is replaced by two smaller holes. The diameter of the smaller holes is chosen so that the flow rate of all nozzles should be equal. The basic strategy of the cluster nozzles is to provide a better primary break up and therefore a better mixture formation caused by the smaller nozzle holes, but a comparable penetration length of the vapor phase due to merging of the sprays. Three possible arrangements of the clustered holes are investigated in this study. Both the cluster angle and the orientation to the injector axis are varied.

Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.

Increasing concern for the environment and the impending scarcity of fossil fuels requires continued development in hydrocarbon combustion science. For compression-ignition engines, adding oxygenated compounds to the fuel can reduce noise, soot formation, and unburned hydrocarbons while simultaneously increasing thermal efficiency. In order to reliably model and design compression-ignition engines to use new fuel blends, accurate spray characteristic data is required. In this study, the spray characteristics of various blends of the oxygenated compound di-n-butyl ether (DNBE) with standard EN590 Diesel fuel are presented, including spray cone angle and spray penetration length for both liquid and gas phases. The experiments were conducted in a spray chamber at ambient conditions of 50 bar and 800 K, simulating TDC conditions in a Diesel engine. Injection pressures were varied from 700-1600 bar.

A reduced kinetic reaction mechanism for the autoignition of dimethyl ether is presented in this paper. Dimethyl ether has proven to be one of the most attractive alternatives to traditional fossil fuels for compression ignition engines. It can either be produced from biomass or from fossil oil. For dimethyl ether, Fischer et al. (Int. J.Chem. Kinet. 32 ( 12 ) (2000) 713-740) proposed a detailed reaction mechanism consisting of 79 species and 351 elementary reactions. In the present work, this detailed mechanism is systematically reduced to 31 species and 49 reactions. The reduced mechanism is discussed in detail with special emphasis on the high temperature thermal decomposition of dimethyl ether and on the fuel specific depleting reactions, which produce the methoxymethyl radical. In addition, a reaction pathway analysis for low temperature combustion is applied, where hydroperoxy-methylformate is found to be the dominating parameter for the low temperature regime.

In order to comply with demanding Greenhous Gas (GHG) standards, future automotive engines employ advanced engine technologies including waste heat recovery (WHR) systems. A waste heat recovery system converts part of engine wasted exergies to useful work which can be fed back to the engine. Utilizing this additional output power leads to lower specific fuel consumption and CO2 emission when the total output power equals the original engine output power. Engine calibration strategies for reductions in specific fuel consumption typically results in a natural increase of NOx emissions. The utilization of waste heat recovery systems provides a pathway which gives both reduction in emissions and reduction in specific fuel consumption. According to DOE (Department of Energy), US heavy-duty truck engines’ technology need to be upgraded towards higher brake thermal efficiencies (BTE). DOE target is BTE>55% for Class-8 heavy-duty vehicles in the United States.