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Hydrogen has been largely proposed as a possible alternative fuel for internal combustion engines. Its wide flammability range allows higher engine efficiency with leaner operation than conventional fuels, for both reduced toxic emissions and no CO2 gases. Independently, Homogenous Charge Compression Ignition (HCCI) also allows higher thermal efficiency and lower fuel consumption with reduced NOX emissions when compared to Spark-Ignition (SI) engine operation. For HCCI combustion, a mixture of air and fuel is supplied to the cylinder and autoignition occurs from compression; engine is operated throttle-less and load is controlled by the quality of the mixture, avoiding the large fluid-dynamic losses in the intake manifold of SI engines. HCCI can be induced and controlled by varying the mixture temperature, either by Exhaust Gas Recirculation (EGR) or intake air pre-heating.

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

Development of new fuels and engine combustion strategies for future ultra-low emission engines requires a greater level of insight into the process of emissions formation than is afforded by the approach of engine exhaust measurement. The paper describes the development of an in-cylinder gas sampling system consisting of a fast-acting, percussion-based, poppet-type sampling valve, and a heated dilution tunnel; and the deployment of the system in a single cylinder engine. A control system was also developed for the sampling valve to allow gas samples to be extracted from the engine cylinder during combustion, at any desired crank angle in the engine cycle, while the valve motion was continuously monitored using a proximity sensor. The gas sampling system was utilised on a direct injection diesel engine co-combusting a range of hydrogen-diesel fuel and methane-diesel fuel mixtures.

Recent pressures on vehicle manufacturers to reduce their average fleet levels of CO2 emissions have resulted in an increased drive to improve fuel economy and enable use of fuels developed from renewable sources that can achieve a net reduction in the CO2 output of each vehicle. The most popular choice for spark-ignition engines has been the blending of ethanol with gasoline, where the ethanol is derived either from agricultural or cellulosic sources such as sugar cane, corn or decomposed plant matter. However, other fuels, such as butanol, have also arisen as potential candidates due to their similarities to gasoline, e.g. higher energy density than ethanol. To extract the maximum benefits from these new fuels through optimized engine design and calibration, an understanding of the behaviour of these fuels in modern engines is necessary.

Diesel fuels usually comprise a wide range of compounds having different molecular structures which can affect both the fuel's physical properties and combustion characteristics. In future, as synthetic fuels from fossil and sustainable sources become increasingly available, it could be possible to control the fuel's molecular structure to achieve clean and efficient combustion. This paper presents experimental results of combustion and emissions studies undertaken on a single cylinder diesel engine supplied with 18 different fuels each comprising a single, acyclic, non-oxygenated hydrocarbon molecule. These molecules were chosen to highlight the effect of straight carbon chain length, degree of saturation and the addition of methyl groups as branches to a straight carbon chain.

Extensive literature exists on spray development, mixing and combustion regarding engine modeling and diagnostics using single-component and model fuels. However, often the variation in data between different fuels, particularly relating to spray development and its effect on combustion, is neglected or overlooked. By injecting into a quiescent chamber, this work quantifies the differences in spray development from a multi-hole direct-injection spark-ignition engine injector for two single-component fuels (iso-octane and n-pentane), a non-fluorescing multi-component model fuel which may be used for in-cylinder Laser Induced Fluorescence experiments, and several grades of pump gasoline (with and without additives). High-speed recordings of the sprays were made for a range of fuel temperatures and gas pressures. It is shown that a fuel temperature above that of the lowest boiling point fraction of the tested fuel at the given gas pressure causes a convergence of the spray plumes.

Synthetic bio-fuels, which can be obtained through the gasification of biomass into synthesis gas and the subsequent catalytic reaction of the synthesis gas into liquid fuel molecules, could play a key-role in providing a sustainable source of automotive fuels during the coming decades. This paper presents an attempt to understand the effect of molecular structure of potential oxygenated synthetic bio-fuel molecules of different structure on the diesel combustion process in both stratified and homogeneous combustion modes. Specifically, the effects of molecular structure on the energy release rates, gaseous exhaust emissions and the sub-micron particulate matter distribution were examined. The experiments were carried out on a single-cylinder direct-injection diesel engine using a specially adapted common-rail fuel-system which allowed the injection of small single-molecule fuel samples at high pressure.

Multidimensional simulations are being used to assist the development of a directly injected natural gas system for heavy-duty diesel engines. In this method of converting diesel engines to natural gas fueling, the gas injection takes place at high pressure at the end of the compression stroke. A small amount of pilot diesel fuel is injected prior to the natural gas to promote ignition. Both fuels are injected through a centrally located injector. The mathematical simulations are sought to provide a better understanding of the injection and combustion process of pilot-ignited directly-injected natural gas. The mathematical simulations are also expected to help optimize the injection process, looking in particular at the tip geometry and at the injection delay between the two fuels. The paper presents the mathematical model, which is based on the KIVA-II code. The model includes modifications for underexpanded natural gas jets, and includes a turbulent combustion model.

The effect on the intake flow field, air fuel mixing processes, thermodynamic performance and emissions output has been investigated for a range of valve operating profiles. A standard speed load point of 2000 rpm and 2.7 bar IMEP720° has been reached by throttling the intake whilst running standard cam profiles, by early closing of both inlet valves (EIVC) and by early closing of each inlet individually to generate bulk swirl motions within the cylinder. Data has been recorded at stoichiometric air fuel ratios for both direct injection and port fuelled operation. The valve profiles have been applied to two single cylinder homogeneous gasoline direct injection (GDI) spark ignition engines, developed to investigate the potential of controlling engine load by limiting the inducted air mass using fully variable valve timing (FVVT) to reduce pumping losses at part load.

For a spark-ignition engine, the parasitic loss suffered as a result of conventional throttling has long been recognised as a major reason for poor part-load fuel efficiency. While lean, stratified charge, operation addresses this issue, exhaust gas aftertreatment is more challenging compared with homogeneous operation and three-way catalyst after-treatment. This paper adopts a different approach: homogeneous charge direct injection (DI) operation with variable valve actuations which reduce throttling losses. In particular, low-lift and early inlet valve closing (EIVC) strategies are investigated. Results from a thermodynamic single cylinder engine are presented that quantify the effect of two low-lift camshafts and one standard high-lift camshaft operating EIVC strategies at four engine running conditions; both, two- and single-inlet valve operation were investigated. Tests were conducted for both port and DI fuelling, under stoichiometric conditions.

An experimental study was carried out to investigate the effects of fuel injection timing on the spatial and temporal development of injected fuel sprays within a firing direct-injection spark-ignition (DISI) engine. It was found that the structure of the injected fuel sprays varied significantly with the timing of the injection event. During the induction stroke and the early part of the compression stroke, the development of the injected fuel sprays was shown to be controlled by the state of the intake and intake-generated gas flows at the start of injection (SOI).The relative influence of these two flow regimes on the injected fuel sprays during this period was also observed to change with injection timing, directly affecting tip penetration, spray/wall impingement and air-fuel mixing. Later in the compression stroke, the results show the development of the injected fuel sprays to be dominated by the increased cylinder pressure at SOI.

A study to investigate the influence of fuel injection timing on exhaust emissions from a single-cylinder direct-injection spark-ignition (DISI) research engine was performed. Experimental results were obtained for carbon monoxide (CO), unburned hydrocarbon (HC), and oxides of nitrogen (NOx). Images showing the variation of liquid-phase fuel distribution with changing injection timing were obtained in a firing optically-accessed engine of similar design. A correlation between measured emissions and observed liquid-phase fuel distribution was performed. This correlation was supported by development of phenomenological models that permit explanation of the variation of CO, HC, and NOx emissions with changes in air-fuel mixture preparation.

The scattering properties (influenced by morphology) and refractive index (dependent on microstructure) of engine-emitted soot influences its effect on climate, as well as how we interpret optical measurements of aerosols. The morphology and microstructure of soot from two different engines were studied. The soot samples were collected from a 1.9L Volkswagen TDI engine for two different fuel types (ULSD and B20) and six speed/load combinations., as well as from a Cummins ISX heavy-duty engine using the Westport pilot-ignited high-pressure direct-injection (HPDI) natural-gas fuelling system for three different speed/load combinations. The transmission electron microscopy (TEM) was employed to investigate the soot morphology, emphasizing the fractal properties. Image processing was used to extract the geometrical properties of the thirty-five randomly chosen aggregates from each sample.

This experimental work was concerned with the combination of internal EGR with an early inlet valve closure strategy for improved part-load fuel economy. The experiments were performed in a new spark-ignited thermodynamic single cylinder research engine, equipped with a mechanical fully variable valvetrain on both the inlet and exhaust. During unthrottled operation at constant engine speed and load, increasing the mass of trapped residual allowed increased valve duration and lift to be used. In turn, this enabled further small improvements in gas exchange efficiency, thermal efficiency and hence indicated fuel consumption. Such effects were quantified under both port and homogeneous central direct fuel injection conditions. Shrouding of the inlet ports as a potential method to increase in-cylinder gas velocities has also been considered.

This paper presents results from a comprehensive experimental study of high-pressure pressure-swirl gasoline injectors tested under a range of simulated operating conditions. This study encompassed photographic analysis of single spray sequences and simultaneous measurement of axial velocity, radial velocity and diameter at point locations using the phase-doppler technique. The combination of these measurement techniques permitted an insight into the fluid dynamics of the injected spray and its development with time. Five primary stages in the spray-history were identified and numerated with experimental data.

This paper presents the results of an experimental study into the effects of fuel injection pressure on mixture formation within an optically accessed direct-injection spark-ignition (DISI) engine. Comparison is made between the spray characteristics and in-cylinder fuel distributions due to supply rail pressures of 50 bar and 100 bar subject to part-warm, part-load homogeneous charge operating conditions. A constant fuel mass, corresponding to stoichiometric tune, was maintained for both supply pressures. The injected sprays and their subsequent liquid-phase fuel distributions were visualized using the 2-D laser Mie-scattering technique. The experimental injector (nominally a hollow-cone pressure-swirl design) was seen to produce a dense filled spray structure for both injection pressures under investigation. In both cases, the leading edge velocities of the main spray suggest the direct impingement of liquid fuel on the cylinder walls.

Soot emissions from direct-injection engines are sensitive to the fuel-air mixing process, and may vary between combustion cycles due to turbulence and injector variability. Conventional exhaust emissions measurements cannot resolve inter- or intra-cycle variations in particle emissions, which can be important during transient engine operations where a few cycles can disproportionately affect the total exhaust soot. The Fast Exhaust Nephelometer (FEN) is introduced here to use light scattering to measure particulate matter concentration and size near the exhaust port of an engine with a time resolution of better than one millisecond. The FEN operates at atmospheric pressure, sampling near the engine exhaust port and uses a laser diode to illuminate a small measurement volume. The scattered light is focused on two amplified photodiodes.

As global energy demands continue to be met with ever evolving and stricter emissions requirements, natural gas (NG) has become a highly researched alternative to conventional fossil fuels in many industrial sectors. Transportation is one such field that can utilize the benefits of NG as a primary fuel for use in internal combustion engines (ICEs). In the context of heavy-duty on-highway transportation applications, diesel-ignited dual-fuel (DIDF) combustion of NG has been identified as a commercially viable alternative technology. Previous investigations of DIDF have examined the various trends present across the spectrum of DIDF operating space. However, in-cylinder processes are still not well understood and this investigation aims to further understanding in this area. An in-cylinder, local infrared absorption fuel concentration sensor is used to examine in-cylinder processes by comparison with previous optical and thermodynamic studies.

The conversion of lignocellulosic biomass to liquid fuels presents an alternative to the current production of renewable fuels for IC engines from food crops. However, realising the potential for reductions in net CO2 emissions through the utilisation of, for example, waste biomass for sustainable fuel production requires that energy and resource inputs into such processes be minimised. This work therefore investigates the combustion and emission characteristics of five intermediate platform molecules potentially derived from lignocellulosic biomass: gamma-valerolactone (GVL), methyl valerate, furfuryl alcohol, furfural and 2-methyltetrahydrofuran (MTHF). The study was conducted on a naturally aspirated, water cooled, single cylinder spark-ignition engine. Each of the platform molecules were blended with reference fossil gasoline at 20 % wt/wt.

Alternative fuel injection systems and advanced in-cylinder diagnostics are two important tools for engine development; however, the rapid and simultaneous achievement of these goals is often limited by the space available in the cylinder head. Here, a research-oriented cylinder head is developed for use on a single cylinder 2-litre engine, and permits three simultaneous in-cylinder combustion diagnostic tools (cylinder pressure measurement, infrared absorption, and 2-color pyrometry). In addition, a modular injector mounting system enables the use of a variety of direct fuel injectors for both gaseous and liquid fuels. The purpose of this research-oriented cylinder head is to improve the connection between thermodynamic and optical engine studies for a wide variety of combustion strategies by facilitating the application of multiple in-cylinder diagnostics.