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Combustion behaviour and emissions characteristics of different blending ratios of diesel and gasoline fuels (Dieseline) were investigated in a light-duty 4-cylinder compression-ignition (CI) engine operating on partially premixed compression ignition (PPCI) mode. Experiments show that increasing volatility and reducing cetane number of fuels can help promote PPCI and consequently reduce particulate matter (PM) emissions while oxides of nitrogen (NOx) emissions reduction depends on the engine load. Three different blends, 0% (G0), 20% (G20) and 50% (G50) of gasoline mixed with diesel by volume, were studied and results were compared to the diesel-baseline with the same combustion phasing for all experiments. Engine speed was fixed at 1800rpm, while the engine load was varied from 1.38 to 7.85 bar BMEP with the exhaust gas recirculation (EGR) application.

Injection pressure oscillations are proven to determine considerable deviations from the expected mass flow rate, leading to the jet velocities non-uniformity, which in turn implies the uneven spatial distribution of A/F ratio. Furthermore, once the injector is triggered, these oscillations might lead the rail pressure to experience a decreasing stage, to the detriment of spray penetration length, radial propagation and jet break-up timing. This has urged the research community to develop models predicting injection-induced pressure fluctuations within the rail. Additionally, several devices have been designed to minimize and eliminate such fluctuations. However, despite the wide literature dealing with the injection-induced pressure oscillations, many aspects remain still unclear. Moreover, the compulsory compliance with environmental regulations has shifted focus onto alternative fuels, which represent a promising pathway for sustainable vehicle mobility.

Homogeneous Charge Compression Ignition (HCCI) has emerged as a promising technology for reduction of exhaust emissions and improvement of fuel economy of internal combustion engines. There are generally two proposed methods of realizing the HCCI operation. The first is through the control of gas temperature in the cylinder and the second is through the control of chemical reactivity of the fuel and air mixture. EGR trapping, i.e., recycling a large quantity of hot burned gases by using special valve-train events (e.g. negative valve overlap), seems to be practical for many engine configurations and can be combined with any of the other HCCI enabling technologies. While this method has been widely researched, it is understood that the operating window of the HCCI engine with negative valve overlap is constrained, and the upper and lower load boundaries are greatly affected by the in-cylinder temperature.

For spark ignition (SI) engines, the optimum spark timing is crucial for maximum efficiency. However, as the spark timing is advanced, so the propensity to knock increases, thus compromising efficiency. One method to suppress knock is to use high octane fuel additives. However, the blend ratio of these additives cannot be varied on demand. Therefore, with the advent of aggressive downsizing, new knock mitigation techniques are required. Fortuitously, there are two well-known lower alcohols which exhibit attractive knock mitigation properties: ethanol and methanol. Both not only have high octane ratings, but also result in greater charge-cooling than with gasoline. In the current work, the authors have exploited these attractive properties with the dual-injection, or the dual-fuel concept (gasoline in PFI and fuel additive in DI) using pure ethanol and methanol.

Ethanol has long been regarded as the optimal gasoline-alternative biofuel for spark-ignition (SI) engines. It is used widely in Latin and North America and is increasingly accepted as an attractive option across Europe. Nevertheless, its low energy density requires a high rate of manufacture; in areas which are deficient of arable land, such rates might prove problematic. Therefore, fuels with higher calorific values, such as butanol or 2,5-dimethylfuran (DMF) deserve consideration; a similar yield to ethanol, in theory, would require much less land. This report addresses the suitability of DMF, to meet the needs as a biofuel substitute for gasoline in SI engines, using ethanol as the biofuel benchmark. Specific attention is given to the sensitivity of DMF to various engine control parameters: combustion phasing (ignition timing), injection timing, relative air-fuel ratio and valve timing (intake and exhaust).

Engine transient operation has attracted a lot of attention from researchers due to its high frequency of occurrence during daily vehicle operation. More emissions are expected compared to steady state operating conditions as a result of the turbo-lag problem. Ambient temperature has significant influences on engine transients especially at engine start. The effects of ambient temperature on engine-out emissions under the New European Driving Cycle (NEDC) are investigated in this study. The transient engine scenarios were carried out on a modern 3.0 L, V6 turbocharged common rail diesel engine fuelled with winter diesel in a cold cell within the different ambient temperature ranging between +20 °C and −7 °C. The engine with fuel, coolant, combustion air and lubricating oil were soaked and maintained at the desired test temperatures during the transient scenarios.

Dieseline combustion as a concept combines the advantages of gasoline and diesel by offline or online blending the two fuels. Dieseline has become an attractive new compression ignition combustion concept in recent years and furthermore an approach to a full-boiling-range fuel. High speed imaging with near-parallel backlit light was used to investigate the spray characteristics of dieseline and pure fuels with a common rail diesel injection system in a constant volume vessel. The results were acquired at different blend ratios, and at different temperatures and back pressures at an injection pressure of 100MPa. The penetrations and the evaporation states were compared with those of gasoline and diesel. The spray profile was analyzed in both area and shape with statistical methods. The effect of gasoline percentage on the evaporation in the fuel spray was evaluated.

Particulate Emissions from Homogeneous Charge Compression Ignition (HCCI) combustion are routinely assumed to be negligible. It is shown here that this is not the case when HCCI combustion is implemented in a direct injection gasoline engine. The conditions needed to sustain HCCI operation were realized using the negative valve overlap method for trapping high levels of residual exhaust gases in the cylinder. Measurements of emitted particle number concentration and electrical mobility diameter were made with a Cambustion DMS500 over the HCCI operating range possible with this hardware. Emissions of oxides of nitrogen, carbon monoxide and unburned hydrocarbons were also measured. These data are presented and compared with similar measurements made under conventional spark ignition (SI) operation in the same engine. Under both SI and HCCI operation, a significant accumulation mode was detected with particle equivalent diameters between 80 and 100 nm.

This paper presents a computational investigation of the in-cylinder charge characteristics within a motored 4-valve direct injection HCCI engine cylinder with applied negative valve overlapping. Non-typical intake valve strategy was investigated; whereby the pair of intake valves was assumed to follow the same low-lift short-duration valve-lift profile but actuated at different timings. The phase of intake-valve-opening relative to that of exhaust-valve-closing was optimized in terms of pumping losses. The flow fields generated with such an intake valve strategy were compared to those produced in the same engine cylinder but with typical early and late intake-valve-timing. The computational results of such an approach showed modifications in the in-cylinder swirl and tumble motions during the intake and compression strokes.

The fuel reforming technology has been extensively investigated as a way to produce hydrogen on-board a vehicle that can be utilized in internal combustion engines, fuel cells and aftertreatment technologies. Maximization of H2 production in the reforming process can be achieved when there is optimized water (steam) addition for the different reforming temperatures. A way to increase the already available water quantity on-board a vehicle (i.e. exhaust gas water content) is by using emulsified fuel (e.g. water-diesel blend). This study presents the effect of an emulsified diesel fuel (a blend of water and diesel fuel with an organic surfactant to make the mixture stable) on combustion in conjunction with exhaust gas assisted fuel reforming on a compression ignition engine. No engine modification was required to carry out these tests. The emulsified diesel fuel consisted of about 80% (mass basis) of conventional ultra low sulphur diesel (ULSD) fuel and fixed water content.

Biofuels development and specification are currently driven by the engine (mainly gasoline- and diesel-type) technology, existing fossil fuel specification and availability of feedstock. The ability to use biofuels with conventional fuels without jeopardising the standard fuel specifications is a very effective means for the implementation of these fuels. In this work the effect of dual fuelling with in-cylinder injected ULSD fuel or synthetic second generation biofuels (a Gas-To-Liquid GTL fuel as a surrogate of these biofuels as its composition, specifications and production process are very similar to second generation biofuels) and with inlet port injected bioethanol on the engine performance and emissions were investigated. The introduction of anhydrous bioethanol improved the NOx and smoke emissions, but increased total hydrocarbons and carbon monoxide.

The new fuel, 2, 5-dimenthylfuran, known as DMF, captured worldwide attention since the discovery of its new production method. As a potential bio-fuel, DMF is competitive to gasoline in many areas, such as energy density, combustion efficiency and emissions. However, little work has been performed on its unconventional combustion mode. In this work, high speed imaging and thermal investigation are carried out to study DMF and gasoline dual-injection on a single cylinder, direct injection spark ignition optical engine. This dual-injection strategy combines direct injection (DI) and port fuel injection (PFI) simultaneously which means two different fuels can blend in the cylinder with any ratio. It provides a flexible way to use bio-fuels with gasoline. DMF DI with gasoline PFI and ethanol DI with gasoline PFI are studied under different injection proportions (by volume) and IMEPs.

In this paper blends of diesel and gasoline (dieseline) fuelled Partially Premixed Compression Ignition (PPCI) combustion and the comparison to conventional diesel combustion is investigated. The tests are carried out using a light duty four cylinder Euro IV diesel engine. The engine condition is maintained at 1800 rpm, 52 Nm (equivalent IMEP around 4.3 bar). Different injection timings and different amounts of EGR are used to achieve the PPCI combustion. The results show that compared to the conventional diesel combustion, the smoke and NOx emissions can be reduced by more than 95% simultaneously with dieseline fuelled PPCI combustion. The particle number total concentration can be reduced by 90% as well as the mean diameter (from 54 nm for conventional diesel to 16 nm for G50 fuelled PPCI). The penalty is a slightly increased noise level and lower indicated efficiency, which is decreased from 40% to 38.5%.

Computational Fluid Dynamics (CFD) is used to simulate chemical reactions and transport phenomena occurring in a single channel of a honeycomb-type automotive catalytic converter under lean burn combustion. Microkinetic analysis is adopted to develop a detailed elementary reaction mechanism for propane oxidation on a silver catalyst. Activation energies are calculated based on the theory of the Unity Bond Index-Quadratic Exponential Potential (UBI-QEP) method. The order-of-magnitude of the pre-exponential factors is obtained from Transition State Theory (TST). Sensitivity analysis is applied to identify the important elementary steps and refine the pre-exponential factors of these reactions. These pre-exponential factors depend on inlet temperatures and propane concentration; therefore optimised pre-exponential factors are written in polynomial forms. The results of numerical simulations are validated by comparison with experimental data.

It is well known that direct injection (DI) is a technology enabler for stratified combustion in spark-ignition (SI) engines. At full load or wide-open throttle (WOT), partial charge stratification can suppress knock, enabling greater spark advance and increased torque. Such split-injection or double-pulse injection strategies are employed when using gasoline in DI (GDI). However, as the use of biofuels is set to increase, is this mode still beneficial? In the current study, the authors attempt to answer this question using two gasoline-alternative biofuels: firstly, ethanol; the widely used gasoline-alternative biofuel and secondly, 2,5-dimethylfuran (DMF); the new biofuel candidate. These results have been benchmarked against gasoline in a single-cylinder, spray-guided DISI research engine at WOT (λ = 1 and 1500 rpm). Firstly, single-pulse start of injection (SOI) timing sweeps were conducted with each fuel to find the highest volumetric efficiency and IMEP.

Research studies show that 2-methylfuran (MF) is a promising gasoline alternative regarding its positive effect on engine performance and emissions. Before using pure MF in spark ignition engines, it is more likely to be used in a low-level blended form in gasoline. An experimental research study was carried out to investigate the impacts of low-level MF content in gasoline (volumetric 10% MF in blend) on direct-injection spark-ignition (DISI) engine combustion behavior and emissions. The tests were conducted on a single-cylinder spray-guided DISI research engine at an engine speed of 1500 rpm under stoichiometric conditions. The engine loads of 3.5 ~ 8.5 bar IMEP were tested and gasoline-optimized spark timing was used. Furthermore, the effects of spark timing, exhaust gas recirculation (EGR) and valve overlap on NOx emissions were tested.

This paper presents the findings of theoretical and practical studies of an exhaust-gas reforming process, as applied to hydrocarbon fuels. It is shown that hydrogen-containing gaseous reformed fuels can be produced by the interaction of hot combustion products and an n-heptane feedstock in a small-scale catalytic reforming reactor. Predicted and observed reformed fuel chemical compositions were found to correlate well at the lower reactor space velocities tested, where chemical equilibrium conditions can be closely approached. Under these conditions, respective hydrogen and carbon monoxide yields of around 32 and 20 volume per cent were obtained. Under certain conditions, it was found that carbon solids were deposited on the reforming catalyst. Measures taken to avoid this problem included changes in the reforming oxidant to fuel ratio, and the addition of excess steam to the oxidant composition.

Exhaust Gas Fuel Reforming has potential to be used for on-board generation of hydrogen rich gas, reformate, and to act as an energy recovery system allowing the capture of waste exhaust heat. High exhaust gas temperature drives endothermic reforming reactions that convert hydrocarbon fuel into gaseous fuel when combined with exhaust gas over a catalyst - the result is an increase in overall fuel energy that is proportional to waste energy capture. The paper demonstrates how the combustion of reformate in a direct injection gasoline (GDI) engine via Reformed Exhaust Gas Recirculation (REGR) can be beneficial to engine performance and emissions. Bottled reformate was inducted into a single cylinder GDI engine at a range of engine loads to compare REGR to conventional EGR. The reformate composition was selected to approximate reformate produced by exhaust gas fuel reforming at typical gasoline engine exhaust temperatures.

While Homogeneous Charge Compression Ignition (HCCI) is a promising combustion mode with significant advantages in fuel economy improvement and emission reductions for vehicle engines, it is subject to a number of limitations, for example, hardware and control complexity, or NOx and NVH deterioration near its operating upper load boundary, diminishing its advantages. Conventional spark-ignition combustion mode is required for higher loads and speeds, thus the operating conditions near the HCCI boundaries and their corresponding alternatives in SI mode must be studied carefully in order to identify practical strategies to minimise the impact of the combustion mode transition on the performance of the engine. This paper presents the results of an investigation of the combustion mode transitions between SI and HCCI, using a combination of an engine cycle simulation code with a chemical kinetics based HCCI combustion code.

Natural gas has a high auto-ignition temperature, requiring high compression ratios and/or intake charge heating to achieve HCCI (homogeneous charge compression ignition) engine operation. Previous work by the authors has shown that hydrogen addition improves combustion stability in various difficult combustion conditions. It is shown here that hydrogen, together with residual gas trapping, helps also in lowering the intake temperature required for HCCI. It has been argued in literature that the addition of hydrogen advances the start of combustion in the cylinder. This would translate into the lowering of the minimum intake temperature required for auto-ignition to occur during the compression stroke. The experimental results of this work show that, with hydrogen replacing part of the fuel, a decrease in intake air temperature requirement is observed for a range of engine loads, with larger reductions in temperature noted at lower loads.