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A numerical analysis was performed to study the variation of the laminar burning speed of gasoline-ethanol blend, pressure, temperature and dilution using the one-dimensional premixed flame code CHEMKIN™. A semi-detailed validated chemical kinetic model (142 species and 672 reactions) for a gasoline surrogate fuel was used. The pure components in the surrogate fuel consist of n-heptane, isooctane and toluene. The ethanol mole fraction was varied from 0 to 85 percent, initial pressure from 4 to 8 bar, initial temperature from 300 to 600K, and the EGR dilution from 0 to 32% to represent the in-cylinder conditions of a spark-ignition engine. The laminar flame speed is found to increase with ethanol concentration and temperature but decrease with pressure and dilution.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Gasoline compression ignition (GCI) technology shows the potential to obtain high thermal efficiencies while maintaining low soot and NOx emissions in light-duty engine applications. Recent experimental studies and numerical simulations have indicated that high reactivity gasoline-like fuels can further enable the benefits of GCI combustion. However, there is limited empirical data in the literature studying the gasoline compression ignition process at relevant in-cylinder conditions, which are required for further optimizing combustion system designs. This study investigates the temporal and spatial evolution of the compression ignition process of various high reactivity gasoline fuels with research octane numbers (RON) of 71, 74 and 82, as well as a conventional RON 97 E10 gasoline fuel. A ten-hole prototype gasoline injector specifically designed for GCI applications capable of injection pressures up to 450 bar was used.

In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.

A major problem with many soot emission control devices is the fact that they quickly become loaded with soot which must be removed by a controlled burning (regeneration) process. The need for regeneration greatly complicates such diesel particle emission control devices. In this paper, an electrostatic agglomerator (ESA) which efficiently collects diesel particles but does not require regeneration is described. The ESA is an electrostatic precipitator which is designed to collect and subsequently reentrain diesel soot particles. The collection and reentrainment processes results in growth of particle diameter from roughly 0.2 μm to larger than 1.0 μm. The agglomerated particles are large enough to be collected by a relatively simple inertial device, e.g., a cyclone separator. The collected particle may be either recycled to the engine or disposed of by other means. Electrostatic collection is made easier by the fact that diesel particles are charged by the combustion process itself.

An experimental and modeling study was conducted to study the passive regeneration of a catalyzed particulate filter (CPF) by the oxidation of particulate matter (PM) via thermal and Nitrogen dioxide/temperature-assisted means. Emissions data in the exhaust of a John Deere 6.8 liter, turbocharged and after-cooled engine with a low-pressure loop EGR and a diesel oxidation catalyst (DOC) - catalyzed particulate filter (CPF) in the exhaust system was measured and used for this study. A series of experiments was conducted to evaluate the performance of the DOC, CPF and DOC+CPF configurations at various engine speeds and loads.

With concerns continuing to grow with respect to global warming from greenhouse gases, further regulations are being examined, developed and are expected for the emission of CO2 as an automobile exhaust. Renewable alternate fuels offer the potential to significantly reduce the CO2 impact of transportation. Hydrogen as a spark - ignition (SI) engine fuel provides this potential for significant CO2 reduction when generated from renewable resources. In addition, hydrogen has advantageous combustion properties including a wide flammable mixture range which facilitates lean burning and high dilution, fast combustion energy release and zero CO2 emissions. However, the high burning rates and fast energy release can lead to excessive in-cylinder pressures and temperatures resulting in combustion knock and high NOx emissions at stoichiometric operation.

Steady-state particulate loading experiments were conducted on an advanced production catalyzed particulate filter (CPF), both with and without a diesel oxidation catalyst (DOC). A heavy-duty diesel engine was used for this study with the experiments conducted at 20, 40, 60 and 75 % of full load (1120 Nm) at rated speed (2100 rpm). The data obtained from these experiments were used and are necessary for calibrating the MTU 1-D 2-Layer CPF model. These experimental and modeling results were compared to previous research conducted at MTU that used the same engine but an earlier development version of the combination of DOC and CPF. The motivation for the comparison of the two systems was to determine whether the reformulated production catalysts performed as good or better than the early development catalysts. The results were compared to understand the filtration and oxidation differences between the two DOC+CPF and the CPF-only aftertreatment systems.

Model-based control strategies are important for meeting the dual objective of maximizing NOx reduction and minimizing NH3 slip in urea-SCR catalysts. To be implementable on the vehicle, the models should capture the essential behavior of the system, while not being computationally intensive. This paper discusses the adequacy of two different reduced order SCR catalyst models and compares their performance with a higher order model. The higher order model assumes that the catalyst has both diffusion and reaction kinetics, whereas the reduced order models contain only reaction kinetics. After describing each model, its parameter identification and model validation based on experiments on a Navistar I6 7.6L engine are presented. The adequacy of reduced order models is demonstrated by comparing the NO, NO2 and NH3 concentrations predicted by the models to their concentrations from the test data.

Exhaust gas recirculation (EGR) has been employed in a diesel engine to reduce NOx emissions by diluting the fresh air charge with gases composed of primarily N2, CO2, H2O, and O2 from the engines exhaust stream. The addition of EGR reduces the production of NOx by lowering the peak cylinder gas temperature and reducing the concentration of O2 molecules, both of which contribute to the NOx formation mechanism. The amount of EGR has been typically controlled using an open loop control strategy where the flow of EGR was calibrated to the engine speed and load and controlled by the combination of an EGR valve and the ratio of the boost and exhaust back pressures. When oxygenated biofuels with lower specific energy are used, the engine control unit (ECU) will demand a higher fuel rate to maintain power output, which can alter the volumetric flow rate of EGR. In addition, oxygenated biofuels affect the oxygen concentration in the intake manifold gas stream.

A one-dimensional model simulating the oxidation of CO, HC, and NO was developed to predict the gaseous emissions downstream of a diesel oxidation catalyst (DOC). The model is based on the conservation of mass, species, and energy inside the DOC and draws on past research literature. Steady-state experiments covering a wide range of operating conditions (exhaust temperatures, flow rates and gaseous emissions) were performed, and the data were used to calibrate and validate the model. NO conversion efficiencies of 50% or higher were obtained at temperatures between 300°C and 350°C. CO conversion efficiencies of 85% or higher and HC conversion efficiencies of 75% or higher were found at every steady state condition above 200°C. The model agrees well with the experimental results at temperatures from 200°C to 500°C, and volumetric flow rates from 8 to 42 actual m3/min.

The effects of a catalyzed particulate filter (CPF) and Exhaust Gas Recirculation (EGR) on heavy-duty diesel engine emissions were studied in this research. EGR is used to reduce the NOx emissions but at the same time it can increase total particulate matter (TPM) emissions. CPF is technology available for retrofitting existing vehicles in the field to reduce the TPM emissions. A conventional low sulfur fuel (371 ppm S) was used in all the engine runs. Steady-state loading and regeneration experiments were performed with CPF I to determine its performance with respect to pressure drop and particulate mass characteristics at different engine operating conditions. From the dilution tunnel emission characterization results for CPF II, at Mode 11 condition (25% load - 311 Nm, 1800 rpm), the TPM, HC and vapor phase emissions (XOC) were decreased by 70%, 62% and 62% respectively downstream of the CPF II.

In order to comply with 2002 EPA emissions regulations, cooled exhaust gas recirculation (EGR) will be used by heavy duty (HD) diesel engine manufacturers as the primary means to reduce emissions of nitrogen oxides (NOx). A feedforward controlled EGR cooling system with a secondary electric water pump and proportional-integral-derivative (PID) feedback has been designed to cool the recirculated exhaust gas in order to better realize the benefits of EGR without overcooling the exhaust gas since overcooling leads to the fouling of the EGR cooler with acidic residues. A system without a variable controlled coolant flow rate is not able to achieve these goals because the exhaust temperature and the EGR schedule vary significantly, especially under transient and warm-up operating conditions. Simulation results presented in this paper have been determined using the Vehicle Engine Cooling System Simulation (VECSS) software, which has been developed and validated using actual engine data.

Extensive studies have addressed diesel sprays under non-vaporizing, vaporizing and combusting conditions respectively, but further insights into the mechanism by which combustion alters the macroscopic characteristics including the spray penetration and the shape of the spray under diesel engine conditions are needed. Contradictory observations are reported in the literature regarding the combusting diesel spray penetration compared to the inert conditions, and it is an objective of this study to provide further insights and analyses on the combusting spray characteristics by expanding the range of operating parameters. Parameters varied in the studies are charge gas conditions including oxygen levels of 0 %, 15%, 19%, charge densities of 22.8 & 34.8 kg/m3, and charge temperatures of 800, 900 & 1050 K for injection pressures of 1200, 1500, and 1800 bar with a single-hole injector with a nozzle diameter of 100 μm.

Reactivity Controlled Compression Ignition (RCCI) is a promising dual-fuel Low Temperature Combustion (LTC) mode with significant potential for reducing NOx and particulate emissions while improving or maintaining thermal efficiency compared to Conventional Diesel Combustion (CDC) engines. The large reactivity difference between diesel and Natural Gas (NG) fuels provides a strong control variable for phasing and shaping combustion heat release. In this work, the Brake Thermal Efficiencies (BTE), emissions and combustion characteristics of a light duty 1.9L, four-cylinder diesel engine operating in single fuel diesel mode and in Diesel-NG RCCI mode are investigated and compared. The engine was operated at speeds of 1300 to 2500 RPM and loads of 1 to 7 bar BMEP. Operation was limited to 10 bar/deg Maximum Pressure Rise Rate (MPRR) and 6% Coefficient of Variation (COV) of IMEP.

For spark-ignition gasoline engines operating under the wide speed and load conditions required for light duty vehicles, ignition quality limits the ability to minimize fuel consumption and NOx emissions via dilution under light and part load conditions. In addition, during transients including tip-outs, high levels of dilution can occur for multiple combustion events before either the external exhaust gas can be adjusted and cleared from the intake or cam phasing can be adjusted for correct internal dilution. Further improvement and a thorough understanding of the impact of the ignition system on combustion near the dilution limit will enable reduced fuel consumption and robust transient operation. To determine and isolate the effects of multiple parameters, a variable output ignition system (VOIS) was developed and tested on a 3.5L turbocharged V6 homogeneous charge direct-injection gasoline engine with two spark plug gaps and three ignition settings.

In this study, a DOC catalyst was experimentally studied in an engine test cell with a2010 Cummins 6.7L ISB diesel and a production aftertreatment system. The test matrix consisted of steady state, active regeneration with in-cylinder fuel dosing and transient conditions. Conversion efficiencies of total hydrocarbon (THC), CO, and NO were quantified under each condition. A previously developed high-fidelity DOC model capable of predicting both steady state and transient active regeneration gaseous emissions was calibrated to the experimental data. The model consists of a single 1D channel where mass and energy balance equations were solved for both surface and bulk gas regions. The steady-state data were used to identify the activation energies and pre-exponential factors for CO, NO and HC oxidation, while the steady-state active regeneration data were used to identify the inhibition factors. The transient data were used to simulate the thermal response of the DOC.

To meet future NO, heavy-duty diesel emissions standards, exhaust gas recirculation (EGR) technology is likely to be used. To improve fuel economy and further lower emissions, the recirculated exhaust gas needs to be cooled, with the possibility that cooling of the exhaust gas may form sulfuric acid condensate in the EGR cooler. This corrosive condensate can cause EGR cooler failure and consequentially result in severe damage to the engine. Both a literature review and a preliminary experimental study were conducted. In this study, a manually controlled EGR system was installed on a 1995 Cummins Ml l-330E engine which was operated at EPA mode 9* (1800 rpm and 75% load). The Goksoyr-Ross method (1)** was used to measure the particle-phase sulfate and vapor-phase H2SO4 and SO2 at the inlet and outlet locations of the EGR cooler, obtaining H2SO4 and SO2 concentrations. About 0.5% of fuel sulfur in the EGR cooler was in the particle-phase.

The effects of exhaust gas recirculation (EGR) on heavy-duty diesel emissions were studied at two EPA steady-state operating conditions, old EPA mode 9* (1800 RPM, 75% Load) and old EPA mode 11 (1800 RPM, 25% Load). Data were collected at the baseline, 10% and 16% EGR rates for both EPA modes. The study was conducted using a 1995 Cummins M11-330E heavy-duty diesel engine and compared to the baseline emissions from the Cummins 1988 and 1991 L10 engines. The baseline gas-, vapor- and particle-phase emissions were measured together with the particle size distributions at all modes of operation. The total particulate matter (TPM) and vapor phase (XOC) samples were analyzed for physical, chemical and biological properties. The results showed that newer engines with electronic engine controls and higher injector pressures produce TPM decreases from the 1988 to 1991 to 1995 engines with the solids decreasing more than the soluble organic fraction (SOF) of TPM.