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Natural Gas engines are viewed as an alternative to diesel power in the quest to reduce heavy duty vehicle emissions in polluted urban areas. In particular, it is acknowledged that natural gas has the potential to reduce the inventory of particulate matter, and this has encouraged the use of natural gas engines in transit bus applications. Extensive data on natural gas and diesel bus emissions have been gathered using two Transportable Heavy Duty Vehicle Emissions Testing Laboratories, that employ chassis dynamometers to simulate bus inertia and road load. Most of the natural gas buses tested prior to 1997 were powered by Cummins L-10 engines, which were lean-burn and employed a mechanical mixer for fuel introduction. The Central Business District (CBD) cycle was used as the test schedule.

The need for a cleaner and less expensive alternative energy source to conventional petroleum fuels for powering the transportation sector has gained increasing attention during the past decade. Special attention has been directed towards natural gas (NG) which has proven to be a viable option due to its clean-burning properties, reduced cost and abundant availability, and therefore, lead to a steady increase in the worldwide vehicle population operated with NG. The heavy-duty vehicle sector has seen the introduction of natural gas first in larger, locally operated fleets, such as transit buses or refuse-haulers. However, with increasing expansion of the NG distribution network more drayage and long-haul fleets are beginning to adopt natural gas as a fuel.

Results of a research effort directed towards identifying and measuring the genotoxic properties of respirable particulate matter involved in mining exposures, especially those which may synergistically affect genotoxic hazard, are presented. Particulate matter emissions from a direct injection diesel engine have been sampled and assayed to determine the genotoxic potential as a function of engine operating conditions. Diesel exhaust from a Caterpillar 3304 diesel engine, representative of the ones found in underground mines, rated 100 hp at 2200 rpm is diluted in a multi-tube mini-dilution tunnel and the particulate matter is collected on 70 mm fluorocarbon coated glass fiber filters as well as on 8″ x 10″ hi-volume filters. A six mode steady state duty cycle was used to relate engine operating conditions to the genotoxic potential.

Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.

Data has been gathered using the West Virginia University Heavy Duty Transportable Emissions Laboratories from buses operating on diesel and a variety of alternate fuels in the field. Typically, the transportable chassis dynamo meter is set up at a local transit agency and the selected buses are tested using the fuel in the vehicle at the time of the test. The dynamometer may be set up to operate indoors or outdoors depending on the space available at the site. Samples of the fuels being used at the site are collected and sent to the laboratory for analysis and this information is then sent together with emissions data to the Alternate Fuels Data Center at the National Renewable Energy Laboratory. Emissions data are acquired from buses using the Central Business District cycle reported in SAE Standard J1376; this cycle has 14 ramps with 20 mph (32.2 km/h) peaks, separated by idle periods.

This paper presents results from a study on speciation of the emission profiles and on the ozone forming potential of heavy-duty diesel exhaust under steady state engine operation. Very limited attempts have been made at determining the ozone forming potential of heavy duty diesel exhaust emissions. In this study a proportional sample of the dilute exhaust was drawn from a CFV-CVS system using a temperature controlled sampling line. The particulate matter was collected on a 70 mm Teflon coated glass fiber filter (TX40HI20WW), the semi-volatiles on XAD-2 copolymer resin and volatiles in Tedlar bags. The samples were analyzed by gas chromatography after conditioning and chemical extractions. The initial phase of the study was directed towards developing techniques and establishing protocols to determine the ozone forming potential of heavy-duty diesel exhaust. A pre-chamber naturally aspirated engine was tested on steady-state modes 1, 3, 5, 7 and 8 of the ISO 8 mode cycle.