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The use of advanced electron microscopy techniques to characterize both the bulk and near-atomic level microstructural evolution of catalyst materials during different dynamometer/vehicle aging cycles is an integral part of understanding catalyst deactivation. The study described here was undertaken to evaluate thermally-induced microstructural changes which caused the progressive loss of catalyst performance in a three-way automotive catalyst. Several different catalyst processing variables, for example changing the washcoat ceria content, were also evaluated as a function of aging cycle and thermal history. A number of thermally-induced microstructural changes were identified using high resolution electron microscopy techniques that contributed to the deactivation of the catalyst, including sintering of all washcoat constituents, γ-alumina transforming to α-, β-, and δ-alumina, precious metal redistribution, and constituent encapsulation.

Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.

A jury evaluation study has been conducted to determine the hearing threshold of IP gauge stepping motor noise using a transformed up-down procedure. The stepping motor noise was recorded in an anechoic chamber and was used as a signal in the study. To determine the masked threshold, this signal was adjusted to various gain levels and mixed with interior engine noise at selected rpm as masking noise. In this study, the Adaptive Procedure was used, and a software application was developed for this purpose. Twenty subjects, selected based on hearing test results, participated in this jury evaluation. The findings of this study indicated that Adaptive Procedure is an effective approach in determining hearing threshold for automotive applications. A design criterion for acoustical characteristics of the IP gauge DC motor noise has been developed based on the results of this study.

As compared to home audio, the automobile has a different spatial and spectral distribution of sound. This can cause stereo images to blur or shift due to conflicting localization cues. The impact of interaural time and level differences is discussed, along with frequency-selective pinna and head cues. Review of the literature shows that our poorest localization is for mid frequencies (∼2kHz). Yet in an automobile, low frequencies are severely relocated with a minimum effect on fidelity. It is suggested this is because middle frequencies dominate the perception and localization of sound. Therefore, some high frequency information might also be relocated.

Performance of two types of NOx adsorber catalysts, one based on Ba and the other based on Ba with alkali metals, was compared fresh and after thermal aging. Incorporation of sodium(Na), potassium(K) and cesium(Cs) into NOx adsorber washcoat containing barium significantly increases the NOx conversions in the temperature range of 350-600°C over that of the alkali metal free NOx adsorber catalysts. NOx performance benefit and HC performance penalty were observed on both engine dynamometer and vehicle tests for the “Ba+alkali metals” NOx adsorber catalysts. “Ba+alkali metals” NOx adsorber catalysts also demonstrate superior sulfur resistance with better NOx performance after repeated sulfur poisonings and desulfations over the “Ba based” NOx adsorber catalysts.

The problem being investigated involves a noise-quality issue on a power steering application, when a sudden change of steering wheel angle generates an unwanted steering system noise or “Squawk.” This phenomenon is mostly observed during parking maneuvers, especially at lock positions and when the hydraulic fluid reaches a critical temperature on the specific application. The objective of the work to solve this noise-quality issue was to first identify the cause and then eliminate the Squawk noise. There were several constraints: No change could be made in the properties or type of hydraulic fluid used due to specification requirements; Steering wheel valve torsion bar characteristic (torque vs. angle) needed to be maintained within specification for ride and handling purposes; and, In addition to the mentioned constraints, a high capability of noise elimination generated by the production tolerances and dispersion has been considered.

Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) are effective emission solutions for both close-coupled and underfloor LEV/ULEV applications due to optimal hydrocarbon light-off, NOx control, and balance of precious metal (PGM) usage. Dual-brick [Pd +Pt/Rh] systems on 3.8L V-6 LEV-calibrated vehicles were characterized as a function of PGM loading, catalyst technology, converter volumes, and substrate cell density. While hydrocarbon emissions improve with increasing Pd loading, decreasing the front catalyst volume at constant Pd content (resulting in higher Pd density) improved light-off emissions. Use of 600cpsi substrates improved underfloor NMHC emissions on a 3.8L vehicle by ∼ 6-10mg/mi compared to 400cpsi catalysts, and thus allowing reduction of catalyst volume while achieving ULEV emission levels without air addition.

Compromises inherent with fixed valve lift and event timing have prompted engine designers to consider Variable Valve Actuation (VVA) systems for many decades. In recent years, some relatively basic forms of VVA have been introduced into production engines. Greater performance and driveability expectations of customers, more stringent emission regulations set by government legislators, and the mutual desire for higher fuel economy are increasingly at odds. As a solution, many OEM companies are seriously considering large-scale application of higher function VVA mechanisms in their next generation vehicles. This paper describes the continuing development progress of a mechanical VVA system. Design features and operation of the mechanism are explained. Test results are presented in two sections: motored cylinder head test data focuses on VVA system friction, control system performance, valve lift and component stress.

Brake squeal phenomenon often involves modal coupling between various component modes. In order to reduce or eliminate squeal, it is very important to understand the coupling mechanism so that the key component(s) can be modified accordingly. This paper demonstrates a quantitative method to define system mode shapes using the concept of modal participation factors. This method is implemented on a front disc brake system to identify the modal coupling mechanism associated with its high frequency squeal. Complex eigenvalue analysis is carried out and the squeal frequency is correlated. System mode shapes are then processed with an in-house program to calculate modal participation factors based on a complex MAC (Modal Assurance Criteria) algorithm. The coupling mechanism is identified and possible countermeasures are discussed.

In the catalytic converter, the thermal conductivity of the insulation material (intumescent mat) placed between the ceramic catalyst and the metal shell is strongly dependent on the temperature, resulting in the solving of non-linear heat conduction equations. In this paper, the analytic solution for the steady heat flow in a cylinder with temperature dependent conductivity is given. Using this analytic solution for the mat and including convection and radiation at the converter skin, an analytical expression for calculating converter skin temperature is obtained. This expression can be easily incorporated in a Fortran code to calculate the temperatures.

The interdependence of consumer features, new electronic and electrical architectures and hybrid propulsion systems are examined. There are two major forces driving future vehicle electronic and electrical systems, one is consumer demand for comfort and safety, and two is the demand for reduced fuel consumption and emissions. These forces are linked by the use of electronics to control vehicle energy generation and usage while providing managed solutions to these demands. Automobile consumer features are discussed and the case is made that these features will require more electric power to be installed on the vehicle. The presence of this increased electric power will then enable the hybrid vehicle functions that will benefit fuel economy and emissions performance.

The electric power required in automotive systems is quickly reaching a level that significantly impacts costs and fuel consumption. This drives the need to reconsider an electric energy management function. Fast evolving factors such as increasing power usage, and stricter engine management and reliability requirements necessitate a global vehicle approach to energy management. Innovations such as new powernet concepts (42 volt or dual voltage systems), new component technologies (high-performance energy storage, high efficiency and controllable generators), and global electronic and software architecture concepts will enable this new energy management concept. This paper describes key issues to maximize energy availability with reasonable components.

With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.

Product sound quality is becoming increasingly critical in recent years. To help improve customer satisfaction and product quality, Delphi Automotive Systems has taken a proactive approach to address sound quality issues. The first step is to identify customers' expectations. This paper describes a sensory approach to develop sound quality criterion for a power product. To identify critical sound quality characteristics, a large number of sound samples were recorded. Jury (focus group) evaluation was conducted to identify the acceptance level and preference of each sample. Then, critical objective measures, and the criterion level of each measure, were identified via correlation analysis with subjective responses. This article presents a practitioner's point of view on how to apply sensory engineering method to engineering practice.

A Barometric Pressure Estimator (BPE) algorithm was implemented in a production speed-density Engine Management System (EMS). The BPE is a model-based, easily calibrated algorithm for estimating barometric pressure using a standard set of production sensors, thereby avoiding the need for a barometric pressure sensor. An accurate barometric pressure value is necessary for a variety of engine control functions. By starting with the physics describing the flow through the induction system, an algorithm was developed which is simple to understand and implement. When used in conjunction with the Pneumatic and Thermal State Estimator (PSE and TSE) algorithms [2], the BPE requires only a single additional calibration table, generated with an automated processing routine, directly from measured engine data collected at an arbitrary elevation, in-vehicle or on a dynamometer. The algorithm has been implemented on several different engines.

This paper describes the technique of in-cylinder ionization sensing in a common rail diesel engine. The technology detects in real time, the start of combustion for both pilot and main combustion enabling the fuel control strategy to change from open to closed loop, thus, maintaining the desired start of combustion for all speeds and loads. Additionally, the ionization sensing enables the ECM to truly correct for changes in ignition delays caused by as an example a change in fuel cetane number or in air, fuel and engine temperature. The conclusions are that ionization sensing improves the ability to control a diesel engine and is a feasible technology for production vehicles.

The purpose of this report is to quantify the methodology for evaluating and isolating rattle noises in power rack & pinion steering systems. In today's ever changing market of vehicle body & suspension changes, it's very important that the correct process be used to identify the correct noise source. The results of this evaluation procedure will help sort out the difference between hydraulic generated noises and mechanical generated noises. The process used in sorting the hydraulic noise from the mechanical noise is through the use of a “standpipe”, which dampens the hydraulic reaction pulse in the hydraulic steering system. We refer to this hydraulic pulse as “hydraulic rattle”, and is often confused with mechanical rattle during vehicle evaluations. The concept of the standpipe is similar to that used in household plumbing, which reduces the effects of hydraulic hammering in the water pipes.

A front disc brake system is used as an example for an investigation of low frequency squeal. Many different modifications to this disc brake system have been proposed and this paper focuses on a solution that reduces the stiffness of the rotor. This is accomplished by a reduction in the Young's modulus of the rotor material. The complex eigenvalue method is used for a detailed analytical study in order to obtain a better understanding of this solution technique. Modal participation factors are calculated to examine the modal coupling mechanism. Parametric studies are also performed to find out the effects of friction coefficient and rotor stiffness. Results show that shifting rotor resonance frequencies may ecouple the modal interaction and eliminate dynamic instability, which is in agreement with experimental results.

A double dielectric barrier discharge reactor driven by an alternating voltage is a relatively simple approach to promote oxidation of NO to NO2 for subsequent reduction in a catalyst bed. The chemical performance of such a non-thermal plasma reactor is determined by its current and electric field behavior in the gap, and by the fraction of the current carried by electrons, because the key reactants which initiate the NO oxidation and accompanying chemical changes are produced there, mostly by electron impact. We have tried to determine by models and experiments the bounds on performance of double dielectric barrier reactors and guidelines for optimization. Models reported here predict chemical results from time-resolved applied voltage and series sense capacitor data.