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The diesel engine can be an effective solution to meet future greenhouse gas and fuel economy standards, especially for larger segment vehicles. However, a key challenge facing the diesel is the upcoming LEV III and Tier 3 emission standards which will require significant reductions in hydrocarbon (HC) and oxides of nitrogen (NOx) emissions. The challenge stems from the fact that diesel exhaust temperatures are much lower than gasoline engines, so the time required to achieve effective emissions control after a cold-start with typical aftertreatment devices is considerably longer. To address this challenge, a novel diesel cold-start emission control strategy was investigated on a 2L class diesel engine. This strategy combines several technologies to reduce tailpipe HC and NOx emissions before the start of the second hill of the FTP75. The technologies include both engine tuning and aftertreatment changes.

The diesel engine can be an effective solution to meet future greenhouse gas and fuel economy standards, especially for larger segment vehicles. However, a key challenge facing the diesel is the upcoming LEV III emissions standard which will require significant reductions of hydrocarbon (HC) and oxides of nitrogen (NOx) from current levels. The challenge stems from the fact that diesel exhaust temperatures are much lower than gasoline engines so the time required to achieve effective emissions control with current aftertreatment devices is considerably longer. The objective of this study was to determine the potential of a novel diesel cold-start emissions control strategy for achieving LEV III emissions. The strategy combines several technologies to reduce HC and NOx emissions before the start of the second hill of the FTP75.

The objective of the work reported in this paper was to develop and demonstrate an injection nozzle which can be used to inject both diesel fuel and methanol in to a direct injection diesel engine. The constraints on the nozzle were that it must provide acceptable fuel metering and atomization for the diesel fuel so that the engine can be operated at rated load on diesel fuel alone, or operate at full load with the diesel fuel as a pilot for the methanol. An additional constraint was that the nozzle design was to be easily adaptable to the existing injection nozzle so that engine head modifications are not required. The initial design was evaluated in a constant volume test chamber in which the pressure was varied from atmospheric to engine compression pressures.

Methods to reduce direct injected diesel engine emissions in the combustion chamber will be discussed in this paper. The following NOx emission reduction technologies will be reviewed: charge air chilling, water injection, and exhaust gas recirculation (EGR). Emphasis will be placed on the development of an EGR system and the effect of EGR on NOx and particulates. The lower limit of NOx that can be obtained using conventional diesel engine combustion will be discussed. Further reductions in NOx may require changing the combustion process from a diffusion flame to a homogeneous charge combustion system.

Alternative combustion crossing stoichiometric air fuel ratio was investigated to utilize a 4-way catalyst system with LNT (lean NOx trap). The chemical mechanism of restricting soot formation reactions with low combustion temperature was combined with the physical mechanism of reducing smoke by lowering local equivalence ratio to enable low smoke rich and near rich combustion. A new combustion chamber for spatially and timely mixture formation phasing was developed to combine the two mechanisms and allow smooth EGR changing over a wide load range. Through this investigation, rich and near rich combustion to effectively utilize a 4-way catalyst system was realized. In addition, conditions suitable for LNT sulfur regeneration were realized from light to medium load.

A new diesel engine system adopting alternative combustion with rich and near rich combustion, and an airflow-dominant control system for precise combustion control was used with a 4-way catalyst system with LNT (lean NOx trap) to achieve Tier II Bin 5 on a 2.2L TDI diesel engine. The study included catalyst temperature control, NOx regeneration, desulfation, and PM oxidation with and without post injection. Using a mass-produced lean burn gasoline LNT with 60,000 mile equivalent aging, compliance to Tier II Bin 5 emissions was confirmed for the US06 and FTP75 test cycles with low NVH, minor fuel penalty and smooth transient operation.

An airflow-dominant control system was developed to provide precise engine and exhaust treatment control with low air fuel ratio alternative combustion. The main elements of the control logic include a real-time state observer for in-cylinder oxygen mass estimation, a simplified packaging scheme for all air-handling and fueling parameters, a finite state machine for control mode switching, combustion control models to maintain robust alternative combustion during transients, and smooth rich/lean switching during lean NOx trap (LNT) regeneration without post injection. The control logic was evaluated on a passenger car equipped with a 4-way catalyst system with LNT and was instrumental in achieving US Tier II Bin 5 emission targets with good drivability and low NVH.

During the 1980's, vegetable oils, microemulsions containing fatty alcohols as surfactants, and fatty esters have been extensively investigaed as alternative fuels to #2 diesel fuel (DF-2) used in farm tractors. Despite the importance of vegetable oils (mainly triglycerides) and fatty derivatives to the alternative fuel program, cetane numbers for pure triglycerides and many fatty derivatives were not reported. In the current study, estimated cetane numbers of these materials have been determined by use of a constant volume combustion bomb. Prior research has shown that this equipment can produce cetane numbers that correlate satisfactorily with engine cetane numbers as determied by ASTM D 613. The influence of chemical structure on ignition delay and cetane number was investigated. Evidence is presented that shows the current cetane number scale is not always suitable for these fatty materials. Suggestions are made as to what might be done to remedy this problem.

The combination of premixed charge compression ignition (PCCI) and conventional DI diesel combustion was studied on a light-duty diesel engine equipped with EGR and a common rail fuel injection system. This combustion mode is referred to as PCCI-DI combustion. The main objectives of the study were to examine the emissions, performance and combustion characteristics of the engine operating under various levels of PCCI-DI combustion to determine if this mode of combustion was a viable in-cylinder NOX emissions reduction strategy. The premixed charge was obtained with early pilot injections (up to three) using a custom engine controller. The engine test conditions were limited to light and medium loads and moderate engine speeds. Engine tests consisted of sweeps of pilot injection timing and quantity, and number of pilot injections.

A technology path has been identified for development of a high efficiency, durable, gasoline engine, targeted at achieving performance and emissions levels necessary to meet heavy-duty, on-road standards of the foreseeable future. Initial experimental and numerical results for the proposed technology concept are presented. This work summarizes internal research efforts conducted at Southwest Research Institute. An alternative combustion system has been numerically and experimentally examined. The engine utilizes gasoline as the fuel, with a combination of enabling technologies to provide high efficiency operation at ultra-low emissions levels. The concept is based upon very highly-dilute combustion of gasoline at high compression ratio and boost levels. Results from the experimental program have demonstrated engine-out NOx emissions of 0.06 g/hp/hr, at single-cylinder brake thermal efficiencies (BTE) above thirty-four percent.

A new combustion concept has been developed and tested for improving the low to moderate load efficiency and NOx emissions of natural gas engines. This concept involves operation of a dual-fuel natural gas engine on Homogeneous Charge Compression Ignition (HCCI) in the load regime of idle up to 35 % of the peak torque. A dual-fuel approach is used to control the combustion phasing of the engine during HCCI operation, and conventional spark-ignited natural gas combustion is used for the high-load regime. This concept has resulted in an engine with power output and high-load fuel efficiency that are unchanged from the base engine, but with a 10 - 15 % improvement to the low to moderate load fuel efficiency. In addition, the engine-out NOx emissions during HCCI operation are over 90% lower than on spark-ignited natural gas operation over the equivalent load range.

This paper reports on the fourth part of a continued study on further research and development with the automated Ignition Quality Tester (IQT™). Research over the past six years (reported in SAE papers #961182, 971636 and 1999-01-3591) has demonstrated the capabilities of this automated apparatus to measure the ignition quality and accurately determine a derived cetane number (DCN) for a wide range of middle distillate and non-conventional diesel fuels. The present paper reports on a number of separate investigations supporting these continued studies.

The engine-out emissions and fuel consumption rates for a modern, heavy-duty diesel engine were compared when fueling with a conventional diesel fuel and three water-blend-fuel emulsions. Four different fuels were studied: (1) a conventional diesel fuel, (2) PuriNOx,™ a water-fuel emulsion using the same conventional diesel fuel, but having 20% water by mass, and (3,4) two other formulations of the PuriNOx™ fuel that contained proprietary chemical additives intended to improve combustion efficiency and emissions characteristics. The emissions data were acquired with three different injection-timing strategies using the AVL 8-Mode steady-state test method in a Caterpillar 3176 engine, which had a calibration that met the 1998 nitrogen oxides (NOX) emissions standard.

Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

An experimental investigation of the effects of partial premixed charge compression ignition (PCCI) combustion and EGR temperature was conducted on a Caterpillar C-12 heavy-duty diesel engine (HDDE). The addition of EGR and PCCI combustion resulted in significant NOx reductions over the AVL 8-mode test. The lowest weighted BSNOx achieved was 2.55 g/kW-hr (1.90 g/hp-hr) using cooled EGR and 20% port fuel injection (PFI). This represents a 54% reduction compared to the stock engine. BSHC and BSCO emissions increased by a factor of 8 and 10, respectively, compared to the stock engine. BSFC also increased by 7.7%. In general, BSHC, BSCO, BSPM, and BSFC increased linearly with the amount of port-injected fuel.

Researchers at Southwest Research Institute (SwRI) have been working for the past several years on the fundamental and practical aspects of homogeneous charge compression ignition (HCCI) operation of reciprocating engines. Much of the work has focused on the use of diesel fuel. The work at SwRI has, however, demonstrated that there are fundamental limitations on the use of current diesel fuels in HCCI engines. The results of engine and constant volume combustion bomb experiments are presented and discussed. The engine experiments were used to identify important fuel properties that must be included in a fuel specification for HCCI fuels. The primary properties relate to the distillation characteristics and the ignition characteristics. The engine test provided preliminary guidance on the distillation requirements and an indication of the important ignition requirements.

Twelve different hole shapes for diesel injector tips were characterized with DF-2 diesel fuel for spray cone angle over a range of injection pressures from 21 MPa (3 kpsi) to 69 MPa (10 kpsi). A baseline and two of the most radical designs were also tested for drop-size distribution and liquid volume fraction (liquid fuel-air ratio) over a range of pressures from 41 MPa (6 kpsi) to 103 MPa (15 kpsi). All hole shapes were circular in cross-section with minimum diameters of 0.4 mm (0.016 in.), and included converging and diverging hole shapes. Overall hole lengths were constant at 2.5 mm (0.098 in.), for an L/d of 6.2. However, the effective L/d may have been less for some of the convergent and divergent shapes.

In-cylinder control of particulate emissions in a diesel engine depends on careful control and understanding of the fuel injection and air/fuel mixing process. It is extremely difficult to measure physical parameters of the injection and mixing process in an operating engine, but it is possible to simulate some diesel combustion chamber conditions in a steady flow configuration whose characteristics can be more easily probed. This program created a steady flow environment in which air-flow and injection sprays were characterized under non-combusting conditions, and emissions measurements were made under combusting conditions. A limited test matrix was completed in which the following observations were made. Grid-generated air turbulence decreased particulates, CO, and unburned hydrocarbons, while CO2 and NOx levels were increased. The turbulence accelerated combustion, resulting in more complete combustion and higher temperatures at the measurement location.

Vegetable oils are candidates for alternative fuels in diesel engines. These oils, such as soybean, sunflower, rapeseed, cottonseed, and peanut, consist of various triglycerides. The chemistry of the degradation of vegetable oils when used as alternate diesel fuels thus corresponds to that of triglycerides. To study the chemistry occurring during the precombustion phase of a vegetable oil injected into a diesel engine, a reactor simulating a diesel engine was constructed. Pure triglycerides were injected into the reactor in order to determine differences in the precombustion behavior of the various triglycerides. The reactor allowed motion pictures to be prepared of the injection event as the important reaction parameters, such as pressure, temperature, and atmosphere were varied. Furthermore, samples of the degradation products of precombusted triglycerides were collected and analyzed (gas chromatography / mass spectrometry).

For the US market, an abundant supply of natural gas (NG) coupled with recent green-house gas (GHG) regulations have spurred renewed interest in dual-fuel combustion regimes. This paper explores the potential of co-direct injection to improve the efficiency and reduce the methane emissions versus equivalent fumigated dual-fuel combustion systems. Using the Westport HPDI engine as the experimental test platform, the paper reports the results obtained using both diffusion controlled (HPDI) combustion strategy as well as a partially-premixed combustion strategy (DI2). The DI2 combustion strategy shows good promise, as it has been found to improve the engine efficiency by over two brake thermal efficiency (BTE) points (% fuel energy) compared to the diffusion controlled combustion strategy (HPDI) while at the same time reducing the engine-out methane emissions by 75% compared to an equivalent fumigated dual-fuel combustion system.