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Ammonia adsorption on the catalyst surface is a crucial step in the selective catalytic reduction of nitrogen oxides over zeolites with NH3 as the reducing agent. In this study, two small pore zeolites with chabazite frameworks, H-SSZ-13 and Cu exchanged SSZ-13, are examined. Adsorption of NH3 on the zeolite causes changing electrical properties of the material. They can be detected by a radio frequency based technique. We have found that with this method it is possible to determine the amount of adsorbed NH3 on these catalysts, examining both the influences of temperature and NH3/NO feed gas ratio. At constant temperature, a fairly linear correlation between the resonance frequency and the amount of adsorbed ammonia was observed. Furthermore, this method also allows differentiation between some of the NH3 adsorption sites.

The integrity of the exhaust emission system in a passenger vehicle can best be maintained by monitoring its performance continuously on board the vehicle. It is with the intent of monitoring emission system performance that the California Air Resources Board has proposed regulations which will require vehicles to be equipped with on-board monitoring systems. These proposed regulations are known as OBDII and will probably be followed by similar Federal EPA regulations.This paper discusses a method of monitoring engine misfire as part of the OBDII requirements for passenger vehicle on-board diagnostics. The method is relatively inexpensive in that it uses an existing sensor for measuring instantaneous crankshaft angular position, and utilizes electronic signal processing which can be implemented in relatively inexpensive custom integrated circuits.

Traditionally in the United States, Diesel engines have negative connotations, primarily due to their association with heavy duty trucks, which are wrongly characterized as “dirty.” Diesel engines are more energy efficient and produce less carbon dioxide than gasoline engines, but their particulate and NOx emissions are more difficult to reduce than spark ignition engines. To tackle this problem, a number of after-treatment technologies are available, such as Diesel Lean NOx Traps (LNTs)), which reduces oxides of nitrogen, and the Diesel particulate filter (DPF), which reduces particulate matter. Sophisticated control techniques are at the heart of these technologies, thus making Diesel engines run cleaner. Another potentially unattractive aspect of Diesel engines is noise.

Urea selective catalytic reduction (SCR) catalysts have the capability to deliver the high NOx conversion efficiencies required for future emission standards. However, the potential for the occasional over-temperature can lead to the irreversible deactivation of the SCR catalyst. On-board diagnostics (OBD) compliance requires monitoring of the SCR function to make sure it is operating properly. Initially, SCR catalyst performance metrics such as NOx conversion, NH3 oxidation, NH3 storage capacity, and BET surface area are within normal limits. However, these features degrade with high temperature aging. In this work, a laboratory flow reactor was utilized to determine the impact on these performance metrics as a function of aging condition. Upon the completion of a full time-at-temperature durability study, four performance criteria were established to help determine a likely SCR failure.

This year, in the third year of FutureTruck competition, the Ohio State University team has taken the challenge to convert a 2002 Ford Explorer into a more fuel efficient and environmentally friendly SUV. This goal was achieved by use of a post-transmission, charge sustaining, parallel hybrid diesel-electric drivetrain. The main power source is a 2.5-liter, 103 kW advanced CIDI engine manufactured by VM Motori. A 55 kW Ecostar AC induction electric motor provides the supplemental power. The powertrain is managed by a state of the art supervisory control system which optimizes powertrain characteristics using advanced energy management and emission control algorithms. A unique driver interface implementing advanced telematics, and an interior designed specifically to reduce weight and be more environmentally friendly add to the utility of the vehicle as well as the consumer appeal.

Over the past decade urea-based selective catalytic reduction (SCR) has become a leading aftertreatment solution to meet increasingly stringent Nitrogen oxide (NOx) emissions requirements in diesel powertrains. A common trend seen in modern SCR systems is the use of "split-brick" configurations where two SCR catalysts are placed in thermally distinct regions of the aftertreatment. One catalyst is close-coupled to the engine for fast light-off and another catalyst is positioned under-floor to improve performance at high space velocities. Typically, a single injector is located upstream of the first catalyst to provide the reductant necessary for efficient NOx reduction. This paper explores the potential benefit, in terms of improved NOx reduction, control of NH3 slip or reduced reductant consumption, of having independently actuated injectors in front of each catalyst.

Many excellent papers have been written about the subject of estimating engine-out NOx on diesel engines based on real-time available data. The claimed accuracy of these models is typically around 6-10% on validation data sets with known inputs. This reported accuracy typically ignores input uncertainties, thus arriving at an optimistic estimate of the model accuracy in a real-time application. In our paper we analyze the effect of input uncertainty on the accuracy of engine-out NOx estimates via a numerical Monte Carlo simulation and show that this effect can be significant. Even though our model is based on an in-cylinder pressure sensor, this sensor is limited in its capability to reduce the effect of other measured inputs on the model.

Fault diagnosis for automotive systems is driven by government regulations, vehicle repairability, and customer satisfaction. Several methods have been developed to detect and isolate faults in automotive systems, subsystems and components with special emphasis on those faults that affect the exhaust gas emission levels. Limit checks, model-based, and knowledge-based methods are applied for diagnosing malfunctions in emission control systems. Incipient and partial faults may be hard to detect when using a detection scheme that implements any of the previously mentioned methods individually; the integration of model-based and knowledge-based diagnostic methods may provide a more robust approach. In the present paper, use is made of fuzzy residual evaluation and of a fuzzy expert system to improve the performance of a fault detection method based on a mathematical model of the engine.

A study, for future applications, of a model-based Idle Speed Control (ISC) system for the L535 Lamborghini 6.2L-48 valve V12 gasoline engine is presented in this paper. Main features of the controller are: Real-time auto-adaptation; Synchronization of Throttle Angle (TA) opening with Spark Advance (SA) timing, through model-based Drive-by-Wire (DBW) control strategies; Auto-adaptive management of the absolute pressure levels in the two, completely separated, intake manifolds; Feed-forward compensation for known loads; Integrated Air-to-Fuel Ratio (AFR) control at idle. Design targets are: Idle speed error from the nominal value imperceptible by the driver, considering that this study is for a high performance engine; Emissions reduction; Minimization of the engine speed undershoot (overshoot) when applying (removing) unknown loads.

Ensuring the reliable operation of the emissions control system is a critical factor in complying with increasingly stringent exhaust emissions standards. In spite of significant advances, the performance of available diagnostic and test equipment is still amenable to further improvement, especially as it pertains to the diagnosis of incipient and intermittent faults. This paper presents experimental results pertaining to the diagnosis of complete, partial and intermittent faults in various components of the engine emissions control system. The instrumentation used in the study permitted simultaneous and essentially continuous analysis of the exhaust gases and of engine variables. Tests were conducted using a section of the EPA urban driving cycle (I/M 240), simulated by means of a throttle/dynamometer controller.

Legislation pertaining to automobile emissions has caused an increased focus on the cold-start performance of internal combustion engines. Of particular concern is the period of time before all available sensors become active. Present engine control strategies must rely on methods other than feedback control while these sensors are not active. Without feedback control during this critical period, engine emissions performance is not optimized. These conditions cause difficulty in performing comprehensive cold-start experiments. For these reasons, we have developed several methods for feedback control during cold-start to aid in laboratory investigations of engine emissions phenomena.

One of the gray areas in the implementation of regulations limiting the generation of pollutants from mobile sources is the actual effectiveness of the exhaust gas emissions control strategy in vehicles that have been in use for some time. While it is possible today to conduct limited diagnostics with the on-board engine computer by performing periodic checks to verify the validity of the signals measured by the on-board sensors, and to measure tailpipe emissions during routine inspection and maintenance, the task of correlating these measurements with each other to provide an on-line, accurate diagnosis of critical malfunctions has thus far proven to be a very challenging task, especially in the case of misfire.

A number of automotive diagnostic equipment and procedures have evolved over the last two decades, leading to two generations of on-board diagnostic requirements (OBDI and OBDII), increasing the number of components and systems to be monitored by the diagnostic tools. The goal of On-Board Diagnostic is to alert the driver to the presence of a malfunction of the emission control system, and to identify the location of the problem in order to assist mechanics in properly performing repairs. The aim of this paper is to suggest a methodology for the development of an Integrated Powertrain Diagnostic System (EPDS) that can combine the information supplied by conventional tailpipe inspection programs with onboard diagnostics to provide fast and reliable diagnosis of malfunctions.

This paper presents a method for air/fuel ratio control using combustion pressure feedback during cold start to be used as an aid in laboratory experiments. The effects of varying air/fuel ratio during cold start are so profound that small differences in air/fuel ratio can create effects that will mask the effects of significant changes in other variables. The ability to control air/fuel ratio is an important aid in comprehensive emission studies during cold start. This work will facilitate future studies of cold start emissions.

The aim of this paper is to document a three year process of product development of the Formula Lightningtm electric race car constructed at the Ohio State University. Today interest in electric vehicles (EV's) is growing, due to the technological advances in recent years, but also in part due to recent legislation which mandates the introduction of ‘zero emission vehicles’ in California before the end of the century. The definition of ‘zero emission vehicle’ is: a vehicle which does not emit any pollutants during operation. Technologically, the only near term vehicle which meets this definition is an EV. One of the most difficult problems of electric racing is that the usable energy in a given set of batteries is not as easily determined as the amount of fuel in a tank. Also, the motor controllers may limit power output as battery voltage drops, further decreasing the amount of usable energy in a battery set.

The evolution of the diagnostic equipment for automotive application is the direct effect of the implementation of sophisticated and high technology control systems in the new generation of passenger cars. One of the most challenging issues in automotive diagnostics is the ability to assess, to analyze, and to integrate all the information and data supplied by the vehicle's on-board computer. The data available might be in the form of fault codes or sensors and actuators voltages. Moreover, as environmental regulations get more stringent, knowledge of the concentration of different species emitted from the tailpipe during the inspection and maintenance programs can become of great importance for an integrated powertrain diagnostic system. A knowledge-based diagnostic tool is one of the approaches that can be adopted to carry out the challenging task of detecting and diagnosing faults related to the emissions control system in an automobile.

In this paper, the detection and isolation of actuator faults (both measured and commanded) occurring in the engine breathing and the fueling systems of a spark-ignition direct-injection (SIDI) engine are described. The breathing system in an SIDI engine usually consists of a fresh air induction path via an electronically controlled throttle (ECT) and an exhaust gas recirculation (EGR) path via an EGR valve. They are dynamically coupled through the intake manifold to form a gas mixture, which eventually enters the engine cylinders for a subsequent combustion process. Meanwhile, the fueling system is equipped with a high-pressure common-rail injection for a precise control of the fuel quantity directly injected into the engine cylinders. Since the coupled system is highly nonlinear in nature, the fault diagnosis will be performed by generating residuals based on multiple nonlinear observers.

Due to the stringent emission regulations, On-Board Diagnostics II (OBD II) and the requirement of enhanced evaporative emissions test procedure, an aggressive canister purge control strategy is required for automotive vehicles. The enhanced evaporative emissions test procedure has forced car manufacturer to purge the carbon canister in the vehicle idle condition so that production vehicles meet the SHED and hot soak test requirements. This not only worsens the idle speed quality but also tends to increase exhaust emission levels. Using analytical models of evaporative air and fuel, feed-forward control strategy for both idle by-pass air and air to fuel ratio can be improved. This paper demonstrates an application of evaporative system modeling to the idle air and air to fuel ratio control.

Electrically assisted turbochargers are a promising technology for improving boost response of turbocharged engines. These systems include a turbocharger shaft mounted electric motor/generator. In the assist mode, electrical energy is applied to the turbocharger shaft via the motor function, while in the regenerative mode energy can be extracted from the shaft via the generator function, hence these systems are also referred to as regenerative electrically assisted turbochargers (REAT). REAT allows simultaneous improvement of boost response and fuel economy of boosted engines. This is achieved by optimally scheduling the electrical assist and regeneration actions. REAT also allows the exhaust turbine to operate within a narrow range of optimal vane positions relative to the unassisted variable geometry turbocharger (VGT). The ability to operate within a narrow range of VGT vane positions allows an opportunity for a more optimal turbine design for a REAT system.

The availability of connectivity and autonomy enabled resources, within the automotive sector, has primarily been considered for driver assist technologies and for extending the levels of vehicle autonomy. It is not a stretch to imagine that the additional information, available from connectivity and autonomy, may also be useful in further improving powertrain functions. Critical powertrain subsystems that must operate with limited or uncertain knowledge of their environment stand to benefit from such new information sources. Unfortunately, the adoption of this new information resource has been slow within the powertrain community and has typically been limited to the obvious problem choices such as battery charge management for electric vehicles and efforts related to fuel economy benefits from adaptive/coordinated cruise control. In this paper we discuss the application of connectivity resources in the management of an aftertreatment sub-system, the Diesel Particulate Filter (DPF).