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In order to detect degradation of engine oil lubricant, bench testing along with a number of diesel-powered Ford trucks were instruments and tested. The purpose of the bench testing was primarily to determine performance aspects such as repeatability, hysteresis effects and so on. Vehicle testing was conducted by designing and installing a separate oil reservoir along with a circulation system which was mounted in the vicinity of the oil pan. An innovative oil sensor was directly installed on the reservoir which can measure five (5) independent oil parameters (viscosity, density, permittivity, conductance, temperature). In addition, the concept is capable of detecting the oil level continuously during normal engine operation. The sensing system consists of an ultrasonic transducer for the oil level detection as well as a Tuning Fork mechanical resonator for the oil condition measurement.

This work intends to present a study about the application of a standard methodology for the evaluation of the mechanical components compromise as result of the use of biodiesel, based on the lubricating oil analyses. The fuel oil that will be analyzed is produced in PUCRS' Faculty of Chemistry. As we know, the physical-chemical analysis of lubricating oils can indicate a series of parameters that allow valuing the quality and the compromising degree of the mechanical engine components. The results of these analyses will be based on tests in an Electronic Microscopy. This type of analysis will allow us to determine the quality of the lubricating oil, degradation and contamination with metal materials (mechanical compromising). The work presupposes the functioning of Diesel engine cycle with several proportions of biodiesel (B2, B5, B10, B20 and B100).

A diesel particulate filter (DPF) controls and maintains a constant pressure drop across the filter by repeating the regeneration process for PM (Particulate Matter). However, the regeneration results in ash accumulation on the DPF. Although this ash accumulation is very slow, it eventually causes increased pressure drop which affects the product life of the DPF. Metal elements in the lubricant additives in the engine oil are the source of the ash. Since ash is an oxidized substance, the amount of ash produced depends on such factors as the amount of oil consumed in the engine and the kinds of lubricant additives contained in engine oil. According to the reference literature [1-3], ash accumulates on a DPF differently depending on use of either a passive regeneration system or an active regeneration system. With the passive regeneration system, ash accumulates uniformly on the filter wall while ash accumulates near the outlet of the filter with the active regeneration system.

This paper reports on a field test with 23 Volvo D12C non-exhaust gas recirculation diesel engines using the Diesel Particulate Filter (DPF), Selective Catalytic Reduction (SCR), and urea system with Ultra-Low-Sulfur-Diesel (ULSD). This combination will be used to meet the on-highway emission standards for U.S. 2010, Japan 2010, and Europe 2013. Because of future widespread use of DPF-SCR, this study reports on our field experience with this system, and focuses on enhancing our understanding of the incombustible materials which are collected in the DPF with API CJ-4 and API CI-4 PLUS oils. The average weight of incombustibles was lower in the trucks using API CJ-4 oils at 1.0% sulfated ash, than in those using API CI-4 PLUS oils at 1.4% sulfated ash. The difference in weight between the two groups was highly significant. Further, the weight of the incombustibles per kilometer substantially decreased with each subsequent cleaning within a truck.

Diesel engine ash emissions are composed of the non-combustible portions of diesel particulate matter derived mainly from lube oil, and over time can degrade diesel particulate filter performance. This paper presents results from a high temperature oxidation method (HTOM) used to estimate ash emissions, and engine oil consumption in real-time. Atomized lubrication oil and diesel engine exhaust were used to evaluate the HTOM performance. Atomized fresh and used lube oil experiments showed that the HTOM reached stable particle size distributions and concentrations at temperatures above 700°C. The HTOM produced very similar number and volume weighted particle size distributions for both types of lube oils. The particle number size distribution was unimodal, with a geometric mean diameter of about 23 nm. The volume size distribution had a geometric volume mean diameter of about 65 nm.

The removal of soot in the lubricating sumps of diesel engines is a formidable task, further compounded by the introduction of Exhaust Gas Recirculation (EGR). Efficient removal of soot would help ensure engine durability and engine performance while increasing oil drain intervals thus reducing maintenance costs. This paper describes a method by which soot can be separated from the oil with the application of an electric field by utilizing the small electrical charge on the soot particles. The electric field is applied to a network of electrodes that support an open porous network which stabilizes the weakly bound soot cake. Significantly higher filtration efficiency was achieved as compared to mechanical particulate filtration and centrifugation. The paper also discusses the controlling conditions while detailing the performance testing at both a bench scale level and pilot scale level.

The US Army is currently assessing the feasibility and defining the requirements of a Single Common Powertrain Lubricant (SCPL). This new lubricant would consist of an all-season (arctic to desert), fuel-efficient, multifunctional powertrain fluid with extended drain capabilities. As a developmental starting point, diesel engine testing has been conducted using the current MIL-PRF-46167D arctic engine oil at high temperature conditions representative of desert operation. Testing has been completed using three high density military engines: the General Engine Products 6.5L(T) engine, the Caterpillar C7, and the Detroit Diesel Series 60. Tests were conducted following two standard military testing cycles; the 210 hr Tactical Wheeled Vehicle Cycle, and the 400 hr NATO Hardware Endurance Cycle. Modifications were made to both testing procedures to more closely replicate the operation of the engine in desert-like conditions.

Initial results are presented for the production of hydrogen from waste lubricating oil using a chemical looping reforming (CLR) process. The development of flexible and sustainable sources of hydrogen will be required to facilitate a "hydrogen economy." The novel CLR process presented in this paper has an advantage over hydrogen production from conventional steam reforming because CLR can use complex, low value, waste oils. Also, because the process is scalable to small and medium size, hydrogen can be produced close to where it is required, minimizing transport costs. Waste lubricating oil typically contains 13-14% weight of hydrogen, which through the steam reforming process could produce a syngas containing around 75 vol% H₂, representing over 40 wt% of the fuel. The waste oil was converted to a hydrogen-rich syngas in a packed bed reactor, using a Ni/ Al₂O₃ catalyst as the oxygen transfer material (OTM).

Wet clutches are important components used in the transmission and drive trains of many modern vehicles. The clutches transfer torque via the friction between a number of friction discs and the friction characteristics is therefore of great importance for the overall behavior of the vehicles. The friction characteristics is governed by a number of parameters such as lubricant base oil and additives, type and permeability of the friction material and temperature and surface roughness of the interacting surfaces. The permeability is considered to influence time of engagement and supply the sliding interface with lubricant and additives during engagement. In this work, a permeability measurement method suitable for wet clutch friction materials is thus used to measure the permeability of friction materials of different types; sintered bronze and paper based materials.

In 2005, the growing emphasis on fuel efficiency coupled with the long-recognized negative effects of viscous friction caused by engine hydrodynamic lubrication, led to considerations of the benefits of lower viscosity engine oils by the SAE Engine Oil Viscosity Classification (EOVC) Task Force. More recently these considerations were given further impetus by OEM enquiry regarding modification of the SAE Viscosity Classification System to include oils of lower viscosity specification than that of SAE 20. For the EOVC Task Force, such considerations of commercially available, significantly lower viscosity engine oils, also produced a need to reassess the precision of high shear rate viscometry of such engine oils as presently practiced at 150°C - as well as interest in temperatures such as 100° and 120°C believed more representative of engine operating conditions.

The global use of biodiesel fuel blends derived from fatty acid methyl esters (FAME) is increasing; driven by legislation derived from political, economic and environmental factors. The presence of FAME biodiesel changes the operating environment of the engine and after treatment devices, affecting the performance characteristics and requirements of the lubricant. As part of a wider research project into the impact of biologically-sourced fuels on crankcase lubricant performance, this paper documents the impact of biodiesel on corrosion-related performance. The effect of FAME biodiesel on lubricant corrosion control and the differences in performance due to FAME source are described. Mechanistic studies into the corrosive nature of FAME are reported. Novel lubricant technologies tailored to control the negative impact of FAME in the crankcase are demonstrated.

Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

Ash, primarily derived from diesel engine lubricants, accumulates in diesel particulate filters directly affecting the filter's pressure drop sensitivity to soot accumulation, thus impacting regeneration frequency and fuel economy. After approximately 33,000 miles of equivalent on-road aging, ash comprises more than half of the material accumulated in a typical cordierite filter. Ash accumulation reduces the effective filtration area, resulting in higher local soot loads toward the front of the filter. At a typical ash cleaning interval of 150,000 miles, ash more than doubles the filter's pressure drop sensitivity to soot, in addition to raising the pressure drop level itself. In order to evaluate the effects of lubricant-derived ash on DPF pressure drop performance, a novel accelerated ash loading system was employed to generate the ash and load the DPFs under carefully-controlled exhaust conditions.

Ash accumulation in diesel particulate filters, mostly from essential lubricant additives, decreases the filter's soot storage capacity, adversely affects fuel economy, and negatively impacts the filter's service life. While the adverse effects of ash accumulation on DPF performance are well known, the underlying mechanisms controlling these effects are not. To address these issues, results of detailed measurements with specially formulated lubricants, correlating ash properties to individual lubricant additives and their effects on DPF pressure drop, are presented. Investigations using the specially-formulated lubricants showed ash consisting primarily of calcium sulfates to exhibit significantly increased flow resistance as opposed to ash primarily composed of zinc phosphates. Furthermore, ash accumulated along the filer walls was found to be packed approximately 25% denser than ash accumulated in the channel end-plugs.

Partly competing objectives, as low fuel consumption, low friction, long oil maintenance rate, and at the same time lowest exhaust emissions have to be fulfilled. Diminishing resources, continuously reduced development periods, and shortened product cycles yield detailed knowledge about oil consumption mechanisms in combustion engines to be essential. There are different ways for the lubricating oil to enter the combustion chamber: for example as blow-by gas, leakage past valve stem seals, piston rings (reverse blow-by) and evaporation from the cylinder liner wall and the combustion chamber. For a further reduction of oil consumption the investigation of these mechanisms has become more and more important. In this paper the influence of the mixture formation and the resulting fuel content in the cylinder liner wall film on the lubricant oil emission was examined.

The purpose of this work is to describe a technique that is capable of determining the induction system deposits (ISD) tendencies of gasoline, applying the ISD apparatus developed at Southwest Research Institute (SwRI®). The results showed that temperature, fuel quality, and presence or absence of lubricant oil in the sample affect the quantity and the characteristic of the deposits. Engine tests, done in a Fiat 1.4 tetra fuel engine, were carried out in order to verify the intake valve deposits (IVDs). Another bench technique, the Intake Valve Deposits Apparatus (IVDA) proposed by SwRI®, was also evaluated. It was observed that the results obtained with ISD have qualitative similarity with the trend observed for the results in the engine and in the IVDA tests. So, it can be concluded that bench-scale tests are a promising alternative to make a first screening of the gasoline samples prior to the engine tests.

Amount and size distribution of wear particles in engine lubricating oil are indicators of the current machine condition. A change in size distribution, especially a rise in the amount of larger particles, often indicates a starting wear of some machine parts. Monitoring wear particles contained in lubricating oil during normal machine operation can help to identify the need for maintenance and more important to prevent sudden failure of the machine. An optical method is used to image a thin layer of oil to count and classify contained particles. Therefore, a continuous flow of undiluted oil from the oil circuit of the machine is pumped through the measurement instrument. Inside the instrument, the oil flow is directed through a thin transparent flow cell. Images are taken using a bright LED flashlight source, a magnification lens, and a digital camera. Algorithms have been developed to process and analyze the images.

Global warming due to exhaust pollution and rapid depletion of petroleum reserves, has given us opportunity to find bio fuels. Bio diesel is an alternative diesel fuel that can be produced from renewable feedstock such as edible and non-edible vegetable oils, wasted frying oils and animal fats. Bio diesel is an oxygenated, sulphur free, non-toxic, biogradable and renewable fuel. Use of karanja oil methyl ester (KOME) biodiesel in a compression ignition engine was found highly compatible with engine performance along with low emission characteristics. A Military 780 hp, CIDI engine was operated using biodiesel (KOME) and diesel fuel respectively. These were subjected to 100 hours long term endurance tests. Lubricating oil samples drawn from engine after a fixed interval (20 hours), were subjected to elemental analysis. Metal debris concentration analysis was done by atomic absorption spectroscopy. Wear of metals were found to be about 30% lower for biodiesel operated engine.

The aim of this study was to synthesize environmentally adapted Trimethylolpropane (TMP) esters from cottonseed and soybean oils and to examine their quality parameters and tribological properties as potential lubricant basestocks. A two stage production process was followed. At first the above mentioned vegetable oils were transformed to the corresponding methyl esters via methanolysis in the presence of sodium methoxide. The desired TMP esters were finally synthesized by alkaline transesterification of the previously produced methylesters with TMP using sodium methoxide as catalyst. Following the purification phase the physicochemical characteristics of the synthesized TMP esters were examined. The tribological properties were evaluated by employing a Four-Ball apparatus. An additive-free mineral oil base oil was used as a reference lubricating fluid.

With the current use of bio-renewable fuel, the application of Ethanol in Flex-Fuel vehicles presents a very low CO2 emission alternative when the complete cycle, from plantation, fuel production, till vehicle use, is considered. In Brazil more than 80% of the car production is composed of Flex-Fuel vehicles. Due to the lower heating content of the Ethanol, more aggressive combustion calibrations are used to obtain the same engine power than when burning gasoline. Such Ethanol demands, associated with the continuous increase of engine specific power has lead to thermo-mechanical loads which challenges the tribology of piston rings. The ethanol use brings also some specific tribological differences not very well understood like fuel dilution in the lube oil, especially on cold start, corrosive environment etc. Under specific driving conditions, incipient failures like spalling on nitrided steel top rings have been observed.