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Journal Article

Review of Prior Studies of Fuel Effects on Vehicle Emissions

2009-04-20
2009-01-1181
A literature review was conducted to survey recent research on the effects of fuel properties on exhaust emissions from gasoline and diesel vehicles, on-road and off-road. Most of the literature has been published in SAE papers, although data have also been reported in other journals and government reports. A full report and database are available from the Coordinating Research Council (www.crcao.org). The review identified areas of agreement and disagreement in the literature and evaluated the adequacy of experimental design and analysis of results. Areas where additional research would be helpful in defining fuel effects are also identified. In many of the research programs carried out to evaluate the effect of new blendstocks, the fuel components were splash blended in fully formulated fuels. This approach makes it extremely difficult to determine the exact cause of the emissions benefit or debit.
Journal Article

Experimental Investigation of Intake Condition and Group-Hole Nozzle Effects on Fuel Economy and Combustion Noise for Stoichiometric Diesel Combustion in an HSDI Diesel Engine

2009-04-20
2009-01-1123
The goal of this research is to investigate the physical parameters of stoichiometric operation of a diesel engine under a light load operating condition (6∼7 bar IMEP). This paper focuses on improving the fuel efficiency of stoichiometric operation, for which a fuel consumption penalty relative to standard diesel combustion was found to be 7% from a previous study. The objective is to keep NOx and soot emissions at reasonable levels such that a 3-way catalyst and DPF can be used in an aftertreatment combination to meet 2010 emissions regulation. The effects of intake conditions and the use of group-hole injector nozzles (GHN) on fuel consumption of stoichiometric diesel operation were investigated. Throttled intake conditions exhibited about a 30% fuel penalty compared to the best fuel economy case of high boost/EGR intake conditions. The higher CO emissions of throttled intake cases lead to the poor fuel economy.
Journal Article

Efficacy of EGR and Boost in Single-Injection Enabled Low Temperature Combustion

2009-04-20
2009-01-1126
Exhaust gas recirculation, fuel injection strategy and boost pressure are among the key enablers to attain low NOx and soot emissions simultaneously on modern diesel engines. In this work, the individual influence of these parameters on the emissions are investigated independently for engine loads up to 8 bar IMEP. A single-shot fuel injection strategy has been deployed to push the diesel cycle into low temperature combustion with EGR. The results indicated that NOx was a stronger respondent to injection pressure levels than to boost when the EGR ratio is relatively low. However, when the EGR level was sufficiently high, the NOx was virtually grounded and the effect of boost or injection pressure becomes irrelevant. Further tests indicated that a higher injection pressure lowered soot emissions across the EGR sweeps while the effect of boost on the soot reduction appeared significant only at higher soot levels.
Journal Article

Benefits and Drawbacks of Compression Ratio Reduction in PCCI Combustion Application in an Advanced LD Diesel Engine

2009-04-20
2009-01-1447
The present paper describes an experimental study on the effect of the compression ratio on the performance of a LD diesel engine operating with a PCCI calibration, near the estimated EURO 6/Tier2 Bin5 NOx emission limits. The research activity is the result of a collaborative project between Istituto Motori and Centro Ricerche Fiat aimed to carry out an exhaustive analysis of the compression ratio (CR) influence on the performance of a LD diesel engine. Starting from a reference engine configuration the CR was reduced in two steps sequentially. Each CR value was characterized under PCCI operation mode and, under conventional diesel operating mode, at maximum torque. The exploration of the PCCI application in the NEDC operating area was performed prefixing limits on maximum fuel consumption, maximum pressure rise and maximum tolerable smoke. The main result was that no significant increment in PCCI application area reducing the CR was possible without overcoming the limits.
Journal Article

Modeling the Cold Start of the Ford 3.5L V6 EcoBoost Engine

2009-04-20
2009-01-1493
Optimization of the engine cold start is critical for gasoline direct injection (GDI) engines to meet increasingly stringent emission regulations, since the emissions during the first 20 seconds of the cold start constitute more than 80% of the hydrocarbon (HC) emissions for the entire EPA FTP75 drive cycle. However, Direct Injection Spark Ignition (DISI) engine cold start optimization is very challenging due to the rapidly changing engine speed, cold thermal environment and low cranking fuel pressure. One approach to reduce HC emissions for DISI engines is to adopt retarded spark so that engines generate high heat fluxes for faster catalyst light-off during the cold idle. This approach typically degrades the engine combustion stability and presents additional challenges to the engine cold start. This paper describes a CFD modeling based approach to address these challenges for the Ford 3.5L V6 EcoBoost engine cold start.
Journal Article

Optimal Use of E85 in a Turbocharged Direct Injection Engine

2009-04-20
2009-01-1490
Ford Motor Company is introducing “EcoBoost” gasoline turbocharged direct injection (GTDI) engine technology in the 2010 Lincoln MKS. A logical enhancement of EcoBoost technology is the use of E85 for knock mitigation. The subject of this paper is the optimal use of E85 by using two fuel systems in the same EcoBoost engine: port fuel injection (PFI) of gasoline and direct injection (DI) of E85. Gasoline PFI is used for starting and light-medium load operation, while E85 DI is used only as required during high load operation to avoid knock. Direct injection of E85 (a commercially available blend of ∼85% ethanol and ∼15% gasoline) is extremely effective in suppressing knock, due to ethanol's high inherent octane and its high heat of vaporization, which results in substantial cooling of the charge. As a result, the compression ratio (CR) can be increased and higher boost levels can be used.
Journal Article

Parametric Studies of the Impact of Turbocharging on Gasoline Engine Downsizing

2009-04-20
2009-01-1472
The internal combustion engine and associated powertrain are likely to remain the mainstay of mobility over the next twenty years and to remain a significant portion of the portfolio of technologies employed over a much longer period of time. Efficient combustion of all fuels (petroleum based or alternative) requires copious amounts of air particularly with downsized engines. Turbocharging technology thus becomes an even more critical part of reducing both global warming gas and urban pollutant emissions from IC engines. Gasoline engine downsizing and turbocharging have been shown to improve fuel economy by ∼20% in production vehicles. In addition to data over a wide range of engines/vehicles, the results of a simple analysis done on vehicles/engines/drive cycles are presented to show the benefits of turbocharging and downsizing in a parametric variation of downsizing in combination with other technologies.
Journal Article

Hydrogen in Diesel Exhaust: Effect on Diesel Oxidation Catalyst Flow Reactor Experiments and Model Predictions

2009-04-20
2009-01-1268
Engine operating strategies typically geared towards higher fuel economy and lower NOx widely affect exhaust composition and temperature. These exhaust variables critically drive the performance of After Treatment (AT) components, and hence should guide their screening and selection. Towards this end, the effect of H2 level in diesel exhaust on the performance of a Diesel Oxidation Catalyst (DOC) was studied using flow reactor experiments, vehicle emission measurements and mathematical models. Vehicle chassis dynamometer data showed that exhaust from light-duty and heavy-duty diesel trucks contained very little to almost no H2 (FTP average CO/H2 ∼ 40 to 70) as compared to that of a gasoline car exhaust (FTP average CO/H2 ∼ 3). Two identical flow reactor experiments, one with H2 (at CO/H2 ∼ 3) and another with no H2 in the feed were designed to screen DOCs under simulated feed gas conditions that mimicked these two extremes in the exhaust H2 levels.
Journal Article

A Urea Decomposition Modeling Framework for SCR Systems

2009-04-20
2009-01-1269
Selective catalytic reduction (SCR) is allowing diesel engines to reach NOx emission levels which are unachievable in-cylinder. This technology is still evolving, and new catalyst formulations which provide higher performance and greater durability continue to be developed. Usually, their performance is measured on a flow reactor using ammonia as the reductant. However, in mobile applications a urea-water solution is used instead, and urea decomposition by thermolysis and hydrolysis provides the required ammonia to the catalyst. It is well known that urea decomposition is incomplete by the inlet face of the converter, and this is at least one reason why on-engine performance is generally lower than would be expected from reactor tests. Previous modeling of urea-water droplets has focused on developing detailed sub-models that can be implemented into computational fluid dynamics (CFD) codes.
Journal Article

Modeling the Emissions Control Performance of a Catalyzed Diesel Particulate Filter (CDPF) System for Light Duty Diesel Applications

2009-04-20
2009-01-1266
The use of catalyzed diesel particulate filter (CDPF) systems in light duty diesel (LDD) vehicles is becoming increasingly common. The primary functions of the system are to remove carbon monoxide (CO) and hydrocarbons (HC) from the vehicle exhaust stream, while simultaneously reducing the level of particulate matter (PM) emissions to ambient background levels. These systems can comprise either a separate diesel oxidation catalyst (DOC) and a downstream CDPF, or a single unit CDPF with the DOC functions incorporated within the CDPF. The single CDPF unit provides higher regeneration efficiency as it is located nearer to the engine and also cost benefits, as only a single unit is required compared to the alternative separate DOC and CDPF arrangement. A model describing the performance of the single unit CDPF for emissions control has been developed, with particular emphasis on achieving predictions of the CO and HC emissions over transient vehicle drive cycles.
Journal Article

Cost and Fuel Efficient SCR-only Solution for Post-2010 HD Emission Standards

2009-04-20
2009-01-0915
A promising SCR-only solution is presented to meet post-2010 NOx emission targets for heavy duty applications. The proposed concept is based on an engine from a EURO IV SCR application, which is considered optimal with respect to fuel economy and costs. The addition of advanced SCR after treatment comprising a standard and a close-coupled SCR catalyst offers a feasible emission solution, especially suited for EURO VI. In this paper, results of a simulation study are presented. This study concentrates on optimizing SCR deNOx performance. Simulation results of cold start FTP and WHTC test cycles are presented to demonstrate the potential of the close-coupled SCR concept. Comparison with measured engine out emissions of an EGR engine shows that a close-coupled SCR catalyst potentially has NOx reduction performance as good as EGR. Practical issues regarding the use of an SCR catalyst in close-coupled position will be addressed, as well as engine and exhaust layout.
Journal Article

Evaluation of SCR Catalyst Technology on Diesel Particulate Filters

2009-04-20
2009-01-0910
Selective Catalytic Reduction (SCR) catalysts have been demonstrated as effective for controlling NOx emissions from diesel engines, maintaining high NOx conversion even after the extended high temperature exposure encountered in systems with active filter regenerations. As future diesel emission regulations are expected to be further reduced, packaging a large volume of SCR catalysts in diesel exhaust systems, along with DOC and particulate filter catalysts, will be challenging. One method to reduce the total volume of catalysts in diesel exhaust systems is to combine the SCR and DPF catalysts by coating SCR catalyst technology on particulate filters. In this work, engine evaluation of SCR coated filters has been conducted to determine the viability of the technology. Steady-state engine evaluations demonstrated that high NOx conversions can be achieved for SCR coated filters after high temperature oven aging.
Journal Article

SCR Catalyst Systems Optimized for Lightoff and Steady-State Performance

2009-04-20
2009-01-0901
A laboratory study was performed to optimize a zoned configuration of an iron (Fe) SCR catalyst and a copper (Cu) SCR catalyst in order to provide high NOx conversion at lean A/F ratios over a broad range of temperature for diesel and lean-burn gasoline applications. With an optimized space velocity of 8,300 hr-1, a 67% (by volume) Fe section followed by a 33% Cu section provided at least 80% NOx conversion from approximately 230°C to 640°C when evaluated with 500 ppm NO and NH3. To improve the lean lightoff performance of the SCR catalyst system during a cold start, a Cu SCR catalyst that was 1/4 as long as the rear Cu SCR catalyst was placed in front of the Fe SCR catalyst. When evaluated with an excess of NH3 (NH3/NO ratio of 2.2), the Cu+Fe+Cu SCR system had significantly improved lightoff performance relative to the Fe+Cu SCR system, although the front Cu SCR catalyst did decrease the NOx conversion at temperatures above 475°C by oxidizing some of the NH3 to N2 or NO.
Journal Article

Analysis of Compromising Degree of an Internal Combustion Engine Using Biodiesel

2009-04-20
2009-01-0895
This work intends to present a study about the application of a standard methodology for the evaluation of the mechanical components compromise as result of the use of biodiesel, based on the lubricating oil analyses. The fuel oil that will be analyzed is produced in PUCRS' Faculty of Chemistry. As we know, the physical-chemical analysis of lubricating oils can indicate a series of parameters that allow valuing the quality and the compromising degree of the mechanical engine components. The results of these analyses will be based on tests in an Electronic Microscopy. This type of analysis will allow us to determine the quality of the lubricating oil, degradation and contamination with metal materials (mechanical compromising). The work presupposes the functioning of Diesel engine cycle with several proportions of biodiesel (B2, B5, B10, B20 and B100).
Journal Article

The Poisoning and Desulfation Characteristics of Iron and Copper SCR Catalysts

2009-04-20
2009-01-0900
A laboratory study was performed to assess the effects of SO2 poisoning on the NOx conversion of iron (Fe) and copper (Cu) SCR catalysts. Thermally aged samples of the catalysts were poisoned with SO2 under lean conditions. At various times during the poisonings, the samples were evaluated for NOx conversion with NO and NH3 using lean temperature ramps. The low temperature NOx conversions of both catalysts decreased by 10 to 20% after 1 to 4 hours of poisoning but were stable with continued exposure to the SO2. The poisoned Cu SCR catalyst could be desulfated repeatedly with 5 minutes of lean operation at 600°C. Initially, the poisoned Fe SCR catalyst required 5 minutes of lean operation at 750°C to recover its maximum NOx conversion.
Journal Article

Treatment of Vehicle Emissions from the Combustion of E85 and Gasoline with Catalyzed Hydrocarbon Traps

2009-04-20
2009-01-1080
Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.
Journal Article

Soot Emission Measurements and Validation of a Mean Value Soot Model for Common-Rail Diesel Engines during Transient Operation

2009-06-15
2009-01-1904
Measurements of the soot emissions and engine operating parameters from a diesel engine during transient operation were used to investigate the influence of transient operation on the soot emissions, as well as to validate a realtime mean value soot model (MVSM, [1]) for transient operation. To maximize the temporal resolution of the soot emission and engine parameter measurements (in particular EGR), fast instruments were used and their dynamic responses characterized and corrected. During tip-in transients, an increase in the soot emissions was observed due to a short term oxygen deficit compared to steady-state operation. No significant difference was seen between steady-state and transient operation for acceleration transients. When the MVSM was provided with inputs of sufficient temporal resolution, it was capable of reproducing the qualitative and, in part, quantitative soot emission trends.
Journal Article

Advanced Injection Strategies for Controlling Low-Temperature Diesel Combustion and Emissions

2009-06-15
2009-01-1962
The simultaneous reduction of engine-out nitrogen oxide (NOx) and particulate emissions via low-temperature combustion (LTC) strategies for compression-ignition engines is generally achieved via the use of high levels of exhaust gas recirculation (EGR). High EGR rates not only result in a drastic reduction of combustion temperatures to mitigate thermal NOx formation but also increases the level of pre-mixing thereby limiting particulate (soot) formation. However, highly pre-mixed combustion strategies such as LTC are usually limited at higher loads by excessively high heat release rates leading to unacceptable levels of combustion noise and particulate emissions. Further increasing the level of charge dilution (via EGR) can help to reduce combustion noise but maximum EGR rates are ultimately restricted by turbocharger and EGR path technologies.
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