Search Results

Diversifying energy resources and reducing greenhouse gas emissions are key priorities in the forthcoming years for the automotive industry. Currently, among the different solutions, sustainable biofuels are considered as one of the most attractive answer to these issues. This paper deals with the vehicle application of an innovative diesel fuel formulation using Ethanol to tackle these future challenges. The main goal is to better understand the impact of using biofuel blends on engine behavior, reliability and pollutants emissions. This alternative oxygenated fuel reduces dramatically particulate matter (PM) emissions; this paves the way to improve the NOx/PM/CO₂ trade-off. Another major interest is to avoid adding a particulate filter in the exhaust line and to avoid modifying powertrain and vehicle hardware and therefore to minimize the overall cost to fulfill upcoming emission regulations.

Dual-fuel combustion strategies combining a premixed charge of natural gas and a pilot injection of diesel fuel offer the potential to reduce CO2 emissions as a result of the high Hydrogen/Carbon (H/C) ratio of methane gas. Moreover, the high octane number of methane means that dual-fuel combustion strategies can be employed on compression ignition engines without the need to vary the engine compression ratio, thereby significantly reducing the cost of engine hardware modifications. The aim of this investigation is to explore the fundamental combustion phenomena occurring when methane is ignited with a pilot injection of diesel fuel. Experiments were performed on a single-cylinder optical research engine which is typical of modern, light-duty diesel engines. A high-speed digital camera recorded time-resolved combustion luminosity and an intensified CCD camera was used for single-cycle OH*chemiluminescence imaging.

Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.

Current progress in the development of diesel engines substantially contributes to the reduction of NOx and Particulate Matter (PM) emissions but will not succeed to eliminate the application of Diesel Particulate Filters (DPFs) in the future. In the past we have introduced a Multi-Functional Reactor (MFR) prototype, suitable for the abatement of the gaseous and PM emissions of the Low Temperature Combustion (LTC) engine operation. In this work the performance of MFR prototypes under both conventional and advanced combustion engine operating conditions is presented. The effect of the MFR on the fuel penalty associated to the filter regeneration is assessed via simulation. Special focus is placed on presenting the performance assessment in combination with the existing differences in the morphology and reactivity of the soot particles between the different modes of diesel engine operation (conventional and advanced). The effect of aging on the MFR performance is also presented.

In this paper, a methodology is presented to study the influence of thermal aging on catalytic DPF performance using small scale coated filter samples and side-stream reactor technology. Different mixed oxide catalytic coating families are examined under realistic engine exhaust conditions and under fresh and thermally aged state. This methodology involves the determination of filter physical (flow resistance under clean and soot loaded conditions and filtration efficiency) and chemical properties (reactivity of catalytic coating towards direct soot oxidation). Thermal aging led to sintering of catalytic nanoparticles and to changes in the structure of the catalytic layer affecting negatively the filter wall permeability, the clean filtration efficiency and the pressure drop behavior during soot loading. It also affected negatively the catalytic soot oxidation activity of the catalyzed samples.

In the frame of tighter emission requirements and environmental protection, future standards will soon lead to the use of an OBD soot sensor to monitor DPF leakage. Such a sensor will first be introduced in the US by MY 2015 and then in Europe for Euro 6.2 in 2017. The resistive ceramic sensing technology has been selected by most OEM as the most appropriate. The sensor collects the soot in a time cumulative manner and has an internal heater to clean the ceramic before each measurement sequence. The actual challenge of the hardware is to design a wide band collecting system with a high sensitivity and repeatability circuit processing. Electricfil has overcome major drawbacks of the resistive technology with an innovative sensor tip, with filtration features and a boosting electronic scheme. This sensor integrates internal diagnostic capability at power on and during operation.

The stability of Diesel/Biodiesel blends can play an important role in deposits formation inside the fuel injection system (FIS). The impact of the stability of FAME/Diesel fuel blends on lacquer deposits formation and on the behavior and reliability of the FIS was investigated using blends of Rapeseed and Soybean methyl esters (RME, SME) and conventional Diesel fuel (volume fractions of RME and SME range from 0 to 20%v/v). Fuels were aged under accelerated conditions and tested on an injection test rig according to an operating cycle developed to provoke injector needle blocking. The soaking duration was found to affect injector fouling. A relationship between the injector fouling tendency and the fuel stability was established. Under current test condition, injectors fouling increased with fuel oxidation measured with Total-Acid-Number.

Trends towards lower vehicle fuel consumption and smaller environmental impact will increase the share of Diesel hybrids and Diesel Range Extended Vehicles (REV). Because of the Diesel engine presence and the ever tightening soot particle emissions, these vehicles will still require soot particle emissions control systems. Ceramic wall-flow monoliths are currently the key players in the Diesel Particulate Filter (DPF) market, offering certain advantages compared to other DPF technologies such as the metal based DPFs. The latter had, in the past, issues with respect to filtration efficiency, available filtration area and, sometimes, their manufacturing cost, the latter factor making them less attractive for most of the conventional Diesel engine powered vehicles. Nevertheless, metal substrate DPFs may find a better position in vehicles like Diesel hybrids and REVs in which high instant power consumption is readily offered enabling electrical filter regeneration.

Diesel urban buses and refuse trucks are part of the particulate emissions sources that affect city air quality. In order to reduce particulate pollutant emissions, a development program has been carried out based on a Euro 4 engine with a DPF technology. Currently, for Euro 4 compliance, SCR is the favoured technology. To avoid a completely new development, the Exoclean™ DPF system was located after the SCR. Catalyst. The severe operating conditions and the location of the DPF necessitated the development of an active system based on the association of a DPF and a Fuel-Borne Catalyst. A Renault Trucks MD9 engine was used. This work was funded by ADEME (French Agency for Environment and Energy Management). Due to severe stop and go duty cycles and the interest to fit the DPF downstream of the SCR, this study shows the benefit of using an active DPF with an FBC to ensure full regeneration even at low temperatures.

As different Diesel Particulate Filter (DPF) designs and media are becoming widely adopted, research efforts in the characterization of their influence on particle emissions intensify. In the present work the influence of a Diesel Oxidation Catalyst (DOC) and five different Diesel Particulate Filters (DPFs) under steady state and transient engine operating conditions on the particulate and gaseous emissions of a common-rail diesel engine are studied. An array of particle measuring instrumentation is employed, in which all instruments simultaneously measure from the engine exhaust. Each instrument measures a different characteristic/metric of the diesel particles (mobility size distribution, aerodynamic size distribution, total number, total surface, active surface, etc.) and their combination assists in building a complete characterization of the particle emissions at various measurement locations: engine-out, DOC-out and DPF-out.

The reduction of NOx emissions required by the future Euro 6 standards leads engine manufacturers to develop Diesel Homogeneous Charge Compression Ignition (HCCI) combustion processes. Because this concept allows reducing both NOx and particulates simultaneously, it appears as a promising way to meet the next environmental challenges. Unfortunately, HCCI combustion often increases CO and HC emissions. Conventional oxidation catalyst technologies, currently used for Euro 4 vehicles, may not be able to convert these emissions because of the saturation of active catalytic sites. As a result, such increased CO and HC emissions have to be reduced under standard levels using innovative catalysts or emergent technologies. The work reported in this paper has been conducted within the framework of the PAGODE project (PSA, IFP, Chalmers University, APTL, CRF, Johnson Matthey and Supelec) and financed by the European Commission.

Due to the increasing use of Fatty Acid Methyl Esters (FAME) in diesel fuel blends and the sensitivity of the latest Diesel engine technology (higher pressures and temperatures), a reliable method for predicting the thermal stability of biodiesel fuels is required. A laboratory bench test, called MicroCoking test, which usually qualifies engine oils, has been modified in order to be used for biodiesel blended fuels. Experimental conditions, and especially temperature range, were optimized in order to lead to a sensitive and discriminating method to qualify pure biodiesel fuels and Diesel blends containing FAME.

Facing more and more stringent regulations, new solutions are developed to decrease pollutant emissions. One of them have shown promising and relevant results. It consists of the use of ethanol as a blending component for diesel fuel Nevertheless, the addition of ethanol to Diesel fuel affects some key properties such as the flash point. Consequently, Diesel blends containing ethanol become highly flammable at a temperature around ambient temperature. This study proposes to improve the formulation of ethanol based diesel fuel in order to avoid flash point drawbacks. First, a focus on physical and chemical properties is done for ethanol based diesel fuels with and without flash point improvement. Second, blends are tested on a passenger car diesel engine, under a wide operating range conditions from low load low speed up to maximum power. The main advantage of the ethanol based fuels generate low smoke level, that allows using higher EGR rate, thus leading to an important NOx decrease.

The IAPAC Direct fuel Injection (DI) system, developed by IFP, has already well proven its capability to reduce pollutants emissions and fuel consumption of 2-stroke engines. This crankcase Compressed Air Assisted Fuel Injection Process allowing the introduction of the fuel separately from the scavenging air, minimizes the fuel short-circuiting. In earlier works, results of the implementation of the IAPAC system on cylinder displacement from 125 cc to 400 cc have been presented in various papers. These first prototypes were all using a camshaft to drive the IAPAC DI poppet valve, which was considered as a limitation for applying this system to small displacement 2-stroke engines. The new SCIP™ system is no more using a camshaft neither driveshaft, or any electric power supply to drive the DI air assisted injection valve.

This paper presents the detailed characterization of particulate emissions from a NADI™ dual mode engine (HCCI at low load and conventional combustion at high load). Morphology, composition and chemical reactivity of the particulate matter generated on an engine running in HCCI mode have been specified and compared to the conventional mode reference. Results showed that HCCI combustion formed particles with a higher volatile organic fraction due to the relatively high level of HC generated by this kind of combustion. Advanced soot characterization emphasized that HCCI soot is oxidized at a slower reaction rate than conventional soot, but with a lower temperature. This last characteristic could partially compensate the poor continuous regeneration effect due to low NO2 emission levels observed in HCCI combustion. Microscopic observation and particle sizing did not show significant differences between HCCI and conventional soot.

Future diesel emission control systems have to effectively operate under non-conventional low-temperature combustion engine operating conditions. In this work the research and development efforts for the realization of a Multi-Functional catalyst Reactor (MFR) for the exhaust of the upcoming diesel engines is presented. This work is based on recent advances in catalytic nano-structured materials synthesis and coating techniques. Different catalytic functionalities have been carefully distributed in the filter substrate microstructure for maximizing the direct and indirect (NO2-assisted) soot oxidation rate, the HC and CO conversion efficiency as well as the filtration efficiency. Moreover, a novel filter design has been applied to enable internal heat recovery capability by the implementation of heat exchange between the outlet and the inlet to the filter flow paths.

Establishing a certain maintenance-free time period regarding modern diesel exhaust emission control systems is of major importance nowadays. One of the most serious problems Diesel Particulate Filter (DPF) manufacturers face concerning system's durability is the performance deterioration due to the filter aging because of the accumulation of the ash particles. The evaluation of the effect of the ash aging on the filter performance is a time and cost consuming task that slows down the process of manufacturing innovative filter structures and designs. In this work we present a methodology for producing filter samples aged by accumulating ash produced by the controlled pyrolysis of oil-fuel solutions. Such ash particles bear morphological (size) and compositional similarity to ash particles collected from engine aged DPFs. The ash particles obtained are compared to those from real engine operation.

This work studies the potential of ethanol-Biodiesel-Diesel fuel blends in both conventional Diesel and HCCI combustion modes. First, ethanol based fuels were tested on a modern commercial multi-cylinder DI diesel engine. The aim of this phase was to assess how such fuels affect Diesel engine performances and emissions. These results indicate that low levels of PM and NOx emissions, with a contained fuel consumption penalty and with an acceptable noise level, are achievable when the Diesel-ethanol blends are used in combination with an optimized combustion control. Moreover, experiments with ethanol based blends were performed using a single cylinder engine, running under both early injection HCCI and Diesel combustion modes. Compared to a conventional fuel, these blends allow increasing the HCCI operating range and also lead to higher maximum power output in conventional Diesel combustion.

In urban areas, particulate emission from Diesel engines is one of the pollutants of most concern. As a result, particulate emission control from urban bus Diesel engines using particulate filter technology is being introducing in La Rochelle. The Diesel Particulate Filter (DPF) introduction on the existing urban bus fleet has been initiated by the CDA La Rochelle through a voluntary retrofit program. The class of urban bus to be retrofitted is based on EURO 1 and EURO 2 Diesel engines, using a standard European Diesel fuel with 300ppm of Sulphur content. In that case, the appropriated technology for DPF regeneration requires a very flexible strategy for DPF regeneration, such as the use of the Ceria-based Fuel-Borne Catalysts. The paper describes the practical approach developed to install and optimize the DPF System on the urban buses.

Diesel particulate trap regeneration is a complex process involving the interaction of phenomena at several scales. A hierarchy of models for the relevant physicochemical processes at the different scales of the problem (porous wall, filter channel, entire trap) is employed to obtain a rigorous description of the process in a multidimensional context. The final model structure is validated against experiments, resulting in a powerful tool for the computer-aided study of the regeneration behavior. In the present work we employ this tool to address the effect of various spatial non-uniformities on the regeneration characteristics of diesel particulate traps. Non-uniformities may include radial variations of flow, temperature and particulate concentration at the filter inlet, as well as variations of particulate loading. In addition, we study the influence of the distribution of catalytic activity along the filter wall.