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Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Fuel wall impingement commonly occurs in small-bore diesel engines. Particularly during engine starting, when wall temperatures are low, the evaporation rate of fuel film remaining from previous cycles plays a significant role in the autoignition process that is not fully understood. Pre-injection chemiluminescence (PIC), resulting from low-temperature oxidation of evaporating fuel film and residual gases, was measured over 3200 μsec intervals at the end of the compression strokes, but prior to fuel injection during a series of starting sequences in an optical diesel engine. These experiments were conducted to determine the effect of this parameter on combustion phasing and were conducted at initial engine temperatures of 30, 40, 50 and 60°C, at swirl ratios of 2.0 and 4.5 at 1000 RPM. PIC was determined to increase and be highly correlated with combustion phasing during initial cycles of the starting sequence.

Operation of flex fuel vehicles requires operation with a range of fuel properties. The significant differences in the heat of vaporization and energy density of E0-E100 fuels and the effect on spray development need to be fully comprehended when developing engine control strategies. Limited enthalpy for fuel vaporization needs to be accounted for when developing injection strategies for cold start, homogeneous and stratified operation. Spray imaging of multi-hole gasoline injectors with fuels ranging from E0 to E100 and environmental conditions that represent engine operating points from ambient cold start to hot conditions was performed in a spray chamber. Schlieren visualization technique was used to characterize the sprays and the results were compared with Laser Mie scattering and Back-lighting technique. Open chamber experiments were utilized to provide input and validation of a CFD model.

In present GDI engines, multiple injection strategies are often employed for engine cold start mixture formation. In the future, these strategies may also be used to control the combustion process, and to prevent misfiring or high emission levels. While the processes occurring during individual injections of GDI injectors have been investigated by a number of researchers, this paper concentrates on the interactions of multiple injection events. Even though multiple injection strategies are already applied in most GDI engines, the impact of the first injection event on the second injection event has not been analyzed in detail yet. Different optical measurement techniques are used in order to investigate the interaction of the two closely timed injection events, as well as the effect of dwell time and the in-cylinder conditions. The injector investigated is a GDI piezo injector with an outwardly opening needle.

Effects of fuel cell material properties on water management were numerically investigated using Volume of Fluid (VOF) method in the FLUENT. The results show that the channel surface wettability is an important design variable for both serpentine and interdigitated flow channel configurations. In a serpentine air flow channel, hydrophilic surfaces could benefit the reactant transport to reaction sites by facilitating water transport along channel edges or on channel surfaces; however, the hydrophilic surfaces would also introduce significantly pressure drop as a penalty. For interdigitated air flow channel design, it is observable that liquid water exists only in the outlet channel; it is also observable that water distribution inside GDL is uneven due to the pressure distribution caused by interdigitated structure. An in-situ water measurement method, neutron imaging technique, was used to investigate the water behavior in a PEM fuel cell.

Emissions of Unburned Hydrocarbons (UHC) from diesel engines are a particular concern during the starting process, when after-treatment devices are typically below optimal operating temperatures. Drivability in the subsequent warm-up phase is also impaired by large cyclic fluctuations in mean effective pressure (MEP). This paper discusses in-cylinder wall temperature influence on unburned hydrocarbon emissions and combustion stability during the starting and warm-up process in an optical engine. A laser-induced phosphorescence technique is used for quantitative measurements of in-cylinder wall temperatures just prior to start of injection (SOI), which are correlated to engine out UHC emission mole fractions and combustion phasing during starting sequences over a range of charge densities, at a fixed fueling rate. Squish zone cylinder wall temperature shows significant influence on engine out UHC emissions during the warm-up process.

Liquid and vapor penetration of sprays from a multi-hole gasoline fuel injector operating under engine-like conditions were systematically investigated utilizing a high-speed imaging system capable of acquiring schlieren and Mie scattering images in a near-simultaneous fashion. The influences of ambient conditions and fuel properties on the formation of liquid and vapor envelopes were evaluated. In addition to the compilation of an extensive data set, results of the investigation indicate that mixing-limited vaporization modeling can be utilized to predict the maximum liquid penetration of short-duration, multi-plume sprays.

Flow field asymmetry can lead to an asymmetric mixture preparation in Diesel engines. To understand the evolution of this asymmetry, it is necessary to characterize the in-cylinder flow over the full compression stroke. Moreover, since bowl-in-piston cylinder geometries can substantially impact the in-cylinder flow, characterization of these flows requires the use of geometrically correct pistons. In this work, the flow has been visualized via a transparent piston top with a realistic bowl geometry, which causes severe experimental difficulties due to the spatial and temporal variation of the optical distortion. An advanced optical distortion correction method is described to allow reliable particle image velocimetry (PIV) measurements through the full compression stroke. Based on the ensemble-averaged velocity results, flow asymmetry characterized by the swirl center offset and the associated tilting of the vortex axis is quantified.

Companion empirical and analytical studies were conducted to assess the feasibility and constraints (hardware and combustion perspectives) associated with operating a Spark Ignition Direct-Injection (SIDI) engine on high ethanol and gasoline mixtures ranging from 0 to 85% by volume. Cold start, part and full-load performance aspects were explored. Analytical experiments were performed to correlate with the empirical data using a commercially available single dimensional engine simulation code. Under WOT operating conditions it was found that the engine's simulated output was overestimated with E85 fuel which was caused by the over prediction of volumetric efficiency. It was necessary to create a sub-routine to accurately model the impingement, vaporization, and heat transfer of fuel on the piston surface. Results could only be correlated after taking fuel impingement into account.

With increasingly stringent emissions regulations and concurrent requirements for enhanced engine thermal efficiency, a comprehensive characterization of the automotive gasoline fuel spray has become essential. The acquisition of accurate and repeatable spray data is even more critical when a combustion strategy such as gasoline direct injection is to be utilized. Without industry-wide standardization of testing procedures, large variablilities have been experienced in attempts to verify the claimed spray performance values for the Sauter mean diameter, Dv90, tip penetration and cone angle of many types of fuel sprays. A new SAE Recommended Practice document, J2715, has been developed by the SAE Gasoline Fuel Injection Standards Committee (GFISC) and is now available for the measurement and characterization of the fuel sprays from both gasoline direct injection and port fuel injection injectors.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

As a result of recent focus on the control of Low Temperature Combustion (LTC) modes, dual-fuel combustion strategies such as Reactivity Controlled Compression Ignition (RCCI) have been developed. Reactivity stratification of the auto-igniting mixture is thought to be responsible for the increase in allowable engine load compared to other LTC combustion modes such as Homogenous Charge Compression Ignition (HCCI). The current study investigates the effect of ethanol intake fuel injection on in-cylinder formaldehyde formation and stratification within an optically accessible engine operated with n-heptane direct injection using optical measurements and zero-dimensional chemical kinetic models. Images obtained by Planar Laser Induced Fluorescence (PLIF) of formaldehyde using the third harmonic of a pulsed Nd:YAG laser indicate an increase in formaldehyde heterogeneity as measured by the fluorescence signal standard deviation.

Liquid and vapor envelopes of sprays from a multi-hole fuel injector operating under closely-spaced double-injection conditions were investigated using a combination of high-speed schlieren and Mie scattering imaging. The effects of mass split ratio and dwell time between injections on liquid and vapor penetration have been investigated under engine-like pressures and temperatures. For the conditions evaluated, the results indicate that closely-spaced double-injection generally reduces liquid and vapor penetration.

In light-duty direct-injection (DI) diesel engines, combustion chamber geometry influences the complex interactions between swirl and squish flows, spray-wall interactions, as well as late-cycle mixing. Because of these interactions, piston bowl geometry significantly affects fuel efficiency and emissions behavior. However, due to lack of reliable in-cylinder measurements, the mechanisms responsible for piston-induced changes in engine behavior are not well understood. Non-intrusive, in situ optical measurement techniques are necessary to provide a deeper understanding of the piston geometry effect on in-cylinder processes and to assist in the development of predictive engine simulation models. This study compares two substantially different piston bowls with geometries representative of existing technology: a conventional re-entrant bowl and a stepped-lip bowl. Both pistons are tested in a single-cylinder optical diesel engine under identical boundary conditions.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.

Surrogates for JP-8 have been developed in the high temperature gas phase environment of gas turbines. In diesel engines, the fuel is introduced in the liquid phase where volatility plays a major role in the formation of the combustible mixture and autoignition reactions that occur at relatively lower temperatures. In this paper, the role of volatility on the combustion of JP-8 and five different surrogate fuels was investigated in the constant volume combustion chamber of the Ignition Quality Tester (IQT). IQT is used to determine the derived cetane number (DCN) of diesel engine fuels according to ASTM D6890. The surrogate fuels were formulated such that their DCNs matched that of JP-8, but with different volatilities. Tests were conducted to investigate the effect of volatility on the autoignition and combustion characteristics of the surrogates using a detailed analysis of the rate of heat release immediately after the start of injection.

An experimental study was carried out to characterize the exhaust flow structure inside the closed-coupled catalytic converter, which is installed on a firing four-cylinder 12-valve passenger car gasoline engine. Simultaneous velocity and pressure measurements were taken using cycle-resolved Laser Doppler anemometer (LDA) technique and pressure transducer. A small fraction of titanium (IV) iso-propoxide was dissolved in gasoline to generate titanium dioxide during combustion as seeding particles for the LDA measurements. It was found that the velocity is highly fluctuating due to the pulsating nature of the engine exhaust flow, which strongly depends on the engine operating conditions and the measuring locations. The pressure oscillation is correlated with the transient exhaust flow characteristics. The main exhaust flow event from each cylinder can only be observed at the certain region in front of the monolith brick.

Two-dimensional pulse-laser Mie scattering visualization of the direct-injection gasoline fuel sprays and wall impingement processes was carried out inside a single-cylinder optically accessible engine under motoring condition. The injectors have been first characterized inside a pressurized chamber using identical technique, as well as high-speed microscopic visualization and phase Doppler measurement techniques. The effects of injector cone angle, location, and injection timings on the wall impingement processes were investigated. It was found that the fuel vaporization is not complete at the constant engine speed tested. Fuel spray droplets were observed to disperse wider in the motored engine when compared with an isothermal quiescent ambient conditions. The extent of wall-impingement varies significantly with the injector mounting position and spray cone angle; however, its effect can be reduced to some extent by optimizing the injection timing.

As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.

By taking advantage of high-intensity and high-brilliance x-ray beams available at the Advanced Photon Source (APS), ultrafast (150 ps) propagation-based phase-enhanced imaging was developed to visualize high-pressure high-speed diesel sprays in the optically dense near-nozzle region. The sub-ns temporal and μm spatial resolution allows us to capture the morphology of the high-speed fuel sprays traveling at 500 m/s with a negligible motion blur. Both quality and quantitative information about the spray feature can be readily obtained. In the experiment, two types of single-hole nozzles have been used, one with a hydroground orifice inlet and the other with a sharp one. Within 3 mm from the nozzle, the sprays from these nozzles behave differently, ranging from laminar flow with surface instability waves to turbulent flow. The sprays are correlated with the nozzle internal geometry, which provides practical information for both nozzle design and supporting numerical simulation models.