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Effects of fuel cell material properties on water management were numerically investigated using Volume of Fluid (VOF) method in the FLUENT. The results show that the channel surface wettability is an important design variable for both serpentine and interdigitated flow channel configurations. In a serpentine air flow channel, hydrophilic surfaces could benefit the reactant transport to reaction sites by facilitating water transport along channel edges or on channel surfaces; however, the hydrophilic surfaces would also introduce significantly pressure drop as a penalty. For interdigitated air flow channel design, it is observable that liquid water exists only in the outlet channel; it is also observable that water distribution inside GDL is uneven due to the pressure distribution caused by interdigitated structure. An in-situ water measurement method, neutron imaging technique, was used to investigate the water behavior in a PEM fuel cell.

In this study the authority of the available engine controls are characterized as the high load limit of homogeneous charge compression ignition (HCCI) combustion is approached. A boosted single-cylinder research engine is used and is equipped with direct injection (DI) fueling, a laboratory air handling system, and a hydraulic valve actuation (HVA) valve train to enable negative valve overlap (NVO) breathing. Results presented include engine loads from 350 to 650 kPa IMEPnet and manifold pressure from 98 to 190 kPaa. It is found that in order to increase engine load to 650 kPa IMEPnet, it is necessary to increase manifold pressure and external EGR while reducing the NVO duration. While both are effective at controlling combustion phasing, NVO duration is found to be a "coarse" control while fuel injection timing is a "fine" control.

In previous work, Gasoline Direct Injection Compression Ignition (GDCI) has demonstrated good potential for high fuel efficiency, low NOx, and low PM over the speed-load range using RON91 gasoline. In the current work, a four-cylinder, 1.8L engine was designed and built based on extensive simulations and single-cylinder engine tests. The engine features a pent roof combustion chamber, central-mounted injector, 15:1 compression ratio, and zero swirl and squish. A new piston was developed and matched with the injection system. The fuel injection, valvetrain, and boost systems were key technology enablers. Engine dynamometer tests were conducted at idle, part-load, and full-load operating conditions. For all operating conditions, the engine was operated with partially premixed compression ignition without mode switching or diffusion controlled combustion.

A 1.8L Gasoline Direct Injection Compression Ignition (GDCI) engine was tested over a wide range of engine speeds and loads using RON91 gasoline. The engine was operated with a new partially premixed combustion process without combustion mode switching. Injection parameters were used to control mixture stratification and combustion phasing using a multiple-late injection strategy with GDi-like injection pressures. At idle and low loads, rebreathing of hot exhaust gases provided stable compression ignition with very low engine-out NOx and PM emissions. Rebreathing enabled reduced boost pressure, while increasing exhaust temperatures greatly. Hydrocarbon and carbon monoxide emissions after the oxidation catalyst were very low. Brake specific fuel consumption (BSFC) of 267 g/kWh was measured at the 2000 rpm-2bar BMEP global test point.

Lithium-ion polymer battery has been widely used for vehicle onboard electric energy storage ranging from 12V SLI (Starting, Lighting, and Ignition), 48V mild hybrid electric, to 300V battery electric vehicle. Formulation on cell parameters acquired from minimum numbers of experiments, the modeling and simulation could be an effective approach in predicting battery performance, thermal effectiveness, and degradation. This paper describes the modeling, simulation, and validation of Lithium-Nickel-Manganese-Cobalt-Oxide (LiNiMnCoO2) based cell with 3.6V nominal voltage and 20Ah capacity. Constant current 20A, 40A, 60A, and 80A discharge tests are conducted in the computer-controlled cycler and temperature chamber. Discharging voltage curves and cell surface temperature distributions are recorded in each discharging test. A three-dimensional cell model is constructed in the COMSOL multi-physics platform based on the cell parameters.

The second generation 1.8L Gasoline Direct Injection Compression Ignition (GDCI) engine was built and tested using RON91 gasoline. The engine is intended to meet stringent US Tier 3 emissions standards with diesel-like fuel efficiency. The engine utilizes a fulltime, partially premixed combustion process without combustion mode switching. The second generation engine features a pentroof combustion chamber, 400 bar central-mounted injector, 15:1 compression ratio, and low swirl and squish. Improvements were made to all engine subsystems including fuel injection, valve train, thermal management, piston and ring pack, lubrication, EGR, boost, and aftertreatment. Low firing friction was a major engine design objective. Preliminary test results indicated good improvement in brake specific fuel consumption (BSFC) over the first generation GDCI engines, while meeting targets for engine out emissions, combustion noise and stability.

The concept of two closely spaced micro-orifices (group hole nozzle) has been studied as a promising technology for the reduction of soot emission from direct injection (DI) diesel engines by improving the fuel atomization and evaporation. One of the main issues on group hole nozzle is the arrangement of orifices with various distances and angles. In this study, the ignition and combustion characteristics of wall-impinging diesel sprays from group-hole nozzles were investigated with various angles between two micro-orifices (included angles). A laser absorption scattering (LAS) technique for non-axisymmetric sprays, developed based on a LAS technique for axisymmetric spray, was applied to investigate the liquid/vapor mass distribution of wall-impinging sprays. The direct flame images and OH radical images inside a high pressure constant volume vessel were captured to analyze the effect of included angle on spray ignition and combustion characteristics.

The group-hole (GH) nozzle concept that uses two closely spaced micro-orifices to substitute the conventional single orifice has the potential to facilitate better fuel atomization and evaporation, consequently attenuate the soot emission formed in direct-injection (D.I.) diesel engines. Studies of quantitative mixture properties of the transient fuel spray injected by the group-hole nozzles were conducted in a constant volume chamber via the laser absorption-scattering (LAS) technique, in comparison with conventional single-hole nozzles. Specific areas investigated involved: the non-evaporating and the evaporating ambient conditions, the free spray and the spray impinging on a flat wall conditions. The particular emphasis was on the effect of one of key parameters, the interval between orifices, of the group-hole (SH) nozzle structure.

Increasing injection pressure and decreasing nozzle hole diameter have been proved to be two effective approaches to reduce the exhaust emissions and to improve the fuel economy. Recently, the micro-hole nozzles and ultra-high injection pressures are applicable in commercial Diesel engines. But the mechanism of these two latest technologies is still unclear. The current research aims at providing information on the spray and mixture formation processes of the micro-hole nozzle (d=0.08mm) under the ultra-high injection pressure (Pinj=300MPa). The flat wall impinging sprays were focused on and the laser absorption-scattering (LAS) technique was employed to obtain the qualitative and quantitative information at both atmospheric and elevated conditions. The spray parameters were collected, the mixing rate was discussed, and the effects of various parameters on mixture formation were clarified.

An experimental study was carried out to characterize the exhaust flow structure inside the closed-coupled catalytic converter, which is installed on a firing four-cylinder 12-valve passenger car gasoline engine. Simultaneous velocity and pressure measurements were taken using cycle-resolved Laser Doppler anemometer (LDA) technique and pressure transducer. A small fraction of titanium (IV) iso-propoxide was dissolved in gasoline to generate titanium dioxide during combustion as seeding particles for the LDA measurements. It was found that the velocity is highly fluctuating due to the pulsating nature of the engine exhaust flow, which strongly depends on the engine operating conditions and the measuring locations. The pressure oscillation is correlated with the transient exhaust flow characteristics. The main exhaust flow event from each cylinder can only be observed at the certain region in front of the monolith brick.

As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.

For the application of advanced clean combustion technologies, such as diesel HCCI/LTC, a compressor with high efficiency over a broad operation range is required to supply a high amount of EGR with minimum pumping loss. A compressor with high pitch of vaneless diffuser would substantially improve the flow range of the compressor, but it is at the cost of compressor efficiency, especially at low mass flow area where most of the city driving cycles resides. In present study, an ultra low solidity compressor vane diffuser was numerically investigated. It is well known that the flow leaving the impeller is highly distorted, unsteady and turbulent, especially at relative low mass flow rate and near the shroud side of the compressor. A conventional vaned diffuser with high stagger angle could help to improve the performance of the compressor at low end. However, adding diffuser vane to a compressor typically restricts the flow range at high end.

By taking advantage of high-intensity and high-brilliance x-ray beams available at the Advanced Photon Source (APS), ultrafast (150 ps) propagation-based phase-enhanced imaging was developed to visualize high-pressure high-speed diesel sprays in the optically dense near-nozzle region. The sub-ns temporal and μm spatial resolution allows us to capture the morphology of the high-speed fuel sprays traveling at 500 m/s with a negligible motion blur. Both quality and quantitative information about the spray feature can be readily obtained. In the experiment, two types of single-hole nozzles have been used, one with a hydroground orifice inlet and the other with a sharp one. Within 3 mm from the nozzle, the sprays from these nozzles behave differently, ranging from laminar flow with surface instability waves to turbulent flow. The sprays are correlated with the nozzle internal geometry, which provides practical information for both nozzle design and supporting numerical simulation models.

The current study focused on the effects B20 fuel (20% soybean-based biodiesel) and SCR entrance shapes on a light-duty, high-speed, 2.8L common-rail 4-cylinder diesel engine, at different exhaust temperatures. The results indicate that B20 has less deNOX efficiency at low temperature than ULSD, and that N₂O emission need to be characterized as well as NH₃ slip. If a mixer and enough mixing length are used, longer divergence section does not improve the deNOX efficiency significantly under the speed ranges tested.

Self recirculation casing treatment has been showed to be an effective technique to extend the flow range of the compressor. However, the mechanism of its surge extension on turbocharger compressor is less understood. Investigation and comparison of internal flow filed will help to understand its impact on the compressor performance. In present study, experimentally validated CFD analysis was employed to study the mechanism of surge extension on the turbocharger compressor. Firstly a turbocharger compressor with replaceable inserts near the shroud of the impeller inlet was designed so that the overall performance of the compressor with and without self recirculation casing treatment could be tested and compared. Two different self recirculation casing treatments had been tested: one is conventional self recirculation casing treatment and the other one has deswirl vanes inside the casing treatment passage.

Unburned hydrocarbon (UBHC) emissions from gasoline engines remain a primary engineering research and development concern due to stricter emission regulations. Gasoline engines produce more UBHC emissions during cold start and warm-up than during any other stage of operation, because of insufficient fuel-air mixing, particularly in view of the additional fuel enrichment used for early starting. Impingement of fuel droplets on the cylinder wall is a major source of UBHC and a concern for oil dilution. This paper describes an experimental study that was carried out to investigate the distribution and “footprint” of fuel droplets impinging on the cylinder wall during the intake stroke under engine starting conditions. Injectors having different targeting and atomization characteristics were used in a 4-Valve engine with optical access to the intake port and combustion chamber.

A quantitative and time-resolved technique has been developed to probe the fuel distribution very near the nozzle of a high-pressure diesel injector. This technique uses the absorption of synchrotron x-rays to measure the fuel mass with good time and position resolution. The penetrating power of x-rays allows measurements that are difficult with other techniques, such as quantitative measurements of the mass and penetration measurements of the trailing edge of the spray. Line-of-sight measurements were used to determine the fuel density as a function of time. The high time resolution and quantitative nature of the measurement also permit an accurate measure of the instantaneous mass flow rate through the nozzle.

Experimental data is used in conjunction with multi-dimensional modeling in a modified version of the KIVA-3V code to characterize the emissions behavior of a high-speed, direct-injection diesel engine. Injection pressure and EGR are varied across a range of typical small-bore diesel operating conditions and the resulting soot-NOx tradeoff is analyzed. Good agreement is obtained between experimental and modeling trends; the HSDI engine shows increasing soot and decreasing NOx with higher EGR and lower injection pressure. The model also indicates that most of the NOx is formed in the region where the bulk of the initial heat release first takes place, both for zero and high EGR cases. The mechanism of NOx reduction with high EGR is shown to be primarily through a decrease in thermal NOx formation rate.

The emissions trade-off and combustion characteristics of a high speed, small-bore, direct injection, single cylinder, diesel engine are investigated at three different load conditions. The experiments covered a wide range of parameters including the injection pressure, exhaust gas recirculation (EGR) rate and swirl ratio (Sw). The effects of each parameter on the ignition delay (ID), apparent rate of energy release (ARER), NOx, Bosch smoke unit (BSU), CO and hydrocarbons are investigated. The results show that the NOx emission dropped continuously with the increase in EGR (up to 55%), but with increasing smoke emission in a classical trade-off relationship. The increase in injection pressure generally reduced smoke with NOx penalty; however, the NOx penalty decreased at higher EGR. There also appears to be an increase in the cool flame intensity at the high EGR rates. Applying swirl at high EGR rate and high injection pressure conditions further reduced smoke emissions.

Simultaneous two-component measurements of gas velocity and multi-dimensional numerical simulation are employed to characterize the evolution of the in-cylinder turbulent flow structure in a re-entrant bowl-in-piston engine under motored operation. The evolution of the mean flow field, turbulence energy, turbulent length scales, and the various terms contributing to the production of the turbulence energy are correlated and compared, with the objectives of clarifying the physical mechanisms and flow structures that dominate the turbulence production and of identifying the source of discrepancies between the measured and simulated turbulence fields. Additionally, the applicability of the linear turbulent stress modeling hypothesis employed in the k-ε model is assessed using the experimental mean flow gradients, turbulence energy, and length scales.