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Ethanol based fuels have seen increased use in recent years due to their renewable nature as well as increased governmental regulatory mandates. While offering performance advantages over gasoline, especially at high compression ratios, these fuels are more sensitive to pre-ignition (PI). Pre-ignition experiments using ethanol (E100) and E85 were performed in a CFR spark ignition engine using a diesel glow plug “hot spot” to induce PI. PI is found to occur over a specific air-fuel ratio range based on hot spot temperature. Additionally, increasing ethanol content or compression ratio (CR) decreases glow plug temperature thresholds for PI. A kinetics-based model was used to simulate pre-ignition of E100 and to elucidate sensitivities of pre-ignition to various operating parameters, including initial charge temperature, air dilution, and residual dilution. The model shows that the most violent cases of PI can be mitigated by switching to either lean or rich operation.

Seven biofuel-diesel fuel configurations were tested in a single-cylinder research diesel CFR engine that allowed variable injection timing. These seven configurations included three biodiesel-diesel blends (20% and 100%); two ethanol-diesel blends (15% and 20%), and two cases in which ethanol was injected into the intake air flow (20% and 33%). Combustion characteristics, NOx emissions, and soot emissions were compared with diesel operation across a range of injection timings. The effect of fuel compressibility affected the timing of injection, with biodiesel-diesel blends having advanced injection and ethanol-diesel blends having delayed injection. Biodiesel-diesel blends showed reduced ignition delay with only modest changes in combustion duration, while ethanol-diesel mixtures showed longer ignition delay but much shorter combustion duration and earlier phasing.

Engine startup experiments with intake port sampling were performed in a modified fuel injected single cylinder gasoline CFR research engine. Immediately after fuel injection, port fuel-air vapor sampling was performed in order to quantify the role of the fuel injector in creating a combustible mixture for the first cycle of engine startup. In-cylinder sampling was also performed to clarify the role of other mixture preparation mechanisms in the startup process. Sample analysis was performed using gas chromatography. Experimental data were also collected during steady-state operating conditions at the same intake port pressure and temperature as that of the first cranking cycle for comparison. Results show that approximately ½ to ¾ of a near stoichiometric combustible 1st cycle charge, as a function of first cycle fueling, is produced immediately after enriched cranking fuel injection.

In the near future increasing use of ethanol in motor fuels will occur due to legislative mandates. E10 (Gasohol) and E85 will see more widespread use in spark ignition engines. This study looks at the performance and knock characteristics of E10 and E85 in comparison to regular gasoline. Detailed experimental engine data and analysis as a function of compression ratio, ignition timing and fueling are presented with associated physical explanations. Comparative results are presented. Increasing ethanol content provides for greater engine torque, efficiency and knock tolerance, yet fuel consumption worsens. Knock limited trends and sensitivities are presented, for example, 5 degrees of spark retard are required with E10 and gasoline for each compression ratio increase, while the much less sensitive E85 requires only 2 degrees of retard for each compression ratio increase. Trends with efficiency and torque are described amongst the fuels tested.

Fischer-Tropsch (FT) synthetic fuels have been shown to produce lower soot and oxides of nitrogen emissions than petroleum-based diesel #2 (D2) in previous studies. This performance is frequently attributed to the very low aromatic content as well as essentially zero sulfur content. The objective of this empirical study was to investigate the high engine load regime using a military FT and D2 fuel in a CFR diesel engine at fueling levels approaching stoichiometric. A testing matrix comprised of various injection advance set points, fueling amounts (e.g. load) above 6 bar gross indicated mean effective pressure (IMEPg), and three different compression ratios (CR) was pursued. The results show that oxides of nitrogen emissions are always equal to or lower running FT compared to diesel. This result is attributed to the higher cetane number of FT leading to lower peak in-cylinder pressures as compared to D2.

Internal combustion engine knock has limited compression ratios of spark ignition engines for most of the history of gasoline engines. This limitation continues to exist today. While knock is generally a low engine speed, high load phenomenon, this operating condition is infrequently used by many vehicle operators, and if the engine is brought to this operating condition generally little time is spent in this knock prone condition. This study seeks to investigate the transition into knock due to throttle changes from part to full load. The experimental results using a CFR engine operating on iso-octane fuel show that knock is delayed by at least one high load engine cycle after the throttle is opened. Optimization of spark timing to account for this effect provides for the best increase of engine load without audible knock occurring.

Bench fuel injection experiments were performed to investigate the levels of generated fuel vapor immediately after fuel injection into a closed vessel. A synthetic fuel mixture was used consisting of six individual fuel components that are representative of gasoline. Vessel (e.g. port) temperature and pressure were varied, as well as sample location and sample delay time after injection. Vessel vapor space samples were collected and processed in a gas chromatograph in order to quantify the contribution to the fuel vapor by the various fuel components. Companion modeling was performed in order to evaluate two fuel vapor mixture preparation models (Raoult's Law and NIST's SUPERTRAPP). Results indicate that approximately 1/6 to 1/3 of the injected fuel mass is in the vapor form immediately after fuel injection (as a function of temperature). SUPERTRAPP modeling indicates that the injected fuel mass is approximately in equilibrium with 6% of the available air.