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Technical Paper

Understanding Soot Mediated Oil Thickening Part 6: Base Oil Effects

1998-10-19
982665
One of the key functions of lubricating oil additives in diesel engines is to control oil thickening caused by soot accumulation. Over the last several years, it has become apparent that the composition of the base oil used within the lubricant plays an extremely important role in the oil thickening phenomenon. In particular, oil thickening observed in the Mack T-8 test is significantly affected by the aromatic content of the base oil. We have found that the Mack T-8 thickening phenomenon is associated with high electrical activity, i.e., engine drain oils which exhibit high levels of viscosity increase show significantly higher conductivities. These findings suggest that electrical interactions are involved in soot-induced oil thickening.
Technical Paper

ULSAB-Advanced Vehicle Concepts: Safety/Crash Management

2002-03-04
2002-01-0638
The goal of ULSAB-Advanced Vehicle Concepts (AVC) is to develop a platform with the highest number of shared parts possible between two vehicle classes -European C-Class and the North American PNGV-Class concepts. Aggressive targets for mass and safety are considered --all the while maintaining affordable cost and achieving safety goals anticipated for 2004 and beyond. The objective of the CAE analysis of crashworthiness for ULSAB-AVC is to analyze and optimize the vehicle structure to provide the opportunity for development of complete vehicles that will obtain excellent star ratings. This paper will discuss crash safety and crash energy management aspects of the ULSAB-AVC, including important considerations for selecting advanced high-strength steels for crashworthiness applications, body-in-white design and materials selection procedures, BIW concept design and major load paths, and performance against crashworthiness targets.
Technical Paper

Tire/Pavement Interaction Noise Source Identification Using Multi-Planar Nearfield Acoustical Holography

1999-05-17
1999-01-1733
In this study, multi-planar Nearfield Acoustical Holography (NAH) is used to investigate noise radiated from the front, side and rear areas of single tires on a two-wheel trailer. Contributions to the radiated noise from the leading edge, trailing edge, and sidewall of the tire are identified. Two tires - an experimental monopitch tire and a production passenger car tire - are evaluated on a smooth asphalt pavement at 58 km/hr. From the measured complex pressure, acoustic intensity is reconstructed on three planes surrounding the tire using modified NAH procedures. Additionally, sound power levels are presented in tabulated and spectra forms. Tire noise generating mechanisms are inferred based on the results.
Technical Paper

The Role of Engine Oil Formulations on Fluid Diagnostics

2002-10-21
2002-01-2677
Historically, vehicle fluid condition has been monitored by measuring miles driven or hours operated. Many current vehicles have more sophisticated monitoring methods that use additional variables such as fuel consumption, engine temperature and engine revolutions to predict fluid condition. None of these monitoring means, however, actually measures a fluid property to determine condition, and that is about to change. New sensors and diagnostic systems are being developed that allow real time measurement of some lubricant physical and/or chemical properties and interpret the results in order to recommend oil change intervals and maximize performance. Many of these new sensors use electrochemical or acoustic wave technologies. This paper examines the use of these two technologies to determine engine oil condition and focuses on the effects of lubricant chemistry on interpreting the results.
Technical Paper

The Lean Oxidation of Iso-Octane | at Elevated Pressures

2005-10-24
2005-01-3734
Experimental results are presented from plug flow reactor studies of the lean oxidation of iso-octane and compared to modeling results using a detailed kinetic mechanism. Two sets of experiments performed at 9 atm are presented: a temperature sweep from low temperature through the NTC region and temporal species profiles for an initial temperature within the low temperature regime. Species observed include C8 conjugate olefins, C8 cyclic ethers, acetone, acetaldehyde, iso-butyraldehyde, 2,2-dimethyl-propanal, iso-butene, propene, C7 olefins, and iso-butene oxide. In general the model predicts the overall trends observed in the experimental results, including the temperatures at which the NTC region begins and ends. However, it significantly over-predicts the extent of reaction in the low temperature regime.
Technical Paper

The KA24E Engine Test for ILSAC GF-3.Part 2. Valve Train Wear Response to Formulation Variables

1998-10-19
982626
The work presented here is the second of two papers investigating the KA24E engine test. The first paper characterized the KA24E engine in terms of the physical and chemical operating environment it presents to lubricants. The authors investigated oil degradation and wear mechanisms, and examined the differences between the KA24E and the Sequence VE engine tests. It was shown that while the KA24E does not degrade the lubricant to the extent that occurs in the Sequence VE, wear could be a serious problem if oils are poorly formulated. This second paper examines the wear response of the KA24E to formulation variables. A statistically designed matrix demonstrated that the KA24E is sensitive to levels of secondary zinc dialkyldithiophosphate (ZDP), dispersant and calcium sulfonate detergent. This matrix also showed that the KA24E appears to have good repeatability for well formulated oils and is a reasonable replacement for the wear component of the Sequence VE.
Technical Paper

The KA24E Engine Test for ILSAC GF-3 Part 1: Engine Design, Operating Conditions and Wear Mechanisms

1998-10-19
982625
The Nissan KA24E engine test is designated to replace the Ford Sequence VE engine test as the low temperature valve train wear requirement for ILSAC (International Lubricant Standardization and Approval Committee) GF-3. The KA24E (recently designated the Sequence IV A) represents much of the current world-wide material and design technology while retaining the sliding cam/follower contact found in earlier engine designs. The work presented here is the first of two reports. In this first report, the physical and chemical environment the KA24E engine presents a lubricant is characterized and compared to those of the Sequence VE engine. Valve train materials and wear modes are investigated and described. Although chemical analysis of drain oils indicate the KA24E procedure does not degrade the lubricant to the extent seen in the Sequence VE test, valve train wear appears to proceed in a similar manner in both tests.
Technical Paper

The Impact of Passenger Car Motor Oils on Emissions Performance

2003-05-19
2003-01-1988
Throughout the evolution of the automobile, passenger car motor oils have been developed to address issues of wear, corrosion, deposit formation, friction, and viscosity stability. As a result, the internal combustion engines are now developed with the expectation that the lubricants to be used in them will deliver certain performance attributes. Metallurgies, clearances, and built-in stresses are all chosen with certain expectations from the lubricant. A family of chemicals that has been universally used in formulating passenger car motor oils is zinc dithiophosphates (ZDPs). ZDPs are extremely effective at protecting highly stressed valve train components against wear failure, especially in engine designs with a sliding contact between cams and followers. While ZDPs' benefits on wear control are universally accepted, ZDPs have been identified as the source of phosphorus, which deactivates noble metal aftertreatment systems.
Technical Paper

The Effect of Platinum Catalysts on Propane Oxidation at Elevated Pressure

1988-10-01
881614
The potential for catalytically enhanced ignition in low-heat rejection Diesel engines has been experimentally studied under engine simulated conditions in a high pressure chemical flow reactor. Results are presented for propane oxidation on platinum at 6 and 10 atmospheres, at temperatures from 800K to 1050K, and at equivalence ratios from 0.5 to 4.0. For turbulent transport rates which are typical of those in an engine, as much as 20% of the fuel was found to react on the catalyst before the onset of the gas-phase ignition reactions. Depending on the adiabaticity of the combustion chamber walls, this could lead to significant thermal enhancement of the gas-phase ignition process. Evidence of chemical enhancement was also observed, at 10 atm under very fuel rich conditions, in terms of a change in the concentration and distribution of the hydrocarbon intermediate species. Possible mechanisms for the observed chemical enhancement due to surface generated species are discussed.
Technical Paper

The Development of Predictive Models for Non-Acidic Lubricity Agents (NALA) using Quantitative Structure Activity Relationships (QSAR)

2005-10-24
2005-01-3900
This study describes the use of Quantitative Structure Activity Relationships (QSAR) to develop predictive models for non-acidic Lubricity agents. The work demonstrates the importance of separating certain chemical families to give better and more robust equations rather than grouping a whole data set together. These models can then be used as important tools in further development work by predicting activities of new compounds before actual synthesis/testing.
Technical Paper

Techniques to Improve Springback Prediction Accuracy Using Dynamic Explicit FEA Codes

2002-03-04
2002-01-0159
Finite Element Analysis (FEA) has been successfully used in the simulation of sheet metal forming process. The accurate prediction of the springback is still a major challenge due to its sensitivity to the geometric modeling of the tools, strain hardening model, yield criterion, contact algorithm, loading pattern, element formulation, mesh size and number of through-thickness integration points, etc. The objective of this paper is to discuss the effect of numerical parameters on springback prediction using dynamic explicit FEA codes. The example used in the study is from the Auto/Steel Partnership High Strength Steel Rail Springback Project. The modeling techniques are discussed and the guidelines are provided for choosing numerical parameters, which influence the accuracy of the springback prediction and the computation cost.
Technical Paper

Study of Fracture Behavior of Cord-Rubber Composites for Lab Prediction of Structural Durability of Aircraft Tires II. Fatigue Damage Accumulation of Bias Carcass

1992-10-01
922011
Current phase of the study was undertaken to examine tensile fatigue behavior of cord-rubber composites representing bias tire carcass under various frequencies up to the level which closely simulates loading during high-speed take-off of aircraft. At a given stress amplitude, the use of higher cyclic frequency was found to affect strain response and heat build-up characteristics of composites significantly. The lower level of initial strain observed at higher frequency stems clearly from strain rate dependence of deformation of rubber matrix composites. The temperature profile of the specimens subjected from 20 to 30 Hz loading showed that hysteretic heating under these conditions may lead to thermal fatigue failure as well as chemical degradation influencing both fiber-matrix adhesion strength and matrix strength.
Technical Paper

Specifying Steel Properties and Incorporating Forming Effects in Full Vehicle Impact Simulation

2002-03-04
2002-01-0639
Mechanical properties of as-rolled steels used in a vehicle vary with many parameters including gages, steel suppliers and manufacturing processes. The residual forming and strain rate effects of automotive components have been generally neglected in full vehicle crashworthiness analyses. Not having the above information has been considered as one of the reasons for the discrepancy between the results from computer simulation models and actual vehicle tests. The objective of this study is to choose the right material property for as-rolled steels for stamping and crash computer simulation, and investigate the effect of forming and strain rate on the results of full vehicle impact analyses. Major Body-in-White components which were in the crash load paths and whose material property would change in the forming process were selected in this study. The post-formed thickness and yield stress distributions on the components were estimated using One Step forming analyses.
Technical Paper

Shifting from Automatic to Continuously Variable Transmissions: A Look at Fluid Technology Requirements

1999-10-25
1999-01-3614
New technologies are being commercialized across the automotive industry to address demands for improved fuel economy, emissions reductions, and improved customer satisfaction. Push-belt continuously variable transmissions (b-CVTs) are beginning to command a significant percentage of the market now dominated by manual and conventional automatic transmissions. In addition, automobile manufacturers plan to introduce the first traction drive toroidal-CVTs to the market place within the next five years. A review of the relative benefits and limitations of each of these automatic transmissions exists in the literature. In this paper we consider how the performance requirements of each of these automatic transmission systems impact automatic transmission fluid technology. The physical characteristics and screen test performance of two commercial ATFs, a b-CVTF, and two traction fluids were examined.
Technical Paper

Residual Forming Effects on Full Vehicle Frontal Impact and Body-in-White Durability Analyses

2002-03-04
2002-01-0640
Forming of sheet metal structures induces pre-strains, thickness variations, and residual stresses. Pre-strains in the formed structures introduce work hardening effects and change material fatigue properties such as stress-life or strain-life. In the past, crashworthiness and durability analyses have been carried out using uniform sheet thickness and stress- and strain-free initial conditions. In this paper, crashworthiness and durability analyses of hydroformed front rails, stamped engine rails and shock towers on a full vehicle and a Body-In-White structure are performed considering the residual forming effects. The forming effects on the crash performance and fatigue life are evaluated.
Technical Paper

Polymer Additives as Mist Suppressants in Metalworking Fluids Part IIa: Preliminary Laboratory and Plant Studies - Water Soluble Fluids

1998-02-23
980097
Mist generated from water-soluble fluids used in machining operations represents a potentially significant contribution to worker exposure to airborne particles. Part I of this study [1], discussed polymer additives as mist suppressants for straight mineral oil metalworking fluids (MWF), which have been successfully employed at several locations. This paper focuses on recent developments in polymer mist suppressants for water-based MWF, particularly in the production environment. The polymer developed and tested in this study functions on a similar basis to that for straight oil anti-mist additives. This water soluble polymer suppresses the formation of small mist droplets and results in a distribution of larger droplet sizes. These larger droplets tend to settle out near the point of machining, resulting in a significant decrease in the total airborne mist concentration.
Technical Paper

Oxidation of 1-Butene and n-Butane at Elevated Pressures

1991-10-01
912317
The oxidation of 1-butene and n-butane in air at elevated pressure was investigated in a high pressure chemical flow reactor. Results are presented for pressures of 3, 6, and 10 atm, temperatures near 900K, and lean equivalence ratio. Gas samples were analyzed using gas chromatography with aldehydes sampled using a dinitrophenylhydrazine/acetonitrile procedure employing gas chromatography/mass spectrometry analysis. Major common products observed include CO, CH2O, C2H4, C3H6, and CO2. Additional major products included 1,3-C4H6 for 1-butene and 1-C4H8 for n-butane. Fuel conversion was increased with increased pressure, temperature, and equivalence ratio with 1-butene more reactive than n-butane. Large levels of lower molecular weight carbonyls resulted from 1-butene whereas significant amounts of conjugate and lower molecular weight alkenes resulted from n-butane. Trends in product distributions with increasing pressure were successfully accounted for by current autoignition theories.
Technical Paper

Oxidation Stability of Some Phosphorus - Free Fully Formulated Crankcase Oils

1998-10-19
982581
Legislation world-wide has made it necessary to find ways to control the level of engine emissions and reduce the damage to our environment. Increasing restrictions have made the elimination of zinc dithiophosphates from crankcase oils and increasing the effectiveness of catalytic converters viable options. Lead and phosphorus containing compounds in the exhaust are known catalyst poisons that shorten the life of current automotive catalysts. Unleaded fuel has successfully resulted in a reduction of harmful emissions due to the fuel. Current government and industry research is actively pursuing replacement of phosphorus additives with phosphorus free additives. Several phosphorus-free oils were developed and are evaluated in bench tests in this study. Test comparisons with phosphorus- containing oils demonstrated satisfactory oxidation stability and wear performance of the phosphorus free oils.
Technical Paper

New High Strength Steels Applied to the Body Structure of ULSAB-AVC

2001-10-16
2001-01-3042
In the ULSAB Project released in 1998, high strength steels (HSS) were applied to 90 percent of the body and structural components, and a mass saving of 25 percent compared to an average of benchmark vehicles was achieved. In the ULSAB-Advanced Vehicle Concepts (AVC) Project, high strength steels are used for most of the components, but many of these materials are identified as ultra high strength steel (UHSS) grades of advanced high strength steels. These grades include dual phase (DP) from 280 MPa yield (YS) to 1000 MPa tensile (UTS), complex phase (CP) 700/800 MPa (YS/UTS), and martensitic (Mart) 1200 MPa and 1520 MPa (UTS) grades. This paper reviews how these materials are applied to specific parts of the ULSAB-AVC Class-C and Class-PNGV vehicle concepts and the reasons for their selection. It also compares the materials used in the body structures of ULSAB and ULSAB-AVC
Technical Paper

Modeling of Strain Rate Effects in Automotive Impact

2003-03-03
2003-01-1383
This paper deals with the effects of various approaches for modeling of strain rate effects for mild and high strength steels (HSS) on impact simulations. The material modeling is discussed in the context of the finite element method (FEM) modeling of progressive crush of energy absorbing automotive components. The characteristics of piecewise linear plasticity strain rate dependent material model are analyzed and various submodels for modeling of impact response of steel structures are investigated. The paper reports on the ranges of strains and strain rates that are calculated in typical FEM models for tube crush and their dependence on the material modeling approaches employed. The models are compared to the experimental results from drop tower tests.
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