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Air can be enriched with oxygen and/or nitrogen by selective permeation through a nonporous polymer membrane; this concept offers numerous potential benefits for piston engines. The use of oxygen-enriched intake air can significantly reduce exhaust emissions (except NOx), improve power density, lessen ignition delay, and allow the use of lower-grade fuels. The use of nitrogen-enriched air as a diluent can lessen NOx emissions and may be considered an alternative to exhaust gas recirculation (EGR). Nitrogen-enriched air can also be used to generate a monatomic-nitrogen stream, with nonthermal plasma, to treat exhaust NOx. With such synergistic use of variable air composition from an on-board polymer membrane, many emissions problems can be solved effectively. This paper presents an overview of different applications of air separation membranes for diesel and spark-ignition engines. Membrane characteristics and operating requirements are examined for use in automotive engines.

Numerical modeling of fuel injection in internal combustion engines in a Lagrangian framework requires the use of a spray-wall interaction sub-model to correctly assess the effects associated with spray impingement. The spray impingement dynamics may influence the air-fuel mixing and result in increased hydrocarbon and particulate matter emissions. One component of a spray-wall interaction model is the splashed mass fraction, i.e. the amount of mass that is ejected upon impingement. Many existing models are based on relatively large droplets (mm size), while diesel and gasoline sprays are expected to be of micron size before splashing under high pressure conditions. It is challenging to experimentally distinguish pre- from post-impinged spray droplets, leading to difficulty in model validation.

The successful commercialization of Electric Vehicles (EVs) and Hybrid Electric Vehicles (HEVs) can provide significant benefits by reducing the United States' growing dependence on petroleum fuels for transportation; decreasing polluting and greenhouse gas emissions; and facilitating a long-term transition to sustainable renewable energy sources. Recognizing these benefits, the U.S. Department of Energy (DOE) supports an active program of long-range R&D to develop electric vehicle (EV) and hybrid electric vehicle (HEV) technologies and to accelerate their commercialization. The DOE Office of Advanced Automotive Technologies (OAAT) supports several innovative R&D programs, conducted in partnership with DOE's national laboratories, industry, other government agencies, universities, and small businesses. The Office has two key R&D cooperative agreements with the U.S. Advanced Battery Consortium (USABC) to develop high-energy batteries for EVs and high-power batteries for HEVs.

Over the past couple of years, Argonne National Laboratory has tested, analyzed, and validated automobile models for the light duty vehicle class, including several types of powertrains including conventional, hybrid electric, plug-in hybrid electric and battery electric vehicles. Argonne’s previous works focused on the light duty vehicle models, but no work has been done on medium and heavy-duty vehicles. This study focuses on the validation of shifting control in advanced automatic transmission technologies for medium duty vehicles by using Argonne’s model-based high-fidelity, forward-looking, vehicle simulation tool, Autonomie. Different medium duty vehicles, from Argonne’s own fleet, including the Ram 2500, Ford F-250 and Ford F-350, were tested with the equipment for OBD (on-board diagnostics) signal data record. For the medium duty vehicles, a workflow process was used to import test data.

This paper reports our efforts to develop an instrument, TG-1, to measure particulate emissions from diesel engines in real-time. TG-1 while based on laser-induced incandescence allows measurements at 10 Hz on typical engine exhausts. Using such an instrument, measurements were performed in the exhaust of a 1.7L Mercedes Benz engine coupled to a low-inertia dynamometer. Comparative measurements performed under engine steady state conditions showed the instrument to agree within ±12% of measurements performed with an SMPS. Moreover, the instrument had far better time response and time resolution than a TEOM® 1105. Also, TG-1 appears to surpass the shortcomings of the TEOM instrument, i.e., of yielding negative values under certain engine conditions and, being sensitive to external vibration.

An increase in spark-ignition engine efficiency can be gained by increasing the engine compression ratio, which requires fuels with higher knock resistance. Oxygenated fuel components, such as methanol, ethanol, isopropanol, or iso-butanol, all have a Research Octane Number (RON) higher than 100. The octane numbers (ON) of fuels are rated on the CFR F1/F2 engine by comparing the knock intensity of a sample fuel relative to that of bracketing primary reference fuels (PRF). The PRFs are a binary blend of iso-octane, which is defined to an ON of 100, and n-heptane, which represents an ON of 0. Above 100 ON, the PRF scale continues by adding diluted tetraethyl lead (TEL) to iso-octane. However, TEL is banned from use in commercial gasoline because of its toxicity. The ASTM octane number test methods have a “Fit for Use” test that validate the CFR engine’s compliance with the octane testing method by verifying the defined ON of toluene standardization fuels (TSF).

The propulsion system in most Electric Drive Vehicles (EDVs) requires an internal combustion engine in combination with an alternating current (AC) electric motor. An electronic device called a power inverter converts battery DC voltage into AC power for the motor. The inverter must be decoupled from the DC source, so a large DC-link capacitor is placed between the battery and the inverter. The DC-link capacitors in these inverters negatively affect the inverters size, weight and assembly cost. To reduce the design/cost impact of the DC-link capacitors, low loss, high dielectric constant (κ) ferroelectric materials are being developed. Ceramic ferroelectrics, such as (Pb,La)(Zr,Ti)O3 [PLZT], offer high dielectric constants and high breakdown strength. Argonne National Laboratory and Delphi Electronics & Safety have been developing thin-film capacitors utilizing PLZT.

The introduction of Toyota's hybrid electric vehicle (HEV), the Prius, in Japan has generated considerable interest in HEV technology among U.S. automotive experts. In a follow-up survey to Argonne National Laboratory's two-stage Delphi Study on electric and hybrid electric vehicles (EVs and HEVs) during 1994-1996, Argonne researchers gathered the latest opinions of automotive experts on the future “top-selling” HEV attributes and costs. The experts predicted that HEVs would have a spark-ignition gasoline engine as a power plant in 2005 and a fuel cell power plant by 2020. The projected 2020 fuel shares were about equal for gasoline and hydrogen, with methanol a distant third. In 2020, HEVs are predicted to have series-drive, moderate battery-alone range and cost significantly more than conventional vehicles (CVs). The HEV is projected to cost 66% more than a $20,000 CV initially and 33% more by 2020.

A two-stage Delphi study was conducted to collect information that would enable a technical and economic assessment of electric (EV) and hybrid electric (HEV) vehicles. The first-stage worldwide survey was completed in fall 1994 while the second-stage was completed by summer 1995. The paper reports results from the second round of the survey and the major differences between the two rounds. This second-stage international survey obtained information from 93 expert respondents from the automotive technology field. The second stage response provided the following key results. EVs will penetrate the market first followed by internal combustion engine powered HEVs while gas turbine and fuel cell powered HEVs will not have any significant penetration until after 2020. By 2020 EVs and internal combustion engine powered HEVs are projected to have approximately a 15% share of the new vehicle market.

Argonne National Laboratory (ANL), working with the Partnership for a New Generation of Vehicles (PNGV), maintains hybrid vehicle simulation software, the PNGV System Analysis Toolkit (PSAT). PSAT, originally proprietary, has been used by both DOE and the “Big Three” as a modeling tool. The number of PSAT users has increased recently because 15 universities participating in the 2001 FutureTruck competition were given the software for their use. PSAT allows companies to look at new types of vehicles (hybrids) and choose the best configuration according to customer expectations within a minimum of time. PSAT, a forward-looking model, allows the user to simulate a large number of different configurations (conventional, series, parallel, and power split). PSAT is well suited for development of control strategies; by using accurate dynamics component models as its code, PSAT can be implemented directly and tested at the bench scale or in a vehicle.

Current-production hybrid electric vehicles (HEVs) have shown a measurable improvement in fuel economy, in comparison with conventional vehicles, by using the internal combustion engine in a more efficient operating region, which therefore reduces petroleum consumption. These HEVs operate with a charge-sustaining control strategy. Plug-in HEVs (PHEVs) show the potential to further decrease petroleum consumption by operating in a charge-depletion control strategy, in which the energy stored in the battery pack in used during normal driving and recharged through stationary, off-board vehicle charging. This charge-depletion strategy uses more electrical energy to propel the vehicle, which displaces more petroleum. This paper discusses the testing and analysis of a Hymotion Prius PHEV, an Energy CS Prius PHEV, and a Renault Kangoo PHEV.

Several plug-in hybrid electric vehicles (PHEVs) have recently been made available by conversion companies for laboratory testing. The viability of the technology must be evaluated by dynamometer benchmark testing, but because the technology is so new, existing and new test methods must first be investigated. Converted Gen 2 Toyota Prius vehicles from Hymotion, EnergyCS, and Hybrids Plus were tested at Argonne's dynamometer facility according to general testing concepts. These vehicles all share basic attributes - all are blended type PHEVs, all use Lithium battery technology, and all deplete charge in a similar fashion (although at different rates). In a time span of one year, lessons learned from one vehicle were carried over into the next test vehicle. A minimum test method was formulated that is well suited for all these vehicles. The method was validated with two vehicles of varying charge-depleting range.

Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications [1,2,3,4]. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH3 storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH3 storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH3 slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.

Alternative fuels for internal combustion engines have been the subject of numerous studies. The new U.S. Renewable Fuel Standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion gallons by 2022. Because corn-based ethanol will be capped at 15 billion gallons, 21 billion gallons must come from the advanced biofuels category. A potential source to fill the gap may be butanol and its isomers as they possess fuel properties superior to ethanol. Recently, concerns have been raised about emission of currently non-regulated constituents, aldehydes in particular, from alcohol-based fuels. In an effort to assess the relative impact of the U.S. Renewable Fuel Standards on emissions from a modern gasoline engine, both regulated and non-regulated gas constituents were measured from the combustion of three different alcohol isomers in a modern direct-injected (DI) spark ignition (SI) gasoline engine.

A new type of approval procedure for light-duty vehicles, the Worldwide harmonized Light vehicles Test Procedure (WLTP), developed by an initiative of the United Nations Economic Commission for Europe, will come into force by the end of 2017. The current European type-approval procedure for energy consumption and CO2 emissions of cars, the New European Driving Cycle (NEDC), includes a number of tolerances and flexibilities that no longer accurately reflect state-of-the-art technologies. Indeed, on the basis of an analysis of real-world driving data from the German website spritmonitor.de, the ICCT concluded that the differences between official laboratory and real-world fuel consumption and CO2 values were around 7% in 2001. This discrepancy has been increasing continuously since then to around 30% in 2013, with notable differences found between individual manufacturers and vehicle models.

Numerical simulations of soot formation were performed for n-dodecane spray using the transported probability density function (TPDF) method. Liquid n-dodecane was injected with 1500 bar fuel pressure into a constant-volume vessel with an ambient temperature, oxygen volume fraction and density of 900 K, 15% and 22.8 kg/m3, respectively. The interaction by exchange with the mean (IEM) model was employed to close the micro-mixing term. The unsteady Reynolds-averaged Navier-Stokes (RANS) equations coupled with the realizable k-ε turbulence model were used to provide turbulence information to the TPDF solver. A 53-species reduced n-dodecane chemical mechanism was employed to evaluate the reaction rates. Soot formation was modelled with an acetylene-based two-equation model which accounts for simultaneous soot particle inception, surface growth, coagulation and oxidation by O2 and OH.

In this study, three batteries were designed and these designs were evaluated in a hybrid vehicle simulation program. The battery designs were based on laboratory tests of 18650 cells for which a Lumped Parameter Battery Model was employed to correlate the cell impedance data. The three battery designs were each tested on three driving cycles, the Federal Urban Driving Schedule, the Highway Fuel Economy Test, and a special cycle developed to test the full power of the vehicle. The results of these simulation tests showed that the battery impedances were low for much of the time because the discharging and charging currents are not maintained at high levels for long periods of time on these cycles. For these conditions, the rates of heat generation in the batteries that were calculated by the simulation programs were low and may not be a serious problem.

Safety issues and current transport (shipment and b-vehicle use) and environmental regulations applicable to sodium-sulfur batteries for electric vehicles are summarized, and an assessment technique is suggested for evaluating potential hazards relative to commonly accepted risks. It is found that shipment regulations do not directly apply to sodium-sulfur batteries. Disposal hazards need to be quantified and decommissioning procedures need to be developed to comply with the environmental regulations. The risk assessment could be used to help commercialize sodium-sulfur and other advanced batteries in electric vehicles.

Cavitation plays an important role in fuel injection systems. It alters the nozzle's internal flow structure and discharge coefficient, and also contributes to injector wear. Quantitatively measuring and mapping the cavitation vapor distribution in a fuel injector is difficult, as cavitation occurs on very short time and length scales. Optical measurements of transparent model nozzles can indicate the morphology of large-scale cavitation, but are generally limited by the substantial amount of scattering that occurs between vapor and liquid phases. These limitations can be overcome with x-ray diagnostics, as x-rays refract, scatter and absorb much more weakly from phase interfaces. Here, we present an overview of some recent developments in quantitative x-ray diagnostics for cavitating flows. Measurements were conducted at the Advanced Photon Source at Argonne National Laboratory, using a submerged plastic test nozzle.

It is widely understood that cold ambient temperatures negatively impact vehicle system efficiency. This is due to a combination of factors: increased friction (engine oil, transmission, and driveline viscous effects), cold start enrichment, heat transfer, and air density variations. Although the science of quantifying steady-state vehicle component efficiency is mature, transient component efficiencies over dynamic ambient real-world conditions is less understood and quantified. This work characterizes wheel assembly efficiencies of a conventional and electric vehicle over a wide range of ambient conditions. For this work, the wheel assembly is defined as the tire side axle spline, spline housing, bearings, brakes, and tires. Dynamometer testing over hot and cold ambient temperatures was conducted with a conventional and electric vehicle instrumented to determine the output energy losses of the wheel assembly in proportion to the input energy of the half-shafts.