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In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.

To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

BMW's concept for recycling old cars seeks to avoid shredder residues in the recycling process to the greatest possible extent. Any absolutely unavoidable, non-utilizable residues are to be suitable for disposal at domestic waste sites. An important feature of this recycling concept is the removal of operating fluids and dismantling of any components, parts and materials worthy of further use from old cars. This corporate policy, supported by legal standards calls for the automobile recycler to meet increasing demands in terms of facilities and equipment as internal processes. Proper fulfilment of these requirements is indeed a fundamental prerequisite for companies wishing to be accepted within the network of recycling plants. Like the production of vehicles, the subsequent utilisation and recycling of vehicles must be considered in the light of economic criteria.

The new BMW Aerodynamisches Versuchszentrum (AVZ) wind tunnel center includes a full-scale wind tunnel, "The BMW Windkanal" and an aerodynamic laboratory "The BMW AEROLAB." The AVZ facility incorporates numerous new technology features that provide design engineers with new tools for aerodynamic optimization of vehicles. The AVZ features a single-belt rolling road in the AEROLAB and a five-belt rolling road in the Windkanal for underbody aerodynamic simulation. Each of these rolling road types has distinct advantages, and BMW will leverage the advantages of each system. The AEROLAB features two overhead traverses that can be configured to study vehicle drafting, and both static and dynamic passing maneuvers. To accurately simulate "on-road" aerodynamic forces, a novel collector/flow stabilizer was developed that produces a very flat axial static pressure distribution. The flat static pressure distribution represents a significant improvement relative to other open jet wind tunnels.

For the first time in volume production, supporting welded aluminum structures were used in the chassis area. Metal sheets, extruded sections, longitudinally seam welded pipes and castings were used as semi-finished products. Extensive strength tests, in cooperation with the Design Department and Production, resulted in sophisticated design solutions. In considering matters important to the customer, these solutions were substantiated through numerous examinations which are especially necessary for aluminum.

A study was performed to develop optimum design strategies for a production V6 engine to maximize catalyst performance at minimum pressure loss and at minimum cost. Test results for an advanced system, designed to meet future emission limits on a production V6 vehicle, are presented based on FTP testing. The on-line pressure loss and temperature data serves to explain the functioning of the catalyst.

For the measurement of exhaust emissions, Constant Volume Sampling (CVS) technology is recommended by legislation and has proven its practical capability in the past. However, the introduction of new low emission standards has raised questions regarding the accuracy and variability of the CVS system when measuring very low emission levels. This paper will show that CVS has the potential to achieve sufficient precision for certification of SULEV concepts. Thus, there is no need for the introduction of new test methods involving high cost. An analysis of the CVS basic equations indicates the importance of the Dilution Factor (DF) for calculating true mass emissions. A test series will demonstrate that, by adjusting the dilution and using state of the art analyzers, the consistency of exhaust results is comparable with those of LEV concepts, measured with conventional CVS systems and former standard analyzers.

Sensing and acting elements to guarantee the locking functions of seat belt retractors can emit noise when the retractor is subjected to externally applied vibrations. For these elements to function correctly, stiffness, inertia and friction needs to be in tune, leading to a complex motion resistance behavior, which makes it delicate to test for vibration induced noise. Requirements for a noise test are simplicity, robustness, repeatability, and independence of laboratory and test equipment. This paper reports on joint development activities for an alternative test procedure, involving three test laboratories with different equipment. In vehicle observation on parcel shelf mounted retractors, commercially available test equipment, and recent results from multi-axial component tests [1], set the frame for this work. Robustness and reliability of test results is being analyzed by means of sensitivity studies on several test parameters.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

Emissions during the useage phase of vehicles are of increasing interest in environmental protection, and consequently, there is considerable interest in exhaust systems. The automotive exhaust system including the catalytic converter is, because of the precious metals in the catalyst, of particular interest for the recycling of automotive parts. The paper will describe the recycling technology of ceramic and metal catalyst substrates. The process will be analyzed in detail with the example of metal supports. As a result the complete life cycle and the recycling efficiency are presented.

BMW - the driving force for progress As we approach the new millenium, to ensure the continuation of the progress into the future, BMW uses leading edge approaches in its materials research and processing. Overview production sites all over the world - Plant Dingolfing Quality requirements for automobile painting The complex and wide-ranging demands that the outer skin of an automobile has to meet offered us the chance to advance with a technological leap from liquid clear coat to the potentials of powder clear coat. The new clear coat technology The clear coat creates the ultimate gloss effect - and powder-based clear coat makes the surface of the car even more brilliant. To achieve this effect the body is covered by microscopically small paint particles. A pioneer achievement A lot of challenges in both material development and systems-engineering had to be made. The automotive world was watching, many experts said it could not be successfully used as an OEM clear coat.

A particulate trap with combined regeneration has been developed for use in light duty vehicles with diesel engines. This new system was tested first on an engine test rig. On-road vehicle tests are going on since August 1998. The results obtained clearly demonstrate the feasibility of this system. With this system trap regeneration has to be ensured under worst case conditions (exhaust gas temperature<400° C). To meet this requirement electrical heating in combination with a fuel-borne catalyst is applied. Different filter materials such as cordierite wall flow and silicon carbide monoliths were tested on the engine test rig. The paper reports on results from the engine test rig as well as from on-road vehicle testing. An overview about pre-heating and regeneration examples are given and energy balances are presented.

Future emission legislation can be met through substantial improvement in the effectiveness of the exhaust gas after-treatment system, the engine and the engine management system. For the catalytic converter, differentiation is necessary between the cold start behavior and the effectiveness at operating temperature. To be catalytically effective, a converter must be heated by the exhaust gas up to its light-off temperature. The major influential parameter for the light-off still is the supply of heat from the exhaust gas. Modification of the cold start calibration of engine control such as spark retard or increased idle speed can increase the temperature level of the exhaust gas. One further possibility is represented by a reduction of the critical mass ahead of the catalyst (exhaust manifold and pipe). Nevertheless the best measure to obtain optimal cold start effectiveness still seems to be locating the converter close to the engine.

Current regulatory developments aim for stricter emission limits, increased environmental protection and purification of air on a local and global scale. In order to find solutions for a cleaner combustion process, it is necessary to identify the critical components and parameters responsible for the formation of emissions. This work provides an evaluation process for particle formation during combustion of a modern direct injection engine, which can help to create new aftertreatment techniques, such as a gasoline particle filter (GPF) system, that are fit for purpose. With the advent of “real driving emission” (RDE) regulations, which include market fuels for the particulate number testing procedure, the chemical composition and overall quality of the fuel cannot be neglected in order to yield a comparable emission test within the EU and worldwide.

Future catalyst systems need to be highly efficient in a limited packaging space. This normally leads to a design where the flow distribution, in front of the catalyst, is not perfectly uniform. Measurements on the flow test bench show that the implementation of perforated foils for the corrugated and flat foils has the capability to distribute the flow within the channels in the radial direction so that the maximum of the given catalyst surface is of use, even under very poor uniformity indices. Therefore a remarkable reduction in back pressure is measured. Emission results demonstrate cold start improvement due to reduced heat capacity. The use of LS - structured ( Longitudinal structured ) corrugated foils creates a high turbulence level within the single channels. The substrate lights-up earlier and the maximum conversion efficiency is reached more quickly.

In order to match catalyst OBDII conditions the common procedure is oven aging with air, which is not suitable for complete converter systems due to mantle corrosion. The goal was, therefore, to find an alternative procedure to ensure a defined catalyst aging that would match 1,75 times the emission standard and is also good for SULEV. The new procedure currently being developed allows the aging of metal and ceramic catalysts as well as complete catalyst systems. The paper will present the aging process, emission data of fresh and aged catalysts and the feedback to the test car OBDII system.

Nearly all real Diesel engine operation is leading to low exhaust temperatures. Standard catalyst technique remains therefore for significant time below light off. To improve the conversion behavior two approaches were made: placement of tailor fitted catalysts as close as possible to the engine exhaust port before turbocharger and usage of close coupled catalysts with the so-called hybrid design. Both measures are providing visible progress in reducing Diesel engine emissions. Tests were made with modern Diesel engines both for passenger cars and heavy duty vehicles.

There is a common understanding that hydrogen has a great potential to be the fuel of the future. In addition to the challenge of developing appropriate hydrogen propulsion systems the development of hydrogen storage systems is the second big issue. Due to its high potential in cost and weight and specific storage capacity, the BMW Group is focusing on the development of liquid hydrogen storage systems. In the next hydrogen 7-Series the BMW Group is about to make for the first time the step from demonstration fleets to cars used by external users with a liquid hydrogen storage system. To realize this significant goal, special focus has to be put on high safety standards so that hydrogen can be considered as safe as common types of fuel, and on the every day reliability of the storage system. Moreover, the development of strong partnerships with suppliers is a key factor to realize the design and identify appropriate manufacturing processes.