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Technical Paper

Year-Long Evaluation of Trucks and Buses Equipped with Passive Diesel Particulate Filters

2002-03-04
2002-01-0433
A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.
Technical Paper

Understanding degradation of engine oil additives and its effect on abnormal combustion in a gasoline engine

2023-09-29
2023-32-0035
Engine oils and their additives are formulated to meet required performance areas such as lubrication, detergency, dispersancy, anti-wear, and so on. Understanding degradation of engine oil additives is important to formulate oils with long time durability. Engine oil additives have been found to affect abnormal combustion in turbocharged gasoline direct injection (TGDI) engines, called low speed pre-ignition (LSPI). Some of metal containing additives such as zinc dithiophosphates (ZnDTP) and molybdenum dithiocarbamates (MoDTC) have been found to reduce LSPI events. In this study, we investigated degradation of ZnDTP and MoDTC in gasoline engine operation and effects of the degradation on LSPI performance.
Journal Article

The Impact of Lubricant Viscosity and Additive Chemistry on Fuel Economy in Heavy Duty Diesel Engines

2011-08-30
2011-01-2124
The heightened interest level in Fuel Economy for Heavy Duty Diesel Engines the industry has seen over the last few years continues to be high, and is not likely to change. Lowering the fuel consumption of all internal combustion engines remains a priority for years to come, driven by economic, legislative, and environmental reasons. While it is generally assumed that lower viscosity grade lubricants offer fuel economy benefits, there is a lot of confusion about exactly what drives the fuel economy benefits. Fuel Economy claims in trade literature vary over a broad range and it is difficult for the end user to determine what to expect when a change in lubricant viscosity is adopted for a fleet of vehicles in a certain type of operation. This publication makes an attempt at clarifying a number of these uncertainties with the help of additional engine test data, and more extensive data analysis.
Technical Paper

The Effect of a Turbocharger Clearance Control Coating on the Performance and Emissions of a 2-Stroke Diesel Engine

1999-10-25
1999-01-3665
Extensive efforts are being made to improve emissions from 2-stroke diesel engines. These improvements are primarily directed towards older model year engines with relatively high emissions compared with modern diesel engines. While most researchers focus their attention on engine design changes that promise substantial emission improvements, this work dealt with the turbocharger characteristics, especially as related to using internal coatings on both the compressor and turbine housings. Two identical turbochargers were tested on a Detroit Diesel 6V-92TA engine. One of the two turbochargers was left in its production configuration while the other was coated with a clearance control coating on the inside of the compressor and turbine housings. This coating led to a significant reduction in the tip clearance of both the compressor and turbine wheels.
Technical Paper

Save the Diesel Fueled Engine: A Clean Diesel Engine with Catalytic Aftertreatment - The Alternative to Alternate Fuels

1993-04-01
931182
Off-Highway diesel engines may benefit from exhaust emission control systems developed for on-highway vehicles. Both the diesel oxidation catalyst and the catalytic soot filter are being used to remove diesel smoke and odor. The advantages of both of these technologies are explained. NOx emissions control from diesel engines are now being addressed. Alternate fuels, such as methanol or natural gas, have been designed to replace diesel fuel as a measure to control NOx emissions. To avoid transfer to alternate fuels and permit continued use of diesel fuel in diesel engines, two approaches are being studied. These are the use of exhaust gas recirculation (EGR) and the development of a new technology called a lean NOx reduction catalyst. EGR, if successfully developed, probably will require the use of a catalytic soot filter. Lean NOx catalysts have been developed but still are not at a practical stage yet.
Technical Paper

PremAir® Catalyst System – A New Approach to Cleaning the Air

1999-10-25
1999-01-3677
Classical approaches to pollution control have been to develop benign, non-polluting processes or to abate emissions at the tailpipe or stack before release to the atmosphere. A new technology called PremAir® Catalyst Systems1 takes a different approach and reduces ambient, ground level ozone directly. This technology takes advantage of the huge volumes of air which are processed daily by both mobile and stationary heat exchange devices. For mobile applications, the new system involves placing a catalytic coating on a vehicle's radiator or air conditioning condenser. For stationary applications, the catalytic coating typically is applied to an insert, which is attached to the air conditioning condenser. In either case, the catalyst converts ozone to oxygen as ozone containing ambient air passes over the coated radiator or condenser surfaces.
Technical Paper

PremAir® Catalyst System

1998-10-19
982728
Traditional approaches to pollution control have been to develop benign non-polluting processes or to abate emissions at the tailpipe or stack before emitting to the atmosphere. A new technology called PremAir®* Catalyst Systems takes a different approach and directly reduces ambient ground level ozone. This technology can be applied to both mobile and stationary applications. For automotive applications, the new system involves placing a catalytic coating on the car's radiator or air conditioner condenser. As air passes over the radiator or condenser, the catalyst converts the ozone into oxygen. Three Volvo vehicles with a catalyst coating on the radiator were tested on the road during the 1997 summer ozone season in southern California to assess performance. Studies were also conducted in Volvo's laboratory to determine the effect of the catalyst coating on the radiator's performance with regard to corrosion, heat transfer and pressure drop.
Technical Paper

In-Service Evaluation of Performance Enhancing Coatings for a Heavy Duty Diesel Truck Engine

1999-10-25
1999-01-3666
This paper presents the results of an on-road evaluation of in-cylinder ceramic thermal barrier coating GPX″-4M and turbocharger clearance control coating. Engelhard Corporation carried out the testing as a part of a pre-production product development and evaluation process. Contained in the paper are the results of a three-year long experiment conducted on an Engelhard's truck. Discussed in the paper are in-service performance and durability of Engelhard's coating. The experimental fuel usage data underwent substantial statistical treatment and analysis. In combination with the unique test conditions this allowed credible conclusions regarding the truck fuel economy. It was clearly demonstrated that the truck equipped with in-cylinder GPX coated components used 1.4% less fuel than a standard truck for the same amount of work performed over a 16-month period. This fuel saving is associated with the engine rebuild.
Journal Article

Frictional Properties of Molybdenum-Based Lubricating Oil Additives Using Green Chemistry

2011-08-30
2011-01-2131
In this study, a green process was developed to synthesize a novel molybdenum disulfide (MoS₂)-based friction modifier (FM) for improving fuel economy performance of lubricants. These new materials were synthesized using less hazardous elemental sulfur as opposed to other sulfur sources like hydrogen sulfide (H₂S) and carbon disulfide (CS₂). Using various bench and motoring friction torque tests, it was shown that friction reduction was benefited by utilizing low molecular weight organic backbone when designing molybdenum FMs. Also, it was shown that newly synthesized molybdenum-based FMs were comparable to other well-known MoS₂ precursors.
Journal Article

Extending the Boundaries of Diesel Particulate Filter Maintenance With Ultra-Low Ash - Zero-Phosphorus Oil

2012-09-10
2012-01-1709
By 2014, all new on- and off-highway diesel engines in North America, Europe and Japan will employ diesel particulate filters (DPF) in the exhaust in order to meet particulate emission standards. If the pressure across the DPF increases due to incombustibles remaining after filter regeneration, the exhaust backpressure will increase, and this in turn reduces fuel economy and engine power, and increases emissions. Due to engine oil consumption, over 90% of the incombustibles in the DPF are derived from inorganic lubricant additives. These components are derived from calcium and magnesium detergents, zinc dithiophosphates (ZnDTP) and metal-containing oxidation inhibitors. They do not regenerate as they are non-volatile metals and salts. Consequently, the DPF has to be removed from the vehicle for cleaning. Ashless oil could eliminate the need for cleaning.
Technical Paper

Enhancement of the Sequence IIIG by the Study of Oil Consumption

2004-06-08
2004-01-1893
The Sequence IIIG is a newly developed 100 hour test used to evaluate the performance of crankcase engine oils in the areas of high temperature viscosity increase, wear, deposits, pumpability, and ring sticking for the North American GF-4 standard. Data from the ASTM Precision Matrix, completed in the spring of 2003, along with early reference data from the Lubricant Test Monitoring System (LTMS) showed unexpected test results for selected oils and indicated that percent viscosity increase and pumpability were highly correlated with oil consumption. This correlation led to an intensive study of the factors that influence oil consumption and an attempt to compensate for non-oil related oil consumption through a model based adjustment of the results. The study and scrutiny of the IIIG data has led to more uniform oil consumption in the test and improved test precision, and has eliminated the need for a correction equation based on non-oil related oil consumption.
Technical Paper

Engine Dynamometer and Vehicle Performance of a Urea SCR-System for Heavy-Duty Truck Engines

2002-03-04
2002-01-0286
The application of SCR deNOx aftertreatment was studied on two about 12 liter class heavy-duty diesel engines within a consortium project. Basically, the system consists of a dosage system for aqueous urea injection and a vanadia based SCR catalyst, without an upstream or downstream oxidation catalyst. The urea injection system for a DAF and a Renault V.I. (Véhicules Industriels) diesel engine was calibrated on the engine test bench taking into account dynamic effects of the catalyst. For both engine applications NOx reduction was 81% to 84% over the ESC and 72% over the ETC. CO emission increased up to 27%. PM emission is reduced by 4 to 23% and HC emission is reduced by more than 80%. These results are achieved with standard diesel fuel with about 350 ppm sulfur. The test engines and SCR deNOx systems were built into a DAF FT95 truck and a Renault V.I. Magnum truck.
Technical Paper

Emissions Implications of a Twin Close Coupled Catalyst System Designed for Improved Engine Performance on an In-line 4 Cylinder Engine

2002-03-04
2002-01-1092
The emission capability of an exhaust system tuned for improved engine performance from an in-line four-cylinder engine has been investigated. The exhaust system comprises two close-coupled catalysts; each located in separate exhaust streams and has been termed the 4-2 close-coupled catalysts (CCC) -1 system. It has been shown that, given equivalent total catalyst volume, this system configuration results in compromised high exhaust flow rate emissions performance compared with a single catalyst (4-1semi-CCC) system. This emissions performance deficit has been attributed to the effect of engine frequency flow pulsations, which result in relatively high peak space velocities in the 4-2CCC-1 system despite the mean space velocity being consistent. Engine-based AFR Bias Sweep tests suggest that hydrocarbon emissions are most strongly affected by this phenomenon. At lower exhaust flow rates, the difference in performance between the two systems is negligible.
Technical Paper

Effects of Sulfur on Performance of Catalytic Aftertreatment Devices

1992-02-01
920557
In the effort to design reliable diesel engines which meet the strict US Federal Regulations for emissions, considerable progress has been made by engine manufacturers. Particulate emissions are now below 0.25 g/BHPh and after 1994 will be below 0.1 g/BHPh. Diesel fuel has a revised specification limit of 0.05% sulfur as a means to assist diesel engine manufacturers in complying with the 1994 standard. Diesel oxidation catalysts (DOC) have been chosen as another means. A DOC can efficiently oxidize soluble organic particulate matter (SOF) and gaseous hydrocarbons while easily oxidizing SO2 to SO3-the latter being a particulate and undesirable. Selective DOCs have been developed which maintain the activity for SOF and minimize the undesirable SO2 oxidation step. However, performance for gaseous hydrocarbons may be negatively affected.
Technical Paper

Effect of Low Viscosity Passenger Car Motor Oils on Fuel Economy Engine Tests

2013-10-14
2013-01-2606
The fuel economy performance of passenger car vehicles has been an area of keen focus due to recent environmental regulations. Various efforts such as the development of new engine technologies have been undertaken to improve the fuel economy performance of these vehicles. Engine oils have also been targeted to contribute to better fuel efficiency. This has been done by introducing new lubricant additive technologies and low viscosity grade oils. In the latter case, passenger car motor oils are about to enter into a new generation in which the lower viscosity grade SAE 16 has been approved and discussion has started on the specification of viscosity grades lower than SAE 16, although SAE 0W-20 viscosity grade is the lowest in the SAE J300 specification during last decade. Nevertheless, additive technology is also important, as we previously reported that simple reduction of viscosity grade is not a solution to improve fuel economy performance in the Sequence VID test.
Technical Paper

Diesel Engines Using Low Sulfur Fuel Showing Excellent Performance and Durability with Reduced TBN Lubricants

2006-10-16
2006-01-3437
More stringent emission legislation has been a driver for changes in the design of Heavy Duty Diesel engines since the 1980s. Significant gains have been made over the years but, in 2007 and again in 2010, diesel engines in North America will have to meet even more stringent requirements for particulate matter and nitrogen oxide emissions. A reduction of the sulfur level in diesel fuel to a maximum of 15 mg/kg has been mandated as an enabler for new diesel engine exhaust gas after-treatment systems. Many studies have been published on the impact of the use of low sulfur diesel fuel. The focus of most of these studies has been on the possible impact on exhaust gas after-treatment system durability, but little has been documented on lubricant degradation and on the long term impact on engine durability. The objectives of the field test discussed in this paper were to evaluate the impact of low sulfur fuel and of a reduction in the TBN of the lubricant on lubricant degradation.
Technical Paper

Development of a New Valvetrain Wear Test - The Sequence IVB Test

2016-04-05
2016-01-0891
The study described in this paper covers the development of the Sequence IVB low-temperature valvetrain wear test as a replacement test platform for the existing ASTM D6891 Sequence IVA for the new engine oil category, ILSAC GF-6. The Sequence IVB Test uses a Toyota engine with dual overhead camshafts, direct-acting mechanical lifter valvetrain system. The original intent for the new test was to be a direct replacement for the Sequence IVA. Due to inherent differences in valvetrain system design between the Sequence IVA and IVB engines, it was necessary to alter existing test conditions to ensure adequate wear was produced on the valvetrain components to allow discrimination among the different lubricant formulations. A variety of test conditions and wear parameters were evaluated in the test development. Radioactive tracer technique (RATT) was used to determine the wear response of the test platform to various test conditions.
Technical Paper

Development of a Bench Test to Predict Oxidative Viscosity Thickening in the Sequence IIIG Engine Test

2004-10-25
2004-01-2985
Of all the performance tests in the current International Lubricant Standardization and Approval Committee (ILSAC) GF-3 and GF-4 categories, the Sequence IIIF and Sequence IIIG are among the most difficult for the formulator. The Sequence III engine dynamometer tests place a premium on oxidation, high-temperature deposits, and valve train wear control. Besides appearing in the North American Passenger Car Motor Oil (PCMO) specifications, the Sequence III is required for European gasoline engine oils, for American Petroleum Institute (API) diesel engine oil categories, and for base oil interchanges (BOI) among licensed engine oils. The ability to screen antioxidants for the Sequence III is of special interest for developers of engine oil technology. Antioxidants are the single most expensive component and the search for cost-effective oxidation control is among the top technical hurdles for the North American PCMO categories.
Technical Paper

Development of Chrysler Oxidation and Deposit Engine Oil Certification Test

2015-09-01
2015-01-2045
With the impending development of GF-6, the newest generation of engine oil, a new standardized oil oxidation and piston deposit test was developed using Chrysler 3.6 L Pentastar engine. The performance requirements and approval for passenger car light duty gasoline engine oil categories are set by the International Lubricants Standardization and Approval committee (ILSAC) and the American Petroleum Institute (API) using standardized testing protocols developed under the guidance of ASTM, the American Society for Testing and Materials. This paper describes the development of a new ASTM Chrysler oxidation and deposit test that will be used to evaluate lubricants performance for oil thickening and viscosity increase, and piston deposits.
Technical Paper

Development and Testing of Optimized Engine Oils for Modern Two-Stroke Cycle Direct Fuel Injected Outboard Engines

2006-11-13
2006-32-0018
Despite the recent increase in fuel prices, the multi-billion dollar recreational boating market in North America continues to experience solid momentum and growth. In the U.S. economy alone, sales of recreational boats continue to increase with over 17 million boats sold in 2004 [1]. Of that share, outboard boats and the engines that power them, accounted for nearly half of all boat sales. Though there has been a shift in outboard technology to four-stroke cycle engines, a significant number of new engine sales represent two-stroke cycle engines employing direct fuel injection as a means to meet emissions regulations. With the life span of modern outboards estimated to be 8 to 10 years, a significant base of two-stroke cycle engines exist in the market place, and will continue to do so for the foreseeable future.
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