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In order to provide effective cooling for astronauts during extravehicular activities (EVAs), a liquid cooling and ventilation garment (LCVG) is used to remove heat by a series of tubes through which cooling water is circulated. To better predict the effectiveness of the LCVG and determine possible modifications to improve performance, computer simulations dealing with the interaction of the cooling garment with the human body have been run using the Wissler Human Thermal Model. Simulations have been conducted to predict the heat removal rate for various liquid cooled garment configurations. The current LCVG uses 48 cooling tubes woven into a fabric with cooling water flowing through the tubes. The purpose of the current project is to decrease the overall weight of the LCVG system. In order to achieve this weight reduction, advances in the garment heat removal rates need to be obtained.

An early development vehicle experienced an unusually high rate of windshield breakage. Most breaks were identified as due to impact, but the severity of impact was low. It was reasoned that the windshield should possess a greater level of robustness to impact. Many theories were put forth to explain the breakage data. It was universally agreed that the unusual breakage rate could be due to only one condition, but its source was indefinite. The condition present must be tensile stress. One of three situations were considered regarding its source: 1) the tensile stress was present in the glass after manufacture due to improper annealing; 2) the installation of the windshield into the vehicle body put the glass into stress; 3) some combination of the other two sources. A gray-field polariscope was used to measure the stresses of the windshield from both the manufacturing process as well as the installation in the vehicle.

Spacecraft radiators reject heat to their surroundings. Radiators can be deployable or mounted on the body of the spacecraft. NASA's Crew Exploration Vehicle is to use body mounted radiators. Coatings play an important role in heat rejection. The coatings provide the radiator surface with the desired optical properties of low solar absorptance and high infrared emittance. These specialized surfaces are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an appliqué. Not specifically designed for a weathering environment, little is known about the durability of conventional paints, coatings, and appliqués upon exposure to weathering and subsequent exposure to solar wind and ultraviolet radiation exposure. In addition to maintaining their desired optical properties, the coatings must also continue to adhere to the underlying radiator panel.

The Internal Active Thermal Control System (IATCS) aboard the International Space Station (ISS) contains an aqueous, alkaline fluid (pH 9.5±0.5) that aids in maintaining a habitable environment for the crew. Because microbes have significant potential to cause disease, adverse effects on astronaut health, and microbe-induced corrosion, the presence of both bacteria and viruses within IATCS fluids is of concern. This study sought to detect and identify viral populations in IATCS samples obtained from the Kennedy Space Center as a first step towards characterizing and understanding potential risks associated with them. Samples were concentrated and viral nucleic acids (NA) extracted providing solutions containing 8.87-22.67 μg NA per mL of heat transfer fluid. After further amplification viral DNA and cDNA were then pooled, fluorescently labeled, and hybridized onto a Combimatrix panvira 12K microarray containing probes for ∼1,000 known human viruses.

Spacecraft thermal control systems are essential to provide the necessary thermal environment for the crew and to ensure that the equipment functions adequately on space missions. The Ultralight Fabric Reflux Tube (UFRT) was developed by the Pacific Northwest National Laboratory as a lightweight radiator concept to be used on planetary surface-type missions (e.g., Moon, Mars). The UFRT consists of a thin-walled tube (acting as the fluid boundary), overwrapped with a low-mass ceramic fabric (acting as the primary pressure boundary). The tubes are placed in an array in the vertical position with the evaporators at the lower end. Heat is added to the evaporators, which vaporizes the working fluid. The vapor travels to the condenser end section and condenses on the inner wall of the thin-walled tube. The resulting latent heat is radiated to the environment. The fluid condensed on the tube wall is then returned to the evaporator by gravity.

The Trace Gas Analyzer (TGA, Figure 1) is a self-contained, battery-powered mass spectrometer that is designed for use by astronauts during extravehicular activities (EVA) on the International Space Station (ISS). The TGA contains a miniature quadrupole mass spectrometer array (QMSA) that determines the partial pressures of ammonia, hydrazines, nitrogen, and oxygen. The QMSA ionizes the ambient gas mixture and analyzes the component species according to their charge-to-mass ratio. The QMSA and its electronics were designed, developed, and tested by the Jet Propulsion Laboratory (1,2). Oceaneering Space Systems supported JPL in QMSA detector development by performing 3D computer for optimal volumetric integration, and by performing stress and thermal analyses to parameterize environmental performance.

Space-faring crews must have safe breathing air throughout their missions to ensure adequate performance and good health. Toxicological assessment of air quality depends on the standards that define acceptable air quality, measurements of pollutant levels during the flight, and reports from the crew on their in-flight perceptions of air quality. Air samples returned from ISS on flights 8A, UF2, 9A, and 11A were analyzed for trace pollutants. On average, the air during this period of operations was safe for human respiration. However, about 3 hours into the regeneration of 2 Metox canisters in the U.S. airlock on 20 February 2002 the crew reported an intolerable odor that caused them to stop the regeneration, take refuge in the Russian segment, and scrub air in the U.S. segment for 30 hours. Analytical data from grab samples taken during the incident showed that the pollutants released were characteristic of nominal air pollutants, but were present in much higher concentrations.

There are many sources of air pollution that can threaten air quality during space missions. The International Space Station (ISS) is an extremely complex platform that depends on a multi-tiered strategy to control the risk of excessive air pollution. During the seven missions surveyed by this report, the ISS atmosphere was in a safe, steady-state condition; however, there were minor loads added as new modules were attached. There was a series of leaks of octafluoropropane, which is not directly toxic to humans, but did cause changes in air purification operations that disrupted the steady state condition. In addition, off-nominal regeneration of metal oxide canisters used during extravehicular activity caused a serious pollution incident.

Development of a second generation Electronic Nose at JPL is focusing on optimization of the sensing films to increase sensitivity and optimization of the array. Toward this goal, studies have focused on sources of noise in the films, alternatives to carbon black as conductive medium, measurement techniques, and development of an analytical approach to polymer selection to maximize the abilities of the array to distinguish among compounds.

The Orbiting Carbon Observatory (OCO) instrument is scheduled for launch onboard an Orbital Sciences Corporation LEOStar-2 architecture spacecraft in December 2008. The instrument will collect data to identify CO2 sources and sinks and quantify their seasonal variability. OCO observations will permit the collection of spatially resolved, high resolution spectroscopic observations of CO2 and O2 absorption in reflected sunlight over both continents and oceans. OCO has three bore-sighted, high resolution, grating spectrometers which share a common telescope with similar optics and electronics. A 0.765 μm channel will be used for O2 observations, while the weak and strong CO2 bands will be observed with 1.61 μm and 2.06 μm channels, respectively. The OCO spacecraft circular polar orbit will be sun-synchronous with an inclination of 98.2 degrees, mean altitude of 705 km and 98.9 minute orbit period.

Flexible fiber-reinforced aerogel composites were studied for use as insulation materials of a future space suit for Moon and Mars exploration. High flexibility and good thermal insulation properties of fiber-reinforced silica aerogel composites at both high and low vacuum conditions make it a promising insulation candidate for the space suit application. This paper first presents the results of a durability (mechanical cycling) study of these aerogels composites in the context of retaining their thermal performance. The study shows that some of these Aerogels materials retained most of their insulation performance after up to 250,000 cycles of mechanical flex cycling. This paper also examines the problem of integrating these flexible aerogel composites into the current space suit elements.

A Small Loop Heat Pipe (SLHP) featuring a wick of only 1.27 cm (0.5 inches) in diameter has been designed for use in spacecraft thermal control. It has several features to accommodate a wide range of environmental conditions in both operating and non-operating states. These include flexible transport lines to facilitate hardware integration, a radiator capable of sustaining over 100 freeze-thaw cycles using ammonia as a working fluid and a structural integrity to sustain acceleration loads up to 30 g. The small LHP has a maximum heat transport capacity of 120 Watts with thermal conductance ranging from 17 to 21 W/°C. The design incorporates heaters on the compensation chamber to modulate the heat transport from full-on to full-stop conditions. A set of start up heaters are attached to the evaporator body using a specially designed fin to assist the LHP in starting up when it is connected to a large thermal mass.

For planetary exploration, new thermal insulation materials are needed to deal with unique environmental conditions presented to extravehicular activity (EVA). The thermal insulation material and system used in the existing space suit were specifically designed for low orbit environment. They are not adequate for low vacuum condition commonly found in planetary environments with a gas atmosphere. This study attempts to identify the types of lofty nonwoven thermal insulation materials and the construction parameters that yield the best performance for such application. Lofty nonwovens with different construction parameters are evaluated for their thermal conductivity performance. Three different types of fiber material: solid round fiber, hollow fiber, and grooved fiber, with various denier, needling intensity, and web density were evaluated.

This paper presents the analysis findings of a study reducing the overall mass of the lightweight liquid cooling garment (LCG). The LCG is a garment worn by crew to actively cool the body, for spacesuits and launch/entry suits. A mass reduction of 66% was desired for advanced missions. A thermal math model of the LCG was developed to predict its performance when various mass-reducing changes were implemented. Changes included varying the thermal conductivity and thickness of the garment or of the coolant tubes servicing the garment. A second model was developed to predict behavior of the suit when the cooling tubes were to be removed, and replaced with a highly-conducting (waterless) material. Findings are presented that show significant reductions in weight are theoretically possible by improving conductivity in the garment material.

New advanced Pd only, Pd:Rh and Pt:Pd:Rh catalysts are compared with a current platinum rhodium catalyst after poisoning and thermal ageing. The results indicate that at equivalent precious metal cost (at 1994 prices) the advanced palladium based catalysts achieve significantly improved performance compared with current Pt, Rh and Pd technology. The new Pd:Rh formulation is recommended for close coupled locations and the Pt:Pd:Rh formulation recommended for underfloor locations where residual fuel lead may be present. The formation of H2S is shown to be low with the palladium based catalysts. Finally, it is shown that the new catalysts with balanced oxidation and reduction capability perform better in multi-brick systems than addition of a highly loaded palladium only front brick.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

The effect of hydroforming on the mechanical properties and dynamic crush behaviors of tapered aluminum 6063-T4 tubes with octagonal cross section are investigated by experiments. First, the thickness profile of the hydroformed tube is measured by non-destructive examination technique using ultrasonic thickness gauge. The effect of hydroforming on the mechanical properties of the tube is investigated by quasi-static tensile tests of specimens prepared from different regions of the tube based on the thickness profile. The effect of hydroforming on the dynamic crush behaviors of the tube is investigated by axial crush tests under dynamic loads. Specimens and tubes are tested in two different heat treatment conditions: hydroformed-T4 (as-received) and T6. The results of the quasi-static tensile tests for the specimens in hydroformed-T4 condition show different amounts of work hardening depending on the regions, which the specimens are prepared from.

Progress made in reducing engine-out particulate emissions has prompted a revival in the design of flow-through oxidation catalysts for diesel engine applications. Effort in this area has focused primarily in the area of SOF control for the further reduction of particulate emissions. The work reported here covers some of the catalyst design parameters important for SOF and gas phase pollutant control. This is illustrated with both laboratory reactor and engine evaluation data for several formulary and operating parameters. Platinum-based catalysts are shown to be generally the most active, but they require treatments or additives to reduce the inherently high activity of platinum for the oxidation of SO2 present in the exhaust. The effect of additives and their loading on the oxidation activity of Pt/alumina for HC, CO, SOF and SO2 oxidation is discussed in detail and additives are identified which reduce SO2 oxidation with minimal effect on HC, CO or SOF oxidation activity.

Resonant frequencies of a resonant bending system with notched crankshaft sections are obtained experimentally and numerically in order to investigate the effect of notch depth on the drop of the resonant frequency of the system. Notches with the depths ranging from 1 to 5 mm, machined by an EDM (Electrical-Discharging Machining) system, were introduced in crankshaft sections at the fillet between the main crank pin and crank cheek. The resonant frequencies of the resonant bending system with the crankshaft sections with various notch depths were first obtained from the experiments. Three-dimensional finite element models of the resonant bending system with the crankshafts sections with various notch depths are then generated. The resonant frequencies based on the finite element computations are in good agreement with those based on the experimental results.

This paper reports several slow reversible and quasi-reversible processes which occur in the porous electrode/solid electrolyte combination at AMTEC operating temperatures. These processes help to elucidate the evolution of the electrode and electrolyte characteristics with time. They also demonstrate that the atomic constituents of the electrode/electrolyte engage in significant dynamic motion. We report the stability of the sodium beta“-alumina phase in low pressure sodium vapor at 1173K up to 3000 hours, and the decomposition of the sodium meta-aluminate (NaAlO2) phase present at about 1% in the BASE ceramic, which gives rise to transient local increases in the solid electrolyte resistivity due to local micro-cracking. We also report slow apparent morphological changes, possibly surface or grain boundary reconstruction, in TiN and RhW electrodes driven by changes in the local sodium activity.