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In order to provide effective cooling for astronauts during extravehicular activities (EVAs), a liquid cooling and ventilation garment (LCVG) is used to remove heat by a series of tubes through which cooling water is circulated. To better predict the effectiveness of the LCVG and determine possible modifications to improve performance, computer simulations dealing with the interaction of the cooling garment with the human body have been run using the Wissler Human Thermal Model. Simulations have been conducted to predict the heat removal rate for various liquid cooled garment configurations. The current LCVG uses 48 cooling tubes woven into a fabric with cooling water flowing through the tubes. The purpose of the current project is to decrease the overall weight of the LCVG system. In order to achieve this weight reduction, advances in the garment heat removal rates need to be obtained.

Spacecraft radiators reject heat to their surroundings. Radiators can be deployable or mounted on the body of the spacecraft. NASA's Crew Exploration Vehicle is to use body mounted radiators. Coatings play an important role in heat rejection. The coatings provide the radiator surface with the desired optical properties of low solar absorptance and high infrared emittance. These specialized surfaces are applied to the radiator panel in a number of ways, including conventional spraying, plasma spraying, or as an appliqué. Not specifically designed for a weathering environment, little is known about the durability of conventional paints, coatings, and appliqués upon exposure to weathering and subsequent exposure to solar wind and ultraviolet radiation exposure. In addition to maintaining their desired optical properties, the coatings must also continue to adhere to the underlying radiator panel.

Spacecraft thermal control systems are essential to provide the necessary thermal environment for the crew and to ensure that the equipment functions adequately on space missions. The Ultralight Fabric Reflux Tube (UFRT) was developed by the Pacific Northwest National Laboratory as a lightweight radiator concept to be used on planetary surface-type missions (e.g., Moon, Mars). The UFRT consists of a thin-walled tube (acting as the fluid boundary), overwrapped with a low-mass ceramic fabric (acting as the primary pressure boundary). The tubes are placed in an array in the vertical position with the evaporators at the lower end. Heat is added to the evaporators, which vaporizes the working fluid. The vapor travels to the condenser end section and condenses on the inner wall of the thin-walled tube. The resulting latent heat is radiated to the environment. The fluid condensed on the tube wall is then returned to the evaporator by gravity.

Space-faring crews must have safe breathing air throughout their missions to ensure adequate performance and good health. Toxicological assessment of air quality depends on the standards that define acceptable air quality, measurements of pollutant levels during the flight, and reports from the crew on their in-flight perceptions of air quality. Air samples returned from ISS on flights 8A, UF2, 9A, and 11A were analyzed for trace pollutants. On average, the air during this period of operations was safe for human respiration. However, about 3 hours into the regeneration of 2 Metox canisters in the U.S. airlock on 20 February 2002 the crew reported an intolerable odor that caused them to stop the regeneration, take refuge in the Russian segment, and scrub air in the U.S. segment for 30 hours. Analytical data from grab samples taken during the incident showed that the pollutants released were characteristic of nominal air pollutants, but were present in much higher concentrations.

There are many sources of air pollution that can threaten air quality during space missions. The International Space Station (ISS) is an extremely complex platform that depends on a multi-tiered strategy to control the risk of excessive air pollution. During the seven missions surveyed by this report, the ISS atmosphere was in a safe, steady-state condition; however, there were minor loads added as new modules were attached. There was a series of leaks of octafluoropropane, which is not directly toxic to humans, but did cause changes in air purification operations that disrupted the steady state condition. In addition, off-nominal regeneration of metal oxide canisters used during extravehicular activity caused a serious pollution incident.

Flexible fiber-reinforced aerogel composites were studied for use as insulation materials of a future space suit for Moon and Mars exploration. High flexibility and good thermal insulation properties of fiber-reinforced silica aerogel composites at both high and low vacuum conditions make it a promising insulation candidate for the space suit application. This paper first presents the results of a durability (mechanical cycling) study of these aerogels composites in the context of retaining their thermal performance. The study shows that some of these Aerogels materials retained most of their insulation performance after up to 250,000 cycles of mechanical flex cycling. This paper also examines the problem of integrating these flexible aerogel composites into the current space suit elements.

For planetary exploration, new thermal insulation materials are needed to deal with unique environmental conditions presented to extravehicular activity (EVA). The thermal insulation material and system used in the existing space suit were specifically designed for low orbit environment. They are not adequate for low vacuum condition commonly found in planetary environments with a gas atmosphere. This study attempts to identify the types of lofty nonwoven thermal insulation materials and the construction parameters that yield the best performance for such application. Lofty nonwovens with different construction parameters are evaluated for their thermal conductivity performance. Three different types of fiber material: solid round fiber, hollow fiber, and grooved fiber, with various denier, needling intensity, and web density were evaluated.

This paper presents the analysis findings of a study reducing the overall mass of the lightweight liquid cooling garment (LCG). The LCG is a garment worn by crew to actively cool the body, for spacesuits and launch/entry suits. A mass reduction of 66% was desired for advanced missions. A thermal math model of the LCG was developed to predict its performance when various mass-reducing changes were implemented. Changes included varying the thermal conductivity and thickness of the garment or of the coolant tubes servicing the garment. A second model was developed to predict behavior of the suit when the cooling tubes were to be removed, and replaced with a highly-conducting (waterless) material. Findings are presented that show significant reductions in weight are theoretically possible by improving conductivity in the garment material.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

The quality of neat biodiesel (B100) is critical for ensuring biodiesel blends used in diesel-powered vehicles do not adversely impact engine performance. In the United States, B100 is required to meet ASTM International’s purity and fuel property requirements in D6751, “Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels.” Here we review the development of this standard for the different grades of B100. The BQ-9000 program, which currently covers over 90% of U.S. and Canadian production volumes, is also described. Engine and original equipment manufacturers have expressed a desire for credible, third-party data on values of various ASTM B100 properties in the commercial market to inform their efforts to address future emissions and durability requirements.

Oxidative degradation of biodiesel under accelerated conditions has been examined by Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR), and gravimetric measurement of deposit formation. The formation of gums and deposits caused by oxidation in storage or in an engine fuel system is a significant issue because of the potential for fuel pump and injector fouling. The results of this study indicate several important pathways for degradation and two pathways leading to formation of oligomers and, ultimately, deposits. Peroxides formed in the initial stage of oxidation can decompose to form aldehydes, ketones, and acids. These can react further in aldol condensation to form oligomers. Additionally, peroxides can react with fatty acid chains to form dimers and higher oligomers. Deposits form when the polarity and molecular weight of these oligomers is high enough.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

Mixing controlled compression ignition, i.e., diesel engines are efficient and are likely to continue to be the primary means for movement of goods for many years. Low-net-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could have advantageous properties for combustion, such as high cetane number and reduced engine-out particle and NOx emissions. We developed a list of over 400 potential biomass-derived diesel blendstocks and populated a database with the properties and characteristics of these materials. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a blendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number ≥40, flashpoint ≥52°C, and boiling point or T90 ≤338°C.

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.

Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent).

A new type of solar-reflective glass that improves reflection of the near-infrared (NIR) portion of the solar spectrum has been developed. Also developed was a prototype solar-reflective paint that increases the NIR reflection of opaque vehicle surfaces while maintaining desired colors in the visible portion of the spectrum. Both of these technologies, as well as solar-powered parked car ventilation, were tested on a Cadillac STS as part of the Improved Mobile Air Conditioning Cooperative Research Program (I-MAC). Significant reductions in interior and vehicle skin temperatures were measured. The National Renewable Energy Laboratory (NREL) performed an analysis to determine the impact of reducing the thermal load on the vehicle. A simplified cabin thermal/fluid model was run to predict the potential reduction in A/C system capacity. The potential reduction in fuel use was calculated using a vehicle simulation tool developed by the U.S. Department of Energy (DOE).

The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).

Lunar dust exposures occurred during the Apollo missions while the crew was in the lunar module on the moon's surface and especially when micro-gravity conditions were attained during rendezvous in lunar orbit. Crews reported that the dust was irritating to the eyes, and in some cases, respiratory symptoms were elicited. NASA's current vision for lunar exploration includes stays of 6 months on the lunar surface hence the health effects of periodic exposure to lunar dust in the habitat need to be assessed. NASA is performing this assessment with a series of in vitro and in vivo tests with authentic lunar dust. Our approach is to “calibrate” the intrinsic toxicity of lunar dust by comparison to a relatively low toxicity dust (TiO2) and a highly toxic dust (quartz) using intrapharyngeal instillation of the dusts to mice. A battery of indices of toxicity is assessed at various time points after the instillations.

Research indicates that adaptation to a microgravity environment includes physiological changes to the cardiovascular-respiratory, musculoskeletal, and neurosensory systems. Many of these alterations emerge even during space flights of short duration. Therefore, the advancement of manned space flight from Shuttle to Space Station Freedom (SSF) requires development of effective methods for augmenting the ability of humans to maintain functional performance. Thus, it is the goal of NASA to minimize the consequences of microgravity-induced deconditioning to provide optimal in-flight performance (intra- and extra-vehicular activities), suitable return to a pedestrian environment, and nominal physiological postflight recovery for an expeditious return-to-flight physical status.

This paper present a summary of the design studies for the suit port proof of concept. The Suit Port reduces the need for airlocks by docking the suits directly to a rover or habitat bulkhead. The benefits include reductions in cycle time and consumables traditionally used when transferring from a pressurized compartment to EVA and mitigation of planetary surface dust from entering into the cabin. The design focused on the development of an operational proof of concept evaluated against technical feasibility, level of confidence in design, robustness to environment and failure, and the manufacturability. A future paper will discuss the overall proof of concept and provide results from evaluation testing including gas leakage rates upon completion of the testing program.