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The use of advanced electron microscopy techniques to characterize both the bulk and near-atomic level microstructural evolution of catalyst materials during different dynamometer/vehicle aging cycles is an integral part of understanding catalyst deactivation. The study described here was undertaken to evaluate thermally-induced microstructural changes which caused the progressive loss of catalyst performance in a three-way automotive catalyst. Several different catalyst processing variables, for example changing the washcoat ceria content, were also evaluated as a function of aging cycle and thermal history. A number of thermally-induced microstructural changes were identified using high resolution electron microscopy techniques that contributed to the deactivation of the catalyst, including sintering of all washcoat constituents, γ-alumina transforming to α-, β-, and δ-alumina, precious metal redistribution, and constituent encapsulation.

Bond wires are used in automotive electronic modules to carry current from external harness to components where flexibility under thermal cyclic loading is very essential between PCB (Printed Circuit Board) and connectors. They are very thin wires (few μm) made up of gold, aluminum or copper and have to undergo mechanical reliability to withstand extreme mechanical and thermal loads during different vehicle operation scenarios. Thermal reliability of bond wire is to make sure that it can withstand prescribed electric current under given boundary conditions without fusing thereby retaining electronic module's functionality. While carrying current, bond wire by virtue of its nature resists electric current flow and generates heat also called as joule heating. Joule heating is proportional to current flow and electrical resistance and if not handled properly can lead to thermal run away conditions.

This paper presents a simplified thermal model for round catalytic converters in steady state operation. Using this model, the analytic solution for the temperature distribution in the monolithic substrate is obtained. This analytic solution in the substrate is, then, combined with those in the intumescent mat [1] and the metal shell to obtain the temperature profile in the radial direction of the converter except for three unknown temperatures at the three material interfaces, which can be solved using an Excel application program. This analytical temperature solution facilitates the studies of the effects of various design parameters such as the exhaust gas temperature, exhaust gas flow rate, substrate cell geometry, converter dimensions, and ambient temperature and flow, etc.

Short timing and complexes strategies are mandatory in a competitive market as automotive industry. Therefore quality problems identification during and after the coding phase, may be the difference between the business success and undesired conflicts with customer, solving problems that were not previously identified. Consequently the usage of technique Mahalanobis Taguchi System (MTS) to analyze coding metrics, create an environment to improve the final product quality and mitigate potential problems later identified.

The most popular aluminum alloys for semi-solid automotive components are A356 and A357. The density of rheocast semi-solid A357 is higher than die cast A357 and allows for both T5 and T6 heat treatment. The mechanical properties of rheocast semi-solid A357 was found to be more dependent upon the heat treat schedule and casting soundness than by the solid content of the semi-solid slurry or the globule shape.

There are an increasing number of applications for resonant micromachines. Accelerometers, angular rate sensors, voltage controlled oscillators, pressure and chemical sensors have been demonstrated using this technology. Several of these devices are employed in vehicles. Vibrating devices have been made from silicon, quartz, GaAs, nickel and aluminum. Resonant microsystems are in constant motion and so present new challenges in the area of reliability for vehicular applications. The impact of temperature extremes, cyclic fatigue, stiction, thermal and mechanical shock on resonant device performance is covered.

Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.

Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) are effective emission solutions for both close-coupled and underfloor LEV/ULEV applications due to optimal hydrocarbon light-off, NOx control, and balance of precious metal (PGM) usage. Dual-brick [Pd +Pt/Rh] systems on 3.8L V-6 LEV-calibrated vehicles were characterized as a function of PGM loading, catalyst technology, converter volumes, and substrate cell density. While hydrocarbon emissions improve with increasing Pd loading, decreasing the front catalyst volume at constant Pd content (resulting in higher Pd density) improved light-off emissions. Use of 600cpsi substrates improved underfloor NMHC emissions on a 3.8L vehicle by ∼ 6-10mg/mi compared to 400cpsi catalysts, and thus allowing reduction of catalyst volume while achieving ULEV emission levels without air addition.

Long repetitive braking, such as one which occurs during a mountain descent, will result in a brake fluid temperature rise and may cause brake fluid vaporization. This may be a concern particularly for passenger cars equipped with aluminum calipers and with a limited air flow to the wheel brake systems. This paper describes the computer modeling techniques to predict the brake fluid temperature rise as well as other brake component temperatures during braking and heat soaking. Numerical results are compared to the measured vehicle data and the effects of relevant brake system parameters on the fluid temperature are investigated. The techniques developed in this study will help brake engineers to build a safer brake system and reduce the extensive vehicle tests currently required.

Mean Value Engine Models (MVEMs) are simplified, dynamic engine models which are physically based. Such models are useful for control studies, for engine control system analysis and for model based engine control systems. Very few published MVEMs have included the effects of Exhaust Gas Recirculation (EGR). The purpose of this paper is to present a modified MVEM which includes EGR in a physical way. It has been tested using newly developed, very fast manifold pressure, manifold temperature, port and EGR mass flow sensors. Reasonable agreement has been obtained on an experiemental engine, mounted on a dynamometer.

The utilization of Laser welding process has increased during last years in several areas of industry, due to many benefits that can be achieved with this technology, such as: flexibility, productivity and quality. Thus, the optimization of Laser welding processes has been considered as a “green field” to be explored by Laser manufacturers, automation companies and process/project engineers. Nowadays there are few researches that provide a roadmap for Laser welding processes improvement that approaches both the aspects and characteristics applied to evaluate the Laser weld application performance. Therefore, this paper has per its main purpose through an exploratory study to provide parameters toward continuous improvement of Laser welding process considering both types of Lasers: Laser spot weld and Laser seam weld of stainless steel joints, thus this work may be considered as theoretical and practical reference to be applied by people involved with Laser welding applications.

In this paper we discuss in detail an algorithm that addresses cylinder-to-cylinder imbalance issues. Maintaining even equivalence-ratio (ϕ) control across all the cylinders of an engine is confounded by imbalances which include fuel-injector flow variations, fresh-air intake maldistribution and uneven distribution of Exhaust Gas Re-circulation (EGR). Moreover, in markets that are growing increasingly cost conscious, with ever tightening emissions regulations, correcting for such mismatches must not only be done, but done at little or no additional cost. To address this challenge, we developed an Individual Cylinder Fuel Control (ICFC) algorithm that estimates each cylinder's individual ϕ and then compensates to correct for any imbalance using only existing production hardware. Prior work in this area exists1,2, yet all disclosed production-intent work was performed using wide-range oxygen sensors, representing cost increases.

Lead-free solders for electronics have been actively pursued since the early 1990's here and abroad for environmental, legislative, and competitive reasons. The National Center for Manufacturing Sciences (NCMS-US)1, the International Tin Research Institute (ITRI-UK)2, Swedish Institute of Production Engineering Research (IVF-Sweden)3, Japan Institute of Electronics Packaging (JIEP Japan)4, Improved Design Life and Environmentally Aware Manufacture of Electronics Assemblies by Lead-free Soldering (IDEALS-Europe)5, and, more recently, the National Electronics Manufacturing Initiative (NEMI-US)6 have been aggressively seeking lead-free solutions The automotive industry has some unique requirements that demand extensive testing of new materials and processes prior to implementation. The specific steps taken at Delphi Automotive Systems with lead-free solder will be described along with the lessons learned along the way.

Performance of two types of NOx adsorber catalysts, one based on Ba and the other based on Ba with alkali metals, was compared fresh and after thermal aging. Incorporation of sodium(Na), potassium(K) and cesium(Cs) into NOx adsorber washcoat containing barium significantly increases the NOx conversions in the temperature range of 350-600°C over that of the alkali metal free NOx adsorber catalysts. NOx performance benefit and HC performance penalty were observed on both engine dynamometer and vehicle tests for the “Ba+alkali metals” NOx adsorber catalysts. “Ba+alkali metals” NOx adsorber catalysts also demonstrate superior sulfur resistance with better NOx performance after repeated sulfur poisonings and desulfations over the “Ba based” NOx adsorber catalysts.

The fundamental relationship between semi-solid processing and microstructure and their effect on the flow characteristics of semi-solid metals have been studied for several years. However, how the process related microstructure influences fatigue properties has not been given the same attention. This study examines the influence of process-related microstructure on the fatigue properties of semi-solid formed A357 alloys. High-solid-fraction (62% solid) and low-solid-fraction (31% and 36% solid) semi-solid formed A357 was tested in axial fatigue with a stress ratio (R) equal to -1. The high solid fraction (HSF) material had better fatigue properties than the low solid fraction (LSF) material. This is attributed to the fatigue crack initiation mechanisms, as related to the fatigue crack initiation features and the strengths of the materials.

This paper describes recent progress in our program to develop a gasoline-fueled vehicle with an on-board reformer to provide near-zero tailpipe emissions. An on-board reformer converts gasoline (or another hydrocarbon-containing fuel) into reformate, containing hydrogen (H2) and carbon monoxide (CO). Reformate has very wide combustion limits to enable SI engine operation under very dilute conditions (either ultra-lean or with heavy exhaust gas recirculation (EGR) concentrations). In previous publications, we have presented engine dynamometer results showing very low emissions with bottled reformate. This paper shows results from an engine linked to an experimental, fast start-up reformer. We present both performance data for the reformer as well as engine emissions and performance results. Program results continue to show an on-board reforming system to be an attractive option for providing near-zero tailpipe emissions to meet low emission standards.

With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.

A dynamic EGR State Estimator (ESE) intended for production engine management systems (EMS) implementation is presented. It better describes the development of external exhaust gas recirculation (EGR) concentration at the engine intake ports during EGR transients than traditional models. The dynamics of EGR concentration time and spatial development in the intake manifold are described as a perfect mixing model in the intake manifold plenum volume and non-mixing plug flow in the intake manifold runners. The time scale of EGR transients precludes the use of traditional EGR measurement techniques for model verification. Instead a wide range air fuel (WRAF) sensor is used. Results are shown for a large variation in operating conditions and compared to the performance of a traditional model.

The development of an analytical model for multilayer stack subjected to temperature change is demonstrated here. Thin continuous layers of materials bonded together deform as a plate due to their differing coefficients of thermal expansion upon subjecting the bonded materials to the change in temperature. Applications of such structures can be found in the electronics industry (the study of warpage issues in printed circuit boards) or in the aerospace industry as (the study of laminated thin sheets used as skin structures for load bearing members such as wings and fuselage). In automotive electronics, critical high-power packages (IGBT, Power FETs) include several layers of widely differing materials (aluminum, solder, copper, ceramics) subjected to wide temperature cyclic ranges. Modeling of such structures by using three-dimensional finite element methods is usually time consuming and may not exactly predict the inter-laminar strains.

A double dielectric barrier discharge reactor driven by an alternating voltage is a relatively simple approach to promote oxidation of NO to NO2 for subsequent reduction in a catalyst bed. The chemical performance of such a non-thermal plasma reactor is determined by its current and electric field behavior in the gap, and by the fraction of the current carried by electrons, because the key reactants which initiate the NO oxidation and accompanying chemical changes are produced there, mostly by electron impact. We have tried to determine by models and experiments the bounds on performance of double dielectric barrier reactors and guidelines for optimization. Models reported here predict chemical results from time-resolved applied voltage and series sense capacitor data.