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In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.

To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

A study was performed to develop optimum design strategies for a production V6 engine to maximize catalyst performance at minimum pressure loss and at minimum cost. Test results for an advanced system, designed to meet future emission limits on a production V6 vehicle, are presented based on FTP testing. The on-line pressure loss and temperature data serves to explain the functioning of the catalyst.

On one hand, latest worldwide emissions legislation developments aim to reduce NOx and Particulate Matter (PM) emissions of all diesel engines, while on the other hand lower fuel consumption diesel engines are still required for lower fleet average CO₂ emissions. As a consequence of the chosen CO₂ optimized combustion mode, the raw NOx emission increases and as such Selective Catalytic Reduction (SCR) technology will be the future choice for high efficiency NOx aftertreatment. This paper deals with SCR technology and its derivative SCRi® technology, when diesel particle reduction is required, especially for heavy-duty applications. Alongside the developed metal catalyst technologies, a complete SCR reducing agent dosing system is presented. Emission results gained with the SCR or SCRi® technologies on European commercial engines illustrate the potential of these technologies for conversion of NOx and PM emissions.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

Emissions during the useage phase of vehicles are of increasing interest in environmental protection, and consequently, there is considerable interest in exhaust systems. The automotive exhaust system including the catalytic converter is, because of the precious metals in the catalyst, of particular interest for the recycling of automotive parts. The paper will describe the recycling technology of ceramic and metal catalyst substrates. The process will be analyzed in detail with the example of metal supports. As a result the complete life cycle and the recycling efficiency are presented.

A particulate trap with combined regeneration has been developed for use in light duty vehicles with diesel engines. This new system was tested first on an engine test rig. On-road vehicle tests are going on since August 1998. The results obtained clearly demonstrate the feasibility of this system. With this system trap regeneration has to be ensured under worst case conditions (exhaust gas temperature<400° C). To meet this requirement electrical heating in combination with a fuel-borne catalyst is applied. Different filter materials such as cordierite wall flow and silicon carbide monoliths were tested on the engine test rig. The paper reports on results from the engine test rig as well as from on-road vehicle testing. An overview about pre-heating and regeneration examples are given and energy balances are presented.

Emission legislations for the light / medium and heavy duty vehicles are becoming more and more stringent worldwide. Tightening of NOx and Particulate Matter (PM) limits further from Euro III to Euro IV levels has provoked the need of either controlling NOx from the engine measures and use PM control after-treatment devices such as Partial Flow Filters, or, controlling PM from the engine measures and use NOx control devices such as Selective Catalytic Reduction (SCR) systems. Manufacturers have adopted different strategies, depending upon the suitability, cost factors, infrastructure development and ease of maintenance of these systems. PM Metalit®, is a partial flow filter, which captures particulates coming out of the exhaust and re-generates on a continuous basis with the help of Nitrogen Dioxide (NO2) in the exhaust.

Future emission legislation can be met through substantial improvement in the effectiveness of the exhaust gas after-treatment system, the engine and the engine management system. For the catalytic converter, differentiation is necessary between the cold start behavior and the effectiveness at operating temperature. To be catalytically effective, a converter must be heated by the exhaust gas up to its light-off temperature. The major influential parameter for the light-off still is the supply of heat from the exhaust gas. Modification of the cold start calibration of engine control such as spark retard or increased idle speed can increase the temperature level of the exhaust gas. One further possibility is represented by a reduction of the critical mass ahead of the catalyst (exhaust manifold and pipe). Nevertheless the best measure to obtain optimal cold start effectiveness still seems to be locating the converter close to the engine.

Future catalyst systems need to be highly efficient in a limited packaging space. This normally leads to a design where the flow distribution, in front of the catalyst, is not perfectly uniform. Measurements on the flow test bench show that the implementation of perforated foils for the corrugated and flat foils has the capability to distribute the flow within the channels in the radial direction so that the maximum of the given catalyst surface is of use, even under very poor uniformity indices. Therefore a remarkable reduction in back pressure is measured. Emission results demonstrate cold start improvement due to reduced heat capacity. The use of LS - structured ( Longitudinal structured ) corrugated foils creates a high turbulence level within the single channels. The substrate lights-up earlier and the maximum conversion efficiency is reached more quickly.

In order to match catalyst OBDII conditions the common procedure is oven aging with air, which is not suitable for complete converter systems due to mantle corrosion. The goal was, therefore, to find an alternative procedure to ensure a defined catalyst aging that would match 1,75 times the emission standard and is also good for SULEV. The new procedure currently being developed allows the aging of metal and ceramic catalysts as well as complete catalyst systems. The paper will present the aging process, emission data of fresh and aged catalysts and the feedback to the test car OBDII system.

Nearly all real Diesel engine operation is leading to low exhaust temperatures. Standard catalyst technique remains therefore for significant time below light off. To improve the conversion behavior two approaches were made: placement of tailor fitted catalysts as close as possible to the engine exhaust port before turbocharger and usage of close coupled catalysts with the so-called hybrid design. Both measures are providing visible progress in reducing Diesel engine emissions. Tests were made with modern Diesel engines both for passenger cars and heavy duty vehicles.

For the NOx removal from diesel exhaust, the selective catalytic reduction (SCR) and lean NOx traps are established technologies. However, these procedures lack efficiency below 200 °C, which is of importance for city driving and cold start phases. Thus, the present paper deals with the development of a novel low-temperature deNOx strategy implying the catalytic NOx reduction by hydrogen. For the investigations, a highly active H2-deNOx catalyst, originally engineered for lean H2 combustion engines, was employed. This Pt-based catalyst reached peak NOx conversion of 95 % in synthetic diesel exhaust with N2 selectivities up to 80 %. Additionally, driving cycle tests on a diesel engine test bench were also performed to evaluate the H2-deNOx performance under practical conditions. For this purpose, a diesel oxidation catalyst, a diesel particulate filter and a H2 injection nozzle with mixing unit were placed upstream to the full size H2-deNOx catalyst.

Cars cause a lot of pollutants during the utilization phase. Within the last years environmental legislation tried to reduce the emissions by the introduction of very tight laws. The results are impressive: Most of the car exhaust emissions like carbonmonoxid and nitrous oxides have been reduced. At this stage new emission reduction limits in Europe as well as in the United States can only be achieved if the formulation of the catalyst system is significantly changed. An increased use of precious metals and rare earth materials is the result of such a modification which succeeds in a more expensive design of the total catalyst systems. More expensive means not only cost aspects but also the environmental burdens related to the increased production of precious metals and other catalyst components. The Life Cycle Engineering (LCE) of the catalyst system which achieves the new legislation is demonstrated as well as the effects to the usage phase.

Exhaust after-treatment systems will have to become increasingly efficient in order to comply with the strict emission limits that will apply in the European Union and worldwide in future. Moreover, space constraints, weight and low pressure drop are just some of the issues that have to be addressed by an EU III-compliant catalytic system. The development of metallic substrates over the past few years has shown that turbulent-like substrates increase specific catalytic efficiency. This has made it possible to enhance overall performance for a specific catalytic volume or reduce the volume while keeping catalytic efficiency constant. This paper focuses on the emission efficiency of standard, TS and PE metallic substrates. A simulation tool and flow bench measurements were used to develop a test matrix with catalyst similar pressure drop in order to examine different cell densities, substrate lengths and coating technologies.

There is a growing need for low-emissions concepts due to stricter emission regulations, more stringent homologation cycles, and the possibility of a ban on new engines by 2035. Of particular concern are the conditions during a cold start, when the Three-Way Catalyst is not yet heated to its light-off temperature. During this period, the catalyst remains inactive, thereby failing to convert pollutants. Reducing the time needed to reach this temperature is crucial to comply with the more stringent emissions standards. The post oxidation by means of secondary air injection, illustrated in this work, is a possible solution to reduce the time needed to reach the above-mentioned temperature. The strategy consists of injecting air into the exhaust manifold via secondary air injectors to oxidize unburned fuel that comes from a rich combustion within the cylinder.

Apart from the reduction of engine-out emissions from the powerplant, the development of an efficient and reliable catalytic converter heating system is an important task of automotive engineering in the future to meet standards that will require reduction of cold start emissions. Carrying out a comprehensive study in this field, BMW has tested and evaluated possible solutions to this challenge. In additon to the electrically heated catalytic converter (E-cat) and the afterburner chamber, an incorporated burner system would meet the requirement for fast catalyst light-off in the future, particularly in the case of larger engines.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.