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The present work is a continuation of the earlier published results by authors on the investigation of Hydrogenated Vegetable Oil (HVO) on a High Efficiency Diesel Combustion System (SAE Int. J. Fuels Lubr. Paper No. 2013-01-1677 and JSAE Paper No. 283-20145128). In order to further validate and interpret the previously published results of soot microstructure and its consequences on oxidation behavior, the test program was extended to analyze the impact of soot composition, optical properties, and physical properties such as size, concentration etc. on the oxidation behavior. The experiments were performed with pure HVO as well as with petroleum based diesel and today's biofuel (i.e. FAME) as baseline fuels. The soot samples for the different analyses were collected under constant engine operating conditions at indicated raw NOx emissions of Euro 6 level using closed loop combustion control methodology.

A new index to evaluate the inherent soot reduction in a diesel-like spray plume is proposed in this study. The index is named “Oxidation Potential Number” and was derived with the help of a computational fluid dynamics (CFD) software. C8 - C16 n-alkanes, 1-alcohols and di-n-ethers were studied with the help of this index over four part load engine operating conditions, representative of a C-class diesel vehicle. The CFD modelling results have shown that C8 molecules feature a higher potentiality to reduce the soot. Thus, C8 molecules were tested in a single cylinder diesel engine over the same operating conditions. In conclusion, the proposed index is compared with the soot engine out emission.

The current and future restrictions on pollutant emissions from internal combustion engines require a holistic investigation of the abilities of alternative fuels to optimize the combustion process and ensure cleaner combustion. In this regard, the Tailor-made Fuels from Biomass (TMFB) Cluster at Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen University aims at designing production processes for biofuels as well as fuels optimal for use in internal combustion engines. The TMFB Cluster's scientific approach considers the molecular structure of the fuels as an additional degree of freedom for the optimization of both the production pathways and the combustion process of such novel biofuels. Thus, the model-based specification of target parameters is of the utmost importance to improve engine combustion performance and to send feedback information to the biofuel production process.

To comply with the new regulations on particulate matter emissions, the manufacturers of light-duty as well as heavy-duty vehicles more commonly use diesel particulate filters (DPF). The regeneration of DPF depends to a significant extent on the properties of the soot stored. Within the Cluster of Excellence "Tailor-Made Fuels from Biomass (TMFB)" at RWTH Aachen University, the Institute for Combustion Engines carried out a detailed investigation program to explore the potential of future biofuel candidates for optimized combustion systems. The experiments for particulate measurements and analysis were conducted on a EURO 6-compliant High Efficiency Diesel Combustion System (HECS) with petroleum-based diesel fuel as reference and a today's commercial biofuel (i.e., FAME) as well as a potential future biomass-derived fuel candidate (i.e., 2-MTHF/DBE). Thermo gravimetric analyzer (TGA) was used in this study to evaluate the oxidative reactivity of the soot.

This study investigated dual-fuel operation with a light duty Diesel engine over a wide engine load range. Ethanol was hereby injected into the intake duct, while Diesel was injected directly into the cylinder. At low loads, high ethanol shares are critical in terms of combustion stability and emissions of unburnt hydrocarbons. As the load increases, the rates of heat release become problematic with regard to noise and mechanical stress. At higher loads, an advanced injection of Diesel was found to be beneficial in terms of combustion noise and emissions. For all tests, engine-out NOx emissions were kept within the EU-6.1 limit.