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Water management is one of the key factors to ensure high performance, cold start and durability of polymer electrolyte fuel cells (PEFCs), and it is important to understand the behavior of liquid water in PEFCs. X-ray computed tomography (X-ray CT) imaging and the two-phase lattice Boltzmann method (two-phase LBM) are applied to analyze the mechanism of water transport in the gas diffusion layers (GDLs) and the gas channels in generating PEFCs. The results of the two-phase LBM are compared with those of X-ray CT imaging, and are found to agree qualitatively in that water is discharged along the hydrophilic channel wall and accumulated in the GDL, especially under the rib. The effects of the wettability of the GDLs, and of the gas channels, the diameter of the carbon fibers, and the porosity of the GDLs on water discharge from the GDLs and gas channels are also investigated.

Cooled EGR is recognized as a solution for the reduction of NOx in diesel exhaust gas. The key component of cooled EGR is a tubular type heat exchanger, however the performance drops because of particulate deposition whose characteristics and mechanism are not clrealy understood. Therefore the requirements for a EGR cooler is not only higher heat exchange performance and lower pressure loss, but also less performance deterioration due to DEP (Diesel Exhaust Particulate) deposition known as fouling. In order to improve heat transfer performance of an EGR cooler, it is considered that the surface with riblets aligned in the flow direction is preferable for the heat transfer surface because of its less skin friction and heat transfer enhancement. To apply riblet design to EGR coolers, however, it is necessary to investigate the performance with fouling from diesel particulate.

We had developed Electric Servo Brake System, which can control brake pressure accurately with a DC motor according to brake pedal force. Therefore, the system attains quality brake feeling while reflecting intentions of a driver. By the way, “Build-up” is characteristics that brake effectiveness increases in accordance with the deceleration of the vehicle, which is recognized as brake feeling with a sense of relief as not to elongate an expected braking distance at a downhill road due to large-capacity brake pad such as sports car and large vehicles. Then, we have applied the optical characteristic control to every car with Electric Servo Brake System by means of brake pressure control but not brake pad. Hereby, we confirmed that the control gives a driver the sense of relief and the reduction of pedal load on the further stepping-on of the pedal. In this paper, we describe the development of brake feel based on the control overview.

In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For lean-burn diesel engines, since it is not possible to use three-way catalytic converters, reducing NOX emissions is a difficult technical challenge. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows more efficient reduction of NOX than its conventional counterparts. However, an appropriate switching control between lean and rich mixture conditions along with compensation for catalyst deterioration was necessary.

As technologies for simultaneously maintaining the current high thermal efficiency of diesel engines and reducing particulate matter (PM) and nitrogen oxide (NOX) emissions, many new combustion concepts have been proposed, including premixed charge compression ignition (PCCI) and low-temperature combustion[1]. However, it is well known that since such new combustion techniques precisely control combustion temperatures and local air-fuel ratios by varying the amount of air, the exhaust gas recirculation (EGR) ratio and the fuel injection timing, they have the issues of being less stable than conventional combustion techniques and of performance that is subject to variance in the fuel and driving conditions. This study concerns a system that addresses these issues by detecting the ignition timing with in-cylinder pressure sensors and by controlling the fuel injection timing and the amount of EGR for optimum combustion onboard.

In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For diesel engines, reducing NOX emissions is a difficult technical challenge.[1],[2],[3],[4]. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows the effective reduction of NOX. However, in order to realize cleaner emission gases, precise engine control in response to the state of the exhaust aftertreatment system is essential.

Lean-burn is an effective means of reducing CO2 emissions. To date, Homogenous Lean Charge Spark Ignition (HLSI) combustion, which lowers emissions of both CO2 and NOx, has been studied. Although HLSI realizes lower emission, it is a major challenge for lean-burn engines to meet SULEV regulations, so we have developed a new aftertreatment system for HLSI engines. It consists of three types of catalysts that have different functions, as well as special engine control methods. As the first stage in achieving SULEV emissions, this study focused on enhancing performance under lean conditions. HLSI engine exhaust gases contain high concentrations of hydrocarbons, including a large amount of paraffin, which are difficult to purify, rather than low concentrations of NOx. Therefore, the key point in low emissions is to purify not only NOx, but also high concentrations of paraffin at the same time.

This paper summarizes the piston pin noise mechanism and show the way to reduce noise level of semi-floating system. A mechanism of piston pin noise of semi-floating system was clarified by measurement of piston and piston pin behavior and visualization of engine oil mist around piston and piston pin. Piston and piston pin behavior was measured by accelerometer and eddy current type gap sensor with linkage system at the actual engine running condition. Engine oil behavior was visualized and measured its flow vector by Particle Tracking Velocimetry (PTV). For PTV, engine oil mist particle image was taken by high speed camera with fiber scope attached to linkage system. From themeasurement, it was cleared that engine oil doesn't reach to piston hole from undersurface of piston land and come rushing out from piston broach via groove. The result shows that lacking of engine oil between piston and piston pin makes noise larger.

Attempts were made to measure knocking phenomenon by an optical method, which is free from influences of mechanical noises and is allowing an easy installation to an engine. Using a newly developed high durability optical probe, the light intensity of hydroxyl radical component, which is diffracted from the emitted light from combustion, was measured. The intensity of this emission component was measured at each crank angle and the maximum intensity in a cycle was identified. After that, the angular range in which the measured intensity exceeded 85% of this maximum intensity was defined as “CA85”. When a knocking was purposely induced by changing the conditions of the engine operation, there appeared the engine cycles that included CA85 less than a crank angle of 4 degrees. The frequency of occurrence of CA85 equal to or less than 4 degrees within a predetermined number of engine cycles, which can be interpreted as a knocking occurrence ratio, was denoted as “CA85-4”.

Modern formulation in a wide variety of lubricants including engine oils and transmission fluids is designed to control friction through film-forming tribochemical reactions induced by the functional additives mixtures. Although many cases on the synergistic or antagonistic effects of additives on friction have been reported, their mechanisms are poorly understood. This study focused on the influences of metallic detergents on tribochemical reactions. We examined the mechanical properties of detergent-containing lubricants confined at a single-asperity contact and their contributions to tribochemical phenomena. We found that detergents enlarged the confinement space required for generating repulsive force and shear resistance. This means that these detergents provide steric effects under nanoconfinement at interfacial contacts.

Recently, much research has been carried out on secondary O2 feedback which performs control based on the output from a secondary O2 sensor (HEGO sensor). In this research it has been found that, regardless of catalyst aging conditions, the HEGO sensor output indicates 0.6 V when the catalyst reduction rate is maintained at the optimum level. Therefore, based on this relationship, we designed an accurate secondary O2 feedback with the aim of reducing emissions by stabilizing the HEGO sensor output to 0.6 V. In order to realize this control, it was necessary to solve the three problems of nonlinear catalyst characteristics, dead time characteristics, and changes in dynamic characteristics due to catalyst aging conditions. Therefore, these problems were solved using the modeling approach of robust control and a new robust adaptive control named Prediction and Identification Type Sliding Mode Control.

Recently, the use of ethanol blended fuel is growing worldwide. Therefore, there is increasing needs for addressing issues relating to ethanol blended fuel use in gasoline engine fuel supply systems. In this paper, we focused on one of such issues, which is the reduced life of a multi-layered fuel filter used at inlet side of a fuel pump when it is used with ethanol blended fuel. In this study, we clarified that ethanol blended fuel tends to disperse dust particles contained in fuel to a greater extent than gasoline, and that it has a mechanism to accelerate clogging by concentrating the clogging only on the finest layer of the multi-layered filter. Also, in the process of clarifying this principle, we confirmed that dust particles dispersed by ethanol are coagulated when passing through the filter layers.

In recent years, studies have been conducted on the relationship between the J factor, which indicates flow of molten aluminum at the time of injection, and the quality of HPDC products. The flow of molten metal at a high J factor is referred to as “Atomized Flow.” The authors and others conducted studies on the relationship between the J factor and the strength of HPDC products. An area exceeding 300MPa was found in the product produced at a high J factor corresponding to the “Atomized Flow.” The defect was less in the above-mentioned position because the gas porosity was finely dispersed. Considering that the fine dispersion of gas porosity is related to the “Atomized Flow”, pictures were taken to analyze “Atomized Flow.” The molten aluminum was ejected into an open space at a high speed and the splashed conditions were photographed. From the images taken by the pulse laser permeation, the conditions of microscopic atomized flow were observed precisely.

This emission reduction technique has been researched on motorcycles equipped with a four-cylinder, liquid-cooled engine of 1100cm3 displacement in order to comply with the EURO-3 emission regulation. The EURO-3 emission regulation will be enforced in Europe beginning in year 2006. Compared to the EURO-2 regulation, reduction of cold-start HC and reduction of NOx from the extra-urban driving cycle are the main issues for EURO-3 compliance. The hydrocarbon reduction during cold-starting was achieved by the method of early catalyst activation using a combination of an Idle Air Control Valve system (IACV), ignition-retard, and atomization of fuel spray. In the extra-urban driving cycle, the fine controlled air-fuel ratio reduced. In addition, optimization of the number of three-way catalyst cells and their capacity also reduced NOx. Moreover, power loss decline caused by increased exhaust resistance due to increasing the catalyst size was avoided by optimizing the catalyst location.

When a vehicle is driven in snowy conditions, if a proper air intake design is not adopted, the snow lifted by the leading vehicles may penetrate into the engine air intake, in case of large snow ingress amount, causing a power drop. The evaluation of such risk for the intake is carried out through climatic wind tunnel tests, which cannot be conducted at the early stage of vehicle development when the prototype vehicle does not exist. In order to study that risk prior to the prototype vehicle delivery, computational fluid dynamics (CFD) which predicts the snow ingress amount accurately was established with taking into account unsteady air flow and snow accumulation. Large Eddy Simulation (LES) was used to reproduce the unsteady flow field, leading to a good agreement of the flow downstream from the snow generator with the experimental one measured by Particle Image Velocimetry (PIV). As for the snow particle behavior model, the Lagrangian method was chosen.

Just as CO2 reduction is required of four wheeled vehicles for environmental protection, similar environmental concerns drive the development of motorcycle oil technology. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Mr. Ito and his co-authors1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods:JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).

Suppression or reduction of soot emissions is an important goal in the development of automotive engines for environmental and human health purposes. A better understanding at the molecular level of the formation process of soot particles resulting from collision and aggregation of smaller particles made of Polycyclic Aromatic Hydrocarbon (PAH) is needed. In addition to experiments, computational methods are efficient and valuable tools for this purpose. As a first step in our detailed computational chemistry study, we applied Ultra-Accelerated Molecular Dynamics (UAQCMD) and Canonical Monte-Carlo (CMC) methods to investigate the nucleation process. The UA-QCMD can calculate chemical reaction dynamics 107 times faster than conventional first principle molecular dynamics methods, while CMC can calculate equilibrium properties at various temperatures, pressures, and chemical compositions.

For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.

To evaluate the relationship between the exhaust gas purification performance and the catalyst pore properties related to gas diffusion, an elementary reaction model was combined with gas diffusion into catalyst pores, referred to as the pseudo-2D gas diffusion/reaction model. It was constructed for Pt/Al2O3 + CeO2 catalyst as lean NOx catalyst. The gas diffusion was described as macro pore diffusion between the catalyst particles and meso pore diffusion within the particle. The kinetic model was composed of 26 reactions of NO/CO/O2 chemistry including 17 Pt/Al2O3 catalyst reactions and 9 CeO2 reactions. Arrhenius parameters were optimized using activity measurement results from various catalysts with various pore properties, meso pore volume and diameter, macro pore volume and diameter, particle size, and washcoat thickness. Good agreement was achieved between the measured and calculated values.

Catalyst simulation, which can analyze the complicated reaction pathway of exhaust gas purifications and identify the rate-determining step, is an essential tool in the development of catalyst materials. This requires an elementary reaction model which describes the detailed processes, i.e. adsorption, decomposition, and others. In our previous work, the elementary reaction model on Pt/CeO2 catalyst was constructed. In this study, we focused on extending the Zeolite catalyst and including the gas diffusivity through the catalyst layer. The reaction rate of a Zeolite catalyst was expressed by an Arrhenius equation, and the elementary reaction model was composed of 17 reactions. Each Arrhenius parameter was optimized by the catalytic activity measurements. The constructed model was validated with NOx conversion in cyclic experiments which were repeated with Lean phase (NOx adsorption) and Rich phase (NOx reduction).