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Over the course of the past decade, the automotive industry has made efforts to reduce the depth of the brazed aluminum, louver fin evaporators typically used in the air conditioning system for automobiles by increasing their compactness. Increasing fin and louver densities have led to the possibility of condensate affecting the air side performance of automotive evaporators. Condensate can “bridge” the space between two adjacent fins or louvers. Condensate bridging of the fins or louvers can alter the flow of air through the evaporator, causing a change in the heat transfer and friction characteristics. This study attempts to quantify these changes and determine which parameters will have an impact on them. Wind tunnel tests measuring the air side sensible heat transfer coefficient and pressure drop were conducted to examine how the air side heat transfer and friction characteristics of automotive evaporators are changed by the presence of condensate.

Diesel fuel is a blend of various middle distillate components separated at the refinery. The composition and characteristics of the diesel fuel blend changes daily if not hourly because of normal process variation, changing refinery processing conditions, changing crude oil diet or changing diesel fuel and kerosene market conditions. Regardless of the situation going on at the refinery or the market, the resultant diesel fuel must consistently meet established cloud point specifications. To consistently meet the cloud point specifications, refiners are forced to blend their diesel fuels in such a way that the resultant blend is always on the low side of the cloud point specification even when the refining process adversely changes the fuel characteristics. This practice has the effect of producing several degrees of cloud point “giveaway” when the refinery is not experiencing adverse swings in product quality.

Internal Diesel Injector Deposits (IDID) in compression ignition engines have been widely studied in the past few years. Published results indicate that commonly observed IDID chemistries may be replicated using full-scale engine tests and subsequently fuel injection equipment (FIE) operated on non-fired electric motor driven test stands. Such processes are costly, complex and by nature can be difficult to repeat. The next logical simplification is to replicate IDID formation using laboratory-scale apparatus that recreate the appropriate chemical reaction process under well controlled steady state conditions. This approach is made more feasible by the fact that IDID, unlike nozzle hole coking, are not directly exposed to gasses involved in the combustion process. The present study uses an instrument designed to measure thermal oxidation stability of aviation turbine fuels to successfully replicate the deposit chemistries observed in full-scale FIE.

The major drivers in the development of the latest generation of engines are environmental. For diesel engines, mitigating the effects of soot contamination remains a significant factor in meeting these challenges. There is general consensus of soot impacting oil performance. Considerable efforts have been made towards a greater understanding of soot-lubricant interaction and its effects on engine performance. However, with evolution of engine designs resulting in changes to soot composition/ properties, the mechanisms of soot-lubricant interaction in the internal combustion engine continue to evolve. A variety of mechanisms have been proposed to explain soot-induced wear in engine components. Furthermore, wear is not the only topic among researchers. Studies have shown that soot contributes to oil degradation by increasing its viscosity leading to pumpability and lubricant breakdown issues.

The Association des Constructeurs Européen d'Automobiles (ACEA) light duty diesel engine specifications requires a kinematic viscosity measurement technique for Peugeot XUD-11 BTE drain oils. This viscosity measurement is used to define the medium temperature dispersivity of soot in the drain oil.(1) This paper discusses the use of rotational rheology methods to measure the Newtonian character of XUD-11 drain oils. The calculation of the rate index using the Hershel Bulkley model indicates the level of non-Newtonian behavior of the drain oil and directly reflects the level of soot dispersion or agglomeration. This study shows that the more non-Newtonian the drain oil the greater the difference between kinematic and rotational viscosity measurements Oscillation (dynamic) rheological techniques are used to characterize build up of soot structure.

One of the key functions of lubricating oil additives in diesel engines is to control oil thickening caused by soot accumulation. Over the last several years, it has become apparent that the composition of the base oil used within the lubricant plays an extremely important role in the oil thickening phenomenon. In particular, oil thickening observed in the Mack T-8 test is significantly affected by the aromatic content of the base oil. We have found that the Mack T-8 thickening phenomenon is associated with high electrical activity, i.e., engine drain oils which exhibit high levels of viscosity increase show significantly higher conductivities. These findings suggest that electrical interactions are involved in soot-induced oil thickening.

This paper illustrates a method to determine the experimental uncertainties in the measurement of tailpipe emissions of carbon dioxide, carbon monoxide, nitrogen oxides, hydrocarbons, and particulates of medium-, and heavy-duty vehicles when tested on a heavy-duty chassis dynamometer and full-scale dilution tunnel. Tests are performed for different chassis dynamometer driving cycles intended to simulate a wide range of operating conditions. Vehicle exhaust is diluted in the dilution tunnel by mixing with conditioned air. Samples are drawn through probes for raw exhaust, diluted exhaust and particulates and measured using laboratory grade emission analyzers and a microbalance. At the end of a driving cycle, results are reported for the above emissions in grams/mile for raw continuous, dilute continuous, dilute bag, and particulate measurements.

Life Cycle Assessment (LCA) is a methodology used to determine quantitatively the environmental impacts of a range of options. The environmental community has used LCA to study all of the impacts of a product over its life cycle. This analysis can help to prevent instances where a greater degree of environmental harm results when changes are made to products based on consideration of impacts in only part of the life cycle. This study applies the methodology to engine lubricants, and in particular chlorine limits in engine lubricant specifications. Concern that chlorine in lubricants might contribute to emissions from vehicle exhausts of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF), collectively called PCDD/F, led to the introduction of chlorine limits in lubricant specifications. No direct evidence was available linking chlorine in lubricants to PCDD/F formation, but precautionary principles were used to set lubricant chlorine limits.

The effect of knock intensity on exhaust emissions was examined in a single cylinder spark ignition engine. The exhaust components surveyed were carbon monoxide, carbon dioxide, oxides of nitrogen (as NO), and total unburned hydrocarbons. Knock was induced solely by changing the spark timing. To describe knock intensity quantitatively, the magnitudes of the rate of pressure irregularities occurring during the combustion process were utilized. The use of the rate of pressure change to define a quantitative knock intensity scale is supported by an apparent generalization of the stoichiometric air-fuel ratio data. Graphs are presented that indicate the dependency of power output as well as exhaust emissions on knock intensity for various air-fuel ratios.

Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.

The world is firmly focused on reducing energy consumption and on increasingly stringent regulations on CO2 emissions. Examples of regulatory changes include the new United States Environmental Protection Agency's (U.S. EPA) fuel economy test procedures which were required beginning with the 2008 model year for vehicles sold in the US market. These test procedures include testing at higher speeds, more aggressive acceleration and deceleration, and hot-weather and cold-temperature testing. These revised procedures are intended to provide an estimate that more accurately reflects what consumers will experience under real world driving conditions. The U.S.

The potential for catalytically enhanced ignition in low-heat rejection Diesel engines has been experimentally studied under engine simulated conditions in a high pressure chemical flow reactor. Results are presented for propane oxidation on platinum at 6 and 10 atmospheres, at temperatures from 800K to 1050K, and at equivalence ratios from 0.5 to 4.0. For turbulent transport rates which are typical of those in an engine, as much as 20% of the fuel was found to react on the catalyst before the onset of the gas-phase ignition reactions. Depending on the adiabaticity of the combustion chamber walls, this could lead to significant thermal enhancement of the gas-phase ignition process. Evidence of chemical enhancement was also observed, at 10 atm under very fuel rich conditions, in terms of a change in the concentration and distribution of the hydrocarbon intermediate species. Possible mechanisms for the observed chemical enhancement due to surface generated species are discussed.

To investigate the effect of removing phosphorus lubricant additives from engine oil, a mileage accumulation programme was run using four 1.6 litre gasoline vehicles, two of which used phosphorus based lubricant oil additives, and the other two used boron based lubricant oil additives. The work showed that the catalyst systems deactivate during mileage accumulation, but emissions were still within the European Stage IV legislative limits at the completion of the mileage accumulation programme. Vehicles run with the boron oil show lower tailpipe emissions than the vehicles run with the phosphorus oil.

The development of new transmission designs continues to affect the vehicle market. Continuously variable transmissions (CVTs) remain one of the more recent designs that impact the vehicle market. A desire for high belt-pulley capacity has driven studies concentrating on metal-on-metal (M/M) friction as a function of the CVT fluid. This paper describes the statistical techniques used to optimize the fluid friction as a function of additive components in a bench-scale, three-element test rig.

This paper outlines the history and background of the NLGI (formerly known as the National Lubricating Grease Institute) lubricating grease specifications, GC-LB classification of Automotive Service Greases as well as details on the development of new requirements for their High-Performance Multiuse (HPM) grease certification program. The performance of commercial lubricating grease formulations through NLGI's Certification Mark using the GC-LB Classification system and the recently introduced HPM grease certification program will be discussed. These certification programs have provided an internationally recognized specification for lubricating grease and automotive manufacturers, users and consumers since 1989. Although originally conceived as a specification for greases for the re-lubrication of automotive chassis and wheel bearings, GC-LB is today recognized as a mark of quality for a variety of different applications.

Characteristics of E diesel, a fuel blend of diesel fuel and ethanol, are considered in a matrix of tests. One characteristic of particular concern and a subject of this investigation is that of stability. Methods to evaluate stability are looked at and compared in light of the potential for distillate and ethanol to separate under certain conditions. The quality of the fuel blend is enhanced by the use of enabling additives to ensure stability which necessitates development of a standard for assessment of the quality of stability. The properties of various base diesel fuels and their influence on stability are also studied. Other key characteristics are evaluated including viscosity, pour point, and oxidative stability.

SAE 2004-01-3009 reported on work conducted to investigate the correlation between the Mack T-11 laboratory engine tests and vehicle field tests. It concluded that the T-11 test provides an effective screening tool to investigate soot-related viscosity increase, and the severity of the engine test limits provides a substantial margin of safety compared to the field. This follow-up paper continues the studies on the 2003 Mack CV713 granite dump truck equipped with an AI-427 internal EGR engine and introduces experimentation on a 2003 CX613 tractor unit equipped with an AC-460P cooled EGR engine. The paper further assesses the correlation of the field trials to the Mack T-11 engine test and reviews the impact of ultra low sulfur diesel (ULSD) and prototype CJ-4 lubricant formulations in these engines.

Soot related viscosity increase has been reported as a field issue in some diesel engines and this led to the development of the T-11 engine test, incorporated in the Mack EO-N Premium Plus 03 specification (014 GS 12037). This study compares T-11 laboratory engine tests and vehicle field tests and seeks to confirm the correlation between them. The findings are that the T-11 test provides an effective screening tool to investigate soot related viscosity increase, and the severity of the engine test limits gives a substantial margin of safety compared to the field. A complementary study was conducted in conjunction with this work that focuses on the successful application of electrochemical sensor technology to diagnose soot content and soot related viscosity increase. This will be the subject of a separate paper.

Raw oils generated by low-temperature coal pyrolysis were chemically characterized and subjected to tests in three diesel engines of different configuration. The coal liquids were tested as blends with conventional No. 2 diesel fuels, the coal liquids being 20-25% by volume. These tests were performed in support of a broader set of studies on the feasibility of using low-temperature pyrolysis to obtain liquid fuel materials from coal that do not require extensive, costly upgrading. Determination of physical and chemical properties of the pyrolysis liquids indicated a higher hydrogen/carbon ratio and lower aromaticity than typical SRC II and EDS middle distillates. Combustion tests were performed in both direct- and indirect-injection engines at three sites. The results were highly variable, the addition of the oil showing no effect on emissions and performance in some cases, reduced emissions on one engine, and increased emissions in other cases.

Recently, research and testing of oxygenated diesel fuels has increased, particularly in the area of exhaust emissions. Included among the oxygenated diesel fuels are blends of diesel fuel with ethanol, or E diesel fuels. Exhaust emissions testing of E diesel fuel has been conducted by a variety of test laboratories under various conditions of engine type and operating conditions. This work reviews the existing public data from previous exhaust emissions testing on E diesel fuel and includes new testing performed in engines of varied design. Emissions data compares E diesel fuel with normal diesel fuel under conditions of different engine speeds, different engine loads and different engine designs. Variations in performance under these various conditions are observed and discussed with some potential explanations suggested.