Technical Paper
Analysis of Transient Thermal and Conversion Characteristics of Dual-Monolith Catalytic Converter with Palladium and Palladium/Rhodium Catalysts
2007-08-05
2007-01-3453
We used a one-dimensional monolithic catalyst model to predict the transient thermal and conversion characteristics of a dual monolithic catalytic converter with a Palladium only (Pd-only) catalyst and a Palladium/Rhodium (Pd/Rh) catalyst. Prior to the numerical investigation of the dual-catalyst converter, we modified the pre-exponential factor and activation energy of each reaction for both catalysts to achieve acceptable agreement with experimental data under typical operating conditions of automobile applications. We validated the conversion behavior of the lumped parameter model for each catalyst against different engine operating conditions. Two higher cell density substrates, Pd-only catalyst (600cpsi/3.9mil) and Pd/Rh catalyst (600cpsi/4mil), for faster light-off and improved warm-up performance are used in this study and the two monoliths has been connected without the space between monoliths.