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Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

When high-intensity discharge (HID) electric lamps are used for plant growth, system inefficiencies occur due to an inability to effectively target light to all photosynthetic tissues of a growing crop stand, especially when it is closed with respect to light penetration. To maintain acceptable crop productivity, light levels typically are increased thus increasing heat loads on the plants. Evapotranspiration (ET) or transparent thermal barrier systems are subsequently required to maintain thermal balance, and power-intensive condensers are used to recover the evaporated water for reuse in closed systems. By accurately targeting light to plant tissues, electric lamps can be operated at lower power settings and produce less heat. With lower power and heat loads, less energy is used for plant growth, and possibly less water is evapotranspired. By combining these effects, a considerable energy savings is possible.

An important function of life support systems developed for a long duration human mission to Mars is the ability to recycle water and air. The Bio-Regenerative Environmental Air Treatment for Health (BREATHe) is part of a multicomponent life support system and will simultaneously treat wastewater and air. The BREATHe system will consist of packed bed biofilm reactors. Model waste streams will be used for experiments conducted during the design phase of the BREATHe system. This paper summarizes expected characteristics of water and air waste steams that would be generated by a crew of six during a human mission to Mars. In addition to waste air and water generation rates, the chemical composition of each waste stream is defined. Specifically, chemical constituents expected to be present in hygiene wastewater, dishwater, laundry water, atmospheric condensate, and cabin air are presented.

This paper provides a comparison of wall heat fluxes and quenching distances as one-dimensional hydrogen and heptane flames impinge head-on onto a wall. It is shown that the quenching distances for stoichiometric H2/air and C7H16/air flames under the specified conditions of this study are about the same, but the wall heat flux for the H2/air flames is approximately a factor of two greater. For lean H2/air mixtures, the quenching distance increases substantially and the wall heat flux decreases. To understand more clearly the interplay of flame speed, temperature, thermal diffusivity, and surface kinetics on the results, studies of H2/O2 flames are also carried out.

A range of cycle characteristics have been used to estimate the hybrid potential for vehicle duty cycles including characteristic acceleration, aerodynamic velocity, kinetic intensity, stop time, etc. These parameters give an indication of overall hybrid potential benefits, but do not contain information on the distribution of the available braking energy and the hybrid system power required to capture the braking energy. In this paper, the authors propose two new cycle characteristics to help evaluate overall hybrid potential of vehicle cycles: P50 and P90, which are non-dimensional power limits at 50% and 90% of available braking energy. These characteristics are independent of vehicle type, and help illustrate the potential hybridization benefit of different drive cycles. First, the distribution of available braking energy as a function of brake power for different vehicle cycles and vehicle classes is analyzed.

In the investigation of a collision involving recreational watercraft, analytical methods are generally limited when compared to incidents involving land-based vehicles. As is indicated in previous publications, investigators often rely on time/distance relationships, human factors, the matching of damage to determine vessel positioning at impact, and the recollections of witnesses. When applicable, speed estimates are generally based on the boat engine's revolutions. By considering the engine speed, the drive gear ratio, the propeller pitch, and the likely slip of the propeller, an estimation of the boat's travel speed can be made. In more recent publications, it has been recognized that Event Data Recorder (EDR) technology incorporated into various Electronic Control Units (ECUs) used in automotive applications can be beneficial to collision investigation and reconstruction.

Resource recovery, including that of urine water extraction, is one of the most crucial aspects of long-term life support in interplanetary space travel. This paper will consequently examine an innovative approach to processing raw, undiluted urine based on low-temperature freezing. This strategy is uniquely different from NASA's current emphasis on either ‘integrated’ (co-treatment of mixed urine, grey, and condensate waters) or ‘high-temperature’ (i.e., VCD [vapor compression distillation] or VPCAR [vapor phase catalytic ammonia removal]) processing strategies, whereby this liquid freeze-thaw (LiFT) procedure would avoid both chemical and microbial cross-contamination concerns while at the same time securing highly desirable reductions in likely ESM levels.

Two-stroke engine keep-clean data is presented to demonstrate the deposit removal capabilities of a premium fuel additive. In this testing, the fuel additive was added as a top-treatment to a 50:1 blended fuel-oil mixture. Engine testing was conducted on an EchoTM SRM-265 (25.4 cc) string trimmer run under a standardized test cycle. Test measurements included piston deposits, ring deposits, and exhaust port blockage. In addition, a more complete data set was analyzed and several variables were investigated including: different base gasoline fuels, ethanol level (E0 and E10), additive dose (none, low, and high), and fuel stabilizer dose (none and high). Post-test inspection of engine parts using fuel additives showed a high level of clean surfaces, which maintained the engine at its original performance.

“Truck Ride” in this study refers to some vehicle ride parameters involved in tractor-trailer combinations. For the study, a mathematical model of a tractor-trailer vehicle as a vibrating system was developed. Principles of vibration theory were applied to the model while a digital computer was employed to investigate the complex system. To parallel the analytical investigation of the tractor-trailer vehicle, vehicle studies were conducted using a magnetic tape recorder and associated instrumentation installed in the tractor. Parameters studied included coupler position on the tractor, laden weight of trailer, spring rates of the different axles of the combination, damping capacity associated with each spring rate, vehicle speed, and “tar strip” spacing of the highway and cab mountings. The mathematical results were used as a basis for empirical study. A comparison of calculated and empirical data are reported.

Light duty vehicle emission standards are getting more stringent than ever before as stipulated by US EPA Tier 2 Standards and LEV III regulations proposed by CARB. The research in this paper sponsored by US DoE is focused towards developing a Tier 2 Bin 2 Emissions compliant light duty pickup truck with class leading fuel economy targets of 22.4 mpg “City” / 34.3 mpg “Highway”. Many advanced technologies comprising both engine and after-treatment systems are essential towards accomplishing this goal. The objective of this paper would be to discuss key engine technology enablers that will help in achieving the target emission levels and fuel economy. Several enabling technologies comprising air-handling, fuel system and base engine design requirements will be discussed in this paper highlighting both experimental and analytical evaluations.

The new devices and missions to achieve the aims of NASA's Science Mission Directorate (SMD) are creating increasingly demanding thermal environments and applications. In particular, the low conductance of metal-to-metal interfaces used in the thermal switches lengthen the cool-down phase and resource usage for spacecraft instruments. During this work, we developed and tested a vacuum-compatible, durable, heat-conduction interface that employs carbon nanotube (CNT) arrays directly anchored on the mating metal surfaces via microwave plasma-enhanced, chemical vapor deposition (PECVD). We demonstrated that CNT-based thermal interface materials have the potential to exceed the performance of currently available options for thermal switches and other applications.

The cost and complexity of aircraft power systems limit the number of integrated system evaluations that can be performed in hardware. As a result, evaluations are often performed using emulators to mimic components or subsystems. As an example, aircraft generation systems are often tested using an emulator that consists of a bank of resistors that are switched to represent the power draw of one or more actuators. In this research, consideration is given to modern wide bandwidth emulators (WBEs) that use power electronics and digital controls to obtain wide bandwidth control of power, current, or voltage. Specifically, this paper first looks at how well a WBE can emulate the impedance of a load when coupled to a real-time model. Capturing the impedance of loads and sources is important for accurately assessing the small-signal stability of a system.

Current production heavy duty diesel engines have a brake thermal efficiency (BTE) between 43-46% [1]. In partnership with the United States Department of Energy (DOE) as part of the Supertruck 2 program, Cummins has undertaken a research program to develop a new heavy-duty diesel engine designed to deliver greater than 50% BTE without the use of waste heat recovery. A system level optimization focused on: increased compression ratio, higher injection rate, carefully matched highly efficient turbocharging, variable lube oil pump, variable cooling components, and low restriction after treatment designed to deliver 50% BTE at a target development point. This work will also illustrate the system level planning and understanding of interactions required to allow that same 50% BTE heavy duty diesel engine to be integrated with a waste heat recovery (WHR) system to deliver system level efficiency of 55% BTE at a single point.

The influence of big-end bore fretting on connecting rod fatigue fracture is investigated. A finite element model, including rod-bearing contact interaction, is developed to simulate a fatigue test rig where the connecting rod is subjected to an alternating uniaxial load. Comparison of the model results with a rod fracture from the fatigue rig shows good correlation between the fracture location and the peak ‘Ruiz’ criterion, rather than the peak tensile stress location, indicating the potential of fretting to initiate a fatigue fracture and the usefulness of the ‘Ruiz’ criterion as a measure of location and severity. The model is extended to simulate a full engine cycle using pressure loads from a bearing EHL analysis. A fretting map and a ‘Ruiz’ criterion map are developed for the full engine cycle, giving an indication of a safe ‘Ruiz’ level from an existing engine which has been in service for more than 5 years.

Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature.

Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.

Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

Rolling element bearings provide near frictionless relative motion between two rotating parts. Automotive transmissions use various ball and rolling element bearings to accommodate the relative motion between rotating elements. In order to understand changes in bearing performance due to the loads imposed through the transmission, advanced modeling of the bearing is required. This paper focuses on the effects of cage flexibility on bearing performance. A flexible cage model was developed and incorporated into a six degree-of-freedom dynamic, deep groove ball bearing model. A lumped mass approach was used to represent the cage flexibility and was validated through an ANSYS forced response analyses of the cage. Results from the newly developed Flexible Cage Model (FCM) and an identical numerical model employing a rigid bearing cage were compared to determine the effects of varying ball-to-cage pocket clearance and cage stiffness on cage motion and ball-to-cage pocket contact forces.

The vertical force generated from terrain-tire interaction has long been of interest for vehicle dynamic simulations and chassis development. To improve simulation efficiency while still providing reliable load prediction, a terrain pre-filtering technique using a constraint mode tire model is developed. The wheel is assumed to convey one quarter of the vehicle load constantly. At each location along the tire's path, the wheel center height is adjusted until the spindle load reaches the pre-designated load. The resultant vertical trajectory of the wheel center can be used as an equivalent terrain profile input to a simplified tire model. During iterative simulations, the filtered terrain profile, coupled with a simple point follower tire model is used to predict the spindle force. The same vehicle dynamic simulation system coupled with constraint mode tire model is built to generate reference forces.