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Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.

Throttle ramp rate effects on the in-cylinder fuel/air (F/A) excursion was studied in a production engine. The fuel delivered to the cylinder per cycle was measured in-cylinder by a Fast Response Flame Ionization detector. Intake pressure was ramped from 0.4 to 0.9 bar. Under slow ramp rates (∼1 s ramp time), the Engine Electronic Control (EEC) unit provided the correct compensation for delivering a stoichiometric mixture to the cylinder throughout the transient. At fast ramp rates (a fraction of a second ramps), a lean spike followed by a rich one were observed. Based on the actual fuel injected in each cycle during the transient, a x-τ model using a single set of x and τ values reproduced the cycle-to-cycle in-cylinder F/A response for all the throttle ramp rates.

The paper considers the thermodynamic irreversibility in Stirling cycle machines at the interface between components with different thermodynamic characteristics. The approach of the paper is to consider the simplest possible cases and to focus on the factors that influence the thermodynamic losses. For example, an ideal adiabatic cylinder facing an ideal isothermal heat exchanger is considered. If there is no mixing in the cylinder (gas remains one dimensionally stratified), there will be no loss (irreversibility) if the gas motion is in phase with the gas pressure changes. If there is a phase shift, as required to have a network for the cylinder, there will be a loss (entropy generation) because the gas will not match the heat exchanger temperature. There will also be a loss if the gas in the cylinder is mixed rather than stratified. Similar simple interface conditions can be considered between components and interconnecting open volumes and between heat exchangers and regenerators.

The objective of this work was to develop an experimental system to support development and validation of a model for the lubrication of two-piece Twin-Land-Oil-Control-Rings (hereafter mentioned as TLOCR). To do so, a floating liner engine was modified by opening the head and crankcase. Additionally, only TLOCR was installed together with a piston that has 100 micron cold clearance to minimize the contribution of the skirt to total friction. Friction traces, FMEP trend, and repeatability have been examined to guarantee the reliability of the experiment results. Then, engine speed, liner temperature, ring tension, and land widths were changed in a wide range to ensure all three lubrication regimes were covered in the experiments.

PARAMOUNT among the problems relating to the efficiency of the internal-combustion engine is that of breathing capacity, or air consumption. Considering volumetric efficiency to be the most valuable parameter in an analytical or experimental approach to this problem, the authors of this paper have devoted several years of study to this factor in relation to 4-stroke engines. The studies have resulted in extensive findings, some of which have already been published. This paper attempts to bring together in readable form the results of the work to date, including both published and unpublished data. The authors discuss in detail the effect of volumetric efficiency on operating variables, piston speed, inlet-valve flow capacity, cylinder design, and size. They introduce a gulp factor, the inlet-valve Mach index, and explain how this factor can be used to guide engineers.

In internal combustion engines, the majority of the friction loss associated with the piston takes place on the thrust side in early expansion stroke. Research has shown that the Friction Mean Effective Pressure (FMEP) of the engine can be reduced if proper modifications to the piston skirt, which is traditionally barrel-shaped, are made. In this research, an existing model was applied for the first time to study the effects of different oil supply strategies for the piston assembly. The model is capable of tracking lubricating oil with the consideration of oil film separation from full film to partial film. It is then used to analyze how the optimized piston skirt profile investigated in a previous study reduces friction.

Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.

Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

THE indicated output of a 2-stroke engine is primarily dependent upon the success with which the products of combustion are driven from the cylinder and are replaced by fresh air or mixture during the scavenging period. Such replacement must, of course, be accomplished with a minimum of blower power. This paper deals with various aspects of 2-stroke research conducted at M.I.T. during the past 10 years. Among the subjects discussed are the methods used in the prediction and measurement of scavenging efficiency, and the effect of engine design and operating variables on the scavenging blower requirements as reflected by the scavenging ratio.

Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.

Higher compression ratio and turbocharging, with engine downsizing can enable significant gains in fuel economy but require engine operating conditions that cause engine knock under high load. Engine knock can be avoided by supplying higher-octane fuel under such high load conditions. This study builds on previous MIT papers investigating Octane-On-Demand (OOD) to enable a higher efficiency, higher-boost higher compression-ratio engine. The high-octane fuel for OOD can be obtained through On-Board-Separation (OBS) of alcohol blended gasoline. Fuel from the primary fuel tank filled with commercially available gasoline that contains 10% by volume ethanol (E10) is separated by an organic membrane pervaporation process that produces a 30 to 90% ethanol fuel blend for use when high octane is needed. In addition to previous work, this paper combines modeling of the OBS system with passenger car and medium-duty truck fuel consumption and octane requirements for various driving cycles.

The increasing demand for environmentally friendly and fuel-efficient transportation and power generation requires further optimization and minimization of friction power losses. With up to 50% of the overall friction, the piston cylinder unit (PCU) shows most potential within the internal combustion engine (ICE) to increase mechanical efficiency. Calculating friction of internal combustion engines, especially the friction contribution from piston rings and skirt, requires detailed knowledge of the dynamics and lubrication regime of the components being in contact. Part I of this research presents a successful match of simulated and measured piston inter-ring pressures at numerous operation points [1] and constitutes the starting point for the comparison of simulated and measured piston group friction forces as presented in this research.

Experiments were carried out to collect in-cylinder pressure data and microphone signals from a single-cylinder test engine using spark timingsbefore, at, and after knock onset for toluene reference fuels. The objective was to gain insight into the phenomena that determine knock onset, detected by an external microphone. In particular, the study examines how the end-gas autoignition process changes as the engine's spark timing is advanced through the borderline knock limit into the engine's knocking regime. Fast Fourier transforms (FFT) and bandpass filtering techniques were used to process the recorded cylinder pressure data to determine knock intensities for each cycle. Two characteristic pressure oscillation frequencies were detected: a peak just above 6 kHz and a range of peaks in the 15-22 kHz range. The microphone data shows that the audible knock signal has the same 6 kHz peak.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

Lubricant viscosity along the engine cylinder liner varies by an order of magnitude due to local temperature variation and vaporization effects. Tremendous potential exists for fuel economy improvement by optimizing local viscosity variations for specific operating conditions. Methods for analytical estimation of friction and wear in the power-cylinder system are reviewed and used to quantify opportunities for improving mechanical efficiency and fuel economy through lubricant formulation tailored specifically to liner temperature distributions. Temperature dependent variations in kinematic viscosity, density, shear thinning, and lubricant composition are investigated. Models incorporating the modified Reynolds equation were used to estimate friction and wear under the top ring and piston skirt of a typical 11.0 liter diesel engine.

Particulate emissions from a production gasoline direct injection spark ignition engine were studied under a typical cold-fast-idle condition (1200 rpm, 2 bar NIMEP). The particle number (PN) density in the 22 to 365 nm range was measured as a function of the injection timing with single pulse injection and with split injection. Very low PN emissions were observed when injection took place in the mid intake stroke because of the fast fuel evaporation and mixing processes which were facilitated by the high turbulent kinetic energy created by the intake charge motion. Under these conditions, substantial liquid fuel film formation on the combustion chamber surfaces was avoided. PN emissions increased when injection took place in the compression stroke, and increased substantially when the fuel spray hit the piston.

This paper explores the combined effects of boosting, intake air temperature, trapped residual gas fraction, and dilution on the Maximum Pressure Rise Rate (MPRR) in a boosted single cylinder gasoline HCCI engine with combustion controlled by negative valve overlap. Dilutions by both air and by cooled EGR were used. Because of the sensitivity of MPRR to boost, the MPRR constrained maximum load (as measured by the NIMEP) did not necessarily increase with boosting. At the same intake temperature and trapped residual gas fraction, dilution by recirculated burn gas was effective in reducing the MPRR, but dilution by air increased the value of MPRR. The dependence of MPRR on the operating condition was interpreted successfully by a simple thermodynamic analysis that related the MPRR value to the volumetric heat release rate.

A technique has been developed to measure the desorption and subsequent oxidation of fuel in the oil layer by spiking the oil with liquid fuel and firing the engine on gaseous fuel or motoring with air. Experiments suggest that fuel desorption is not diffusion limited above 50 °C and indicated that approximately two to four percent of the cylinder oil layer is fresh oil from the sump. The increase in hydrocarbon emissions is of the order of 100 ppmC1 per 1% liquid fuel introduced into the fresh oil in a methane fired engine at mid-speed and light load conditions. Calculations indicate that fuel desorbing from oil is much more likely to produce hydrocarbon emissions than fuel emerging from crevices.

The distribution of lubricating oil plays a critical role in determining the friction between piston skirt and cylinder liner, which is one of the major contributors to the total friction loss in internal combustion engines. In this work, based upon the experimental observation an existing model for the piston secondary motion and skirt lubrication was improved with a physics-based model describing the oil film separation from full film to partial film. Then the model was applied to a modern turbo-charged SI engine. The piston-skirt FMEP predicted by the model decreased with larger installation clearance, which was also observed from the measurements using IMEP method at the rated. It was found that the main period of the cycle exhibiting friction reduction is in the expansion stroke when the skirt only contacts the thrust side for all tested installation clearances.

Frictional losses in the piston ring-pack of an engine account for approximately half of the total frictional losses within the power cylinder of an engine. Three-dimensional honing groove texture was modeled, and its effect on piston ring-pack friction and engine brake thermal efficiency was investigated. Adverse effects on engine oil consumption and durability were also considered. Although many non-conventional cylinder liner finishes are now being developed to reduce friction and oil consumption, the effects of surface finish on ring-pack performance is not well understood. A rough surface flow simulation program was developed to calculate flow and stress factors that adjust the solution of the Reynolds equation for the effects of surface roughness as has been done in the literature. Rough surface contact between the ring and liner was modeled using a previously published methodology for asperity contact pressure estimation between rough surfaces.