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COMPARISON of work capacity per unit mass and volume of different energy carriers shows that liquid hydrocarbons are superior to other energy sources. Solar and nuclear powerplants as well as their use in conjunction with a steam engine are examined in this paper. Suitability of an electric drive is discussed. Using a production 2-stroke diesel engine and its development forecast, a comparison is made of spark ignition, diesel, and gas turbine engines. The status of the free-piston engine turbine combination is reviewed.

To establish performance trends in ultra thin wall substrates and help support their selection criteria for designing catalytic converter systems, the light-off behavior of five Ultra Thin Wall ceramic substrates and two catalysts on an engine dynamometer are hereby examined. Modeling predictions are also compared to the engine results and the trends and implications are discussed. To quantify the performance of these different systems, light-off tests were performed on an engine dynamometer using a simulated FTP cycle. Five systems were evaluated (600/4, 600/3, 600/2, 900/2 and 1200/2) each with two different catalyst formulations. Engine bench aging was used to simulate typical aged conditions in the converter systems. Second by second emissions data for temperature, hydrocarbons and carbon monoxide, were used to evaluate the relative performances of the substrates.

A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.

Experimental measurements of the instantaneous exhaust gas temperature, mass flowrate, and hydrocarbon concentration have been made in the exhaust of a single cylinder research engine. The temperature measurements were accomplished using an infrared optical technique and observing the radiation of the exhaust gas at the 4.4 μm band of CO2. Instantaneous exhaust gas mass flowrates were monitored by placing a restriction in the exhaust manifold and measuring the instantaneous pressures across the restriction. Time-resolved hydrocarbon concentrations were measured using a fast-acting sampling valve with an open time of 2 ms. From these measurements, the hydrocarbon mass flowrate is calculated as a function of crank angle.

Measurements were made of exhaust histories of the following species: unburned hydrocarbons (HC), carbon monoxide, carbon dioxide, oxygen, and nitric oxide (NO). The measurements show that the exhaust flow can be divided into two distinct phases: a leading gas low in HC and high in NO followed by a trailing gas high in HC and low in NO. Calculations of time resolved equivalence ratio throughout the exhaust process show no evidence of a stratified combustion. The exhaust mass flow rate is time resolved by forcing the flow to be locally quasi-steady at an orifice placed in the exhaust pipe. The results with the quasi-steady assumption are shown to be consistent with the measurements. Predictions are made of time resolved mass flow rate which compare favorably to the experimental data base. The composition and flow histories provide sufficient information to calculate the time resolved flow rates of the individual species measured.

This study evaluated multi-layer steel and composite head gaskets of various thicknesses (0.43 to 1.5 mm) and fire-ring diameters to determine the influence of head gasket crevices on engine-out hydrocarbon (HC) emissions. The upper limit in the percent reduction in HC emissions from gasket-design modifications is estimated to be about 15%. At part-load conditions, the lowest HC emissions were measured for head-gasket thickness of about 1 mm. Significantly smaller thicknesses of the order of 0.4 mm result in an increase in HC emissions. Substantial hydrocarbon-emissions advantage may be realized by minimizing the gasket-to-cylinder bore offset.

To understand the effects of crevices on the engine-out hydrocarbon emissions, a series of engine experiments was carried out with different piston crevice volumes and with simulated head gasket crevices. The engine-out HC level was found to be modestly sensitive to the piston crevice size in both the warmed-up and the cold engines, but more sensitive to the crevice volume in the head gasket region. A substantial decrease in HC in the cold-to-warm-up engine transition was observed and is attributed mostly to the change in port oxidation.

The topic of CO₂ and fuel consumption reductions from vehicles is a very broad and complex issue, encompassing vehicle regulations, biofuel mandates, and a vast assortment of engine and vehicle technologies. This paper attempts to provide a high-level review of all these issues. Reducing fuel consumption appears not to be driven by the amount of hydrocarbon reserves, but by energy security and climate change issues. Regarding the latter, a plan was proposed by the United Nations for upwards of 80% CO₂ reductions from 1990 levels by 2050. Regulators are beginning to respond by requiring ~25% reductions in CO₂ emissions from light-duty vehicles by 2016 in major world markets, with more to come. The heavy-duty sector is poised to follow. Similarly, fuel policy is aimed at energy diversity (security) and climate change impacts. Emerging biofuel mandates require nominally 5-10% CO₂ life cycle emissions reductions by 2020.

Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.

Improved designs of extruded metal electrically heated catalysts (EHC) in combination with a traditional converter achieved the California ultra-low emission vehicle (ULEV) standard utilizing 50% less electrical energy than previous prototypes. This energy reduction is largely achieved by reducing the mass of the EHC. In addition to energy reduction, the battery voltage is reduced from 24 volts to 12 volts, and the power is reduced from 12 kilowatts to 3 kilowatts. Also discussed is the impact EHC mass, EHC catalytic activity, and no EHC preheating has on non-methane hydrocarbon emissions, energy requirements, and power requirements.

The ozone forming potential (OFP) and specific reactivity (SR) of tailpipe exhaust are among the regulated factors that determine the environmental impact of a motor vehicle. OFP and SR measurements require a lengthy determination of about 160 non-methane hydrocarbon species. A rapid gas chromatography (GC) instrument has been constructed to separate both the light (C2 - C4) and the midrange (C5 - C12) hydrocarbons in less than 10 minutes. The limit of detection was about 0.002 parts per million carbon (ppmC). Twelve exhaust samples from two vehicles were analyzed to compare the rapid GC method with the standard GC method, which required 40-minute analyses on two different instruments. Speciation and reactivity data from the two methods were comparable. The increased sample throughput of rapid GC promises to improve OFP and SR measurements, particularly when good statistical data are necessary to insure accurate, precise results for low emission vehicles

Low mass extruded electrically heated catalysts (EHC) followed directly by light-off and main converters resulted in non-methane hydrocarbon emissions (NMHC) between .020 and .023 g/mi at power levels as low as 1 kw and energy levels as low as 4 whr. These results were achieved on a 1993, 2.2 liter vehicle. The success of this system is due to rapid heat up of the catalyzed surface areas of both the heater and light-off converter. The energy added to the exhaust from both the heater and the light-off is then efficiently transferred to the main converter. In addition, the impact of power and energy on NMHC levels was determined. The Ultra-Low Emissions Vehicle (ULEV) standard was also achieved with uncatalyzed heaters and on a 1990, 3.8 L vehicle. The new California Low Emission Vehicle (LEV) and Ultra Low Emission Vehicle (ULEV) standards require a significant reduction in tail pipe emissions compared to current standards.

About 50-90 percent of the hydrocarbons that escape combustion during flame passage in spark-ignition engine operation are oxidized in the cylinder before leaving the system. The process involves the transport of unreacted fuel from cold walls towards the hotter burned gas regions and subsequent reaction. In order to understand controlling factors in the process, a transient one-dimensional reactive-diffusive model has been formulated for simulating the oxidation processes taking place in the reactive layer between hot burned gases and cold unreacted air/fuel mixture, with initial and boundary conditions provided by the emergence of hydrocarbons from the piston top land crevice. Energy and species conservation equations are solved for the entire process, using a detailed chemical kinetic mechanism for propane.

A technique has been developed to measure the desorption and subsequent oxidation of fuel in the oil layer by spiking the oil with liquid fuel and firing the engine on gaseous fuel or motoring with air. Experiments suggest that fuel desorption is not diffusion limited above 50 °C and indicated that approximately two to four percent of the cylinder oil layer is fresh oil from the sump. The increase in hydrocarbon emissions is of the order of 100 ppmC1 per 1% liquid fuel introduced into the fresh oil in a methane fired engine at mid-speed and light load conditions. Calculations indicate that fuel desorbing from oil is much more likely to produce hydrocarbon emissions than fuel emerging from crevices.

Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.

In order to understand better the operation of spark-ignition engines during the warm-up period, a computer model had been developed which simulates the thermal processes of the engine. This model is based on lumped thermal capacitance methods for the major engine components, as well as the exhaust system. Coolant and oil flows, and their respective heat transfer rates are modeled, as well as friction heat generation relations. Piston-liner heat transfer is calculated based on a thermal resistance method, which includes the effects of piston and ring material and design, oil film thickness, and piston-liner crevice. Piston/liner crevice changes are calculated based on thermal expansion rates and are used in conjunction with a crevice-region unburned hydrocarbon model to predict the contribution to emissions from this source.

A model has been developed which predicts engine-out hydrocarbon (HC) emissions for spark-ignition engines. The model consists of a set of scaling laws that describe the individual processes that contribute to HC emissions. The model inputs are the critical engine design and operating variables. This set of individual process scaling relations was then calibrated using production spark-ignition engine data at a fixed light-load operating point. The data base consisted of engine-out HC emissions from two-valve and four-valve engine designs with variations in spark timing, valve timing, coolant temperature, crevice volume, and EGR, for five different engines. The model was calibrated separately for the three different engines to accommodate differences in engine design details and to determine the relative magnitudes of each of the major sources. A good fit to this database was obtained.

The in-cylinder hydrocarbon (HC) mole fraction was measured on a cycle-resolved basis during simulated starting and warm-up of a port-injected single-cylinder SI research engine on a dynamometer. The measurements were made with a fast-response flame ionization detector with a heated sample line. The primary parameters that influence how rapidly a combustible mixture builds up in the cylinder are the inlet pressure and the amount of fuel injected; engine speed and fuel injection schedule have smaller effects. When a significant amount of liquid fuel is present at the intake port in the starting process, the first substantial firing cycle is often preceded by a cycle with abnormally high in-cylinder HC and low compression pressure. An energy balance analysis suggests that a large amount of liquid vaporization occurs within the cylinder in this cycle.

A method to collect and speciate the components of gasoline absorbed in the lubricant oil using gas chromatography has been developed. Samples were collected continuously from the piston skirt, baffle and sump in a Saturn engine. A long (18 hours) test was performed to determine the build up of hydrocarbons in the sump, and a shorter (25 min) test was performed to determine the build up of hydrocarbons in the piston skirt and baffle during engine warm-up. The first experiment showed that the total hydrocarbon concentration in the sump oil reached a steady state of about 1.35% mass fraction after 11 hours of engine operation. The relative concentration of individual fuel hydrocarbon species absorbed in the oil increases exponentially with boiling point. Most of the identified species in the oil consist of the heavy end aromatics. Similar compositions but lower concentrations were found for samples collected from the piston skirt during engine warm-up.

The presence of liquid fuel inside the engine cylinder is believed to be a strong contributor to the high levels of hydrocarbon emissions from spark ignition (SI) engines during the warm-up period. Quantifying and determining the fate of the liquid fuel that enters the cylinder is the first step in understanding the process of emissions formation. This work uses planar laser induced fluorescence (PLIF) to visualize the liquid fuel present in the cylinder. The fluorescing compounds in indolene, and mixtures of iso-octane with dopants of different boiling points (acetone and 3-pentanone) were used to trace the behavior of different volatility components. Images were taken of three different planes through the engine intersecting the intake valve region. A closed valve fuel injection strategy was used, as this is the strategy most commonly used in practice. Background subtraction and masking were both performed to reduce the effect of any spurious fluorescence.