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Technical Paper

Using Mass Spectrometry to Detect Ethanol and Acetaldehyde Emissions from a Direct Injection Spark Ignition Engine Operating on Ethanol/Gasoline Blends

2011-04-12
2011-01-1159
Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.
Technical Paper

Time-Resolved, Speciated Emissions from an SI Engine During Starting and Warm-Up

1996-10-01
961955
A sampling system was developed to measure the evolution of the speciated hydrocarbon emissions from a single-cylinder SI engine in a simulated starting and warm-up procedure. A sequence of exhaust samples was drawn and stored for gas chromatograph analysis. The individual sampling aperture was set at 0.13 s which corresponds to ∼ 1 cycle at 900 rpm. The positions of the apertures (in time) were controlled by a computer and were spaced appropriately to capture the warm-up process. The time resolution was of the order of 1 to 2 cycles (at 900 rpm). Results for four different fuels are reported: n-pentane/iso-octane mixture at volume ratio of 20/80 to study the effect of a light fuel component in the mixture; n-decane/iso-octane mixture at 10/90 to study the effect of a heavy fuel component in the mixture; m-xylene and iso-octane at 25/75 to study the effect of an aromatics in the mixture; and a calibration gasoline.
Technical Paper

Time Resolved Measurements of Exhaust Composition and Flow Rate in a Wankel Engine

1975-02-01
750024
Measurements were made of exhaust histories of the following species: unburned hydrocarbons (HC), carbon monoxide, carbon dioxide, oxygen, and nitric oxide (NO). The measurements show that the exhaust flow can be divided into two distinct phases: a leading gas low in HC and high in NO followed by a trailing gas high in HC and low in NO. Calculations of time resolved equivalence ratio throughout the exhaust process show no evidence of a stratified combustion. The exhaust mass flow rate is time resolved by forcing the flow to be locally quasi-steady at an orifice placed in the exhaust pipe. The results with the quasi-steady assumption are shown to be consistent with the measurements. Predictions are made of time resolved mass flow rate which compare favorably to the experimental data base. The composition and flow histories provide sufficient information to calculate the time resolved flow rates of the individual species measured.
Technical Paper

Thermodynamic Properties of the Working Fluid in Internal-Combustion Engines

1936-01-01
360140
THE thermodynamic analysis of an internal-combustion engine, even in the idealized case, is in general more complex than a similar analysis of an engine cycle in which the fluid undergoes no chemical change. It is the purpose of this paper to show that, despite the inherent complexity of the problem, an exact solution by graphical methods is possible, and the method is very similar in nature to those used in connection with the Mollier diagram for steam. Two types of charts are presented, one descriptive of the thermodynamic properties of the airfuel mixture (and residual products of combustion) before combustion, the other descriptive of the properties of the equilibrium mixture after combustion. Full allowance is made for the variation of specific heats with temperature and for the complex dissociation at the high temperatures attained after combustion. All calculations are based on the most recent basic thermodynamic data available in the literature.
Technical Paper

Thermodynamic Loss at Component Interfaces in Stirling Cycles

1992-08-03
929468
The paper considers the thermodynamic irreversibility in Stirling cycle machines at the interface between components with different thermodynamic characteristics. The approach of the paper is to consider the simplest possible cases and to focus on the factors that influence the thermodynamic losses. For example, an ideal adiabatic cylinder facing an ideal isothermal heat exchanger is considered. If there is no mixing in the cylinder (gas remains one dimensionally stratified), there will be no loss (irreversibility) if the gas motion is in phase with the gas pressure changes. If there is a phase shift, as required to have a network for the cylinder, there will be a loss (entropy generation) because the gas will not match the heat exchanger temperature. There will also be a loss if the gas in the cylinder is mixed rather than stratified. Similar simple interface conditions can be considered between components and interconnecting open volumes and between heat exchangers and regenerators.
Technical Paper

Thermal Management and Control in Testing Packaged Integrated Circuit (IC) Devices

1999-08-02
1999-01-2723
This paper describes the thermal management and design challenges of testing packaged integrated circuit (IC) devices, specifically device thermal conditioning and device-under-test (DUT) temperature control. The approach taken is to discuss the individual thermal design issues as defined by the device type (e.g. memory, microcontroller) and tester capabilities. The influence of performance-parameter specifications, such as the DUT parallelism, test time, index time, test-temperature range and test-temperature tolerance are examined. An understanding of these performance requirements and design constraints enables consideration of existing test handler thermal processing systems (e.g., gravity feed, pick and place), future test handler thermal concepts, and future high-parallelism testing needs for high-wattage memory and microprocessor devices. New thermal designs in several of these areas are described.
Technical Paper

The Theory of Cost Risk in Design

1999-03-01
1999-01-0495
In a recent paper (Hoult & Meador, [1]) a novel method of estimating the costs of parts, and assemblies of parts, was presented. This paper proposed that the metric for increments of cost was the function log (dimension/tolerance). Although such log functions have a history,given in [1], starting with Boltzman and Shannon, it is curious that it arises in cost models. In particular, the thermodynamic basis of information theory, given by Shannon [2], seems quite implausible in the present context. In [1], we called the cost theory “Complexity Theory”, mainly to distinguish it from information theory. A major purpose of the present paper is to present a rigorous argument of how the log function arises in the present context. It happens that the agrument hinges on two key issues: properties of the machine making or assembling the part, and a certain limit process. Neither involves thermodynamic reasoning.
Technical Paper

The National Space Biomedical Research Institute Education and Public Outreach Program: Engaging the Public and Inspiring the Next Generation of Space Explorers

2005-07-11
2005-01-3105
The National Space Biomedical Research Institute (NSBRI), established in 1997, is a twelve-university consortium dedicated to research that will impact mankind's next exploratory steps. The NSBRI's Education and Public Outreach Program (EPOP), is supporting NASA's education mission to, “Inspire the next generations…as only NASA can,” through a comprehensive Kindergarten through post-doctoral education program. The goals of the EPOP are to: communicate space exploration biology to schools; support undergraduate and graduate space-based courses and degrees; fund postdoctoral fellows to pursue space life sciences research; and engage national and international audiences to promote understanding of how space exploration benefits people on Earth. NSBRI EPOP presents its accomplishments as an educational strategy for supporting science education reform, workforce development, and public outreach.
Technical Paper

The Mars Gravity Biosatellite: Thermal Design Strategies for a Rotating Partial Gravity Spacecraft

2007-07-09
2007-01-3078
A rotating spacecraft which encloses an atmospheric pressure vessel poses unique challenges for thermal control. In any given location, the artificial gravity vector is directed from the center to the periphery of the vehicle. Its local magnitude is determined by the mathematics of centripetal acceleration and is directly proportional to the radius at which the measurement is taken. Accordingly, we have a system with cylindrical symmetry, featuring microgravity at its core and increasingly strong gravity toward the periphery. The tendency for heat to move by convection toward the center of the craft is one consequence which must be addressed. In addition, fluid flow and thermal transfer is markedly different in this unique environment. Our strategy for thermal control represents a novel approach to address these constraints. We present data to theoretically and experimentally justify design decisions behind the Mars Gravity Biosatellite's proposed payload thermal control subassembly.
Technical Paper

The Mars Gravity Biosatellite: Atmospheric Reconditioning Strategies for Extended-Duration Rodent Life Support

2007-07-09
2007-01-3224
We present results which verify the design parameters and suggest performance capabilities/limitations of the Mars Gravity Biosatellite's proposed atmospherics control subassembly. Using a combination of benchtop prototype testing and analytic techniques, we derive control requirements for ammonia. Further, we demonstrate the dehumidification performance of our proposed partial gravity condensing heat exchanger. Ammonia production is of particular concern in rodent habitats. The contaminant is released following chemical degradation of liquid waste products. The rate of production is linked to humidity levels and to the design of habitat modules in terms of bedding substrate, air flow rates, choice of structural materials, and other complex factors. Ammonia buildup can rapidly lead to rodent health concerns and can negatively impact scientific return.
Technical Paper

The General Motors Driving Simulator

1994-03-01
940179
A driving simulator development project at the Systems Engineering and Technical Process Center (SE/TP) is exploring the role of driving simulation in the vehicle design process. The simulator provides two vehicle mockup testing arenas that support a wide field of view, computer-generated image of the road scene which dynamically responds to driver commands as a function of programmable vehicle model parameters. Two unique aspects of the simulator are the fast 65 ms response time and low incidence rate of simulator induced syndrome (about 5%). Preliminary model validation results and data comparing driver performance in a vehicle vs. the simulator indicate accurate handling response dynamics within the on-center handling region (<0.3g lateral acceleration). Applications have included supporting the development of new steering system concepts, as well as evaluating the usability of vehicle controls and displays.
Technical Paper

The Effects of Sulfated Ash, Phosphorus and Sulfur on Diesel Aftertreatment Systems - A Review

2007-07-23
2007-01-1922
This paper reviews the relevant literature on the effects of sulfated ash, phosphorus, and sulfur on DPF, LNT, and SCR catalysts. Exhaust backpressure increase due to DPF ash accumulation, as well as the rate at which ash is consumed from the sump, were the most studied lubricant-derived DPF effects. Based on several studies, a doubling of backpressure can be estimated to occur within 270,000 to 490,000 km when using a 1.0% sulfated ash oil. Postmortem DPF analysis and exhaust gas measurements revealed that approximately 35% to 65% less ash was lost from the sump than was expected based on bulk oil consumption estimates. Despite significant effects from lubricant sulfur and phosphorus, loss of LNT NOX reduction efficiency is dominated by fuel sulfur effects. Phosphorus has been determined to have a mild poisoning effect on SCR catalysts. The extent of the effect that lubricant phosphorus and sulfur have on DOCs remains unclear, however, it appears to be minor.
Technical Paper

The Effect of Exhaust System Geometry on Exhaust Dilution and Odor Intensity

1971-02-01
710219
Diesel exhaust gas dilution and odor intensity were measured in the immediate vicinity of a transit bus equipped with a rear-mounted horizontal exhaust pipe, a rear-mounted vertical exhaust pipe, and a roof-top diffusion system. Exhaust dilution ratios were measured indoors during vehicle idle operation, using propane added to the exhaust gas as a tracer. Exhaust odor intensities were measured also indoors during vehicle idle operation by a human panel, using a threshold odor measurement technique. On the average, the dilution of the exhaust gas around the bus with the vertical exhaust pipe was about eight times greater than it was with the horizontal pipe. Odor intensity, as measured by the threshold response distance, was about 35% less with the vertical pipe than with the horizontal pipe. The roof-top diffuser was not as effective as the vertical exhaust pipe in increasing exhaust gas dilution or in reducing exhaust odor intensity.
Technical Paper

The Application of Direct Body Excitation Toward Developing a Full Vehicle Objective Squeak and Rattle Metric

2001-04-30
2001-01-1554
In order to engineer Squeak & Rattle (S&R) free vehicles it is essential to develop an objective measurement method to compare and correlate with customer satisfaction and subjective S&R assessments. Three methods for exciting S&Rs -type surfaces. Excitation methods evaluated were road tests over S&R surfaces, road simulators, and direct body excitation (DBE). The principle of DBE involves using electromagnetic shakers to induce controlled, road-measured vibration into the body, bypassing the tire patch and suspension. DBE is a promising technology for making objective measurements because it is extremely quiet (test equipment noise does not mask S&Rs), while meeting other project goals. While DBE is limited in exposing S&Rs caused by body twist and suspension noises, advantages include higher frequency energy owing to electro-dynamic shakers, continuous random excitation, lower capital cost, mobility, and safety.
Technical Paper

The Anatomy of Knock

2016-04-05
2016-01-0704
The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties
Technical Paper

Technical Potential for Thermally Driven Mobile A/C Systems

2001-03-05
2001-01-0297
Aqua-ammonia absorption refrigeration cycle and R-134a Vapor jet-ejector refrigeration cycle for automotive air-conditioning were studied and analyzed. Thermally activated refrigeration cycles would utilize combustion engine exhaust gas or engine coolant to supply heat to the generator. For the absorption system, the thermodynamic cycle was analyzed and pressures, temperatures, concentrations, enthalpies, and mass flow rates at every point were computed based on input parameters simulate practical operating conditions of vehicles. Then, heat addition to the generator, heat removal rates from absorber, condenser, and rectifying unit, and total rejection heat transfer area were all calculated. For the jet-ejector system, the optimum ejector vapor mass ratio based on similar input parameters was found by solving diffuser's conservation equations of continuity, momentum, energy, and flow through primary ejector nozzle simultaneously.
Technical Paper

THE BUICK Air Poise SUSPENSION

1958-01-01
580046
THIS paper describes the springs, control system, and ride of the air suspension system on the 1958 Buick. The system is a semiclosed one, providing a variable-rate suspension, automatic leveling and trim control, and manual lift. The latter feature is a knob below the instrument panel which can be operated when necessary to cope with unusual clearance conditions. The car remains at the same height with loads of up to five passengers and 500 lb in the trunk. The authors describe the road-holding ability of a car with this suspension system as excellent.
Journal Article

Study of On-Board Ammonia (NH3) Generation for SCR Operation

2010-04-12
2010-01-1071
Mechanisms of NH₃ generation using LNT-like catalysts have been studied in a bench reactor over a wide range of temperatures, flow rates, reformer catalyst types and synthetic exhaust-gas compositions. The experiments showed that the on board production of sufficient quantities of ammonia on board for SCR operation appeared feasible, and the results identified the range of conditions for the efficient generation of ammonia. In addition, the effects of reformer catalysts using the water-gas-shift reaction as an in-situ source of the required hydrogen for the reactions are also illustrated. Computations of the NH₃ and NOx kinetics have also been carried out and are presented. Design and impregnation of the SCR catalyst in proximity to the ammonia source is the next logical step. A heated synthetic-exhaust gas flow bench was used for the experiments under carefully controlled simulated exhaust compositions.
Technical Paper

Statistical Energy Analysis of Airborne and Structure-Borne Automobile Interior Noise

1997-05-20
971970
This paper describes the application of Statistical Energy Analysis (SEA) and Experimental SEA (ESEA) to calculating the transmission of air-borne and structure-borne noise in a mid-sized sedan. SEA can be applied rapidly in the early stages of vehicle design where the degree of geometric detail is relatively low. It is well suited to the analysis of multiple paths of vibrational energy flow from multiple sources into the passenger compartment at mid to high frequencies. However, the application of SEA is made difficult by the geometry of the vehicle's subsystems and joints. Experience with current unibody vehicles leads to distinct modeling strategies for the various frequency ranges in which airborne or structure-borne noise predominates. The theory and application of ESEA to structure-borne noise is discussed. ESEA yields loss factors and input powers which are combined with an analytical SEA model to yield a single hybrid model.
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