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Technical Paper

Detailed Chemical and Physical Characterization of Ash Species in Diesel Exhaust Entering Aftertreatment Systems

2007-04-16
2007-01-0318
Irreversible plugging of diesel particulate filters caused by lubricant-derived metallic ash is the single most important factor responsible for long-term performance degradation and reduction in the service life of these filters. While a number of studies in the open literature have already demonstrated the benefits of diesel particulate traps and highlighted some of the difficulties associated with trap operation, many specific factors affecting trap performance and service life are still not well understood. The exact composition and nature of the exhaust entering the trap is one of the most important parameters affecting both short-term trap operation and long-term durability. In this study a fully instrumented Cummins ISB 300 six-cylinder, 5.9 liter, diesel engine was outfitted with a diesel particulate filter and subjected to a subset of the Euro III 13-mode stationary test cycle.
Technical Paper

Correlations among Ash-Related Oil Species in the Power Cylinder, Crankcase and the Exhaust Stream of a Heavy-Duty Diesel Engine

2007-07-23
2007-01-1965
In this study, changes in the composition of lubricant additives in the power cylinder oil are examined. Samples are extracted from a single cylinder heavy-duty diesel engine in two locations during engine operation; the crankcase and the top ring groove of the piston. Emissions of lubricant-derived ash-forming elements are lower than would be expected based on oil consumption and crankcase oil composition. This occurs partly because the inorganic additive compounds are less volatile than light-end hydrocarbons in the base oil. The tribology of the piston ring pack also affects the composition of the oil consumed in the power cylinder system. The elemental composition of oil extracted from the top ring groove is significantly different than the crankcase oil. Additive metals are concentrated in the top ring groove of the power cylinder. Detergent compounds (i.e. Ca and Mg) concentrate due to the volatility of the base oil. The metals associated with ZDDP (i.e.
Technical Paper

Characteristics and Effects of Ash Accumulation on Diesel Particulate Filter Performance: Rapidly Aged and Field Aged Results

2009-04-20
2009-01-1086
Ash, mostly from essential lubricant additives, affects diesel particulate filter (DPF) pressure-drop sensitivity and limits filter service life. It raises concern in the lubricant industry to properly specify new oils, and engine and aftertreatment system manufacturers have attempted to find ways to mitigate the problem. To address these issues, results of detailed measurements of ash characteristics in the DPF and their effects on filter performance are presented. In this study, a heavy-duty diesel engine was outfitted with a specially designed rapid lubricant degradation and aftertreatment ash loading system. Unlike previous studies, this system allows for the control of specific exhaust characteristics including ash emission rate, ash-to-particle ratio, ash composition, and exhaust temperature and flow rates independent of the engine operating condition.
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