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Φ-sensitivity is a fuel characteristic that has important benefits for the operation and control of low-temperature gasoline combustion (LTGC) engines. A fuel is φ-sensitive if its autoignition reactivity varies with the fuel/air equivalence ratio (φ). Thus, multiple-injection strategies can be used to create a φ-distribution that leads to several benefits. First, the φ-distribution causes a sequential autoignition that reduces the maximum heat release rate. This allows higher loads without knock and/or advanced combustion timing for higher efficiencies. Second, combustion phasing can be controlled by adjusting the fuel-injection strategy. Finally, experiments show that intermediate-temperature heat release (ITHR) increases with φ-sensitivity, increasing the allowable combustion retard and improving stability. A detailed mechanism was applied using CHEMKIN to understand the chemistry responsible for φ-sensitivity.

A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

The question of whether increasing the fuel economy of light-duty natural gas fueled vehicles can improve their economic competitiveness in the U.S. market, and help the US Department of Energy meet stated goals for such vehicles is explored. Key trade-offs concerning costs, exhaust emissions and other issues are presented for a number of possible advanced engine designs. Projections of fuel economy improvements for a wide range of lean-burn engine technologies have been developed. It appears that compression ignition technologies can give the best potential fuel economy, but are less competitive for light-duty vehicles due to high engine cost. Lean-burn spark ignition technologies are more applicable to light-duty vehicles due to lower overall cost. Meeting Ultra-Low Emission Vehicle standards with efficient lean-burn natural gas engines is a key challenge.

The National Renewable Energy Laboratory (NREL) collaborated with Millennium Cell and DaimlerChrysler to study heat and water management in a sodium borohydride (NaBH4) storage/processor used to supply hydrogen to a fuel cell in an automotive application. Knowledge of heat and water flows in this system is necessary to maximize the storage concentration of NaBH4, which increases vehicle range. This work helps evaluate the NaBH4 system's potential to meet the FreedomCAR program technical target of 6 wt% hydrogen for hydrogen storage technologies. This paper also illustrates the advantages of integrating the NaBH4 hydrogen processor with the fuel cell.

We investigate the mixing, penetration, and ignition characteristics of high-pressure n-dodecane sprays having a split injection schedule (0.5/0.5 dwell/0.5 ms) in a pre-burn combustion vessel at ambient temperatures of 750 K, 800 K and 900 K. High-speed imaging techniques provide a time-resolved measure of vapor penetration and the timing and progression of the first- and second-stage ignition events. Simultaneous single-shot planar laser-induced fluorescence (PLIF) imaging identifies the timing and location where formaldehyde (CH2O) is produced from first-stage ignition and consumed following second-stage ignition. At the 900-K condition, the second injection penetrates into high-temperature combustion products remaining in the near-nozzle region from the first injection. Consequently, the ignition delay for the second injection is shorter than that of the first injection (by a factor of two) and the second injection ignites at a more upstream location near the liquid length.

Shadowgraph/schlieren imaging techniques have often been used for flow visualization of reacting and non-reacting systems. In this paper we show that high-speed shadowgraph visualization in a high-pressure chamber can also be used to identify cool-flame and high-temperature combustion regions of diesel sprays, thereby providing insight into the time sequence of diesel ignition and combustion. When coupled to simultaneous high-speed Mie-scatter imaging, chemiluminescence imaging, pressure measurement, and spatially-integrated jet luminosity measurements by photodiode, the shadowgraph visualization provides further information about spray penetration after vaporization, spatial location of ignition and high-temperature combustion, and inactive combustion regions where problematic unburned hydrocarbons exist. Examples of the joint application of high-speed diagnostics include transient non-reacting and reacting injections, as well as multiple injections.

As connected and automated vehicle technologies emerge and proliferate, lower frequency vehicle trajectory data is becoming more widely available. In some cases, entire fleets are streaming position, speed, and telemetry at sample rates of less than 10 seconds. This presents opportunities to apply powertrain simulators such as the National Renewable Energy Laboratory’s Future Automotive Systems Technology Simulator to model how advanced powertrain technologies would perform in the real world. However, connected vehicle data tends to be available at lower temporal frequencies than the 1-10 Hz trajectories that have typically been used for powertrain simulation. Higher frequency data, typically used for simulation, is costly to collect and store and therefore is often limited in density and geography. This paper explores the suitability of lower frequency, high availability, connected vehicle data for detailed powertrain simulation.

Diesel engine combustion is simulated using Large Eddy Simulation (LES) with a multi-mode combustion (MMC) model. The MMC model is based on the combination of chemical kinetics, chemical equilibrium, and quasi-steady flamelet calculations in different local combustion regimes. The local combustion regime is identified by two combustion indices based on the local temperature and the extent of mixture homogeneity. The LES turbulence model uses the dynamic structure model (DSM) for sub-grid stresses. A new spray model in the LES context is used, and the Reynolds-averaged Navier-Stokes (RANS) based wall model is retained with the LES derived scales. These models are incorporated in the KIVA3V-ERC-Release 2 code for engine combustion simulations. A wide range of diesel engine operating conditions were chosen to validate the combustion model.

The objectives of this paper are to describe the research efforts in diesel engine combustion at Sandia National Laboratories' Combustion Research Facility and to provide recent experimental results. We have four diesel engine experiments supported by the Department of Energy, Office of Heavy Vehicle Technologies: a one-cylinder version of a Cummins heavy-duty engine, a diesel simulation facility, a one-cylinder Caterpillar engine to evaluate combustion of alternative fuels, and a homogeneous-charge, compression-ignition (HCCI) engine. Recent experimental results of diesel combustion research will be discussed and a description will be given of our HCCI experimental program and of our HCCI modeling work.

One way to increase the load range in an HCCI engine is to increase boost pressure. In this modeling study, we investigate the effect of increased boost pressure on the fuel chemistry in an HCCI engine. Computed results of HCCI combustion are compared to experimental results in a HCCI engine. We examine the influence of boost pressure using a number of different detailed chemical kinetic models - representing both pure compounds (methylcyclohexane, cyclohexane, iso-octane and n-heptane) and multi-component models (primary reference fuel model and gasoline surrogate fuel model). We examine how the model predictions are altered by increased fueling, as well as reaction rate variation, and the inclusion of residuals in our calculations. In this study, we probe the low temperature chemistry (LTC) region and examine the chemistry responsible for the low-temperature heat release (LTHR) for wide ranges of intake boost pressure.

To cope with regulatory standards, minimizing tailpipe emissions with rapid catalyst light-off during cold-start is critical. This requires catalyst-heating operation with increased exhaust enthalpy, typically by using late post injections for retarded combustion and, therefore, increased exhaust temperature. However, retardability of post injection(s) is constrained by acceptable pollutant emissions such as unburned hydrocarbon (UHC). This study provides further insight into the mechanisms that control the formation of UHC under catalyst-heating operation in a medium-duty diesel engine, and based on the understanding, develops combustion strategies to simultaneously improve exhaust enthalpy and reduce harmful emissions. Experiments were performed with a full boiling-range diesel fuel (cetane number of 45) using an optimized five-injections strategy (2 pilots, 1 main, and 2 posts) as baseline condition.

For better understanding of soot formation and oxidation processes applicable to diesel engines, the size, morphology, and nanostructure of soot particles directly sampled in a diesel spray flame generated in a constant-volume combustion chamber have been investigated using Transmission Electron Microscopy (TEM). For this soot diagnostics, the effects of the sampling processes, TEM observation methodology and image processing methods on the uncertainty in the results have not been extensively discussed, mainly due to the complexity of the analysis.

The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.

Exhaust gas recirculation (EGR) cooler fouling has emerged as an important issue in diesel engine development. Uncertainty about the level of impact that fuel chemistry may have upon this issue has resulted in a need to investigate the cooler fouling process with emerging non-traditional fuel sources to gage their impact on the process. This study reports experiments using both ultra-low sulfur diesel (ULSD) and 20% biodiesel (B20) at elevated exhaust hydrocarbon conditions to investigate the EGR cooler fouling process. The results show that there is little difference between the degradation in cooler effectiveness for ULSD and B20 at identical conditions. At lower coolant temperatures, B20 exhibits elevated organic fractions in the deposits compared with ULSD, but this does not appear to lead to incremental performance degradation under the conditions studied.

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

Laser excitation wavelengths for two-line planar laser-induced fluorescence (PLIF) of 3-pentanone have been optimized for simultaneous imaging of temperature and composition under engine-relevant conditions. Validation of the diagnostic was performed in a motored optical IC engine seeded homogeneously with 3-pentanone. PLIF measurements of the uniform mixture during the compression stroke were used to measure the average temperature and to access the random uncertainty in the measurements. To determine the accuracy of the temperature measurements, experimental average temperatures were compared to values computed assuming isentropic compression and to the output of a tuned 1-D engine simulation. The comparison indicated that the absolute accuracy of the temperature measurements is better than ±5%. Probability density functions (PDFs) calculated from the single-shot images were used to estimate the precision of the measurements.

Two-scale command shaping is a recently proposed feedforward control method aimed at mitigating undesirable vibrations in nonlinear systems. The TSCS strategy uses a scale separation to cancel oscillations arising from nonlinear behavior of the system, and command shaping of the remaining linear problem. One promising application of TSCS is in reducing engine restart and shutdown vibrations found in conventional and in hybrid electric vehicle powertrains equipped with start-stop features. The efficacy of the TSCS during internal combustion engine restart has been demonstrated theoretically and experimentally in the authors’ prior works. The present article presents simulation results and describes the verified experimental apparatus used to study TSCS as applied to the ICE shutdown case. The apparatus represents a typical HEV powertrain and consists of a 1.03 L three-cylinder diesel ICE coupled to a permanent magnet alternating current electric machine through a spur gear coupling.

In-cylinder concentrations of nitric oxide (NO) in a diesel engine were studied using a laser-induced fluorescence (LIF) technique that employs two-photon excitation. Two-photon NO LIF images were acquired during the expansion and exhaust portions of the engine cycle providing useful NO fluorescence signal levels from 60° after top dead center through the end of the exhaust stroke. The engine was fueled with the oxygenated compound diethylene glycol diethyl ether to minimize soot within the combustion chamber. Results of the two-photon NO LIF technique from the exhaust portion of the cycle were compared with chemiluminescence NO exhaust-gas measurements over a range of engine loads from 1.4 to 16 bar gross indicated mean effective pressure. The overall trend of the two-photon NO LIF signal showed good qualitative agreement with the NO exhaust-gas measurements.

Despite ongoing research efforts directed at reducing engine-out emissions, diesel engines are known to be one of the largest sources of atmospheric particulate matter (i.e., soot). Quantitative measurements are of primary importance to address soot production during the combustion process in the cylinder of diesel engines. This study presents the capabilities of an extinction-based diagnostic developed to quantitatively measure the soot volume fraction in n-dodecane sprays injected in a high-pressure, high-temperature vessel. Coupled with high-speed imaging, the technique yields time-resolved measurements of the soot field by relying on a diffused back-illumination scheme to improve extinction quantification in the midst of intense beam steering. The experiments performed in this work used two wavelengths, which, when combined with the Rayleigh-Debye-Gans theory, provide information about the optical and physical properties of soot.

The friction and wear characteristics of three commercially-available, electrolytic coatings for aluminum engine cylinder bores were compared to those of cast iron liners. A Ni/SiC electrocomposite, a hard anodized treatment, and a Plasma Electrolytic Oxidation (PEO) coating were investigated. ASTM standard test method G133-95, non-firing test method, for linearly reciprocating sliding wear was modified to use segments of piston rings and cylinder liners. Tests were conducted using Mr. Goodwrench™ 5W30 as a lubricant at room temperature. The normal force was 150N, the reciprocating frequency was 15Hz, the stroke length was 8mm, and the test duration was 60 minutes. Kinetic friction coefficients ranged from 0.1 to 0.22, typical of boundary lubrication. The Ni/SiC and cast iron samples exhibited the lowest friction. The wear resistance of the Ni/SiC coating was superior to that of cast iron.