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Regulated and unregulated exhaust emissions (individual hydrocarbons, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), and nitro-polynuclear aromatic hydrocarbons (NPAH)) were characterized for the following alternate diesel combustion modes: premixed charge compression ignition (PCCI), and low-temperature combustion (LTC). PCCI and LTC were studied on a PSA light-duty high-speed diesel engine. Engine-out emissions of carbonyl compounds were significantly increased for all LTC modes and for PCCI-Lean conditions as compared to diesel operation; however, PCCI-Rich produced much lower carbonyl emissions than diesel operations. For PAH compounds, emissions were found to be substantially increased over baseline diesel operation for LTC-Lean, LTC-Rich, and PCCI-Lean conditions. PCCI-Rich operation, however, gave PAH emission rates comparable to baseline diesel operation.

Results from work focusing on the development of an ultra low emissions, high efficiency, natural gas-fueled heavy- duty engine are discussed in this paper. The engine under development was based on a John Deere 8.1L engine; this engine was significantly modified from its production configuration during the course of an engine optimization program funded by the National Renewable Energy Laboratory. Previous steady-state testing indicated that the modified engine would provide simultaneous reductions in nonmethane hydrocarbon emissions and fuel consumption while maintaining equivalent or lower NOx levels. Federal Test Procedure transient tests confirmed these expectations. Very low NOx emissions, averaging 1.0 g/bhp-hr over hot-start cycles, were attained; at these conditions, reductions in engine-out nonmethane hydro-carbons emissions (NMHC) were approximately 30 percent, and fuel consumption over the cycle was also reduced relative to the baseline.

The use of compressed natural gas as an alternative to conventional fuels has received a great deal of attention as a strategy for reducing air pollution from motor vehicles. In many cases, regulatory action has been taken to displace diesel fuel with natural gas in truck and bus applications. Emissions results of heavy-duty transient FTP testing of two Cummins L10-240G natural gas engines are presented. Regulated emissions of non-methane hydrocarbons, total hydrocarbons, CO, NOx, and particulate were characterized, along with emissions of formaldehyde. The effects of air/fuel ratio adjustments on these emissions were explored, as well as the effectiveness of catalytic aftertreatment in reducing exhaust emissions. Compared to typical heavy-duty diesel engine emissions, CNG-fueled engines using exhaust aftertreatment have great potential for meeting future exhaust emission standards, although in-use durability is unproven.

Two large, heavy light-duty gasoline vehicles (2004 model year Ford F-150 with a 5.4 liter V8 and GMC Yukon Denali with a 6.0 liter V8) were baselined for emission performance over the FTP driving cycle in their stock configurations. Advanced emission systems were designed for both vehicles employing advanced three-way catalysts, high cell density ceramic substrates, and advanced exhaust system components. These advanced emission systems were integrated on the test vehicles and characterized for low mileage emission performance on the FTP cycle using the vehicle's stock engine calibration and, in the case of the Denali, after modifying the vehicle's stock engine calibration for improved cold-start and hot-start emission performance.

The spark ignition (SI) engine has been known to exhibit several different abnormal combustion phenomena, such as knock or pre-ignition, which have been addressed with improved engine design or control schemes. However, in highly boosted SI engines, Low-Speed Pre-Ignition (LSPI), a pre-ignition event typically followed by heavy knock, has developed into a topic of major interest due to its potential for engine damage. Previous experiments associated increases in hydrocarbon emissions with the blowdown event of an LSPI cycle [1]. Also, the same experiments showed that there was a dependency of the LSPI activity on fuel and/or lubricant compositions [1]. Based on these findings it was hypothesized that accumulated hydrocarbons play a role in LSPI and are consumed during LSPI events. A potential source for accumulated HC is the top land piston crevice.

Tests were conducted on a variety of commercially available spark plugs to determine the influence of igniter design on initial kernel formation and overall performance. Flame kernel formation was investigated using high-speed schlieren visualization. The flame growth rate was quantified using the area of the burned gas region. The results showed that kernel growth rate was heavily influenced by electrode geometry and configuration. The igniters were also tested in a bomb calorimeter to determine the levels of supplied and delivered energy. The typical ratio of supplied to delivered energy was 20% and igniters with a higher internal resistance delivered more energy and had faster kernel formation rates. The exception was plugs with large amounts of conductive mass near the electrodes, which had very slow kernel formation rates despite relatively high delivered energy levels.

The use of biodiesel fuels derived from vegetable oils or animal fats as a substitute for conventional petroleum fuel in diesel engines has received increased attention. This interest is based on a number of properties of biodiesel including the fact that it is produced from a renewable resource, its biodegradability, and its potential beneficial effects on exhaust emissions. As part of Tier 1 compliance requirements for EPA's Fuel Registration Program, a detailed chemical characterization of the transient exhaust emissions from three modern diesel engines was performed, both with and without an oxidation catalyst. This characterization included several forms of hydrocarbon speciation, as well as measurement of aldehydes, ketones, and alcohols. In addition, both particle-phase and semivolatile-phase PAH and nitro-PAH compounds were measured. Unregulated emissions were characterized with neat biodiesel and with a blend of biodiesel and conventional diesel fuel.

This paper describes a research program on exhaust emissions from snowmobile engines, including both emissions characterization and estimation of national emissions impact. Tests were conducted on three popular 2-stroke twins and on one rotary (Wankel) engine. Emissions that were measured included total hydrocarbons, (paraffinic) hydrocarbons by NDIR, CO, CO2, NO (by two methods), NOx, O2, aldehydes, light hydrocarbons, particulate, and smoke. Emissions of SOx were estimated on the basis of fuel consumed, and evaporative hydrocarbons were projected to be negligible for actual snowmobile operation. During emissions tests, intake air temperature was controlled to approximately -7°C (20°F), and room air at approximately 24°C (75°F) was used for engine cooling. Based on test results and the best snowmobile population and usage data available, impact of snowmobile emissions on a national scale was computed to be minimal.

In an attempt to characterize emissions from small air-cooled utility engines, five gasoline-fueled models were operated over a variety of speeds and loads, and important exhaust constituents were measured. These emissions included hydrocarbons, CO, CO2, NO, O2, aldehydes, light hydrocarbons, particulates, and smoke. Emissions of SOx were estimated on the basis of the fuel consumed; evaporative losses of hydrocarbons were also estimated. The impact of small engine emissions was calculated on the basis of the test results and information on national engine populations and usage. From these data, it appears that the 50 million or more small engines currently being used account for only a small part of pollutants from all sources.

The optical spark plug probe and ionization head gasket probe developed at Sandia Laboratories were applied to one cylinder of a production multicylinder automotive gasoline engine. The purpose of this application is to eventually study combustion phenomena leading to high emissions under cold start and cold idle conditions. As a first step in studying cold start combustion and emissions issues, diagnostic instrumentation was simultaneously applied to a production engine under steady state idle, road load and an intermediate load-speed condition. The preliminary application of such instrumentation is the subject of the present paper. The spark plug probe was redesigned for ease of use in production engines and to provide a more robust design. The two probes were geometrically oriented to obtain radial line-up between the optical windows and ionization probes. Data were taken simultaneously with both probes at the three load-speed conditions mentioned above.

Gasoline direct injection (GDI) has changed the exhaust composition in comparison with the older port fuel injection (PFI) systems. More recently, light-duty vehicle engine manufactures have combined these two technologies to take advantage of the knock benefits and fuel economy of GDI with the low particulate emission of PFI. These dual injection strategy engines have made a change in the combustion emission composition produced by these engines. Understanding the impact of these changes is essential for automotive companies and aftertreatment developers. A novel sampling system was designed to sample the exhaust generated by a dual injection strategy gasoline vehicle using the United States Federal Test Procedure (FTP). This sampling system was capable of measuring the regulated emissions as well as collecting the entire exhaust from the vehicle for measuring unregulated emissions.

Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent).

Improved designs of extruded metal electrically heated catalysts (EHC) in combination with a traditional converter achieved the California ultra-low emission vehicle (ULEV) standard utilizing 50% less electrical energy than previous prototypes. This energy reduction is largely achieved by reducing the mass of the EHC. In addition to energy reduction, the battery voltage is reduced from 24 volts to 12 volts, and the power is reduced from 12 kilowatts to 3 kilowatts. Also discussed is the impact EHC mass, EHC catalytic activity, and no EHC preheating has on non-methane hydrocarbon emissions, energy requirements, and power requirements.

An emissions reduction strategy was developed and demonstrated to significantly reduce cold-start hydrocarbon (HC) and CO emissions from a spark ignition (SI), gasoline-fueled engine. This strategy involved cold-starting the engine with an ultra-fuel rich calibration, while metering near-stoichiometric fractions of air directly into the exhaust ports. Using this approach, exhaust constituents spontaneously ignited at the exhaust ports and burned into the exhaust manifold and exhaust pipe leading to the catalytic converter. The resulting exotherm accelerated catalyst heating and significantly decreased light-off time following a cold-start on the FTP-75 with a Ford Escort equipped with a 1.9L engine. Mass emissions measurements acquired during the first 70 seconds of the FTP-75 revealed total-HC and CO reductions of 68 and 50 percent, respectively, when compared to baseline measurements.

This paper describes experiments conducted to determine Federal Test Procedure (FTP) exhaust emissions, ozone-forming potentials, specific reactivities, and reactivity adjustment factors for several butane/propane alternative fuel blends run on a light-duty EHC-equipped gasoline vehicle converted to operate on liquefied petroleum gas (LPG). Duplicate emission tests were conducted on the light-duty vehicle at each test condition using appropriate EPA FTP test protocol. Hydrocarbon speciation was utilized to determine reactivity-adjusted non-methane organic gas (NMOG) emissions for one test on each fuel.

This paper describes experiments conducted to determine the ozone-forming potentials, specific reactivities, and reactivity adjustment factors for various heavy-duty engines operating on “industry average” (RF-A) gasoline, California Phase 2 gasoline, compressed natural gas (CNG), liquefied petroleum gas (LPG), and diesel fuel. Each engine/fuel combination was tested in triplicate using the EPA heavy-duty transient cold- and hot-start test protocol. Hydrocarbon speciation was conducted for all tests to allow for the determination of ozone-forming potentials, using California Air Resources Board maximum incremental reactivity factors as well as determination of the Clean Air Act “toxic” emissions.

Road tests of class 8 tractor trailers were conducted by the US Environmental Protection Agency (EPA) on a new and retreaded tires of varying rolling resistance in order to provide estimates of the quantitative relation between rolling resistance and fuel consumption. Reductions in fuel consumption were measured using the SAE J1231 (reaffirmation of 1986) test method. Vehicle rolling resistance was calculated as a load-weighted average of the rolling resistance (as measured by ISO28580) of the tires in each axle position. Both new and retreaded tires were tested in different combinations to obtain a range of vehicle coefficient of rolling resistance from a baseline of 7.7 kg/ton to 5.3 kg/ton. Reductions in fuel consumption displayed a strong linear relationship with coefficient of rolling resistance, with a maximum reduction of fuel consumption of 10 percent relative to the baseline.

The engine intake process governs many aspects of the flow within the cylinder. The inlet valve is the minimum area, so gas velocities at the valve are the highest velocities seen. Geometric configuration of the inlet ports and valves, and the opening schedule create organized large scale motions in the cylinder known as swirl and tumble. Good charge motion within the cylinder will produce high turbulence levels at the end of the compression stroke. As the turbulence resulting from the conversion energy of the inlet jet decays fast, the strategy is to encapsulate some of the inlet jet in the organized motions. In this work the baseline port of a 2.0 L gasoline engine was modified by inserting a tumble plate. The work was done in support of an experimental study for which a new single-cylinder research engine was set up to allow combustion system parameters to be varied in steps over an extensive range. Tumble flow was one such parameter.

Since the conception of the internal combustion engine, smoky and ill-smelling exhaust was prevalent. Over the last century, significant improvements have been made in improving combustion and in treating the exhaust to reduce these effects. One group of compounds typically found in exhaust, polycyclic aromatic hydrocarbons (PAH), usually occurs at very low concentrations in diesel engine exhaust. Some of these compounds are considered carcinogenic, and most are considered hazardous air pollutants (HAP). Many methods have been developed for sampling, handling, and analyzing PAH. For this study, an improved method for dilute exhaust sampling was selected for sampling the PAH in diesel engine exhaust. This sampling method was used during transient engine operation both with and without aftertreatment to show the effect of aftertreatment.

Fumigation, inline mixing, chemically stabilized emulsions and cetane improvers were evaluated as a means of using ethanol in diesel engines. Two turbocharged six-cylinder engines of identical bore and stroke were used, differing in combustion chamber type. Three alcohol proofs were evaluated: 200, 190, and 160. Alcohol was added at the following concentrations: 10, 25, and 50% except in the case of the cetane-improved alcohol. In the latter case a commercial ignition improver for diesel fuel, DII-3, was added to neat alcohol in the proportions of 10, 15, and 20%. Generally, the emissions of CO, total hydrocarbons, and oxides of nitrogen reflected the trends observed in the thermal efficiencies. At light loads, CO and HC emissions were higher than baseline, decreasing to near baseline levels at heavy loads accompanied with higher NOx.