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This paper summarizes the validation testing of the Horiba Instruments OBS-2200 gaseous portable emissions measurement system (PEMS) for in-use compliance testing per Title 40 of the Code of Federal Regulations (CFR) Part 1065.920 (Section 1065.920). The qualification process included analyzer verifications as well as engine testing on a model-year 2007 heavy-duty diesel engine produced by Volvo Powertrain. The measurements of brake-specific emissions with the OBS-2200 were compared to those of a CFR Part 1065-compliant CVS test cell over a series of not-to-exceed (NTE) events. The OBS-2200 passed all linearity verifications and analyzer checks required of PEMS. Engine test validation was achieved for all three regulated gaseous emissions (CO, NMHC, and NOX) per 40 CFR Part 1065.920(b)(5)(i), which requires a minimum of 91 percent of the measurement allowance adjusted deltas to be less than or equal to zero.

Vegetable oils are candidates for alternative fuels in diesel engines. These oils, such as soybean, sunflower, rapeseed, cottonseed, and peanut, consist of various triglycerides. The chemistry of the degradation of vegetable oils when used as alternate diesel fuels thus corresponds to that of triglycerides. To study the chemistry occurring during the precombustion phase of a vegetable oil injected into a diesel engine, a reactor simulating a diesel engine was constructed. Pure triglycerides were injected into the reactor in order to determine differences in the precombustion behavior of the various triglycerides. The reactor allowed motion pictures to be prepared of the injection event as the important reaction parameters, such as pressure, temperature, and atmosphere were varied. Furthermore, samples of the degradation products of precombusted triglycerides were collected and analyzed (gas chromatography / mass spectrometry).

A program to demonstrate the performance of advanced emission control systems in light of the California LEV II light-duty vehicle standards and the EPA's consideration of Tier II emission standards was conducted. Two passenger cars and one light-duty pick-up truck were selected for testing, modification, and emission system performance tuning. All vehicles were 1997 Federal Tier I compliant. The advanced emission control technologies evaluated in this program included advanced three-way catalysts, high cell density substrates, and advanced thermally insulated exhaust components. Using these engine-aged advanced emission control technologies and modified stock engine control strategies (control modifications were made using an ERIC computer intercept/control system), each of the three test vehicles demonstrated FTP emission levels below the proposed California LEV II 193,000 km (120,000 mile) ULEV levels.

This paper describes experiments conducted to determine the regulated emissions, ozone-forming potentials, specific reactivities, and reactivity adjustment factors for eight butane and propane alternative fuel blends run on a light-duty vehicle, emission certified to be a California transitional low emission vehicle (TLEV) and converted to operate on liquefied petroleum gas (LPG). Duplicate EPA FTP emission tests were conducted with each fuel. Hydrocarbon speciation was utilized to determine reactivity-adjusted non-methane organic gases (NMOG) emissions for one test on each fuel. Results showed that all eight fuels could allow the converted vehicle to pass California ultra-low emission vehicle (ULEV) NMOG and oxides of nitrogen (NOx) standards. Six of the eight fuels could allow the vehicle to pass ULEV carbon monoxide (CO) standards. BUTANE has been an important gasoline blending component for many years.

The use of alcohol as a supplemental fuel for a medium-speed diesel engine was investigated using a two-cylinder, two-stroke test engine. Both stabilized and unstabilized emulsions of methanol-in-diesel fuel and ethanol-in-diesel fuel were tested. Also, anhydrous ethanol/diesel fuel solutions were evaluated. Maximum alcohol content of the emulsions and solutions was limited by engine knocking due to a reduction in fuel cetane number. Engine power and thermal efficiency were slightly below baseline diesel fuel levels in the high and mid-speed ranges, but were somewhat improved at low speeds during tests of the unstabilized emulsions and the ethanol solutions. However, thermal efficiency of the stabilized emulsions fell below baseline levels at virtually all conditions.

Regulated and unregulated exhaust emissions (individual hydrocarbons, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), and nitro-polynuclear aromatic hydrocarbons (NPAH)) were characterized for the following alternate diesel combustion modes: premixed charge compression ignition (PCCI), and low-temperature combustion (LTC). PCCI and LTC were studied on a PSA light-duty high-speed diesel engine. Engine-out emissions of carbonyl compounds were significantly increased for all LTC modes and for PCCI-Lean conditions as compared to diesel operation; however, PCCI-Rich produced much lower carbonyl emissions than diesel operations. For PAH compounds, emissions were found to be substantially increased over baseline diesel operation for LTC-Lean, LTC-Rich, and PCCI-Lean conditions. PCCI-Rich operation, however, gave PAH emission rates comparable to baseline diesel operation.

Results from work focusing on the development of an ultra low emissions, high efficiency, natural gas-fueled heavy- duty engine are discussed in this paper. The engine under development was based on a John Deere 8.1L engine; this engine was significantly modified from its production configuration during the course of an engine optimization program funded by the National Renewable Energy Laboratory. Previous steady-state testing indicated that the modified engine would provide simultaneous reductions in nonmethane hydrocarbon emissions and fuel consumption while maintaining equivalent or lower NOx levels. Federal Test Procedure transient tests confirmed these expectations. Very low NOx emissions, averaging 1.0 g/bhp-hr over hot-start cycles, were attained; at these conditions, reductions in engine-out nonmethane hydro-carbons emissions (NMHC) were approximately 30 percent, and fuel consumption over the cycle was also reduced relative to the baseline.

The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.

Comparative emission measurements were made in two dynamometer-based diesel engines using protocol specified by the U.S. Environmental Protection Agency (EPA) and the California Air Resources Board (CARB). A single JP-8 fuel with a sulfur level of 0.06 weight percent (wt%) was adjusted to sulfur levels of 0.11 and 0.26 wt%. The emission characteristics of the three fuels were compared to the 1994 EPA certification low-sulfur diesel fuel (sulfur level equal to 0.035 wt%) in the Detroit Diesel Corporation (DDC) 1991 prototype Series 60 diesel engine and in the General Motors (GM) 6.2L diesel engine. Comparisons were made using the hot-start transient portion of the heavy-duty diesel engine Federal Test Procedure. Results from the Army study show that the gaseous emissions for the DDC Series 60 engine using kerosene-based JP-8 fuel are equivalent to values obtained with the 0.035 wt% sulfur EPA certification diesel fuel.

A project was conducted by Southwest Research Institute on behalf of the California Air Resources Board and the South Coast Air Quality Management District to demonstrate the technical feasibility of utilizing closed-loop three-way catalyst technology in off-road equipment applications. Five representative engines were selected, and baseline emission-tested using both gasoline and LPG. Emission reduction systems, employing three-way catalyst technology with electronic fuel control, were designed and installed on two of the engines. The engines were then installed in a fork lift and a pump system, and limited durability testing was performed. Results showed that low emission levels, easily meeting CARB's newly adopted large spark-ignited engine emission standards, could be achieved.

A new approach to reclaiming the spoil areas produced by area-type mining operations has been developed. This system uses a machine known as a winch-dozer, consisting of a pair of large back-to-back buckets which are drawn by cable across spoil piles, moving back and forth between a “tailblock” anchor and a “drawworks” winch unit developed as an attachment to a large crawler tractor. The system is expected to reduce the cost of reclamation leveling by 40-50%. The system permits more effective power utilization due to the blade system's light weight, induces caving of spoil banks, and permits moving spoil in both directions of blade travel.

Radioactive tracer technology (RATT™) is an important tool for measuring real-time wear in operating engines and other mechanical systems. The use of this technology provides important wear information that is not available by other, more conventional wear measurement methods. The technology has advanced to the point where several components can be interrogated simultaneously, and new methods have extended the method to materials that are normally not amenable to radioactive tracer evaluation. In addition, sensitivity has increased so that the onset of wear can be detected long before practical with non-tracer methods. This improves the ability to measure and determine cause and effect relationships, thus providing a better understanding of wear responses to specific operating conditions and to changes in operating conditions. This paper reviews the radioactive tracer process and recent improvements that have extended its reach in both automotive and non-automotive applications.

The Texas Department of Transportation (TxDOT) began using an emulsified diesel fuel in July 2002. They initiated a simultaneous study of the effectiveness of this fuel in comparison to 2D on-road diesel fuel, which they use in both their on-road and off-road equipment. The study also incorporated analyses for the fleet operated by the Associated General Contractors (AGC) in the Houston area. Some members of AGC use 2D off-road diesel fuel in their equipment. The study included comparisons of fuel economy and emissions for the emulsified fuel relative to the conventional diesel fuels. Cycles that are known to be representative of the typical operations for TxDOT and AGC equipment were required for use in this study. Four test cycles were developed from data logged on equipment during normal service: 1) the TxDOT Telescoping Boom Excavator Cycle, 2) the AGC Wheeled Loader Cycle, 3) the TxDOT Single-Axle Dump Truck Cycle, and 4) the TxDOT Tandem-Axle Dump Truck Cycle.

The objective was to demonstrate the feasibility of operating a natural gas two-stroke engine using glow plug ignition with very lean mixtures. Based on the results obtained, the term SCGI (stratified charge glow plug ignition) was coined to describe the engine. An JLO two-stroke diesel engine was converted first to a natural gas fueled spark-ignited engine for the baseline tests, and then to an SCGI engine. The SCGI engine used a gas operated valve in the cylinder head to admit the natural gas fuel, and a glow plug was used as a means to initiate the combustion. The engine was successfully run, but was found to be sensitive to various conditions such as the glow plug temperature. The engine would run very lean, to an overall equivalence ratio of 0.33, offering the potential of good fuel economy and low NOx emissions.

A dilute spark-ignited engine concept has been developed as a potential low cost competitor to diesel engines by Southwest Research Institute (SwRI), with a goal of diesel-like efficiency and torque for light- and medium-duty applications and low-cost aftertreatment. The targeted aftertreatment method is a traditional three-way catalyst, which offers both an efficiency and cost advantage over typical diesel aftertreatment systems. High levels of exhaust gas recirculation (EGR) have been realized using advanced ignition systems and improved combustion, with significant improvements in emissions, efficiency, and torque resulting from using high levels of EGR. The primary motivation for this work was to understand the impact high levels of EGR would have on particulate matter (PM) formation in a port fuel injected (PFI) engine. While there are no proposed regulations for PFI engine PM levels, the potential exists for future regulations, both on a size and mass basis.

Two large, heavy light-duty gasoline vehicles (2004 model year Ford F-150 with a 5.4 liter V8 and GMC Yukon Denali with a 6.0 liter V8) were baselined for emission performance over the FTP driving cycle in their stock configurations. Advanced emission systems were designed for both vehicles employing advanced three-way catalysts, high cell density ceramic substrates, and advanced exhaust system components. These advanced emission systems were integrated on the test vehicles and characterized for low mileage emission performance on the FTP cycle using the vehicle's stock engine calibration and, in the case of the Denali, after modifying the vehicle's stock engine calibration for improved cold-start and hot-start emission performance.

SwRI has developed a new technology concept involving the use of high EGR rates coupled with a high-energy ignition system in a gasoline engine to improve fuel economy and emissions. Based on a single-cylinder study [1], this study extends the concept of a high compression ratio gasoline engine with EGR rates > 30% and a high-energy ignition system to a multi-cylinder engine. A 2000 MY Isuzu Duramax 6.6 L 8-cylinder engine was converted to run on gasoline with a diesel pilot ignition system. The engine was run at two compression ratios, 17.5:1 and 12.5:1 and with two different EGR systems - a low-pressure loop and a high pressure loop. A high cetane number (CN) diesel fuel (CN=76) was used as the ignition source and two different octane number (ON) gasolines were investigated - a pump grade 91 ON ((R+M)/2) and a 103 ON ((R+M)/2) racing fuel.

Extensive efforts are being made to improve emissions from 2-stroke diesel engines. These improvements are primarily directed towards older model year engines with relatively high emissions compared with modern diesel engines. While most researchers focus their attention on engine design changes that promise substantial emission improvements, this work dealt with the turbocharger characteristics, especially as related to using internal coatings on both the compressor and turbine housings. Two identical turbochargers were tested on a Detroit Diesel 6V-92TA engine. One of the two turbochargers was left in its production configuration while the other was coated with a clearance control coating on the inside of the compressor and turbine housings. This coating led to a significant reduction in the tip clearance of both the compressor and turbine wheels.

A combined, experimental and numerical program is presented. This work summarizes an internal research effort conducted at Southwest Research Institute. Meeting new, stringent emissions regulations for diesel engines requires a way to reduce NOx and soot emissions. Most emissions reduction strategies reduce one pollutant while increasing the other. Water injection is one of the few promising emissions reduction techniques with the potential to simultaneously reduce soot and NOx in diesel engines. While it is widely accepted that water reduces NOx via a thermal effect, the mechanisms behind the reduction of soot are not well understood. The water could reduce the soot via physical, thermal, or chemical effects. To aid in developing water injection strategies, this project's goal was to determine how water enters the soot formation chemistry.

Tests were conducted on a variety of commercially available spark plugs to determine the influence of igniter design on initial kernel formation and overall performance. Flame kernel formation was investigated using high-speed schlieren visualization. The flame growth rate was quantified using the area of the burned gas region. The results showed that kernel growth rate was heavily influenced by electrode geometry and configuration. The igniters were also tested in a bomb calorimeter to determine the levels of supplied and delivered energy. The typical ratio of supplied to delivered energy was 20% and igniters with a higher internal resistance delivered more energy and had faster kernel formation rates. The exception was plugs with large amounts of conductive mass near the electrodes, which had very slow kernel formation rates despite relatively high delivered energy levels.