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The objectives of this project were to investigate the corrosivity of condensate in a stoichiometric spark-ignited (SI) engine when running exhaust gas recirculation (EGR) and to determine the effects of sulfur-in-fuel on corrosion. A 2.0 L turbocharged direct-injected SI engine was operated with low-pressure EGR for this study. The engine was instrumented for visual, thermodynamic, and electrochemical analyses to determine the potential for corrosion at locations where condensation was deemed likely in a low-pressure loop EGR (LPL-EGR) engine. The electrochemical analysis was performed using multi-electrode array (MEA) corrosion probes. Condensate was also collected and analyzed. These analyses were performed downstream of both the charge air cooler (CAC) and the EGR cooler. It was found that while conditions existed for sulfuric acid to form with high-sulfur fuel, no sulfuric acid was detected by any of the measurement methods.

The impact of additive and oil chemistry on low speed pre-ignition (LSPI) was evaluated. An additive metals matrix varied the levels of zinc dialkyldithiophosphate (ZDDP), calcium sulfonate, and molybdenum within the range of commercially available engine lubricants. A separate test matrix varied the detergent chemistry (calcium vs. magnesium), lubricant volatility, and base stock chemistry. All lubricants were evaluated on a LSPI test cycle developed by Southwest Research Institute within its Pre-Ignition Prevention Program (P3) using a GM LHU 2.0 L turbocharged GDI engine. It was observed that increasing the concentration of calcium leads to an increase in the LSPI rate. At low calcium levels, near-zero LSPI rates were observed. The addition of zinc and molybdenum additives had a negative effect on the LSPI rate; however, this was only seen at higher calcium concentrations.

Because of the thermodynamic relationship of pressure, temperature and volume for processes which occur in an internal-combustion engine (ICE), and their relationship to ideal efficiency and efficiency-limiting phenomena e.g. knock in spark-ignition engines, changing the thermo-chemical properties of the in-cylinder charge should be considered as an increment in the development of the ICE engine for future efficiency improvements. Exhaust gas recirculation (EGR) in spark-ignited gasoline engines is one increment that has been made to alter the in-cylinder charge. EGR gives proven thermal efficiency benefits for SI engines which improve vehicle fuel economy, as demonstrated through literature and production applications. The thermal efficiency benefit of EGR is due to lower in-cylinder temperatures, reduced heat transfer and reduced pumping losses. The next major increment could be modifying the constituents of the EGR stream, potentially through the means of a membrane.

Diesel fuels derived from different types of crude oil can exhibit different chemistry while still meeting market requirements and specifications. Oil sands derived fuels typically contain a larger proportion of cycloparaffinic compounds, which result from the cracking and hydrotreating of bitumens in the crude. In the current study, 17 refinery streams consisting of finished fuels and process streams were obtained from a refinery using 100% oil sands derived crude oil. All samples except one met the ULSD standard of 15 ppm sulfur. The samples were characterized for properties and chemistry and run in a simple premixed HCCI engine using intake heating for combustion phasing control. Results indicate that the streams could be equally well characterized by chemistry or properties, and some simple correlations are presented. Cetane number was found to relate mainly to mono-aromatic content and the cycloparaffins did not appear to possess any unique diesel related chemical effects.

The performance of an organic Rankine cycle (ORC) used to recover waste heat from the exhaust of a diesel and a spark ignition engine for electric power generation was modeled. The design elements of the ORC incorporated into the thermodynamic model were based on an experimental study performed at Oak Ridge National Laboratory in which a regenerative organic Rankine cycle system was designed, assembled and integrated into the exhaust of a 1.9 liter 4-cylinder automotive turbo-diesel. This engine was operated at a single fixed-load point at which Rankine cycle state point temperatures as well as the electrical power output of an electric generator coupled to a turbine that expanded R245fa refrigerant were measured. These data were used for model calibration.

A number of studies have identified a tendency for exhaust gas recirculation (EGR) coolers to foul to a steady-state level and subsequently not degrade further. One possible explanation for this behavior is that the shear force imposed by the gas velocity increases as the deposit thickens. If the shear force reaches a critical level, it achieves a removal of the deposit material that can balance the rate of deposition of new material, creating a stabilized condition. This study reports efforts to observe removal of deposit material in-situ during fouling studies as well as an ex-situ removal through the use of controlled air flows. The critical gas velocity and shear stress necessary to cause removal of deposit material is identified and reported. In-situ observations failed to show convincing evidence of a removal of deposit material. The results show that removal of deposit material requires a relatively high velocity of 40 m/s or higher to cause removal.

To better understand real fuel effects on LSPI, a matrix was developed to vary certain chemical and physical properties of gasoline. The primary focus of the study was the impact of paraffinic, olefinic, and aromatic components upon LSPI. Secondary goals of this testing were to study the impact of ethanol content and fuel volatility as defined by the T90 temperature. The LSPI rate increased with ethanol content but was insensitive to olefin content. Additionally, increased aromatic content uniformly led to increased LSPI rates. For all blends, lower T90 temperatures resulted in decreased LSPI activity. The correlation between fuel octane (as RON or MON) suggests that octane itself does not play a role; however, the sensitivity of the fuel (RON-MON) does have some correlation with LSPI. Finally, the results of this analysis show that there is no correlation between the laminar flame speed of a fuel and the LSPI rate.

The thermal efficiency benefits of low-pressure (LP) exhaust gas recirculation (EGR) in spark-ignition engine combustion are well known. One of the greatest barriers facing adoption of LP-EGR for high power-density applications is the challenge of boosting. Variable nozzle turbines (VNTs) have recently been developed for gasoline applications operating at high exhaust gas temperatures (EGTs). The use of a single VNT as a boost device may provide a lower-cost option compared to two-stage boosting systems or 48 V electronic boost devices for some LP-EGR applications. A predictive model was created based on engine testing results from a 1.6 L turbocharged gasoline direct injection (GDI) engine [1]. The model was tuned so that it predicted burn-rates and end-gas knock over an engine operating map with varying speeds, loads, EGR rates and fuel types.

Reactivity Controlled Compression Ignition (RCCI) is an engine combustion strategy that produces low NO and PM emissions with high thermal efficiency. Previous RCCI research has been investigated in single-cylinder heavy-duty engines. The current study investigates RCCI operation in a light-duty multi-cylinder engine at 3 operating points. These operating points were chosen to cover a range of conditions seen in the US EPA light-duty FTP test. The operating points were chosen by the Ad Hoc working group to simulate operation in the FTP test. The fueling strategy for the engine experiments consisted of in-cylinder fuel blending using port fuel-injection (PFI) of gasoline and early-cycle, direct-injection (DI) of diesel fuel. At these 3 points, the stock engine configuration is compared to operation with both the original equipment manufacturer (OEM) and custom-machined pistons designed for RCCI operation.

Additive manufacturing was used to fabricate a head for an automotive-scale single-cylinder engine operating on natural gas. The head was consisted of a bimetallic composition of stainless steel and bronze. The engine performance using the bimetallic head was compared against the stock cast iron head. The heads were tested at two speeds (1200 and 1800 rpm), two brake mean effective pressures (6 and 10 bar), and two equivalence ratios (0.7 and 1.0). The bimetallic head showed good durability over the test and produced equivalent efficiencies, exhaust temperatures, and heat rejection to the coolant to the stock head. Higher combustion temperatures and advanced combustion phasing resulted from use with the bimetallic head. The implication is that with optimization of the valve timing, an efficiency benefit may be realized with the bimetallic head.

Low temperature combustion (LTC) has been shown to yield higher brake thermal efficiencies with lower NOx and soot emissions, relative to conventional diesel combustion (CDC). However, while demonstrating low soot carbon emissions it has been shown that LTC operation does produce particulate matter whose composition appears to be much different than CDC. The particulate matter emissions from dual-fuel reactivity controlled compression ignition (RCCI) using gasoline and diesel fuel were investigated in this study. A four cylinder General Motors 1.9L ZDTH engine was modified with a port-fuel injection system while maintaining the stock direct injection fuel system. The pistons were modified for highly premixed operation and feature an open shallow bowl design. RCCI operation was carried out using a certification grade 97 research octane gasoline and a certification grade diesel fuel.

The size and distribution of a vehicle’s tailpipe particulate emissions can have a strong impact on human health, especially if the particles are small enough to enter the human respiratory system. Gasoline direct injection (GDI) has been adopted widely to meet stringent fuel economy and CO2 regulations across the globe for recent engine architectures. However, the introduction of GDI has led to challenges concerning the particulate matter (PM) and particle number (PN) emissions from such engines. This study aimed to compare the particulate emissions of three SI combustion strategies: conventional SI, conventional stoichiometric low-pressure exhaust gas recirculation (LP-EGR), and Dedicated-EGR (D-EGR) at four specific test conditions. It was shown that the engine-out PM/PN for both the EGR strategies was lower than the conventional SI combustion under normal operating conditions. The test conditions were chosen to represent the WLTC test conditions.

Alternative fuels such as methanol can significantly reduce greenhouse gas (GHG) emissions when used in internal combustion engines (ICEs). This study characterized the combustion of methanol, methanol/diesel, and methanol/renewable diesel numerically. Numerical findings were also compared with engine experiments using a single-cylinder engine (SCE). The engine was operated under a dual-fuel combustion mode: methanol was fumigated at the intake port, and diesel was injected inside the cylinder. The characteristic of ignition delay trend as methanol concentration increased is being described at low temperature (low engine load) and high temperature (high engine load) conditions.

Exhaust gas recirculation (EGR) cooler fouling has become a significant issue for compliance with NOX emissions standards and has negative impacts on cooler sizing and engine performance. In order to improve our knowledge of cooler fouling as a function of engine operating parameters and to predict and enhance performance, 19 tube-in-shell EGR coolers were fouled using a 5-factor, 3-level design of experiments with the following variables: (1) EGR flow rate, (2) EGR inlet gas temperature, (3) coolant temperature, (4) soot level, and (5) hydrocarbon concentration. A 9-liter engine and ULSD fuel were used to form the cooler deposits. Coolers were run until the effectiveness stabilized, and then were cooled down to room temperature and run for an additional few hours in order to measure the change in effectiveness due to shut down. The coolers were cut open and the mass per unit area of the deposit was measured as a function of distance down the tube.

The primary focus of this investigation was to determine the hydrogen reformation, efficiency and knock mitigation benefits of methanol-fueled Dedicated EGR (D-EGR®) operation, when compared to other EGR types. A 2.0 L turbocharged port fuel injected engine was operated with internal EGR, high-pressure loop (HPL) EGR and D-EGR configurations. The internal, HPL-EGR, and D-EGR configurations were operated on neat methanol to demonstrate the relative benefit of D-EGR over other EGR types. The D-EGR configuration was also tested on high octane gasoline to highlight the differences to methanol. An additional sub-task of the work was to investigate the combustion response of these configurations. Methanol did not increase its H2 yield for a given D-EGR cylinder equivalence ratio, even though the H:C ratio of methanol is over twice typical gasoline.

Dual fuel engines have shown significant potential as high efficiency powerplants. In one example, SwRI® has run a high EGR, dual-fuel engine using gasoline as the main fuel and diesel as the ignition source, achieving high thermal efficiencies with near zero NOx and smoke emissions. However, assuming a tank size that could be reasonably packaged, the diesel fuel tank would need to be refilled often due to the relatively high fraction of diesel required. To reduce the refill interval, SwRI investigated various alternative fluids as potential ignition sources. The fluids included: Ultra Low Sulfur Diesel (ULSD), Biodiesel, NORPAR (a commercially available mixture of normal paraffins: n-pentadecane (normal C15H32), and n-hexadecane (normal C16H34)) and ashless lubrication oil. Lubrication oil was considered due to its high cetane number (CN) and high viscosity, hence high ignitability.

Ethanol offers significant potential for increasing the compression ratio of SI engines resulting from its high octane number and high latent heat of vaporization. A study was conducted to determine the knock-limited compression ratio of ethanol-gasoline blends to identify the potential for improved operating efficiency. To operate an SI engine in a flex fuel vehicle requires operating strategies that allow operation on a broad range of fuels from gasoline to E85. Since gasoline or low ethanol blend operation is inherently limited by knock at high loads, strategies must be identified which allow operation on these fuels with minimal fuel economy or power density tradeoffs. A single-cylinder direct-injection spark-ignited engine with fully variable hydraulic valve actuation (HVA) is operated at WOT and other high-load conditions to determine the knock-limited compression ratio (CR) of ethanol fuel blends. The geometric CR is varied by changing pistons, producing CR from 9.2 to 12.87.

Modern diesel engines used in light-duty transportation applications have peak brake thermal efficiencies in the range of 40-42% for high-load operation with substantially lower efficiencies at realistic road-load conditions. Thermodynamic energy and exergy analysis reveals that the largest losses from these engines are due to combustion irreversibility and heat loss to the coolant, through the exhaust, and by direct convection and radiation to the environment. Substantial improvement in overall engine efficiency requires reducing or recovering these losses. Unfortunately, much of the heat transfer either occurs at relatively low temperatures resulting in large entropy generation (such as in the air-charge cooler), is transferred to low-exergy flow streams (such as the oil and engine coolant), or is radiated or convected directly to the environment.

In-cylinder fuel blending of gasoline with diesel fuel is investigated on a multi-cylinder light-duty diesel engine as a strategy to control in-cylinder fuel reactivity for improved efficiency and lowest possible emissions. This approach was developed and demonstrated at the University of Wisconsin through modeling and single-cylinder engine experiments. The objective of this study is to better understand the potential and challenges of this method on a multi-cylinder engine. More specifically, the effect of cylinder-to-cylinder imbalances and in-cylinder charge motion as well as the potential limitations imposed by real-world turbo-machinery were investigated on a 1.9-liter four-cylinder engine. This investigation focused on one engine condition, 2300 rpm, 5.5 bar net mean effective pressure (NMEP). Gasoline was introduced with a port-fuel-injection system.

Conventional diesel combustion (CDC) is known to provide high efficiency and reliable engine performance, but often associated with high particulate matter (PM) and nitrogen oxides (NOX) emissions. Combustion of fossil diesel fuel also produces carbon dioxide (CO2), which acts as a harmful greenhouse gas (GHG). Renewable and low-carbon fuels such as renewable diesel (RD) and methanol can play an important role in reducing harmful criteria and CO2 emissions into the atmosphere. This paper details an experimental study using a single-cylinder research engine operated under dual-fuel combustion using methanol and RD. Various engine operating strategies were used to achieve diesel-like fuel efficiency. Measurements of engine-out emissions and in-cylinder pressure were taken at test conditions including low-load and high-load operating points.