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Journal Article

Visualization of Oxidation of Soot Nanoparticles Trapped on a Diesel Particulate Membrane Filter

2011-04-12
2011-01-0602
Through microscopic visualization experiments, a process generally known as depth filtration was shown to be caused by surface pores. Moreover, the existence of a soot cake layer was an important advantage for filtration performance because it could trap most of the particulates. We proposed an ideal diesel particulate filter (DPF), in which a silicon carbide (SiC) nanoparticle membrane (made from a mixture of 80 nm and 500 nm powders) instead of a soot cake was sintered on the DPF wall surface; this improved the filtration performance at the beginning of the trapping process and reduced energy consumption during the regeneration process. The proposed filter was called a diesel particulate membrane filter (DPMF). A diesel fuel lamp was used in the trapping process to verify the trapping and oxidation mechanisms of ultrafine particulate matter. Thus, the filtration performance of the membrane filters was shown to be better than that of conventional DPFs.
Technical Paper

Visualization Study of PM Trapping and Reaction Phenomena in Micro-structural Pores through Cross Section of DPF Wall

2007-04-16
2007-01-0917
Trapping of diesel particulates and phenomena of chemical reaction in regeneration were investigated by visualization through the cross-sectional area of a diesel-particulate-filter wall, using a digital-microscope with a high focusing depth. Herein, SiC-DPF walls were polished up to make a uniform height and to create a mirror-like surface on each SiC-particle-grain. At the beginning of the trapping process, it was observed that large particulates were trapped once in the small pores inside the wall, and then, since the flow-pattern was changed drastically, the trapped particulates were pushed out and blown off again, and finally, trapped in a region further downstream. As time passed, image analysis disclosed that since fine particulates were deposited around the SiC-particle-grain surface, the flow-channels became increasingly narrow.
Technical Paper

The Effect of Exhaust Gas Recirculation on Performance and Emission of Ethanol Fumigated Diesel Engine

2017-11-05
2017-32-0101
Primary energy source such as fossil fuel keep decreasing due to various kind of usage. According to less amount of the fossil fuel, human seeks for an alternative fuel source such as alcohol. Alcohol like ethanol can be produced easily from strarchy plant. But using alcohol as blended fuel with diesel fuel doesn't work well because alcohol has low cetane number, lack of lubricity and very low miscibility with diesel fuel. To overcome this, fumigation system or port fuel injection of alcohol seems interesting. Although it requires more complicate system but it can compensate the miscibility issue and alcohol can be used in higher dose to give more energy. Diesel engine produces a lot of emission such as NOx and some other carbon content emission like HC, CO and soot due to they run in lean condition as their characteristic. Modern diesel engines are now coupled with exhaust gas recirculation system to help reduce in main emission like NOx.
Technical Paper

Study on Fuel-Saving Durability of Ultra-Low Viscosity 0W-8 Gasoline Engine Oil

2021-04-06
2021-01-0566
The JASO GLV-1 standard was introduced in Japan for 0W-8 ultra-low viscosity gasoline engine oil to improve fuel economy. Fuel economy targets are specified for new oil but not for aged oil. In contrast, Sequence VI in the ILSAC GF-6 standard requires fuel economy improvement for both new and aged oils. This test simulates fuel economy improvement after 6400 km (FEI 1) and 16000 km (FEI 2) of driving based on US fuel economy certification testing. Currently, 0W-8 is not included in the ILSAC standard and the fuel-saving durability of 0W-8 has not been investigated. To include ultra-low viscosity oil like 0W-8 in future engine oil standards, it is necessary to know its fuel-saving durability and to examine the evaluation test method. This study focused on the fuel-saving durability of 0W-8 with or without the Mo friction modifier and considered the evaluation method.
Technical Paper

Stereoscopic Micro-PIV Measurement of Near-Wall Velocity Distribution in Strong Tumble Flow under Motored SI Engine Condition

2020-09-15
2020-01-2019
In a state-of-the-art lean-burn spark ignition engine, a strong in-cylinder flow field with enhanced turbulence intensity is formed, and understanding the wall heat transfer mechanism of such a complex flow is required. The flow velocity and temperature profiles inside the wall boundary layer are strongly related to the heat transfer mechanism. In this study, two-dimensional three-component (2D3C) velocity distribution near the piston top surface was measured during the compression stroke in a strong tumble flow using a rapid compression and expansion machine (RCEM) and a stereoscopic micro-PIV system. The bore, stroke, compression ratio, and compression time were 75 mm, 128 mm, 15, and 30 ms (equivalent to 1000 rpm), respectively.
Technical Paper

Soot Oxidation Characteristics of SiC Nanoparticle Membrane Filters

2012-04-16
2012-01-0848
A diesel particulate membrane filter (DPMF) has good trapping efficiency of soot and reduces the pressure loss through the soot accumulation process on the diesel particulate filter wall. The activation energy reduction effect of the soot oxidation reaction by DPMF was clarified. The membrane consists of SiC nanoparticles with a diameter of 10-100 nm. A thin oxide layer is formed on the SiC particle surface, and nanoscale noble metal particles are distributed on the surface. The reduction mechanism for the activation energy was investigated in detail. Nanoscale soot was accumulated on DPMF from a diesel lamp. Furthermore, the soot oxidation in the regeneration process was observed using an optical microscope. An Arrhenius plot was made from the change of the concentration of the product gases CO and CO₂ with respect to time. The performance and the temperature dependence of oxygen desorption on the oxide layer was measured by thermal desorption spectroscopy (TDS).
Technical Paper

Simultaneous Measurements of Temperatures of Flame and Wall Surface in a Combustion Chamber of Diesel Engine

2011-08-30
2011-01-2047
In order to investigate the combustion phenomena in a combustion chamber of the diesel engine at transient operations, the simultaneous measurements of temperatures of flame and wall surface in a combustion chamber were conducted. The new technique for simultaneous measurements of flame temperature and wall surface was developed. Laser-Induced phosphorescence was used for the measurement of wall surface temperature which was coupled with the flame temperature measurement by a two-color pyrometry. The NOx and soot emissions were also measured simultaneously in transient operations. The relation between the temporal changes of emissions and temperatures of flame and surface wall are discussed. The results show that the temporal change of NOx emission during transient operation is similar to that of the average gas temperature in a chamber. On the other hand, the temporal change of soot emission is similar to neither that of flame temperature nor that of average gas temperature.
Journal Article

Simultaneous Measurements of Aromatic Hydrocarbons in Exhaust using a Laser Ionization Method

2009-11-02
2009-01-2742
A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.
Technical Paper

Simultaneous 2-D Imaging of OH Radicals and Soot in a Diesel Flame by Laser Sheet Techniques

1996-02-01
960834
The OH and soot in an unsteady flame, which was achieved in a rapid compression machine, were visualized simultaneously by the laser-induced fluorescence and laser-induced scattering techniques. The fuel mixture consisting of 90% paraffin hydrocarbon (reference fuel) and 10% polypropylene-glycol was used to reduce the optical attenuation caused by dense soot cloud. The simultaneous images of the fluorescence from OH and scattering from soot show that the soot and OH exist separately from each other in the leading portion of the spray flame, and the OH is formed earlier than the soot in the near field region of spray flame.
Technical Paper

Scanning Electron Microscopic Visualization of Transition from Surface Pore Filtration to Cake Filtration Inside Diesel Particulate Filter Walls

2015-04-14
2015-01-1018
Surface pores that are open to the inlet channel below the surface play a particularly important role in the filtration of particulate matter (i.e., soot) inside the walls of a diesel particulate filter (DPF); they are closely related to the pressure drop and filtration efficiency through the DPF as well as the performance of the regeneration process. In this study, a scanning electron microscope (SEM) was used to dynamically visualize the soot deposition process at the particle scale as “time-lapse” images corresponding to the different increases in the pressure drop at each time step. The soot was first trapped at the deepest areas of the surface pores because the porous channels in this area were constricted by silicon carbide grains; soot dendrite structures were observed to grow and finally cause obstructions here.
Journal Article

Scanning Electron Microscopic Visualization of Bridge Formation inside the Porous Channels of Diesel Particulate Filters

2016-10-24
2016-01-9079
Time-lapse images of particulate matter (PM) deposition on diesel particulate filters (DPFs) at the PM-particle scale were obtained via field-emission scanning electron microscopy (FE-SEM). This particle scale time-series visualization showed the detailed processes of PM accumulation inside the DPF. First, PM introduced into a micro-pore of the DPF wall was deposited onto the surface of SiC grains composing the DPF, where it formed dendritic structures. The dendrite structures were locally grown at the contracted flow area between the SiC grains by accumulation of PM, ultimately constructing a bridge and closing the porous channel. To investigate the dominant parameters governing bridge formation, the filtration efficiency by Brownian diffusion and by interception obtained using theoretical filtration efficiency analysis of a spherical collector model were compared with the visualization results.
Technical Paper

Research on Super-Lean Burn Spark Ignition Engine with In-Cylinder Water Injection using Gasoline Surrogate Fuels

2023-09-29
2023-32-0055
The combination of super-lean burn spark ignition engine (excess air ratio λ ≈ 2) and in-cylinder water injection (WI) makes it possible to achieve thermal efficiency higher than 50%. Toward future fuel diversification including carbon-neutral fuels, technologies to improve SI engine thermal efficiency applicable to various fuels are required. In this study, the effect of in-cylinder WI on SI engine performance with a compression ratio of 17 and λ = 1.85 is investigated using premium gasoline, 5 components surrogate fuels for premium gasoline (S5H), and for regular gasoline (S5R). In the case of premium gasoline and S5H, spark timing can be advanced to MBT (minimum advance for best torque) by WI and gross indicated thermal efficiency (gITE) increases to 51.2% (premium gasoline) at water/fuel weight ratio (W/F) = 57.7% and 50.8% (S5H) at W/F = 62.9%. In the case of S5R, on the other hand, a strong knock forces a large spark retard at no-water condition.
Technical Paper

Real-World Emission Analysis Methods Using Sensor-Based Emission Measurement System

2020-04-14
2020-01-0381
Every year, exhaust gas regulations are getting stricter with the intention to solve the average air pollution problem, however, local roadside pollution is still a pressing issue. In order to solve this local roadside pollution problem, it is necessary to evaluate and/or predict “where” and “how much” pollutants such as NOx are emitted. To predict the local roadside pollution, it is necessary to collect emissions data from various kinds of vehicles driving on real-world and analyze them. In recent years, Real Driving Emission regulations using PEMS (Portable Emission Measurement System) have been introduced mainly in Europe. A typical PEMS configuration can weigh close to 100 kg however, and its weight affects the driving conditions of vehicles running on actual roads. In this study, we focused on the analysis of real-world emissions using SEMS (Sensor-based Emission Measurement System).
Technical Paper

Real World Emissions Analysis Using Sensor-based Emissions Measurement System for Light-duty Direct-Injection Gasoline Vehicle

2022-03-29
2022-01-0572
In recent years, particulate matter (PM) emitted from direct-injection gasoline vehicles is becoming an increasingly concerning problem. In addition, it is often reported that ammonia (NH3) is emitted from gasoline vehicles equipped with a three-way catalyst. These emissions might be largely emitted especially when driving in on-road driving conditions. In this study, we investigated the emissions, NOx, NH3, and PM/PN (particulate number) of a light-duty direct-injection gasoline vehicle when driving on actual roads. Using a small direct-injection gasoline vehicle equipped with a three-way catalyst, experiment was conducted 8 times on the same route, and these emissions were measured. In this study, vehicle specific power (VSP) was introduced, which can be calculated using vehicle parameters, vehicle speed, and road gradient. The effects of parameters acquired through on-board diagnostics (OBD) port and VSP on emissions were investigated.
Technical Paper

Quantitative Measurement of Fuel Vapor Concentration in an Unsteady Evaporating Spray via a 2-D Mie-Scattering Imaging Technique

1993-10-01
932653
The cross-sectional distribution of fuel vapor concentration in an evaporating spray was measured quantitatively by a new scattering imaging technique, silicone particle scattering imaging method, which was proposed in a previous paper[1]. When fuel containing silicone oil injected into a nitrogen environment at high temperature, the volatile base fuel in the droplets vaporized rapidly, leaving behind small droplets of silicone oil suspended in the vapor-gas mixture. The silicone oil droplets were illuminated by a thin laser sheet, and the scattered light was imaged by a CCD camera. The cross-sectional distribution of vapor concentration was estimated from the scattering image of the silicone oil droplets by Mie scattering theory. The results demonstrated clearly the inhomogeneity of the fuel vapor concentration. The distribution of vapor concentration was discontinuous, and islands of rich mixture with a scale of several millimeters existed in the center region of the spray.
Technical Paper

Quantitative Measurement of 2-D Fuel Vapor Concentration in a Transient Spray via Laser-Induced Fluorescence Technique

1994-10-01
941953
A new method to determine simultaneously the temperature and the fuel vapor concentration inside an evaporating spray was described by using a laser-induced fluorescence technique. A TMPD doped base fuel composed of C12H26: 22%, C13H28: 54% and C14H30: 30% was injected into the combustion chamber of a rapid compression machine which is filled with a high temperature and high pressure nitrogen. The laser sheet was used for incident light, which was reflected by a prism located inside the combustion chamber and propagated through the center of an evaporating spray. The laser induced fluorescence intensity was imaged by a high speed-gated intensifier from a direction perpendicular to the incident light. The results shows that mixtures with high equivalence ratio are observed in the central region, while low equivalence ratio mixtures are observed in the periphery of the spray. It is also observed that the temperature of richest mixture is 50 K as low as the surrounding gas temperature.
Technical Paper

Pyrene-LIF Thermometry of the Early Soot Formation Region in a Diesel Spray Flame

2005-09-11
2005-24-006
In order to investigate early soot formation process in diesel combustion, spectral analysis and optical thermometry of early soot formation region in a transient spray flame under diesel-like conditions (Pg2.8 MPa, Tg620-820K) was attempted via laser-induced fluorescence (LIF) from pyrene (C16H10) doped in the fuel. Pyrene is known to exhibit a temperature\-dependent variation of LIF spectrum; the ratio of S2/S1 fluorescence yields, from the lowest excited singlet state S1 and the second excited singlet state S2, depends on temperature. In the present study, pyrene was doped (1%wt) in a model diesel fuel (0-solvent) and the variation of LIF spectra from the pyrene in the spray flame in a rapid compression machine were examined at different ambient temperatures, ambient oxygen concentrations, measurement positions and timings after start of fuel injection.
Technical Paper

Physical Characterization of Biodiesel Particle Emission by Electron Microscopy

2013-10-15
2013-32-9150
Nanostructures of diesel and biodiesel engine particulate matters (PMs) were investigated by using a Transmission Electron Microscopy (TEM). The average single particle sizes of biodiesel and diesel PMs are approximately 30-40 nm and 50-60 nm, respectively. Image processing process was used to estimate each carbon platelet length by using TEM image. The average carbon platelet length of biodiesel and diesel PMs are in the range of 0.1-7.0 nm. Moreover, carbon atoms per cubic volume of PMs are approximately 500-900. The result shows that engine load and fuel property are strongly impact on the size of single particle and carbon atom density of particle. This is one of interesting behaviors need to be investigated for better understanding. The results of this research would be used as basic information for design and develop removing process of PM emitted from engine combustion which using in diesel and biodiesel fuels.
Journal Article

Particulate Matter Trapping and Oxidation on a Catalyst Membrane

2010-04-12
2010-01-0808
Particulate matter (PM) trapping and oxidation in regeneration on the surface of a diesel particulate catalyst-membrane filter (DPMFs) were investigated in detail using an all-in-focus optical microscope. The DPMF consists of two-layer sintered filters, where a SiC-nanoparticle membrane (made from a mixture of 80 nm and 500 nm powders) covers the surface of a conventional SiC filter. Using a visualization experiment, it was shown that PMs were trapped homogeneously along fine surface pores of the membrane's top surface, whereas in the regeneration process, the particulates in contact with the membrane may have been oxidized with some catalytic effect of the SiC nanoparticles. A soot cake was reacted continuously on the nanoparticles since pushed by a gas flow. The oxidation temperature of particulate trapped on the SiC-nanoparticle membrane was about 75 degrees lower than that on the conventional diesel particulate filters (DPF) without a catalyst.
Technical Paper

Particulate Formation and Flame Structure in Diesel Engines

1989-02-01
890436
The present paper describes the particulate formation in diesel flames considering the flame structure and its similarity to that of gaseous turbulent diffusion flames. A comparison of spatial variations of soot concentration, equivalence ratio and flame temperature between diesel flames and turbulent diffusion flames reveals the facts that soot particles are mostly farmed in a region where the equivalence ratio is near stoichiometric and the flame temperature is the highest in both flames, and that in diesel flames this region exists generally near the flame tip. A close inspection of high speed photographs of diesel flames suggests the three major routes of soot emission from diesel engines: quenching of flamelets detached from the flame tip due to 1) the flame impingement onto the wall; and 2) cooling of the flamelets by the bulk air; and 3) survival of soot containing flamelets inside the flame.
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