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Technical Paper

Voltage and Voltage Consistency Attenuation Law of the Fuel Cell Stack Based on the Durability Cycle Condition

2019-04-02
2019-01-0386
Based on the durability cycle test of fuel cell stack and the characteristics of cyclic working conditions, this paper defines the characteristic current point and studies the attenuation rule of the fuel cell stack voltage over time under the characteristic current point. The results show that the voltage of the fuel cell stack appears to be linear downward under the characteristic current point. and the voltage attenuation rate of the fuel cell stack increases quadratically with the increase of the current density in addition to the open-circuit voltage point. Then the coefficient of variation is introduced in statistics as the index to characterize the voltage consistency attenuation of the fuel cell stack, and its variation rule is explored. The results show that the voltage consistency of vehicle fuel cell stack decreases seriously with the increase of running time under the condition of durable cycling.
Research Report

Use of Proton-exchange Membrane Fuel Cells in Ground Vehicles

2022-09-26
EPR2022020
Fuel cell electric vehicles (FCEVs) require multiple components to operate properly, and the fuel cell stack—the source of power—is one of the most important components. While the number of enterprises manufacturing and selling fuel cell stacks is increasing globaly year after year, the residual challenges of core components and technologies still need to be resolved in order to keep pace with the development of lithium-ion batteries (i.e., its primary competitor). Additionally, many production and distribution standards are seen as unsettled. These barriers make large-scale commercialization an issue. Use of Proton-exchange Membrane Fuel Cells in Ground Vehicles explores the opportunities and challenges within the PEMFC industry. With the help of expert contributors, a critical overview of fuel cells and the FCEV industry is presented, and core technology, applications, costs, and trends are analyzed.
Technical Paper

Uniformity Identification and Sensitivity Analysis of Water Content of Each PEM Fuel Cell Based on New Online High Frequency Resistance Measurement Technique

2024-04-09
2024-01-2189
Water content estimation is a key problem for studying the PEM fuel cell. When several hundred fuel cells are connected in serial and their active surface area is enlarged for sufficient power, the difference between cells becomes significant with respect to voltage and water content. The voltage of each cell is measurable by the cell voltage monitor (CVM) while it is difficult to estimate water content of the individual. Resistance of the polymer electrolyte membrane is monotonically related to its water content, so that the new online high frequency resistance (HFR) measurement technique is investigated to identify the uniformity of water content between cells and analyze its sensitivity to operating conditions in this paper. Firstly, the accuracy of the proposed technique is experimentally validated to be comparable to that of a commercialized electrochemical impedance spectroscopy (EIS) measurement equipment.
Technical Paper

Understanding the Transient Behavior and Consistency Evolution of PEMFC from the Perspective of Temperature

2022-03-29
2022-01-0189
The temperature of proton exchange membrane fuel cell (PEMFC) is the key factor restricting fuel cell’s performance. A deep understanding of temperature on stack voltage consistency and transient characteristics is necessary for improving the output performance of fuel cell. In this paper, the variation trend of consistency and transient characteristics of 20kW PEMFC stack at different temperatures is studied by experiment. In consistency, the amplitude of voltage changes and voltage difference (voltage coefficient variation σV) under different thermal loading conditions is examined. In transient characteristics, discussing the trends of transient voltage at different thermal loading. As the result, once the stack temperature increases from 65 °C to 70 °C, the stack performance and dynamic response are significantly improved, which may be caused by the rise in temperature promoting the establishment of the internal quality transmission channel.
Technical Paper

Thermal Management of Power Batteries for Electric Vehicles Using Phase Change Materials: A Review

2016-04-05
2016-01-1204
As one of the most crucial components in electric vehicles, power batteries generate abundant heat during charging and discharging processes. Thermal management system (TMS), which is designed to keep the battery cells within an optimum temperature range and to maintain an even temperature distribution from cell to cell, is vital for the high efficiency, long calendar life and reliable safety of these power batteries. With the desirable features of low system complexity, light weight, high energy efficiency and good battery thermal uniformity, thermal management using composite phase change materials (PCMs) has drawn great attention in the past fifteen years. In the hope of supplying helpful guidelines for the design of the PCM-based TMSs, this work begins with the summarization of the most commonly applied heat transfer enhancement methods (i.e., the use of thermally conductive particles, metal fin, expanded graphite matrix and metal foam) for PCMs by different researchers.
Technical Paper

Theoretical and Practical Mechanisms on Lowering Exhaust Emission Levels for Diverse Types of Spark Ignition Engines

2008-06-23
2008-01-1545
The exhaust aftertreatment strategy is one of the most fundamental aspects of spark ignition engine technologies. For various types of engines (e.g., carburetor engine, PFI engine and GDI engine), measuring, purifying, modeling, and control strategies regarding the exhaust aftertreatment systems vary significantly. The primary goal of exhaust aftetreatment systems is to reduce the exhaust emission levels of NOx, HC and CO as well as to lower combustion soot. In general, there is a tradeoff among different engine performance aspects. The exhaust catalytic systems, such as the three way catalyst (TWC) and lean NOx trap (LNT) converters, can be applied together with the development of other engine technologies (e.g., variable valve timing, cold start). With respect to engine soot, some advanced diagnosing techniques are essential to obtain thorough investigation of exhaust emission mechanisms.
Technical Paper

The Social Economical Benefit Estimation by HEVs Application-Shanghai Case Study

2008-06-23
2008-01-1565
In this paper, a case study of Shanghai HEVs application and its effects on the social and environmental benefits are presented based on the multi views on the different aspects, such as, not only for the fuel consumption saving, but also emissions reduction and health effect, agriculture loss and cleaning cost. The results show that the potential benefits for the society from HEVs application are markedly with the increase of the ratio of HEV in the population of vehicle. Based on this, the policy to promote the HEV purchased by consumers is very important at the beginning of HEV into market.
Technical Paper

The Investigation of Self-Balanced Property and Vibration on the Particular Crankshaft System for an Opposed Piston Engine

2016-06-15
2016-01-1768
For an in-line diesel engine with four cylinder operating in four-stroke mode, the second-order reciprocating inertia forces generally cannot be well balanced with direct approach. The unbalanced second-order inertia forces are the main reason to cause vibration and noise in a diesel engine within low frequency range. The more superior tone quality for modern diesel engine has been expected even for bus application all the time, and there are tougher requirements for truck noise in developed countries, i.e. in Europe and USA. In present research a unique crankshaft system configuration was proposed, which including opposed piston, inner and outer connecting rod, and crankshaft but running in two-stroke mode, to eliminate the second-order inertia force considerably rather than by adding an extra balance shaft mechanism.
Technical Paper

The Emission of a Diesel Engine in Different Coolant Temperature during Cold Start at High Altitude

2019-04-02
2019-01-0730
Emissions of diesel engine have been received much more attention since the Volkswagen Emission Scandal. The Euro VI emission standard has already included cold start emissions in the legislative emission driving cycles which is one of the hardest part of emission control. High altitude performance is also considered in the latest regulations which will be stricter in the future. Heating the coolant is one of the most common method to improve the cold start performance. But researches focus on the emission of a diesel engine in different coolant temperature at high altitude which up to 4500m have not been seen. The present research investigated the effect of coolant temperature on performance and exhaust emissions (gaseous and particulate emissions) during the cold start of a diesel engine. A plateau simulation system controlled the inlet and exhaust pressure to create altitude environments from 0m to 4500m, and the coolant temperature was controlled from 20°C to 60°C.
Journal Article

The Direct Methanol Fuel Cell (DMFC): Determination of Model Parameters

2008-11-11
2008-01-2856
This paper is contributed to determining model parameters for DMFCs. Theoretical evaluations are carried out to set up the relationship between the unknown and measurable parameters or variables. A laboratory-scale liquid-feed cell was simulated under different operating conditions. The resulting measurable static performance curves are used as basic information. Some key kinetic and physical parameters can be determined or estimated for a DMFC model.
Journal Article

The Control Strategy for 4WD Hybrid Vehicle Based on Wavelet Transform

2021-04-06
2021-01-0785
In this paper, in order to avoid the frequent switching of engine operating points and improve the fuel economy during driving, this paper proposes a control strategy for the 4-wheel drive (4WD) hybrid vehicle based on wavelet transform. First of all, the system configuration and the original control strategy of the 4WD hybrid vehicle were introduced and analyzed, which summarized the shortcomings of this control strategy. Then, based on the analyze of the original control strategy, the wavelet transform was used to overcome its weaknesses. By taking advantage over the superiority of the wavelet transform method in multi signal disposition, the demand power of vehicle was decomposed into the stable drive power and the instantaneous response power, which were distributed to engine and electric motor respectively. This process was carried out under different driving modes.
Technical Paper

Study on the Performance-Determining Factors of Commercially Available MEA in PEMFCs

2020-04-14
2020-01-1171
Proton exchange membrane fuel cells (PEMFC), which convert the chemical energy into electrical energy directly through electrochemical reactions, are widely considered as one of the best power sources for new energy vehicles (NEV). Some of the major advantages of a PEMFC include high power density, high energy conversion efficiency, minimum pollution, low noise, fast startup and low operating temperature. The Membrane Electrode Assembly (MEA) is one of the core components of fuel cells, which composes catalyst layers (CL) coated proton exchange membrane (PEM) and gas diffusion layers (GDL). The performance of MEA is closely related to mass transportation and the rate of electrochemical reaction. The MEA plays a key role not only in the performance of the PEMFCs, but also for the reducing the cost of the fuel cells, as well as accelerating the commercial applications. Commercialized large-size MEA directly plays a major role in determining fuel cell stack and vehicle performance.
Technical Paper

Study on the Constant Voltage, Current and Current Ramping Cold Start Modes of Proton Exchange Membrane Fuel Cell

2021-04-06
2021-01-0746
The cold-start of proton exchange membrane fuel cell (PEMFC) has been one of the technical challenges for fuel cell vehicle table ommercialization. In this study, a one-dimensional cold start transient model of PEMFC was developed for the transfer of water, heat, electrons and protons during the cold start process. Different loading modes, including constant voltage, constant current, and current ramping, were adopted for fuel cell cold starting analysis, respectively. The internal water-heat transfer within fuel cell was investigated under different loading modes. The results show that in the constant current mode, for the high current, the cold start process can produce more heat than other modes, which can increase fuel cell temperature rapidly. However, this process may easily fail before the ice fully covers the cathode catalyst layers (CL).
Journal Article

Study on Soot Oxidation Characteristics of Ce and La Modified Pt-Pd CDPF Catalysts

2023-04-11
2023-01-0390
The catalyzed diesel particulate filter with Pt and Pd noble metals as the main loaded active components are widely used in the field of automobile engines, but the high cost makes it face huge challenges. Rare earth element doping can improve the soot oxidation performance of the catalyzed diesel particulate filter and provide a new way to reduce its cost. In this paper, thermogravimetric tests and chemical reaction kinetic calculations were used to explore the effect of Pt-Pd catalysts doped Ce, and La rare earth elements on the oxidation properties of soot. The results shown that, among Pt-Pd-5%Ce, Pt-Pd-5%La, and Pt-Pd-5%Ce-5%La catalysts, Pt-Pd-5%La catalyst has the highest soot conversion, the highest low-temperature oxidation speed, and the activation energy is the smallest. Compared with soot, this catalyst reduced T10 and T20 by 82% and 26%, respectively, meaning the catalytic activity of Pt-Pd-5%La catalyst was the best.
Technical Paper

Study on Real-World NOx and Particle Emissions of Bus: Influences of VSP and Fuel

2019-04-02
2019-01-1181
In this study, the real-world NOx and particle emissions of buses burning pure diesel fuel (D100), biodiesel fuel with 20% blend ratio (B20) and liquefied natural gas (LNG) were measured with portable emission measurement system (PEMS). The measurement conducted at 6 constant speed, which ranged from 10km/h to 60 km/h at 10km/h intervals, and a period of free driving condition. The relationship between vehicle specific power (VSP) and NOx/particle emissions of each bus were analyzed. The results show that the change rules of NOx, PN and PM emission factors with the increase of VSP were basically the same for the same bus, but for the bus using different fuel, the change rules may change. In VSP bin 0, the vehicles were mostly in idle condition and the emission factors of NOx, PN and PM of three buses were all in a relatively high level. In low VSP interval, which ranged from bin 0 to bin 4, the emissions of three buses first decreased and then increased with the growth of VSP.
Technical Paper

Study on Improving the Fuel Economy of the Engine on EP Energy-Saving Vehicle

2008-06-23
2008-01-1780
“Soichiro Honda Cup, Honda Econo-Power Competition”, is an annual international energy-saving competition which is hosted by Honda Motor Co., Ltd. Till now it has been held 27 sessions. The aims of the EP project are: promoting the development of environmental protection, making full use of limit earth resources, challenging the fuel consumption limitation of vehicle. Tongji University's students' team has participated in the competition for seven consecutive times. In order to minimize the fuel consumption of the EP energy-saving vehicle, this paper focuses on the technical methods of improving the fuel economy of the engine. Firstly, the optimization of the carburetor. Secondly, for the purpose of improving combustion efficiency, researches on dual spark plug and compression ratio are done.
Technical Paper

Study on EP Energy-Saving Vehicle

2008-06-23
2008-01-1775
The price of fossil fuels and the increasing inexorable energy crisis have become vital issues for everyone. Tongji University EconoPower Racing Team was established to participate in the “Honda EconoPower Cup” annually. Every contestant in the competition must finish a certain distance in the fixed time, with the gasoline supplied by the committee. After that the committee will measure the fuel consumption of every team and calculate the distance per liter fuel (the farther the better) to determine the champion. In order to enhance the EP vehicle's achievement we've made some improvements, such as framework, body, engine's optimization and so on. In this passage we mainly state some details of our research approaches in framework, steering, transmission, shape and driving strategy. The main technologies were: friction reduction, lightweight, enhancement of power train efficiency, tire selection and driving strategy.
Technical Paper

Study on Correlation between After-Treatment Performance and Running Conditions, Exhaust Parameters of Heavy-Duty Diesel Vehicle

2018-04-03
2018-01-0338
The increasingly stringent emission regulations have mandated the use of CCRT (catalyzed continuously regeneration trap) made by upstream DOC (diesel oxidation catalyst) and downstream CDPF (catalyzed diesel particulate filter) for heavy-duty diesel vehicles, which is proved to be the only way that can efficiently control the gaseous and particulate emissions. The performance of after-treatment is greatly influenced by the running conditions of the diesel vehicle and its exhaust parameters, so this paper intended to use grey relational analysis to study the correlation between running conditions (velocity, acceleration, VSP (vehicle specific power)), exhaust parameters (exhaust flow rate, DOC inlet temperature, concentrations of CO, THC, O2 and NOX) and the performance of DOC and CCRT based on chassis dynamometer test. Results showed that the effect of DOC on CO and THC is mainly affected by exhaust flow rate, exhaust temperature and THC concentration.
Technical Paper

Study on Air Pressure-Flow Decoupling Control in Fuel Cell System Based on Feedforward Algorithm

2019-11-04
2019-01-5042
Proton exchange membrane fuel cell (PEMFC) system is considered to be one of the ideal replacement for conventional Internal Combustion Engines (ICE) due to its zero emission, low operating temperature and high power density. The high-pressure PEMFC system has become the future development direction because the higher gas pressure can effectively improve the performance and power density of stack. However, the high gas pressure can lead to the damage of membrane electrode assembly (MEA) and even the failure of fuel cell stack. As the air supply system is a nonlinear system, the flow and pressure have a strong coupling relation. For this problem, firstly, the mathematical model of air supply system is established in MATLAB/Simulink. Then a dual-loop control strategy is used in controller.
Journal Article

Study of the Combustion Characteristics of a HCCI Engine Coupled with Oxy-Fuel Combustion Mode

2017-03-28
2017-01-0649
The present work proposed to implement oxy-fuel combustion mode into a homogeneous charge compression ignition engine to reduce complexity in engine emissions after-treatment and lower carbon dioxide emission. The combination of oxy-fuel combustion mode with homogeneous charge compression ignition engine can be further optimized by the utilization of direct high temperature and pressure water injection to improve cycle performance. A retrofitted conventional diesel engine coupled with port fuel injection and direct water injection is utilized in this study. A self-designed oxygen and carbon dioxide mixture intake system with flexible oxygen fraction adjustment ability is implemented in the test bench to simulate the adoption of exhaust gas recirculation. Water injection system is directly installed in the combustion chamber with a modified high speed solenoid diesel injector.
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