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Research Report

Use of Proton-exchange Membrane Fuel Cells in Ground Vehicles

2022-09-26
EPR2022020
Fuel cell electric vehicles (FCEVs) require multiple components to operate properly, and the fuel cell stack—the source of power—is one of the most important components. While the number of enterprises manufacturing and selling fuel cell stacks is increasing globaly year after year, the residual challenges of core components and technologies still need to be resolved in order to keep pace with the development of lithium-ion batteries (i.e., its primary competitor). Additionally, many production and distribution standards are seen as unsettled. These barriers make large-scale commercialization an issue. Use of Proton-exchange Membrane Fuel Cells in Ground Vehicles explores the opportunities and challenges within the PEMFC industry. With the help of expert contributors, a critical overview of fuel cells and the FCEV industry is presented, and core technology, applications, costs, and trends are analyzed.
Technical Paper

Topology Optimization of Metal and Carbon Fiber Reinforced Plastic (CFRP) Structures under Loading Uncertainties

2019-04-02
2019-01-0709
Carbon fiber reinforced plastic (CFRP) composite materials have gained particular interests due to their high specific modulus, high strength, lightweight and perfect corrosion resistance. However, in reality, CFRP composite materials cannot be used alone in some critical places such as positions of joints with hinges, locks. Therefore, metal reinforcements are usually necessary in local positions to prevent structure damage. Besides, if uncertainties present, obtained optimal structures may experience in failures as the optimization usually pushes solutions to the boundaries of constraints and has no room for tolerance and uncertainties, so robust optimization should be considered to accommodate the uncertainties in practice. This paper proposes a mixed topology method to optimize metal and carbon fiber reinforced plastic composite materials simultaneously under nondeterministic load with random magnitude and direction.
Technical Paper

Thermal Model of High-Power Lithium Ion Battery Under Freezing Operation

2018-04-03
2018-01-0445
Lithium ion battery is considered as one of the most possible energy storage equipment for new energy vehicles (EV, HEV, etc.) because of the advantages of long cycle life, high power density and low self-discharge rate. However, under freezing condition high power battery suffers of significant performances losses. For example, they would suffer from significant power capability losses and poor rate performance, which would restrict the availability to delivery or to gain of high current in transient conditions. To evaluate those performance drawbacks and to make an efficient design, good mathematical models are required for system simulation especially for battery thermal management. In this paper, a three-dimensional homogenization thermal model of a 20 Ah prismatic lithium ion battery with LiFePO4 (LFP) cathode is described.
Technical Paper

The Aging Law of Low Temperature Charging of Lithium-Ion Battery

2019-04-02
2019-01-1204
With the rise of new energy vehicles, lithium-ion batteries have been widely used. However, the safety, cruising range and practicality of electric vehicles are still major obstacles to their development. Among them, the low-temperature performance of electric vehicles is receiving more and more attention. Lithium-ion batteries have poor low-temperature performance. At low temperatures, not only the charging efficiency is lowered, but also the energy that can be flushed is correspondingly reduced, thereby resulting in a decrease in capacity and an increase in aging. At present, the mechanism and influence factors of battery discharge aging have been studied relatively well, but there are few researches on low temperature charging aging of batteries.
Technical Paper

Simplified Modeling of an Innovative Heating Circuit for Battery Pack Based on Traction Motor Drive System

2023-04-11
2023-01-0515
Alternating current (AC) heating is an efficient and homogeneous manner to warm Lithium-ion batteries (LIBs) up. The integrated design of AC heating combined with the motor drive circuit has been studied by many scholars. However, the problems of excessive heating frequency (>1kHz) and zeros torque output of the motor during the heating process have not been solved. High-frequency AC excitation may be detrimental to the battery because the effect of high-frequency AC excitation on the state of health of the battery is unknown. In addition, although the zero-torque output can be realized by controlling the q-axis current to zero, the torque ripple is still difficult to eliminate in a real-world application. To further solve the above problems, the motor’s neutral conductor is pulled out and connected to a large capacitor to increase the current amplitude of the AC heating at low frequencies.
Technical Paper

SOC Estimation of Battery Pack Considering Cell Inconsistency

2019-04-02
2019-01-1309
Range anxiety problem has always been one of the biggest concern of consumers for pure electric vehicles. Accurate driving range prediction is based on accurate lithium-ion battery pack SOC (State of Charge) estimation. In this article, a complete SOC estimation algorithm is proposed from cell level to battery pack level. To begin with, the equivalent circuit model (ECM) is applied as the model of battery cell. ECM parameters are identified every 10% SOC interval through genetic algorithm. The dual extended Kalman filtering (DEKF) algorithm is adopted for cell-level SOC and ohmic resistance R0 estimation. The estimation accuracy of cell SOC and R0 is verified under NEDC dynamic working condition. The cell-level SOC estimation error is below 1%. However, cell inconsistency can always result in inaccurate cell SOC estimation inside the battery pack. The impact of initial SOC inconsistency and internal resistance inconsistency between cells on battery pack SOC is specifically analyzed.
Technical Paper

Revealing the Impact of Mechanical Pressure on Lithium-Ion Pouch Cell Formation and the Evolution of Pressure During the Formation Process

2024-04-09
2024-01-2192
The formation is a crucial step in the production process of lithium-ion batteries (LIBs), during which the solid electrolyte interphase (SEI) is formed on the surface of the anode particles to passivate the electrode. It determines the performance of the battery, including its capacity and lifetime. A meticulously designed formation protocol is essential to regulate and optimize the stability of the SEI, ultimately achieving the optimal performance of the battery. Current research on formation protocols in lithium-ion batteries primarily focuses on temperature, current, and voltage windows. However, there has been limited investigation into the influence of different initial pressures on the formation process, and the evolution of cell pressure during formation remains unclear. In this study, a pressure-assisted formation device for lithium-ion pouch cells is developed, equipped with pressure sensors.
Technical Paper

Research on Effect of Dynamic Working Condition on Electrochemical Impedance

2021-04-06
2021-01-0747
Impedance is an important parameter of power lithium-ion batteries, which can represent battery characteristics and can also be used as an indicator for battery fault diagnosis. Since Electrochemical Impedance Spectroscopy (EIS) includes various electrode processes and information, it is more significant and worthwhile for lithium-ion batteries research. However, it is quite difficult to attain EIS online because of the nonlinear characteristics of batteries. Therefore, this paper focus on studying the nonlinear impedance characteristics of lithium-ion batteries and proposing a new method to calculate the EIS online based on Fast Fourier Transform (FFT). Data similarity analysis is used to study the influence of resting time, excitation current amplitude, bias current amplitude and the state of charge (SOC) on the impedance quantitatively.
Technical Paper

Research on Charging Strategy of Lithium-ion Battery

2015-04-14
2015-01-1192
Lithium-ion battery charging strategy affects charging time of electric vehicles, energy efficiency of entire vehicle, service life and safety. This paper focuses on the lithium iron phosphate (LiFePO4) battery, based on the battery internal mechanism and the working conditions, taking charging time, effective full-charge capacity and charge energy efficiency as the evaluation indexes. Firstly, through a series of comparative experiments of the constant-current constant-voltage and the constant current charging strategy, the evaluation indexes variations in different temperatures and charging currents have been studied in the paper. By analyzing the respective characteristics of constant current charging phase and constant voltage charging phase in the whole charging process and their own contributions, we have found out the superiority of the constant current charging strategy.
Technical Paper

Recent Progress on In-Situ Monitoring and Mechanism Study of Battery Thermal Runaway Process

2020-04-14
2020-01-0861
Lithium-ion batteries (LIBs) with relatively high energy, power density and eco-friendly characteristic are considered as a vital energy source in consumer market of portable electronics and transportation sector especially in electric vehicles (EVs). To meet the higher capacity requirements, the nickel-rich LIBs with higher capacity has been used as the commercial power batteries. However, the battery with higher energy density is more destructive, which could result in thermal runaway accidents and make the battery safety issues become more and more prominent. Thermal runaway of LIBs is one of the key scientific problems in safety issues. Until now, the inducement of thermal runaway process is complicated which perplex researchers and industry a lot. On the one hand, the internal mechanism about thermal runaway should be deeply studied. On the other hand, in-situ monitoring should be developed to supply the mechanism study and early warning.
Technical Paper

Performance Analysis of Fuel Cells for High Altitude Long Flight Multi-rotor Drones

2024-04-09
2024-01-2177
In recent years, the burgeoning applications of hydrogen fuel cells have ignited a growing trend in their integration within the transportation sector, with a particular focus on their potential use in multi-rotor drones. The heightened mass-based energy density of fuel cells positions them as promising alternatives to current lithium battery-powered drones, especially as the demand for extended flight durations increases. This article undertakes a comprehensive exploration, comparing the performance of lithium batteries against air-cooled fuel cells, specifically within the context of multi-rotor drones with a 3.5kW power requirement. The study reveals that, for the specified power demand, air-cooled fuel cells outperform lithium batteries, establishing them as a more efficient solution.
Technical Paper

Parameter Identification of Battery Pack Considering Cell Inconsistency

2017-03-28
2017-01-1214
Lithium-ion batteries have been applied in the new energy vehicles more and more widely. The inconsistency of battery cells imposes a lot of difficulties in parameter and state estimations. This paper proposes a new algorithm which can online identify the parameters of each individual battery cell accurately with limited increase of computational cost. An equivalent circuit battery model is founded and based on the RLS (recursive least squares) algorithm, an optimization algorithm with the construction of weight vectors is proposed which can identify the parameters of lithium battery pack considering inconsistency of single battery cell. Firstly, the average value of the parameters of the battery pack is identified with the traditional RLS algorithm. Then the ratios between the parameters of each battery cell can be deduced from the mathematical model of battery. These ratios are used to determine the weight vector of each parameter of individual battery cells.
Technical Paper

On-line Lithium-Ion Battery State-of-Power Prediction by Twice Recursive Method Based on Dynamic Model

2019-04-02
2019-01-1311
State-of-Power (SoP) prediction of Li-ion battery is necessary in battery management system for electric vehicles in order to deal with limited conditions, prevent overcharge and over discharge situations, increase the life of the battery and provide effective battery operation. This article suggests a method to on-line predict the 10-s charge and discharge peak power of Li-ion battery by twice recursions. First with the dynamic battery model we use the first recursion based on a least square method to get parameters which are influenced by the state of charge of Li-ion battery and temperature, etc. The dynamic model is an equivalent circuit model. Current and voltage are input online into the battery model. By recursive least square method the parameters are updated in real time. Moreover, when we use a recursive method to get real-time parameters, we add an extra proper factor to abandon old datum, which increases the real-time capability of state-of-power prediction.
Technical Paper

Misfiring Control in Current Cycle at Engine Start Employing Ion Sensing Technology

2009-11-02
2009-01-2713
In this paper a method of misfiring control in current cycle at engine start is presented. With this novel method, the high HC emissions of gasoline engine employed in traditional or hybrid electrical vehicles will be avoided. By the feedback of ion current signal, misfire phenomenon is identified within 30 degrees crank angle after spark plug ignited. Then, the ignition coil will be recharged and the plug sparked again to promote air fuel mixture oxidation and deplete the unburned hydrocarbon produces in exhaust gas. On the other hand, too late ignition will not always result in normal combustion, a kind of reaction similar with slow oxidation also occurs in such case.
Technical Paper

Material Compatibilities of Biodiesels with Elastomers, Metals and Plastics in a Diesel Engine

2009-11-02
2009-01-2799
The effects of biodiesel on the swelling of the elastomers and plastics and the corrosion of metals are studied by the immersion tests. The results indicate that biodiesels make little corrosion effect on aluminum, steel and little swelling impact on plastics, but a significant corrosion may be taken place on cooper and brass for some sourced biodiesels. For nitrile-butadiene rubber, the variation of swelling properties in biodiesels is slightly higher than that in diesel. For the non-diesel-resistant elatomers, the variation of swelling properties is lower than those in diesel. The production process and biodiesel source have an influence on the result of elastomer swelling and corrosion. The relationship between the impact of biodiesel on materials and biodiesels properties are also discussed.
Journal Article

Investigation on the Impact of High-Temperature Calendar and Cyclic Aging on Battery Overcharge Performance

2022-03-29
2022-01-0698
With the degradation of lithium-ion batteries, the battery safety performance changes, which further influences the safe working window. In this paper, the pouch ternary lithium-ion battery whose rated capacity is 4.2 Ah is used as the research object to investigate the impact of the high-temperature calendar and cyclic aging on tolerance performance. The overcharge-to-thermal-runaway test is performed on the fresh cell and aged cell (90% SOH). The inflection point of voltage for aged cells appears earlier than that of the fresh cell, while the voltage corresponding to the inflection point is the same for them, which means that the voltage at which lithium plating occurs is the same. However, the voltage plateau and the crest voltage before thermal runaway of aged cell are significantly higher than that of the fresh cell. Besides, ohmic heat, reversible heat, and side reaction heat make contribution to the thermal runaway triggering.
Journal Article

Investigation on Dynamic Recovery Behavior of Boron Steel 22MnB5 under Austenite State at Elevated Temperatures

2011-04-12
2011-01-1057
Hot forming process of ultrahigh strength boron steel 22MnB5 is widely applied in vehicle industry. It is one of the most effective approaches for vehicle light weighting. Dynamic recovery is the major softening mechanism of the boron steel under austenite state at elevated temperatures. Deformation mechanism of the boron steel can be revealed by investigation on the behavior of dynamic recovery, which could also improve the accuracy of forming simulations for hot stamping. Uniaxial tensile experiments of the boron steel are carried out on the thermo-mechanical simulator Gleeble3800 at elevated temperatures. The true stress-strain curves and the relations between the work hardening rate and flow stress are obtained in different deformation conditions. The work hardening rate decreases linearly with increasing the flow stress.
Technical Paper

Investigation of Factors Controlling the Attainable Equivalent Plastic Strain in the Gauge Region of Cruciform Specimens

2018-04-03
2018-01-0809
The maximum equivalent plastic strain (EPSmax), which can be achieved in the gauge region of a cruciform specimen during in-plane biaxial tensile tests, is limited due to early fracture on the cruciform specimen arm. In this paper, a theoretical model was proposed to determine the factors related to the EPSmax of a cruciform specimen following ISO 16842: 2014. Biaxial tensile tests were carried out to verify the theoretical analyses. Results show that the material strength coefficient (k) has no effect on the EPSmax, and EPSmax increases with the increase of the material hardening exponent (n) and the cross-sectional-area ratio (c) of the arm region to the gauge region. It is found that the applied load ratio (α) has an effect on EPSmax, which decreases as the load ratio increases from 0:1 (i.e. uniaxial tension) to 1:2 (i.e. plane strain state) and then increases as the load ratio increases to 1:1 (i.e. balanced biaxial tension).
Technical Paper

Impedance Modeling and Aging Research of the Lithium-Ion Batteries Using the EIS Technique

2019-04-02
2019-01-0596
As the core component of electric vehicles (EVs), batteries attach increasingly general attention along with the rapid expansion of electric vehicle market. Battery performance effect directly the safety and reliability of the EVs, so its managing technologies are more and more crucial. Among them, the methods of estimating the state of health (SoH) and predicting remaining useful life become the focuses, which are essential to ensure their dependability and optimum performance over time. This paper mainly focuses on impedance modeling and aging research (aging diagnosis and life prediction) of lithium-ion batteries. Electrochemical impedance spectroscopy (EIS) technique is used to obtain impedance characteristic of batteries. On the one hand, equivalent circuit modeling (ECM) can be motivated by EIS, with the goal to fit measured impedance data using circuit elements.
Technical Paper

High Frequency Impedance and Electromagnetic Interference Suppression of Lithium-Ion Power Battery Pack

2019-04-02
2019-01-1060
When electric vehicle speeds up or slows down, rapidly changing current and voltage (di/dt and du/dt) would occurs in its lithium-ion power battery. In this way, the impedance of power battery would changes with parasitic parameters because that the ion transport in electrolytes would influence diffusion effect and polarization effect of battery. Thus, the lithium-ion battery cannot be regarded as ideal component in high frequency, which could cause unpredictable problem in electromagnetic interference (EMI). However, most previous studies took lithium-ion power batteries as disturbed objects or transmission routes, which ignore the electromagnetic interference of battery itself. Based on it, this paper analyses the internal mechanism of EMI in lithium-ion power battery, and simulates the distribution of electromagnetic field as well as it corresponding interference suppression measures. Firstly, the test platform for parameter extraction of battery cell is built.
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