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From the viewpoint of primary energy diversification and CO2 reduction, interests of using Biomass Fuel are rising. Some kinds of FAME (Fatty Acid Methyl Ester), which are obtained from oil fats like vegetable oil using transesterification reaction with methanol, are getting Palm Oilpular for bio-diesel recently. In this study, we have conducted many experiments of palm oil hydrogenations using our pilot plants, and checked the reactivity and the pattern of product yields. As a result, we figured out that the hydrocarbon oil equivalent to the conventional diesel fuel can be obtained from vegetable oils in good yield under mild hydrogenation conditions. Moreover, as a result of various evaluations for the hydrogenated palm oil (oxidation stability, lowtemperature flow property, LCA, etc.), we found that the hydrogenated palm oil by our technology has performances almost equivalent to conventional diesel fuel.

Urea/SCR systems have been proven effective at reducing NOx over a wide range of operating conditions on mid/heavy duty diesel vehicles. However, design changes due to reduction in the size of modern compact Urea/SCR systems and lower exhaust temperature have increased the possibility of urea deposit formation. Urea deposits are formed when urea in films and droplets undergoes undesirable secondary reactions and generate by-products such as ammelide, biuret and cyanuric Acid (CYA). Ammelide and CYA are difficult to decompose which lead to the formation of solid deposits on the surface. This phenomenon degrades the performance of the after treatment system by decreasing overall mixing efficiency, lowering de-NOx efficiency and increasing pressure drop. Therefore, mitigating urea deposits is a primary design goal of modern diesel after-treatment systems.

An estimation model which uses the gross heat release data and the fuel energy to estimate the total amount of emissions and unburned Hydro Carbon (HC) is developed. Gross heat release data is calculated from a self-tuned heat release method which uses in-cylinder pressure data for computing the energy released during combustion. The method takes all heat and mass losses into account. The method estimates the polytropic exponent and pressure offset during compression and expansion using a nonlinear least square method. Linear interpolation of polytropic exponent and pressure offset is then performed during combustion to calculate the gross heat release during combustion. Moreover the relations between the emissions specifically HC and Carbon Monoxide (CO) are investigated. The model was validated with experimental data and promising results were achieved.

This paper presents typical flow structures around a 60%-scale wind-tunnel model of a Formula One (F1) car, using planar particle image velocimetry (PIV). The customized PIV system is permanently installed in a wind tunnel to help aerodynamicists in the development loop. The PIV results enhance the understanding of the mean velocity field in the two-dimensional plane in some important areas of the car, such as the front-wheel wake and the underfloor flow. These real phenomena obtained in the wind tunnel also help maintain the accuracy of simulations using computational fluid dynamics (CFD) by allowing regular checking of the correlation with the real-world counterpart. This paper first surveys recent literature on unique flow structures around the rotating exposed wheel, mostly that on the isolated wheel, and then gives the background to F1 aerodynamics in the late 2000s.

Phosphor thermometry was used during fuel injection in an optical engine with the glass piston of reentrant type. SiO2 coated phosphor particle was used for the gas-phase temperature measurements, which gave much less background signal. The measurements were performed in motored mode, in combustion mode with injection of n-heptane and in non-combustion mode with injection of iso-octane. In the beginning of injection period, the mean temperature of each injection cases was lower than that of the motored case, and temperature of iso-octane injection cases was even lower than that of n-heptane injection cases. This indicates, even if vaporization effect seemed to be the same at both injection cases, the effect of temperature decrease changed due to the chemical reaction effect for the n-heptane cases. Chemical reaction seems to be initiated outside of the fuel liquid spray and the position was moving towards the fuel rich area as the time proceeds.

An experiment was conducted to investigate the effect of charge stratification on the combustion phasing in a single cylinder, heavy duty (HD) compression ignition (CI) engine. To do this the start of injection (SOI) was changed from -180° after top dead centre (ATDC) to near top dead centre (TDC) during which CA50 (the crank angle at which 50% of the fuel energy is released) was kept constant by changing the intake temperature. At each SOI, the response of CA50 to a slight increase or decrease of either intake temperature or SOI were also investigated. Afterwards, the experiment was repeated with a different intake oxygen concentration. The results show that, for the whole SOI period, the required intake temperature to keep constant CA50 has a “spoon” shape with the handle on the -180° side.

Partially premixed combustion (PPC) is a promising way to achieve high efficiency and low engine-out emissions simultaneously in a heavy-duty engine. Compared to Homogeneous Charge Compression Ignition (HCCI), it can be controlled by injection events and much lower HC and CO emissions can be achieved. This work focuses on the transition from HCCI to PPC and combustion and emissions characteristics during the process are investigated. Injection strategies, EGR and boost pressure were the main parameters used to present the corresponding effect during the transition.

In order to reduce fine particle emission, a diesel particulate filter (DPF) has begun to be equipped to a diesel engine. During regeneration of DPF, nanoparticles are known to be formed downstream of DPF. VOCs emission during regeneration is of interest in view of toxicity and formation mechanism of nanoparticles. A heavy duty diesel engine equipped with DPF was investigated to measure particle and VOCs emissions using PTR-TOFMS (Proton Transfer Reaction - Time of Flight Mass Spectrometer). PTR-TOFMS is a new on-line mass spectrometer using chemical ionization and its application to engine exhaust measurements is new. During active regeneration of the DPF, fine particle emission was increased by nucleation. But VOCs as well as THC emissions increased prior to particle increase. After the regeneration the particle and VOCs emissions decreased immediately to the level of normal operation.

Exhaust emissions are well known to have adverse impacts on human health. Studies have demonstrated that there is an association between ambient particulate matter (PM) levels and various harmful cardiopulmonary conditions. Soot exhaust from diesel engines can be a significant contributor to airborne pollutants. A key component in PM level control for a diesel engine is a diesel particulate filter (DPF). This device traps soot while allowing other exhaust gases to pass unhindered. However, the performance of diesel particulate filters can change with increasing soot loadings and thus may require regeneration or replacement. Improved understanding of diesel particulate filters is dependent upon the knowledge of the actual soot loading and the soot distribution within the DPF. Neutron radiography (NR) has been identified as an effective means of non-destructively identifying hydrogen or carbon adsorbed in PM.

The double compression expansion engine (DCEE) is a promising concept for high engine efficiency while fulfilling the most stringent European and US emission legislation. The complete thermodynamic cycle of the engine is split among several cylinders. Combustion of fuel occurs in the combustion cylinder and in the expansion cylinder the exhaust gases are over expanded to obtain high efficiency. A high-pressure tank is installed between these two cylinders for after-treatment purposes. One proposal is to utilize thermal reduction of nitrogen oxides (NOx) in the high-pressure tank as exhaust temperatures can be sufficiently high (above 700 °C) for the selective non-catalytic reduction (SNCR) reactions to occur. The exhaust gas residence time at these elevated exhaust temperatures is also long enough for the chemical reactions, as the volume of the high-pressure tank is substantially larger than the volume of the combustion cylinders.

Partially premixed combustion has the potential of high efficiency and simultaneous low soot and NOx emissions. Running the engine in PPC mode with high octane number fuels has the advantage of a longer premix period of fuel and air which reduces soot emissions, even at higher loads. The problem is the ignitability at low load and idle operating conditions. The objective is to investigate the usefulness of negative valve overlap on a light duty diesel engine running with gasoline partially premixed combustion at low load operating conditions. The idea is to use negative valve overlap to trap hot residual gases to elevate the global in-cylinder temperature to promote auto-ignition of the high octane number fuel. This is of practical interest at low engine speed and load operating conditions because it can be assumed that the available boost is limited. The problem with NVO at low load operating conditions is that the exhaust gas temperature is low.

Selective Non-Catalytic Reduction (SNCR), used to reduce the emissions of nitrogen oxides (NOx), has been a well-established technology in the power plant industry for several decades. The SNCR technique is an aftertreatment strategy based on thermal reduction of NOx at high temperatures. In the compression ignition engine application, the technology has not been applicable due to low exhaust temperatures, which makes the SCR (Selective Catalytic Reduction) system essential for efficient nitrogen oxide reduction to fulfill the environment legislation. For a general Double Compression Expansion Engine (DCEE) the complete expansion cycle is split in two separate cycles, i.e. the engine is a split cycle engine. In the first cylinder the combustion occurs and in the second stage the combustion gas is introduced and further expanded in a low-pressure expansion cylinder. The combustion cylinder is connected with the expansion cylinder through a large insulated high-pressure tank.

Hydrogen can be produced by electrolyzation with renewable electricity and the combustion products of hydrogen mixture include no CO, CO2 and hydrocarbons. In this study, engine performance with hydrogen / diesel dual fuel (hydrogen DDF) operation in a multi-cylinder diesel engine is investigated due to clarify advantages and disadvantages of hydrogen DDF operation. Hydrogen DDF operation under several brake power conditions are evaluated by changing a rate of hydrogen to total input energy (H2 rate). As H2 rate is increased, an amount of diesel fuel is decreased to keep a given torque constant. When the hydrogen DDF engine is operated with EGR, Exhaust gas components including carbon are improved or suppressed to same level as conventional diesel combustion. In addition, brake thermal efficiency is improved to 40% by increase in H2 rate that advances combustion phasing under higher power condition. On the other hand, NOx emission is much higher than one of conventional diesel engine.

In an effort to reduce CO2 emissions, governments are increasingly mandating the use of various levels of biofuels. While this is strongly supported in principle within the energy and transportation industries, the impact of these mandates on the transport stock’s CO2 emissions and overall operating efficiency has yet to be fully explored. This paper provides information on studies to assess biodiesel influences and effects on engine performance, driveability, emissions and fuel consumption on state-of-the-art Euro IV compliant Toyota Avensis D4-D vehicles with DPNR aftertreatment systems. Two fuel matrices (Phases 1 & 2) were designed to look at the impact of fuel composition on vehicle operation using a wide range of critical parameters such as cetane number, density, distillation and biofuel (FAME) level and type, which can be found within the current global range of Diesel fuel qualities.

Heavy-duty direct injection compression ignition (DICI) engine running on methanol is studied at a high compression ratio (CR) of 27. The fuel is injected with a common-rail injector close to the top-dead-center (TDC) with two injection pressures of 800 bar and 1600 bar. Numerical simulations using Reynold Averaged Navier Stokes (RANS), Lagrangian Particle Tracking (LPT), and Well-Stirred-Reactor (WSR) models are employed to investigate local conditions of injection and combustion process to identify the mechanism behind the trend of increasing nitrogen oxides (NOx) emissions at higher injection pressures found in the experiments. It is shown that the numerical simulations successfully replicate the change of ignition delay time and capture variation of NOx emissions.

Since ethanol is a renewable source of energy and it contributes to lower CO2 emissions, ethanol produced from biomass is expected to increase in use as an alternative fuel. It is recognized that for spark ignition (SI) engines ethanol has advantages of high octane number and high combustion speed and has a disadvantage of difficult startability at low temperature. This paper investigates the influence of ethanol fuel on SI engine performance, thermal efficiency, and emissions. The combustion characteristics under cold engine conditions are also examined. Ethanol has high anti-knock quality due to its high octane number, and high latent heat of evaporation, which decreases the compressed gas temperature during the compression stroke. In addition to the effect of latent heat of evaporation, the difference of combustion products compared with gasoline further decreases combustion temperature, thereby reducing cooling heat loss.

In the quest for efficiency improvement in heavy duty truck engines, waste heat recovery could play a valuable role. The evaporative cycle is a waste heat recovery technology aimed at improving efficiency and decreasing emissions. A humid air motor (HAM) uses the waste heat from the exhaust of the engine to humidify the inlet air; this humid air, with higher specific heat, reduces NOx emission to a greater extent [1] [2]. Despite this benefit of emission reduction, the increase or decrease in efficiency of the humid air motor compared to the conventional engine is not discussed in the literature [3] [4] [5]. In this paper, an attempt is made to study the efficiency of the HAM using system model simulations of a 13-liter heavy duty Volvo engine with a humidifier. The commercial software GT-SUITE is used to build the system model and to perform the simulations. The efficiency improvement of the HAM comes from the expansion of the vapor mass flow produced as a result of humidification.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).

In order to determine the main factors causing the mileage-related increase in formaldehyde emission from methanol-fueled vehicles, mileage was accumulated on three types of vehicle, each of which had a different air-fuel calibration system. From exhaust emission data obtained during and after the mileage accumulation, it was found that lean burn operation resulted in by far the highest formaldehyde emission increase. An investigation into the reason for the rise in engine-out formaldehyde emission revealed that deposits in the combustion chamber emanating from the lubricating oil promotes formaldehyde formation. Furthermore it was learnt that an increase in engine-out NOx emissions promotes partial oxidation of unburned methanol in the catalyst, leading to a significant increase in catalyst-out formaldehyde emission.