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A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

As connected and automated vehicle technologies emerge and proliferate, lower frequency vehicle trajectory data is becoming more widely available. In some cases, entire fleets are streaming position, speed, and telemetry at sample rates of less than 10 seconds. This presents opportunities to apply powertrain simulators such as the National Renewable Energy Laboratory’s Future Automotive Systems Technology Simulator to model how advanced powertrain technologies would perform in the real world. However, connected vehicle data tends to be available at lower temporal frequencies than the 1-10 Hz trajectories that have typically been used for powertrain simulation. Higher frequency data, typically used for simulation, is costly to collect and store and therefore is often limited in density and geography. This paper explores the suitability of lower frequency, high availability, connected vehicle data for detailed powertrain simulation.

In response to more stringent emission requirements, catalysts for reducing NO to molecular nitrogen were developed. One of the most promising of these, the three-way catalyst, has been the subject of an EPA study to determine if it produces new tailpipe contaminants. This study and its results are described.

The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.

The key hurdles to achieving wide consumer acceptance of battery electric vehicles (BEVs) are weather-dependent drive range, higher cost, and limited battery life. These translate into a strong need to reduce a significant energy drain and resulting drive range loss due to auxiliary electrical loads the predominant of which is the cabin thermal management load. Studies have shown that thermal sub-system loads can reduce the drive range by as much as 45% under ambient temperatures below −10 °C. Often, cabin heating relies purely on positive temperature coefficient (PTC) resistive heating, contributing to a significant range loss. Reducing this range loss may improve consumer acceptance of BEVs. The authors present a unified thermal management system (UTEMPRA) that satisfies diverse thermal and design needs of the auxiliary loads in BEVs.

Due to its high efficiency and superior durability the diesel engine is again becoming a prime candidate for future light-duty vehicle applications within the United States. While in Europe the overall diesel share exceeds 40%, the current diesel share in the U.S. is 1%. Despite the current situation and the very stringent Tier 2 emission standards, efforts are being made to introduce the diesel engine back into the U.S. market. In order to succeed, these vehicles have to comply with emissions standards over a 120,000 miles distance while maintaining their excellent fuel economy. The availability of technologies such as high-pressure common-rail fuel systems, low sulfur diesel fuel, NOx adsorber catalysts (NAC), and diesel particle filters (DPFs) allow the development of powertrain systems that have the potential to comply with the light-duty Tier 2 emission requirements. In support of this, the U.S.

The use of advanced electron microscopy techniques to characterize both the bulk and near-atomic level microstructural evolution of catalyst materials during different dynamometer/vehicle aging cycles is an integral part of understanding catalyst deactivation. The study described here was undertaken to evaluate thermally-induced microstructural changes which caused the progressive loss of catalyst performance in a three-way automotive catalyst. Several different catalyst processing variables, for example changing the washcoat ceria content, were also evaluated as a function of aging cycle and thermal history. A number of thermally-induced microstructural changes were identified using high resolution electron microscopy techniques that contributed to the deactivation of the catalyst, including sintering of all washcoat constituents, γ-alumina transforming to α-, β-, and δ-alumina, precious metal redistribution, and constituent encapsulation.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

In this paper, researchers at the National Renewable Energy Laboratory present the results of simulation studies to evaluate potential fuel savings as a result of improvements to vehicle rolling resistance, coefficient of drag, and vehicle weight as well as hybridization for four powertrains for medium-duty parcel delivery vehicles. The vehicles will be modeled and simulated over 1,290 real-world driving trips to determine the fuel savings potential based on improvements to each technology and to identify best use cases for each platform. The results of impacts of new technologies on fuel saving will be presented, and the most favorable driving routes on which to adopt them will be explored.

Methylcyclopentadienylmanganese tricarbonyl (MMT) while originally marketed in the late 50's and early 60's as a secondary antiknock to leaded fuels, is presently being marketed as a primary antiknock targeted for the EPA required lead-free gasoline grade tailored for use in catalyst-equipped vehicles. This paper reviews and discusses new information related to the effect of manganese gasoline additives on the performance of catalysts, regulated emissions, and several currently unregulated emissions. In addition, estimates of human exposures to automotive-generated manganese particulate and the toxicological characteristics of manganese are discussed as they related to an assessment of the potential public health consequences should manganese additives come into widespread use. EPA's position regarding the use of manganese additives is presented and discussed.

Regulated emissions (THC, CO, NOx, and PM) and particulate SOF and sulfate fractions were determined for a 1995 Detroit Diesel Series 50 urban bus engine at varying fuel sulfur levels, with and without catalytic converters. When tested on EPA certification fuel without an oxidation catalyst this engine does not appear to meet the 1994 emissions standards for heavy duty trucks, when operating at high altitude. An ultra-low (5 ppm) sulfur diesel base stock with 23% aromatics and 42.4 cetane number was used to examine the effect of fuel sulfur. Sulfur was adjusted above the 5 ppm level to 50, 100, 200, 315 and 500 ppm using tert-butyl disulfide. Current EPA regulations limit the sulfur content to 500 ppm for on highway fuel. A low Pt diesel oxidation catalyst (DOC) was tested with all fuels and a high Pt diesel oxidation catalyst was tested with the 5 and 50 ppm sulfur fuels.

The U.S. Environmental Protection Agency (EPA) contracted with FEV, Inc. to estimate the per-vehicle cost of employing selected advanced efficiency-improving technologies in light-duty motor vehicles. The development of transparent, reliable cost analyses that are accessible to all interested stakeholders has played a crucial role in establishing feasible and cost effective standards to improve fuel economy and reduce greenhouse gas (GHG) emissions. The FEV team, together with engineering staff from EPA's National Vehicle and Fuel Emissions Laboratory, and FEV's subcontractor, Munro & Associates, developed a robust costing methodology based on tearing down, to the piece part level, relevant systems, sub-systems, and assemblies from vehicles ?with and without? the technologies being evaluated.

The U.S. Environmental Protection Agency (EPA) contracted with FEV, Inc. to estimate the per-vehicle cost of employing selected advanced efficiency-improving technologies in light-duty motor vehicles. The development of transparent, reliable cost analyses that are accessible to all interested stakeholders has played a crucial role in establishing feasible and cost effective standards to improve fuel economy and reduce greenhouse gas (GHG) emissions. The FEV team, together with engineering staff from EPA's National Vehicle and Fuel Emissions Laboratory, and FEV's subcontractor, Munro & Associates, developed a robust costing methodology based on tearing down, to the piece part level, relevant systems, sub-systems, and assemblies from vehicles “with and without” the technologies being evaluated.

This paper discusses the systems used by the Office of Mobile Source Air Pollution Control of EPA to measure and analyze automotive sulfuric acid emissions. This system involves mixing the entire vehicle exhaust with dilution air in a dilution tunnel. Sulfuric acid samples are collected by passing a small portion of the dilute exhaust through Fluoropore filters. The sulfuric acid content of the filters is determined by an automated barium chloranilate method. This paper also discusses test results from a number of advanced prototype vehicles including two stratified charge cars, a Dresser carburetor vehicle, three dual catalyst cars, and a 3-way catalyst car.

The Advanced Petroleum-Based Fuels - Diesel Emissions Control (APBF-DEC) project is a joint U.S. government/industry research effort to identify optimal combinations of fuels, lubricants, engines, and emission control systems to meet projected emissions regulations during the period 2000 to 2010. APBF-DEC is conducting five separate projects involving light- and heavy-duty engine platforms. Four projects are focusing on the performance of emission control technologies for reducing criteria emissions using different fuels. This project is investigating the effects of lubricant formulation on engine-out emissions (Phase I) and the resulting impact on emission control systems (Phase II). This paper describes the statistical design and analysis methods used during Phase I of the lubricants project.

EPA published the first results from evaluations of electrically heated catalyst (EHC) technology for light-duty automotive applications. Since then, a number of automakers, suppliers, and government agencies have published results from their heated catalyst development and evaluation programs. EPA has evaluated a number of start catalyst systems incorporating an EHC start catalyst followed by a larger, conventional main catalyst. These systems have proven very effective at reducing cold start related emissions from methanol vehicles at low mileage. This paper compares the results from several EHC + main catalyst evaluations conducted by EPA.

Oxidative degradation of biodiesel under accelerated conditions has been examined by Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR), and gravimetric measurement of deposit formation. The formation of gums and deposits caused by oxidation in storage or in an engine fuel system is a significant issue because of the potential for fuel pump and injector fouling. The results of this study indicate several important pathways for degradation and two pathways leading to formation of oligomers and, ultimately, deposits. Peroxides formed in the initial stage of oxidation can decompose to form aldehydes, ketones, and acids. These can react further in aldol condensation to form oligomers. Additionally, peroxides can react with fatty acid chains to form dimers and higher oligomers. Deposits form when the polarity and molecular weight of these oligomers is high enough.

It is widely understood that cold ambient temperatures increase vehicle fuel consumption due to heat transfer losses, increased friction (increased viscosity lubricants), and enrichment strategies (accelerated catalyst heating). However, relatively little effort has been dedicated to thoroughly quantifying these impacts across a large set of real world drive cycle data and ambient conditions. This work leverages experimental dynamometer vehicle data collected under various drive cycles and ambient conditions to develop a simplified modeling framework for quantifying thermal effects on vehicle energy consumption. These models are applied over a wide array of real-world usage profiles and typical meteorological data to develop estimates of in-use fuel economy. The paper concludes with a discussion of how this integrated testing/modeling approach may be applied to quantify real-world, off-cycle fuel economy benefits of various technologies.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

Mixing controlled compression ignition, i.e., diesel engines are efficient and are likely to continue to be the primary means for movement of goods for many years. Low-net-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could have advantageous properties for combustion, such as high cetane number and reduced engine-out particle and NOx emissions. We developed a list of over 400 potential biomass-derived diesel blendstocks and populated a database with the properties and characteristics of these materials. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a blendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number ≥40, flashpoint ≥52°C, and boiling point or T90 ≤338°C.