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Technical Paper

The Effect of Diesel Sulfur Content and Oxidation Catalysts on Transient Emissions at High Altitude from a 1995 Detroit Diesel Series 50 Urban Bus Engine

1996-10-01
961974
Regulated emissions (THC, CO, NOx, and PM) and particulate SOF and sulfate fractions were determined for a 1995 Detroit Diesel Series 50 urban bus engine at varying fuel sulfur levels, with and without catalytic converters. When tested on EPA certification fuel without an oxidation catalyst this engine does not appear to meet the 1994 emissions standards for heavy duty trucks, when operating at high altitude. An ultra-low (5 ppm) sulfur diesel base stock with 23% aromatics and 42.4 cetane number was used to examine the effect of fuel sulfur. Sulfur was adjusted above the 5 ppm level to 50, 100, 200, 315 and 500 ppm using tert-butyl disulfide. Current EPA regulations limit the sulfur content to 500 ppm for on highway fuel. A low Pt diesel oxidation catalyst (DOC) was tested with all fuels and a high Pt diesel oxidation catalyst was tested with the 5 and 50 ppm sulfur fuels.
Technical Paper

Portable Emissions Measurement for Retrofit Applications – The Beijing Bus Retrofit Experience

2008-06-23
2008-01-1825
In 2005, the United States Environmental Protection Agency (EPA) and Southwest Research Institute (SwRI) embarked on a mission to help the city of Beijing, China, clean its air. Working with the Beijing Environmental Protection Bureau (BEPB), the effort was a pilot diesel retrofit demonstration program involving three basic retrofit technologies to reduce particulate matter (PM). The three basic technologies were the diesel oxidation catalyst (DOC), the flowthrough diesel particulate filter (FT-DPF), and the wallflow diesel particulate filter (WF-DPF). The specific retrofit systems selected for the project were verified through the California Air Resources Board (CARB) or the EPA verification protocol [1]. These technologies are generally verified for PM reductions of 20-40 percent for DOCs, 40-50 percent for the FT-DPF, and 85 percent or more for the high efficiency WF-DPF.
Technical Paper

Performance of Partial Flow Sampling Systems Relative to Full Flow CVS for Determination of Particulate Emissions under Steady-State and Transient Diesel Engine Operation

2002-05-06
2002-01-1718
The use of a partial flow sampling system (PFSS) to measure nonroad steady-state diesel engine particulate matter (PM) emissions is a technique for certification approved by a number of regulatory agencies around the world including the US EPA. Recently, there have been proposals to change future nonroad tests to include testing over a nonroad transient cycle. PFSS units that can quantify PM over the transient cycle have also been discussed. The full flow constant volume sampling (CVS) technique has been the standard method for collecting PM under transient engine operation. It is expensive and requires large facilities as compared to a typical PFSS. Despite the need for a cheaper alternative to the CVS, there has been a concern regarding how well the PM measured using a PFSS compared to that measured by the CVS. In this study, three PFSS units, including AVL SPC, Horiba MDLT, and Sierra BG-2 were investigated in parallel with a full flow CVS.
Technical Paper

Inspection/Maintenance in the 1990's

1987-08-01
870621
In the 1990's there will be a different mix of vehicle technologies than existed in the late 1970's when inspection/Maintenance (I/M) programs were first mandated. These changes include the widespread use of “closed-loop” computer control of engine parameters and fuel injection. Several studies by EPA are examined to determine the effect of these changes on existing I/M programs and to investigate new methods of vehicle inspection. The report discusses the effectiveness of a standard idle emission test versus other inspection methods, the role of proper preconditioning, self-diagnostic trouble code checks as a method to identify high emitting vehicles, uncertainties in predicting tampering and misfueling rates for the future, problems with decentralized programs, and the effectiveness of I/M repairs in reducing vehicle emissions as measured on the Federal Test Procedure.
Technical Paper

In-Use Emissions of 1980 and 1981 Passenger Cars: Results of EPA Testing

1982-02-01
820975
This paper presents the results of several emission testing programs conducted by the U.S. Environmental Protection Agency. The test vehicles were primarily 1980 and 1981 passenger cars which were obtained at random from private owners. Some 1982 models were also tested. The 1328 vehicles were selected from the Los Angeles area as well as from a number of other low-altitude locations. The test sequence included the Federal Test Procedure, the Highway Fuel Economy Test and several short cycle tests. The primary purpose of the program was to gather information on current vehicles which could be used in calculations and projections of air quality and aid development of programs to improve it. The results of the program indicate that these vehicles are capable of maintaining low emission levels although high levels are also possible due to defects, deterioration, or tampering. Inspection/Maintenance programs are a feasible and effective means for correcting high levels when they occur.
Technical Paper

Identifying Excess Emitters with a Remote Sensing Device: A Preliminary Analysis

1991-08-01
911672
There has been considerable interest in applying remote measuring methods to sample in-use vehicle emissions, and to characterize fleet emission behavior. A Remote Sensing Device (RSD) was used to measure on-road carbon monoxide (CO) emissions from approximately 350 in-use vehicles that had undergone transient mass emission testing at a centralized I/M lane. On-road hydrocarbon (HC) emissions were also measured by the RSD on about 50 of these vehicles. Analysis of the data indicates that the RSD identified a comparable number of the high CO emitters as the two speed I/M test only when an RSD cutpoint much more stringent than current practice was used. Both RSD and I/M had significant errors of omission in identifying High CO Emitters based on the mass emission test. The test data were also used to study the ability of the RSD to characterize fleet CO emissions.
Technical Paper

Exhaust Emissions from In-Use Passenger Cars Equipped with Three-Way Catalysts

1980-06-01
800823
This paper presents the results of an exhaust emission testing program conducted by the U.S. Environmental Protection Agency. The test vehicles were 1978–1980 passenger cars of various makes and models. Each of the 686 vehicles tested was equipped with a three-way catalyst system and was certified to California standards. The purpose of the program was to gather information on current systems in customer use for projections on the ability of the three-way system to meet emission standards of the future. The results indicate that these systems are capable of achieving low emission levels although high levels are also possible due to defects, deterioration, or tampering.
Technical Paper

Exhaust Emissions from Heavy-Duty Trucks Tested on a Road Course and by Dynamometer

1975-02-01
750901
This is a summary compilation and analysis of exhaust-emission results and operating parameters from forty-five heavy-duty gasoline and diesel-powered vehicles tested over a 7.24-mile road course known as the San Antonio Road Route (SARR); and, for correlative purposes, on a chassis dynamometer.(2) Exhaust samples were collected and analyzed using the Constant Volume Sampler (CVS) technique similar to that used in emission testing of light-duty vehicles. On the road course, all equipment and instrumentation were located on the vehicle while electrical power was supplied by a trailer-mounted generator. In addition to exhaust emissions, operating parameters such as vehicle speed, engine speed, manifold vacuum, and transmission gear were simultaneously measured and recorded on magnetic tape. The forty-five vehicles tested represent various model years, GVW ratings, and engine types and sizes.
Technical Paper

Evaluation of Emission Control Technology Approaches for Heavy-Duty Gasoline Engines

1978-02-01
780646
This paper summarizes a laboratory effort toward reducing nine-mode cycle composite emissions and fuel consumption in a heavy-duty gasoline engine, while retaining current durability performance. Evaluations involved standard carburetors, a Dresserator inductor, a Bendix electronic fuel injection system, exhaust manifold thermal reactors, and exhaust gas recirculation, along with other components and engine operating parameters. A system consisting of electronic fuel injection, thermal reactors with air injection and exhaust gas recirculation, was assembled which met specified project goals. An oxidation catalyst was included as an add-on during the service accumulation demonstration. In addition, the driveability of this engine configuration was demonstrated.
Technical Paper

Emissions from Catalyst Cars Beyond 50 000 Miles and the Implications for the Federal Motor Vehicle Control Program

1978-02-01
780027
High mileage vehicles (in excess of 50,000 miles) contribute more than half of all vehicular emissions. With the new catalytic converter equipped cars, the proportional contribution of these vehicles may be even higher than for pre-catalyst vehicles. Thus a substantial portion of motor vehicle related air pollution may be caused by vehicles not subject to the manufacturer directed provisions of the Clean Air Act. This paper presents a modeling effort based on hypotheses and some preliminary data, and suggests some alternatives to combat this potential problem.
Technical Paper

Effect of Engine Condition on FTP Emissions and In-Use Repairability

1992-02-01
920822
Twenty in-use vehicles that had failed the I/M test in the State of Michigan were inspected for engine mechanical condition as well as the state of the emission control system. Mass emission tests were conducted before and after repairs to the emission control system. The internal engine condition (i.e., high or low levels of cylinder leakage, or compression difference) showed little effect on the ability of the repaired vehicles to achieve moderate mass emission levels. Nine of the twenty vehicles were recruited after three years, and with the exception of tampering, the original emission control system repairs proved to be durable.
Journal Article

Disassembly of Small Engine Catalytic Converters and Analysis of Washcoat Material for Platinum Group Metals by X-Ray Fluorescence Spectrometry

2014-06-02
2014-01-9078
The United States Environmental Protection Agency (U.S. EPA) National Enforcement Investigations Center (NEIC) has developed a test method for the analysis of washcoat material in small engine catalytic converters. Each small engine catalytic converter contains a metallic monolith. Each metallic monolith is removed from its outer casing, manually disassembled, and then separated into washcoat and substrate. The washcoat material is analyzed for platinum group metals (PGMs) using X-ray fluorescence (XRF) spectrometry. Results from the XRF analysis are used to calculate PGM ratios in the washcoat. During monolith disassembly, care is taken to minimize loss of washcoat or substrate, but some material is inevitably lost. The recovered washcoat mass does not necessarily equal the quantity of washcoat that was present in the intact catalytic converter.
Journal Article

Development of Greenhouse Gas Emissions Model (GEM) for Heavy- and Medium-Duty Vehicle Compliance

2015-09-29
2015-01-2771
In designing a regulatory vehicle simulation program for determining greenhouse gas (GHG) emissions and fuel consumption, it is necessary to estimate the performance of technologies, verify compliance with the regulatory standards, and estimate the overall benefits of the program. The agencies (EPA/NHTSA) developed the Greenhouse Gas Emissions Model (GEM) to serve these purposes. GEM is currently being used to certify the fuel consumption and CO2 emissions of the Phase 1 rulemaking for all heavy-duty vehicles in the United States except pickups and vans, which require a chassis dynamometer test for certification. While the version of the GEM used in Phase 1 contains most of the technical and mathematical features needed to run a vehicle simulation, the model lacks sophistication. For example, Phase 1 GEM only models manual transmissions and it does not include engine torque interruption during gear shifting.
Technical Paper

Detection of Catalyst Failure On-Vehicle Using the Dual Oxygen Sensor Method

1991-02-01
910561
On-vehicle proof-of-concept testing was conducted to evaluate the ability of the dual oxygen sensor catalyst evaluation method to identify serious losses in catalyst efficiency under actual vehicle operating conditions. The dual oxygen sensor method, which utilizes a comparison between an upstream oxygen sensor and an oxygen sensor placed downstream of the catalyst, was initially studied by the Environmental Protection Agency (EPA) under steady-state operating conditions on an engine dynamometer and reported in Clemmens, et al. (1).* At the time that study was released, questions were raised as to whether the technological concepts developed on a test fixture could be transferred to a vehicle operating under normal transient conditions.
Technical Paper

Compound Injection to Assure the Performance of Motor Vehicle Emissions Sampling Systems

1996-05-01
961118
There are many sources of variability when sampling motor vehicle emissions, including intermittant losses to “wetted” sampling system surfaces if water condensation occurs and thermal decomposition if sampling system surfaces get excessively hot. The risk of losses varies during typical transient speed emissions tests and depends upon many variables such as temperature, pressure, exhaust dilution ratio, dilution air humidity, fuel composition, and emissions composition. Procedures are described for injection of known concentrations of compounds of interest into transient motor vehicle exhaust for the purpose of characterizing losses between the vehicle tailpipe and emissions analyzer.
Technical Paper

Catalysts for Methanol Vehicles

1987-11-01
872052
A Methanol catalyst test program has been conducted in two phases. The purpose of Phase I was to determine whether a base metal or lightly-loaded noble metal catalyst could reduce Methanol engine exhaust emissions with an efficiency comparable to conventional gasoline engine catalytic converters. The goal of Phase II was the reduction of aldehyde and unburned fuel emissions to very low levels by the use of noble metal catalysts with catalyst loadings higher than those in Phase I. Catalysts tested in Phase I were evaluated as three-way converters as well as under simulated oxidation catalyst conditions. Phase II catalysts were tested as three-way converters only. For Phase I, the most consistently efficient catalysts over the range of pollutants measured were platinum/rhodium configurations. None of the catalysts tested in Phase I were able to meet a NOx level of 1 gram per mile when operated in the oxidation mode.
Technical Paper

A Quality Control Technique for Correlating Exhaust Gas Analysis Systems

1977-02-01
770138
A simple, inexpensive, critical flow blender has been developed for filling a tedlar bag with controllable concentrations of HC, NOx, CO2, and CO gases at levels encountered in automobile emissions testing. According to a daily schedule, a technician takes the bag to all analyzer sites in the laboratory for analysis. The concentrations indicated by each site are compared to the overall averages. The results are stored in a computerized data base from which control charts, statistical analyses, and interpretations of significant differences among test sites can be made. The precision, accuracy, and statistical interpretations of the data are discussed.
Technical Paper

42 Catalytic Reduction of Marine Sterndrive Engine Emissions

2002-10-29
2002-32-1811
A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.
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