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A commercial NOx-storage catalyst for gasoline applications containing Ba/CeO2/Al2O3, platinum, palladium and rhodium has been sulfated on the engine bench at 390 and 510°C with a nominal exposure of 1.3 g sulfur/liter catalyst. Lower exposures proved too low to have a notable impact on the catalytic performance. At 390°C the sulfur is completely adsorbed while at 510°C only partial adsorption is being observed. Sulfur is mainly deposited at the catalyst inlet thereby shielding the downstream region. Desulfation on synthetic gas bench at 700°C leads to a partial removal of the sulfur. The residual sulfur is more evenly distributed along the length of the catalyst compared to the sulfur profile in the sulfated catalyst. This causes an improvement of the NOx-activity at the inlet side while the NOx-performance at the outlet side decreases after desulfation.

The introduction of vehicle emission and fuel economy standards (CO2) accelerates the introduction of new platform and powertrain combinations into the market place. All of these combinations will require unique exhaust gas aftertreatment systems that comply with the current emission legislation. The optimization of each unique aftertreatment solution requires the proper application of catalyst technologies at the lowest PGM concentrations. The optimization process needs to be fast, reliable, realistic and cost attractive. It is arguable that performing the aftertreatment optimization on a chassis dynamometer is variable, time consuming and expensive. This work demonstrates how a synthetic gas bench (SGB) can be used to simulate stoichiometric engine emissions and aftertreatment performance. The SGB procedure duplicates the vehicle NEDC engine-out emissions and catalyst heat-up profiles.

Within the framework of the French research program PREDIT, a study was undertaken by ADEME, IFP, LGRE, PSA Peugeot Citroën and Umicore, whose main objective was a better understanding of the NOx storage and reduction phenomena on an aged, sulfated and desulfated NOx-trap. The target of this work was to use the information on catalyst working conditions to optimize catalyst management for a gasoline direct injection engine. The catalysts were characterized on both engine and synthetic gas benches. Aging and poisoning phenomena were studied and a variety of different chemical analytical tools were used. The behavior of two different thermally aged cores was investigated under rich conditions on a synthetic gas test bench. The dependence of the NOx regeneration efficiency of the traps is reported for several operating parameters, including reductant concentrations, durations of the rich pulse and trap loadings.

To meet future emission levels, the automotive industry is trying to reduce tailpipe emissions through both possible pathways, i.e. emission from engines as well as and the development of novel catalytic emission control concepts. The present study will focus on the close coupled SCR on Filter commonly known as SDPF which is a main pathway to reduce NOx along with particulate mass and number for light duty passenger cars and sport utility vehicles for BS 6 RDE/OBD 2 and future legislation like BS-7. The SDPF is a challenging technology as it is critical component in exhaust after treatment system involving in NOx and PM/PN reductions hence careful optimization of this technology is necessary in terms of space velocity requirements, temperature, feed NOx emission levels, particulate mass and ash holding capacities, NH3 storage on the SDPF, and back pressure.

Catalyzed diesel particulate filter systems have now been successfully introduced and implemented in Europe. In the meantime, automotive manufacturers are working on the second generation of catalytic filters with the aim of reducing the overall system costs. In particular savings in precious metal costs are focussed by the use of highly-active catalysts which are stable at high temperatures. A possible approach here is the implementation of oxidation catalysts and catalytically coated filters based on platinum and palladium. In this context, the functio-nality of platinum/palladium-based, catalyzed filters was investigated by numerous measurements on a synthetic gas and an engine bench as well as by vehicle tests on a roller dynamometer. The HC/CO oxidation activity, the poisoning resistance towards sulfur and the desulfurization capability, the exothermic behaviour due to the conversion of subsequently injected hydrocarbons and the NO2 formation potential were examined in detail.

In this paper we report on a new state of the art diesel LNT (Lean NOx Trap) formulation that is designed to comply with North American emission legislation for diesel passenger cars. Improved performance and durability is demonstrated in an aging study using hydrothermal furnace aging and a prolonged procedure behind the engine consisting of repeated cycles containing sulfur exposure, desulfation and simulated regeneration of a diesel particulate filter. The improved barium based technology shows an increased thermal stability in terms of upper not-to-exceed temperature of at least 50°C. Our data show that potassium based technologies can represent a viable solution for certain applications that require extremely high NOx-conversions at temperatures above 500°C. Potassium based technologies with improved anchoring of the alkali metal show significant reduction in potassium loss to the exhaust gas.

The impending emission regulations in both China (CN7) and the United States (Tier 4) are set to impose more stringent emission limits on hydrocarbons (HC), carbon monoxide (CO), nitrogen oxides (NOx), and particulate matter (PM). CN7 places particular emphasis on reducing particulate number (PN) thresholds, while the forthcoming United States Tier 4 legislation is primarily concerned with reducing the allowable particulate matter (PM) to an assumed limit of 0.5 mg/mile. Given the more stringent constraints on both PN and PM emissions, the development of enhanced aftertreatment solutions becomes imperative to comply with these new regulatory demands. Coated Gasoline Particulate Filters (cGPFs) play a pivotal role as essential components for effective PN and PM abatement.

Recently, the European Union has adopted a new regulation on Real-Driving-Emissions (RDE) and also China is considering RDE implementation into new China 6 legislation. The new RDE regulation is focused on measuring nitrogen oxides (NOx) and particulate number (PN) emissions of both light-duty gasoline and diesel vehicles under real world conditions. A supplemental RDE test procedure was developed for European type approval, which includes on-road testing with cars equipped with portable emission measurement systems (PEMS). This new regulation will significantly affect the engine calibrations and the exhaust gas aftertreatment. In this study the impact of the new RDE regulation on two recent EU 6b certified turbocharged direct injected gasoline vehicles has been investigated. A comparison of several chassis dyno drive cycles with two new defined on-road RDE cycles was performed.

Particulate filters are currently the method of choice for reducing soot levels in diesel exhaust to the extremely low levels required for meeting future emission standards. For cost effective, reliable and manageable soot regeneration, the Catalytic Diesel Particulate Filter (CDPF) has proven to be one of the most promising solutions for maintaining filter performance. The activity of the CDPF can help lower soot ignition temperature thereby promoting active, oxygen-based filter regeneration. It can also facilitate passive regeneration of a filter at temperatures below 400 °C through formation of NO2 by catalyzing the oxidation of NO. There are two important factors which affect the passive regeneration of a CDPF. One is the influence of NOX/soot ratio. The other is the deterioration of the catalytic function upon aging. Together they determine the quantity of NO2 available for soot oxidation.

The development of diesel powered passenger cars is driven by the enhanced emission legislation. To fulfill the future emission limits there is a need for advanced aftertreatment devices. A comprehensive study was carried out focusing on the improvement of the DOC as one part of these systems, concerning high HC/CO conversion rates, low temperature light-off behaviour and high temperature aging stability, respectively. The first part of this study was published in [1]. Further evaluations using a high temperature DPF aging were carried out for the introduced systems. Again the substrate geometry and the catalytic coating were varied. The results from engine as well as vehicle tests show advantages in a highly systematic context by changing either geometrical or chemical factors. These results enable further improvement for the design of the exhaust system to pass the demanding emission legislation for high performance diesel powered passenger cars.

Gasoline particulate filters (GPFs) are an important aftertreatment system that enables gasoline direct injection (GDI) engines to meet current emission standardsn note of GPFs may need to improonont accumulates on the GPF during engine operation. GPFs are often ‘pa during vehicle operation when the exhaust is sufficiently hot and it contains sufficient oxygen. This paper explores the effect that engine-out soot emissions and the frequency of GPF regeneration have on GPF filtration efficiency. Two GPF technologies were tested on two engine dynamometers as well as two production vehicles on a chassis dynamometer. The engines span a wide range of engine-out particle emissions (a range of almost one order of magnitude). The filtration efficiency of the GPFs were measured with a regulation-compliant particle number system (non-volatile particles > 23 nm), as well as with a particle counter with a lower cutoff of 2.5 nm, and with a differential mobility spectrometer.

Future NOx-emission standards for diesel engines imply an after treatment system, e.g. in the form of an NH3-SCR system. For the technical realization a sound understanding of the catalytic processes is mandatory. To gain this knowledge a model of the SCR of NO with NH3 on Fe zeolite catalysts has been developed on the basis of a transient test cycle. The model is able to map the performance of the catalyst both under steady state and transient conditions. As practical examples the model is used to parameterize lookup tables and to compare different formats of lookup tables in terms of suitability for a urea dosage system.

The use of fatty acid methyl esters (FAME), often referred to as biodiesel, instead of fossil diesel fuel is under consideration in order to increase the share of fuels from renewable sources and to reduce greenhouse gas emissions. In Europe, commercial diesel fuels already contain up to 7% biodiesel. Higher biodiesel blends or the use of pure biodiesel are probable measures to further increase the share of fuels from renewable sources. Due to its different feedstock and refining process, the specification of biodiesel reveals some important distinctions in comparison with standard diesel fuel. The current work aims to discuss the possible implications of biodiesel utilization on the aftertreatment systems of recent heavy-duty diesel (HDD) vehicles compliant with EURO VI legislation. In particular, the effect of biodiesel on heat-up operation, i.e., the increase of the exhaust gas temperature by catalytic combustion of fuel within a diesel oxidation catalyst (DOC), is investigated.

This paper describes a study of ternary V2O5/WO3/TiO2 SCR catalysts coated on standard Celcor® and new highly porous cordierite substrates. At temperatures below 275°C, where NOx conversion is kinetically limited, high catalyst loadings are required to achieve high conversion efficiencies. In principle there are two ways to achieve high catalyst loadings: 1. On standard Celcor® substrates the washcoat thickness can be increased. 2. With new highly porous substrates a high amount of washcoat can be deposited in the walls. Various catalyst loadings varying from 120g/l to 540 g/l were washcoated on both standard Celcor® and new high porosity cordierite substrates with standard coating techniques. Simulated laboratory testing of these samples showed that high catalyst loadings improved both low temperature conversion efficiency and high temperature ammonia storage capacity and consequently increased the overall conversion efficiency.

NOx storage catalyst systems (or lean NOx trap, LNT) will most likely play an important role in meeting the future global Diesel emission standards. DaimlerChrysler introduced in 2006 the E 320 BLUETEC Diesel, which represents the first Clean Diesel car with NOx storage catalysts in North America [1]. The vast number of different applications result in a wide spectrum of different operating conditions for the LNT systems. Each of those different environments requires a fine-tuning of the catalyst's properties, particularly sulfur release properties and thermal durability. High average exhaust temperatures typical for a placement close to the engine require high thermal durability. Higher desulfation temperatures are acceptable in such a case since those temperatures are easier to achieve in such a configuration.

The oil ash accumulation on modern three way catalyst (TWC) as well as its influence on catalyst deactivation is evaluated as a parameter of oil consumption, kind of oil additive compound and additive concentration. The oil ash accumulation is characterized by XRF and SEM/EDX in axial direction and into the washcoat depth of the catalyst. The deposition patterns of Ca, Mg, P and Zn are discussed. The catalytic activity of the vehicle and engine bench aged catalysts is measured by performing model gas tests and vehicle tests, respectively. The influence of oil ash accumulation on the lifetime emission behavior of the vehicle is discussed.

With the growing awareness about the presence of fine/ultra fine particulates in the ambient air and their negative impact on climate and health, some regions of the world have started to look closer at the contribution of road traffic. Since Gasoline engines, in particular when injecting fuel directly into the combustion chamber, proved to emit relevant numbers of particulates, even hardly visible, the growing share of Gasoline DI engines and their small size of particulate emissions is a concern. To address the same, the EU has already set limits for the particulate number with EU6 from 2015 onwards. The US considers setting challenging limits by particulate mass. Since mass of ultra fine particulates is very low and difficult to measure, experts investigate if a measurement by number might better address the particular concern. The implementation of a coated Particulate Filter enables meeting not only basic demands during traditional emission test cycles.

Due to benefits from the use of electric power, Hybrid Electric Vehicles (HEVs) and Plug-in Hybrid Electric Vehicles (PHEVs) are regarded to be superior over conventional Internal Combustion Engine (ICE) only vehicles in fuel economy and emissions. However, recent studies find out that this is not always true. On certain conditions, hybrid vehicles can be even more polluted. In order to identify these challenges and develop catalysts to meet more stringent emission requirement in the future, e.g. Euro 7, for hybrid application, as a part of our xHEV project, this study includes exclusively extensive investigation on a latest Euro 6d temp Parallel PHEV.

Besides the further reduction of the harmful gaseous emissions (HC, CO and NOx) to reach upcoming emission limits, the discussion on lowering the CO₂ emissions is omnipresent. From engine development point of view further optimization of the stoichiometric-operated gasoline engine as well as the introduction of lean-operated engines are the main development trend. The emission control system can support the engine development by dedicated catalyst technologies as presented in this paper. A new family of TWC technologies offers to tune the catalyst system to the engine performance and the back pressure requirement - which helps to reduce CO₂ emissions. In addition these technologies show improved performance in HC, CO, NOx light-off, and in CO and NOx conversions under dynamic conditions - this again can positively impact the CO₂ emissions as less harsh heating strategies for cold start is required.

To meet future emission levels the industry is trying to reduce tailpipe emissions by both, engine measures and the development of novel aftertreatment concepts. The present study focuses on a joint development of aftertreatment concepts for gasoline engines that are optimized in terms of the exhaust system design, the catalyst technology and the system costs. The best performing system contains a close-coupled catalyst double brick arrangement using a new high thermal stable catalyst technology with low precious metal loading. This system also shows an increased tolerance against catalyst poisoning by engine oil.