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Using renewable fuels is a reliable approach for decarbonization of combustion engines. iso-Butanol and n-butanol are known as longer chain alcohols and have the potential of being used as gasoline substitute or a renewable fraction of gasoline. The combustion behavior of renewable fuels in modern combustion engines and advanced combustion concepts is not well understood yet. Low-temperature combustion (LTC) is a concept that is a basis for some of the low emissions-high efficiency combustion technologies. Fuel ɸ-sensitivity is known as a key factor to be considered for tailoring fuels for these engines. The Lund ɸ-sensitivity method is an empirical test method for evaluation of the ɸ-sensitivity of liquid fuels and evaluate fuel behavior in thermal. iso-Butanol and n-butanol are two alcohols which like other alcohol exhibit nonlinear behavior when blended with (surrogate) gasoline in terms of RON and MON.

The transportation industry has been scrutinized for its contribution towards the global greenhouse gas emissions over the years. While the automotive sector has been regulated by strict emission legislation globally, the emissions from marine transportation have been largely neglected. However, during the past decade, the international maritime organization focused on ways to lower the emission intensity of the marine sector by introducing several legislations. This sets limits on the emissions of different oxides of carbon, nitrogen and sulphur, which are emitted in large amounts from heavy fuel oil (HFO) combustion (the primary fuel for the marine sector). A 40% and 70% reduction per transport work compared to the levels of 2008 is set as target for CO2 emission for 2030 and 2050, respectively. To meet these targets, commonly, methanol, as a low-carbon fuel, and ammonia, as a zero-carbon fuel, are considered.

Dual-mode dual-fuel combustion is a promising combustion concept to achieve the required emissions and CO2 reductions imposed by the next standards. Nonetheless, the fuel formulation requirements are stricter than for the single-fuel combustion concepts as the combustion concept relies on the reactivity of two different fuels. This work investigates the effect of the low reactivity fuel sensitivity (S=RON-MON) and the octane number at different operating conditions representative of the different combustion regimes found during the dual-mode dual-fuel operation. For this purpose, experimental tests were performed using a PRF 95 with three different sensitivities (S0, S5 and S10) at operating conditions of 25% load/950 rpm, 50%/1800 rpm and 100%/2200 rpm. Moreover, air sweeps varying ±10% around a reference air mass were performed at 25%/1800 rpm and 50%/1800 rpm. Conventional diesel fuel was used as high reactivity fuel in all the cases.

The spatial and temporal locations of autoignition depend on fuel chemistry and the temperature, pressure, and mixing trajectories in the fuel jets. Dual-fuel systems can provide insight into fuel-chemistry aspects through variation of the proportions of fuels with different reactivities, and engine operating condition variations can provide information on physical effects. In this context, the spatial and temporal progression of two-stage autoignition of a diesel-fuel surrogate, n-heptane, in a lean-premixed charge of synthetic natural gas (NG) and air is imaged in an optically accessible heavy-duty diesel engine. The lean-premixed charge of NG is prepared by fumigation upstream of the engine intake manifold.

In this work a detailed soot model based on stationary flamelets is used to simulate soot emissions of a reactive Diesel spray. In order to represent soot formation and oxidation processes properly, a calibration of the soot reaction rates has to be performed. This model calibration is usually performed on basis of engine out soot measurements. Contrary to this, in this work the soot model is calibrated on local soot concentrations along the spray axis obtained from laser extinction chamber measurements. The measurements are performed with B7 certification Diesel and a series production multihole injector to obtain engine similar boundary conditions. In order to ensure that the flow and mixture field is captured well by the CFD-simulation, the simulated liquid penetration lengths and flame lift-off lengths are compared to chamber measurements.

In the past few years’ various studies have shown how the application of a highly premixed dual fuel combustion for CI engines leads a strong reduction for both pollutant emissions and fuel consumption. In particular a drastic soot and NOx reduction were achieved. In spite of the most common strategy for dual fueling has been represented by using two different injection systems, various authors are considering the advantages of using a single injection system to directly inject blends in the chamber. In this scenario, a characterization of the behavior of such dual-fuel blend spray became necessary, both in terms of inert and reactive ambient conditions. In this work, a light extinction imaging (LEI) has been performed in order to obtain two-dimensional soot distribution information within a spray flame of different diesel/gasoline commercial fuel blends. All the measurements were conducted in an optically accessible two-stroke engine equipped with a single-hole injector.

Emissions regulations for engine and vehicle manufacturers are bound to become more limiting to prevent greenhouse gas emissions and mitigate the negative effects that potentiate global warming. To fulfill the energy demand necessary in the transportation sector for the short-to-medium term, a parallel optimization of the internal combustion engine, powertrain and fuels is necessary. The combination of novel combustion modes like the reactivity-controlled compression ignition (RCCI), that seeks the benefits of both compression ignition and spark ignition engines, with the so-called e-fuels, that reduce the carbon footprint from well-to-wheel, is worth exploring. This work investigates the potential of the RCCI concept using OMEx-gasoline to reduce the engine-out emissions beyond the current EURO VI legislation. To do so, eight representative operating conditions from several driving cycles for heavy-duty vehicles will be explored experimentally.

Focusing on the dual-mode dual-fuel (DMDF) combustion concept, a combined optimization of the piston bowl geometry with the fuel injection strategy was conducted at low, mid, and high loads. By coupling the KIVA-3V code with the enhanced genetic algorithm (GA), a total of 14 parameters including the piston bowl geometric parameters and the injection parameters were optimized with the objective of meeting Euro VI regulations while improving the fuel efficiency. The optimal piston bowl shape coupled with the corresponding injection strategy was summarized and integrated at various loads. Furthermore, the effects of the key geometric parameters were investigated in terms of organizing the in-cylinder flow, influencing the energy distribution, and affecting the emissions. The results indicate that the behavior of the DMDF combustion mode is further enhanced in the aspects of improving the fuel economy and controlling the emissions after the bowl geometry optimization.

A genetic algorithm (GA) optimization methodology is applied to the design of the combustion system of a heavy-duty (HD) Diesel engine fueled with dimethyl ether (DME). The study has two objectives, the optimization of a conventional diffusion-controlled combustion system aiming to achieve US2010 targets and the optimization of a stoichiometric combustion system coupled with a three way catalyst (TWC) to further control NOx emissions and achieve US2030 emission standards. These optimizations include the key combustion system related hardware, bowl geometry and injection nozzle design as input factors, together with the most relevant air management and injection settings. The GA was linked to the KIVA CFD code and an automated grid generation tool to perform a single-objective optimization. The target of the optimizations is to improve net indicated efficiency (NIE) while keeping NOx emissions, peak pressure and pressure rise rate under their corresponding target levels.

It is challenging to develop highly efficient and clean engines while meeting user expectations in terms of performance, comfort, and drivability. One of the critical aspects in this regard is combustion noise control. Combustion noise accounts for about 40 percent of the overall engine noise in typical turbocharged diesel engines. The experimental investigation of noise generation is difficult due to its inherent complexity and measurement limitations. Therefore, it is important to develop efficient numerical strategies in order to gain a better understanding of the combustion noise mechanisms. In this work, a novel methodology was developed, combining computational fluid dynamics (CFD) modeling and genetic algorithm (GA) technique to optimize the combustion system hardware design of a high-speed direct injection (HSDI) diesel engine, with respect to various emissions and performance targets including combustion noise.

Compression ignition engines are widely used for transport and energy generation due to their high efficiency and low fuel consumption. To minimize the environmental impact of this technology, the pollutant emissions levels at the exhaust are strictly regulated. To reduce the after-treatment needs, alternative strategies as the low temperature combustion (LTC) concepts are being investigated recently. The reactivity controlled compression ignition (RCCI) uses two fuels (direct- and port- injected) with different reactivity to control the in-cylinder mixture reactivity by adjusting the proportion of both fuels. In spite of the proportion of the port-injected fuel is typically higher than the direct-injected one, the characteristics of the latter play a main role on the combustion process. Use of gasoline for direct injection is attractive to retard the start of combustion and to improve the air-fuel mixing process.

The dual-fuel combustion mode known as reactivity controlled compression ignition (RCCI) allows an effective control of the combustion process by means of modulating the in-cylinder fuel reactivity depending on the engine operating conditions. This strategy has been found to be able to avoid the NOx-soot trade-off appearing during conventional diesel combustion (CDC), with diesel-like or better thermal efficiency in a great part of the engine map. The role of the low reactivity fuel properties and engine settings over RCCI combustion has been widely investigated in literature, concluding that the direct-injected fuel injection timing is a key parameter for controlling the in-cylinder fuel stratification. From this, it can be inferred that the physical and chemical characteristics of the direct-injected fuel should have also an important role on the RCCI combustion process.

In several regions, such as Europe, California, among others, the switch to Electric Vehicles (EVs) has been heavily pushed by policymakers for their high powertrain efficiency and zero tailpipe emissions compared to conventional Internal Combustion Engine Vehicles (ICEVs). Consequently, only zero tailpipe emission vehicles will be sold in Europe from 2035 for the passenger cars and vans segment. But an EV does emit CO2 emissions across its life cycle, mainly during production, and the Well-to-Tank (WTT) phase, i.e., from the electricity generation used to charge the batteries. Nonetheless, due to the high efficiency of the electric powertrain, the energy consumption is significantly less, making the cost of operation significantly low for EVs. Thus, clean electricity grid and cheap energy costs can make EVs one of the best options for decarbonizing transportation systems.

There is growing global interest in using renewable alcohols to reduce the greenhouse gases and the reliance on conventional fossil fuels. Recent studies show that methanol combined with partially premixed combustion provide clear performance and emission benefits compared to conventional diesel diffusion combustion. Nonetheless, high unburned hydrocarbon (HC) and carbon monoxide (CO) emissions can be stated as the main PPC drawback in light load condition when using high octane fuel such as Methanol with single injection strategy. Thus, the present experimental study has been carried out to investigate the influence of multiple injection strategies on the performance and emissions with methanol fuel in partially premixed combustion. Specifically, the main objective is to reduce HC, CO and simultaneously increase the gross indicated efficiency compared to single injection strategy.

In pursuing sustainable automotive technologies, exploring alternative fuels for hybrid vehicles is crucial in reducing environmental impact and aligning with global carbon emission reduction goals. This work compares methanol and naphtha as potential suitable alternative fuels for running in a battery-driven light-duty hybrid vehicle by comparing their performance with the diesel baseline engine. This work employs a 0-D vehicle simulation model within the GT-Power suite to replicate vehicle dynamics under the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The vehicle choice enables the assessment of a delivery application scenario using distinct payload capacities: 0%, 25%, 50%, and 100%. The model is fed with engine maps derived from previous experimental work conducted in the same engine, in which a full calibration was obtained that ensures the engine's operability in a wide region of rotational speed and loads.

Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.

Economy decarbonization will be one of the main goals for the following years. Research efforts are being focused on reducing carbon-based emissions, by increasing the efficiency of the transport power plants while developing new fuel production methods that reduce the environmental footprint of the refinement process. Consequently, the depletion of conventional fuels derived from petroleum with high carbon content, such as gasoline and diesel, motivated the development of propulsive alternatives for the transportation sector. In this paradigm, methane (CH4) fuel appears as a mid-term solution due to its low carbon content, if compared with traditional fuels, and the low CO2 emissions during its production from renewable sources. However, the intrinsic properties of methane compromise the combustion process, subsequently increasing the emission of CO2.

The influence of pressure and temperature on some of the important thermodynamic properties of diesel fuels has been assessed for a set of fuels. The study focuses on the experimental determination of the speed of sound, density and compressibility (via the bulk modulus) of these fuels by means of a method that is thoroughly described in this paper. The setup makes use of a common-rail injection system in order to transmit a pressure wave through a high-pressure line and measure the time it takes for the wave to travel a given distance. Measurements have been performed in a wide range of pressures (from atmospheric pressure up to 200 MPa) and temperatures (from 303 to 353 K), in order to generate a fuel properties database for modelers on the field of injection systems for diesel engines to incorporate to their simulations.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.