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Meeting the California Medium-Duty truck emissions standards presents a significant challenge to automotive engineers due to the combination of sustained high temperature exhaust conditions, high flow rates and relatively high engine out emissions. A successful catalyst for an exhaust treatment system must be resistant to high temperature deactivation, maintain cold start performance and display high three-way conversion efficiencies under most operating conditions. This paper describes a catalyst technology and precious metal loading study targeting a California Medium-Duty truck LEV (MDV2) application. At the same time a direction is presented for optimizing toward the Federal Tier 1 standard through reduction of precious metal use. The paper identifies catalytic formulations for a twin substrate, 1.23 L medium-coupled converter. Two are used per vehicle, mounted 45 cm downstream of each manifold on a 5.7 L V8 engine.

Exhaust Gas Recirculation (EGR) coolers are commonly used in on-road and off-road diesel engines to reduce the recirculated gas temperature in order to reduce NOx emissions. One of the common performance behaviors for EGR coolers in use on diesel engines is a reduction of the heat exchanger effectiveness, mainly due to particulate matter (PM) deposition and condensation of hydrocarbons (HC) from the diesel exhaust on the inside walls of the EGR cooler. According to previous studies, typically, the effectiveness decreases rapidly initially, then asymptotically stabilizes over time. Prior work has postulated a deposit removal mechanism to explain this stabilization phenomenon. In the present study, five field aged EGR cooler samples that were used on construction machines for over 10,000 hours were analyzed in order to understand the deposit structure as well as the deposit composition after long duration use.

Exhaust gas recirculation (EGR) coolers are used on diesel engines to reduce peak in-cylinder flame temperatures, leading to less NOx formation during the combustion process. There is an ongoing concern with soot and hydrocarbon fouling inside the cold surface of the cooler. The fouling layer reduces the heat transfer efficiency and causes pressure drop to increase across the cooler. A number of experimental studies have demonstrated that the fouling layer tends to asymptotically approach a critical height, after which the layer growth ceases. One potential explanation for this behavior is the removal mechanism derived by the shear force applied on the soot and hydrocarbon deposit surface. As the deposit layer thickens, shear force applied on the fouling surface increases due to the flow velocity growth. When a critical shear force is applied, deposit particles start to get removed.

Exhaust Gas Recirculation (EGR) coolers are commonly used in diesel and modern gasoline engines to reduce the re-circulated gas temperature. A common problem with the EGR cooler is a reduction of the effectiveness due to the fouling layer primarily caused by thermophoresis, diffusion, and hydrocarbon condensation. Typically, effectiveness decreases rapidly at first, and asymptotically stabilizes over time. There are several hypotheses of this stabilizing phenomenon; one of the possible theories is a deposit removal mechanism. Verifying such a mechanism and finding out the correlation between the removal and stabilization tendency would be a key factor to understand and overcome the problem. Some authors have proposed that the removal is a possible influential factor, while other authors suggest that removal is not a significant factor under realistic conditions.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

Exhaust Gas Recirculation (EGR) coolers are widely used on diesel engines to reduce in-cylinder NOx formation. A common problem is the accumulation of a fouling layer inside the heat exchanger, mainly due to thermophoresis that leads to deposition of particulate matter (PM), and condensation of hydrocarbons (HC) from the diesel exhaust. From a recent investigation of deposits from field samples of EGR coolers, it was confirmed that the densities of their deposits were much higher than reported in previous studies. In this study, the experiments were conducted in order to verify hypotheses about deposit growth, especially densification. An experimental set up which included a custom-made shell and tube type heat exchanger with six surrogate tubes was designed to control flow rate independently, and was installed on a 1.9 L L-4 common rail turbo diesel engine.

This paper presents an experimental investigation of the impact of EGR dilution on the tradeoff between flame and end-gas autoignition heat release in a Spark-Assisted Compression Ignition (SACI) combustion engine. The mixture was maintained stoichiometric and fuel-to-charge equivalence ratio (ϕ′) was controlled by varying the EGR dilution level at constant engine speed. Under all conditions investigated, end-gas autoignition timing was maintained constant by modulating the mixture temperature and spark timing. Experiments at constant intake pressure and constant spark timing showed that as ϕ′ is increased, lower mixture temperatures are required to match end-gas autoignition timing. Higher ϕ′ mixtures exhibited faster initial flame burn rates, which were attributed to the higher laminar flame speeds immediately after spark timing and their effect on the overall turbulent burning velocity.

Present-day implementations of premixed compression ignition low temperature (PCI) combustion in diesel engines use higher levels of exhaust gas recirculation (EGR) than conventional diesel combustion. Two common devices that can be used to achieve high levels of EGR are an intake throttle and a variable geometry turbocharger (VGT). Because the two techniques affect the engine air system in different ways, local combustion conditions differ between the two in spite of, in some cases, having similar burn patterns in the form of heat release. The following study has developed from this and other observations; observations which necessitate a deeper understanding of emissions formation within the PCI combustion regime. This paper explains, through the use of fundamental phenomenological observations, differences in ignition delay and emission indices of particulate matter (EI-PM) and nitric oxides (EI-NOx) from PCI combustion attained via the two different techniques to flow EGR.

Experimental study on a turbine housing with inner insulation structure has been conducted for rapid light-off of the catalyst unit, which is located at the downstream side of turbochargers. The turbine housing with feasible inner-insulation structures has been designed and prototyped. It is referred to as the inner-insulated turbine housing. The concept of inner-insulation structures is a combination of sheet metals and insulators. The turbine housing was built using metal additive manufacturing with powder bed fusion technique. The gas stand test demonstrates the inner-insulated turbine housing under cold start-up with high temperature and idle condition to evaluate the time reduction for activation of the catalyst unit. To acquire the thermal and flow characteristic of the catalyst element, sheathed thermocouples were installed in the catalyst element.

Previous work done at the University of Michigan shows the capability of the vacuum-insulated catalytic converter (VICC) to retain heat during soak and the resulting benefits in reducing cold start emissions. This paper provides an improved version of the design which overcomes some of the shortcomings of the previous model and further improves the applicability and benefits of VICC. Also, newer materials have been evaluated and their effects on heat retention and emissions have studied using the 1-D after treatment model. Cold start emissions constitute around 60% to 80% of all the hydrocarbon and CO emissions in present day vehicles. The time taken to achieve the catalyst light-off temperature in a three-way catalytic converter significantly affects the emissions and fuel efficiency. The current work aims at developing a method to retain heat in catalytic converter, thus avoiding the need for light-off and reducing cold start emissions effectively.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

Vacuum insulation and phase-change thermal storage have been used to enhance the heat retention of a prototype catalytic converter. Storing heat in the converter between trips allows exhaust gases to be converted more quickly, significantly reducing cold-start emissions. Using a small metal hydride, the thermal conductance of the vacuum insulation can be varied continuously between 0.49 and 27 W/m2K (R-12 to R-0.2 insulation) to prevent overheating of the catalyst. A prototype was installed in a Dodge Neon with a 2.0-liter engine. Following a standard preconditioning and a 23-hour cold soak, an FTP (Federal Test Procedure) emissions test was performed. Although exhaust temperatures during the preconditioning were not hot enough to melt the phase-change material, the vacuum insulation performed well, resulting in a converter temperature of 146°C after the 23-hour cold soak at 27°C.

This paper presents an in-cylinder pressure measurement system for cycle-to-cycle feedback combustion control purposes. Such a system uses off-the-shelf components to measure cylinder pressure and performs user-defined algorithms for heat release analysis. The working principle of the device is discussed as well as the simplifications for heat release analysis required for fast computation. The system is benchmarked against a commercially-available combustion analyzer in order to quantify the accuracy and time response. The results showed that the system is satisfactorily accurate for combustion phasing control. The main advantage, however, comes from the reduction of calculation and communication delays observed in the commercially-available system. This enables the use of cycle-to-cycle cylinder pressure-based feedback control algorithms.

Early exhaust valve opening (eEVO) increases the exhaust gas temperature by faster termination of the power stroke and is considered as a potential warm up strategy for diesel engines aftertreatment thermal management. In this study, first, it is shown that when eEVO is applied, the engine main variables such as the boost pressure, exhaust gas recirculation (EGR) and injection (timing and quantity) must be re-calibrated to develop the required torque, avoid exceeding the exhaust temperature limits and keep the air fuel ratio sufficiently high. Then, a two-step procedure is presented to optimize the engine operation after the eEVO system is introduced, using a validated diesel engine model. In the first step, the engine variables are optimized at a constant eEVO shift. In the second step, optimal eEVO trajectories are calculated using Dynamic Programming (DP) for a transient test cycle.

Real-world tailpipe emissions from properly-functioning, model year 1991-94 conventional gasoline-fueled cars associated with vehicle operations not emphasized in the FTP are analyzed. Tailpipe emissions are expressed as the product of three factors: fuel rate, engine-out emissions index, and catalyst pass fraction, which are modeled using empirical data from the FTP-Revision Project and applied to in-use driving survey data to estimate real-world emissions. Average tailpipe emissions due to fuel enrichment in warmed-up vehicles are estimated to be 8 g/mile for CO, and 0.3 g/mile for HC. For NOx, the contribution due to incremental loads on the engine (i.e. air conditioner, grade, high acceleration, and high speed) that are not accounted for in the FTP but are encountered in real-world driving are estimated to be roughly 0.3 g/mile.

EGR coolers are mainly used on diesel engines to reduce intake charge temperature and thus reduce emissions of NOx and PM. Soot and hydrocarbon deposition in the EGR cooler reduces heat transfer efficiency of the cooler and increases emissions and pressure drop across the cooler. They may also be acidic and corrosive. Fouling has been always treated as an approximate factor in heat exchanger designs and it has not been modeled in detail. The aim of this paper is to look into fouling formation in an EGR cooler of a diesel engine. A 1-D model is developed to predict and calculate EGR cooler fouling amount and distribution across a concentric tube heat exchanger with a constant wall temperature. The model is compared to an experiment that is designed for correlation of the model. Effectiveness, mass deposition, and pressure drop are the parameters that have been compared. The results of the model are in a good agreement with the experimental data.

Natural gas-fueled vehicles impose unique requirements on exhaust aftertreatment systems. Methane conversion, which is very difficult for conventional automotive catalysts, may be required, depending on future regulatory directions. Three-way converter operating windows for simultaneous conversion of HC, CO, and NOx are considerably more narrow with gas engine exhaust. While several studies have demonstrated acceptable fresh converter performance, aged performance remains a concern. This paper presents the results of a durability study of eight catalytic converters specifically developed for natural gas engines. The converters were aged for 300 hours on a natural gas-fueled 7.0L Chevrolet engine operated at net stoichiometry. Catalyst performance was evaluated using both air/fuel traverse engine tests and FTP vehicle tests. Durability cycle severity and a comparison of results for engine and vehicle tests are discussed.

Low-Pressure Exhaust Gas Recirculation (LP-EGR) has been shown to be an effective means of improving fuel economy and suppressing knock in downsized, boosted, spark ignition engines. LP-EGR is particularly beneficial at low-speed, high-load conditions, but can lead to combustion instability at lower loads. The transport delays inherent in LP-EGR systems slow the reduction of intake manifold EGR concentrations during tip-out events, which may lead to excessive EGR concentrations at low load. This paper explores leveraging Variable Valve Timing (VVT) as a means of improving the rate of reduction of intake manifold EGR concentration prior to tip-out. At higher boost levels, high valve overlap may result in intake manifold gas passing directly to the exhaust manifold. This short-circuiting behaviour could potentially improve EGR evacuation rates.

Adjusting the Residual Gas Fraction (RGF) by means of Variable Valve Actuation (VVA) is a strong candidate for controlling the ignition timing in Homogeneous Charge Compression Ignition (HCCI) engines. However, at high levels of residual gas fraction, insufficient mixing can lead to the presence of considerable temperature and composition variations. This paper extends previous modeling efforts to include the effect of RGF distribution on the onset of ignition and the rate of combustion using a multi-dimensional fluid mechanics code (KIVA-3V) sequentially with a multi-zone code with detailed chemical kinetics. KIVA-3V is used to simulate the gas exchange processes, while the multi-zone code computes the combustion event. It is shown that under certain conditions the effect of composition stratification is significant and cannot be captured by a single-zone model or a multi-zone model using only temperature zones.

Natural gas (NG) is attractive for heavy-duty (HD) engines for reasons of cost stability, emissions, and fuel security. NG cannot be reliably compression-ignited, but conventional gasoline ignition systems are not optimized for NG and are challenged to ignite mixtures that are lean or diluted with exhaust-gas recirculation (EGR). NG ignition is particularly challenging in large-bore engines, where completing combustion in the available time is more difficult. Using two high-speed infrared (IR) cameras with borescopic access to one cylinder of an HD NG engine, the effect of ignition system on the early flame-kernel development and cycle-to-cycle variability (CCV) was investigated. Imaging in the IR yielded strong signals from water emission lines, which located the flame front and burned-gas regions and obviated image intensifiers. A 9.7-liter, six-cylinder engine was modified to enable exhaust-gas recirculation and to provide optical access.