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Stochastic Preignition (SPI) is an abnormal combustion phenomenon for internal combustion engines (ICE), which has been a significant impact to automotive companies developing high efficiency, turbocharged, direct fuel injection, spark ignited engines. It is becoming clearer what fuel properties are related to the cause of SPI, whether directly with fuel preparation in the cylinder, or mechanisms related to the deposit build-up which contributes to initial and follow-on SPI events. The purpose of this paper is to provide a summary of global market gasoline fuel properties with special attention given to properties and specific compounds from the fuel and fuel additives that can contribute to SPI and the deposit build-up in engines. Based on a review of the global fuel quality, it appears that the fuel quality has not caught up to meet the technology requirements for fuel economy from modern technology engines.

Exhaust Gas Recirculation (EGR) coolers are commonly used in on-road and off-road diesel engines to reduce the recirculated gas temperature in order to reduce NOx emissions. One of the common performance behaviors for EGR coolers in use on diesel engines is a reduction of the heat exchanger effectiveness, mainly due to particulate matter (PM) deposition and condensation of hydrocarbons (HC) from the diesel exhaust on the inside walls of the EGR cooler. According to previous studies, typically, the effectiveness decreases rapidly initially, then asymptotically stabilizes over time. Prior work has postulated a deposit removal mechanism to explain this stabilization phenomenon. In the present study, five field aged EGR cooler samples that were used on construction machines for over 10,000 hours were analyzed in order to understand the deposit structure as well as the deposit composition after long duration use.

This paper presents an experimental investigation of the impact of EGR dilution on the tradeoff between flame and end-gas autoignition heat release in a Spark-Assisted Compression Ignition (SACI) combustion engine. The mixture was maintained stoichiometric and fuel-to-charge equivalence ratio (ϕ′) was controlled by varying the EGR dilution level at constant engine speed. Under all conditions investigated, end-gas autoignition timing was maintained constant by modulating the mixture temperature and spark timing. Experiments at constant intake pressure and constant spark timing showed that as ϕ′ is increased, lower mixture temperatures are required to match end-gas autoignition timing. Higher ϕ′ mixtures exhibited faster initial flame burn rates, which were attributed to the higher laminar flame speeds immediately after spark timing and their effect on the overall turbulent burning velocity.

With the implementation of the China VI gasoline standards, the use of ethanol is expanding and is intended to further reduce vehicle criteria gaseous and particulate emissions. However, due to the constraints of biomass ethanol production, petroleum derived Methyl tert-Butyl Ether (MTBE) is being used in addition to ethanol to improve fuel octane and maintain oxygen content. The impact of these mixed oxygenates on vehicle emissions are studied in this paper. The correlation of fuel characteristics to vehicle particulate emissions and their predictive indices has been investigated. The results from this study suggest some alternatives to existing fuel indices due to oxygenate contribution. Additionally, this paper studies, the emissions of three direct-injection turbocharged vehicle models focusing on particulate emissions from the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The test fuels were China VIb gasoline, blended with different ratios of ethanol and MTBE.

In this study, the performance and emissions of a 4 cylinder 2.5L light-duty diesel engine with methane fumigation in the intake air manifold is studied to simulate a dual fuel conversion kit. Because the engine control unit is optimized to work with only the diesel injection into the cylinder, the addition of methane to the intake disrupts this optimization. The energy from the diesel fuel is replaced with that from the methane by holding the engine load and speed constant as methane is added to the intake air. The pilot injection is fixed and the main injection is varied in increments over 12 crank angle degrees at these conditions to determine the timing that reduces each of the emissions while maintaining combustion performance as measured by the brake thermal efficiency. It is shown that with higher substitution the unburned hydrocarbon (UHC) emissions can increase by up to twenty times. The NOx emissions decrease for all engine conditions, up to 53%.

This study experimentally investigates the impact of Miller cycle strategies on the combustion process, emissions, and thermal efficiency in heavy-duty diesel engines. The experiments were conducted at constant engine speed, load, and engine-out NOx (1160 rev/min, 1.76 MPa net IMEP, 4.5 g/kWh) on a single cylinder research engine equipped with a fully-flexible hydraulic valve train system. Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC) timing strategies were compared to a conventional intake valve profile. While the decrease in effective compression ratio associated with the use of Miller valve profiles was symmetric around bottom dead center, the decrease in volumetric efficiency (VE) was not. EIVC profiles were more effective at reducing VE than LIVC profiles. Despite this difference, EIVC and LIVC profiles with comparable VE decrease resulted in similar changes in combustion and emissions characteristics.

A gasoline’s chemical composition impacts a vehicle’s sooting tendency and therefore has been the subject of numerous emissions studies. From these studies, several mathematical correlation equations have been developed to predict a gasoline’s sooting tendency in modern spark-ignited internal combustion engine vehicles. This paper reviews the recently developed predictive tool methods and summarizes five years of global market fuel survey data to characterize gasoline sooting tendency trends around the world. Additionally, the paper will evaluate and suggest changes to the predictive methods to improve emissions correlations.

A gasoline’s distillation profile is directly related to its hydrocarbon composition and the volatility (boiling points) of those hydrocarbons. Generally, the volatility profiles of U.S. market fuels are characterized using a very simple, low theoretical plate distillation separation, detailed in the ASTM D86 test method. Because of the physical chemistry properties of some compounds in gasoline, this simple still or retort distillation has some limitations: separating azeotropes, isomers, and heavier hydrocarbons. Chemists generally rely on chromatographic separations when more detailed and precise results are needed. High-boiling aromatic compounds are the primary source of particulate emissions from spark ignited (SI), internal combustion engines (ICE), hence a detailed understanding and high-resolution separation of these heavy compounds is needed.

This experimental study involves optimization of the scheduling of diesel post injections to reduce soot emissions from a light-duty diesel engine. Previous work has shown that certain post injection schedules can reduce engine-out soot emissions when compared to conventional injection schedules for the same engine load. The purpose of this study is to investigate the impact of post injection scheduling for a range of engine conditions on a light duty multicylinder turbodiesel engine (1.9L GM ZDTH). For each engine operating condition, a test grid was developed so that only two variables (post injection duration and the commanded dwell time between main injection and post injection) were varied, with all other conditions held constant, in order to isolate the effects of the post injection schedule. Results have identified two distinct regimes of post injection schedules that reduce soot emissions.

Cooled EGR provides benefits in better fuel economy and lower emissions by reducing knocking tendency and decreasing peak cylinder temperature in gasoline engines. However, GDI engines have high particle emissions due to limited mixing of fuel and air, and these particle emissions can be a major source of EGR cooler fouling. In order to improve our knowledge of GDI engine EGR cooler fouling, the effects of tube geometry and coolant temperature on EGR cooler performance and degradation were studied using a four cylinder 2.0L turbocharged GDI engine. In addition, deposit microstructure was analyzed to explore the nature of deposits formed under GDI engine operation. The results of this study showed that a dented tube geometry was more effective in cooling the exhaust gas than a smooth tube due to its large surface area and turbulent fluid motion. However, more deposits were accumulated and higher effectiveness loss was observed in the dented tube.

With ongoing concerns about the elevated levels of ambient air pollution in urban areas and the contribution from heavy-duty diesel vehicles, hybrid electric vehicles are considered as a potential solution as they are perceived to be more fuel efficient and less polluting than their conventional engine counterparts. However, recent studies have shown that real-world emissions may be substantially higher than those measured in the laboratory, mainly due to operating conditions that are not fully accounted for in dynamometer test cycles. At the U.S. EPA National Fuel and Vehicle Emissions Laboratory (NVFEL) the in-use criteria emissions and energy efficiency of heavy-duty class 8 vehicles (up to 36280 kg) can be evaluated under controlled conditions in the heavy-duty chassis dynamometer test.

There have been tremendous improvements in China fuel quality in recent years in conjunction with newly implemented vehicle emissions standards to combat air pollution. The focus of concern is particulate emissions from gasoline engines especially from high volume gasoline direct inject (GDI) engines, therefore the China 6 (GB 18351.6-2016) emission standard introduces strict PM/PN requirements. Because the fuel and vehicle are an integrated system, the composition of gasoline is one of the factors affecting PM/PN emissions. Ethanol and aromatics are widely used as octane boosters, changing the composition of China’s gasoline pool. In this study, two gasoline oxygenates, ethanol and methyl tert-butyl ether (MTBE), and heavy aromatic hydrocarbons were studied in vehicles with a GDI engines. Vehicle tests were performed on the Worldwide Harmonized Light Vehicles Test Cycle (WLTC).

Syngas (synthesis gas) aided combustion from various fuel reforming strategies is of increasing interest in boosted lean burn SI engines due to its impact on dilution tolerance and knock resistance. Due to the interest in reformed fuels, more concrete understanding of how to leverage syngas supplementation under various lean conditions is essential to optimize engine performance and derive the most benefit from the availability of syngas in the combustion process. While the impact of syngas supplementation on combustion stability has been studied adequately, detailed understanding of the impact of syngas on knocking is still limited. Hence, this study investigates the effect of syngas (H2/CO) addition on knock tendency under boosted EGR (Exhaust Gas Recirculation) and air diluted conditions. Syngas amount is controlled on an energy basis from 0% to 15% to compare the difference between EGR and air dilution.

Combined direct and port fuel injection (i.e., dual injection) in spark ignition engines is of increasing interest due to the advantages for fuel flexibility and the individual merits of each system for improving engine performance and reducing engine-out emissions. Greater understanding of the impact of dual injection will enable deriving the maximum benefit from the two injection systems. This study investigates the effects of dual injection on combustion, especially knock propensity and tolerance to exhaust gas recirculation (EGR) dilution at different levels of EGR. A baseline for comparison with dual injection results was made using direct injection fueling only. A splash blended E20 fuel was used for the direct injection only tests. For the dual injection tests, gasoline, representing 80% by volume of the total fuel, was injected using the direct injector, and ethanol, representing 20% by volume of the total fuel, was injected using the port fuel injector.

The Particulate Matter Index (PMI) is a helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and OEMs as a metric to understand the gasoline fuels impact on both sooting found on engine hardware and vehicle out emissions. This paper will explore a new method that could be used to give indication of the sooting tendency of the gasoline range fuels, called the Particulate Evaluation Index (PEI), and provide the detailed equation in its initial form. In addition, the PEI will be shown to have a good correlation agreement to PMI. The paper will then give a detailed explanation of the data used to develop it. Initial vehicle PM/PN data will also be presented that shows correlations of the indices to the vehicle response.

Investigating combustion characteristics of oxygenated gasoline and gasoline blended ethanol is a subject of recent interest. The non-linearity in the interaction of fuel components in the oxygenated gasoline can be studied by developing chemical kinetics of relevant surrogate of fewer components. This work proposes a new reduced four-component (isooctane, heptane, toluene, and ethanol) oxygenated gasoline surrogate mechanism consisting of 67 species and 325 reactions, applicable for dynamic CFD applications in engine combustion and sprays. The model introduces the addition of eight C1-C3 species into the previous model (Li et al; 2019) followed by extensive tuning of reaction rate constants of C7 - C8 chemistry. The current mechanism delivers excellent prediction capabilities in comprehensive combustion applications with an improved performance in lean conditions.

Several predictive equations based on the chemical composition of gasoline have been shown to estimate the particulate emissions of light-duty, internal combustion engine (ICE) powered vehicles and are reviewed in this paper. Improvements to one of them, the PEISimDis equation are detailed herein. The PEISimDis predictive equation was developed by General Motor’s researchers in 2022 based on two laboratory gas chromatography (GC) analyses; Simulated Distillation (SimDis), ASTM D7096 and Detailed Hydrocarbon Analysis (DHA), ASTM D6730. The DHA method is a gas chromatography mass spectroscopy (GC/MS) methodology and provides the detailed speciation of the hundreds of hydrocarbon species within gasoline. A DHA’s aromatic species from carbon group seven through ten plus (C7 – C10+) can be used to calculate a Particulate Evaluation Index (PEI) of a gasoline, however this technique takes many hours to derive because of its long chromatography analysis time.

With increasing use of ethanol in automotive fuel in recent years, which can be made from renewable feedstocks, the chemical composition of gasoline is changed. The compositional change results in many changes in fuel properties. One key property is the octane rating of gasoline. Market data has shown the shifts of octane rating (antiknock index or AKI) upward due to more penetration of E10 gasoline in the US market. However, the increase in research octane is more pronounced as compared to motor octane, therefore the increase in octane sensitivity in gasoline. Refineries have used the change in octane due to ethanol contribution by sending so called sub-grade gasoline to terminals expecting the final blend after mixing with ethanol to meet the market requirement in octane. Thus the octane rating of the final blend will largely depend on the sub-grade gasoline composition and ethanol.

The impact of gasoline composition on vehicle particulate emissions response has been widely investigated and documented. Correlation equations between fuel composition and particulate emissions have also been documented, e.g. Particulate Matter Index (PMI) and Particulate Evaluation Index (PEI). Vehicle PM/PN emissions correlate very well with these indices. In a previous paper, global assessment with PEI on fuel sooting tendency was presented [1]. This paper will continue the previous theme by the authors, and cover China gasoline in more detail. With air pollution an increasing concern, along with more stringent emission requirements in China, both OEMs and oil industries are facing new challenges. Emissions controls require a systematic approach on both fuels and vehicles. Chinese production vehicle particulate emissions for a range of PEI fuels are also presented.

The Honda Particulate Matter Index (PMI) is a very helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and vehicle OEMs as a metric to understand a fuels impact on automotive engine sooting, in preparation for new global emissions regulations. The calculation of the index involves generating detailed hydrocarbon analysis (hydrocarbon molecular speciation) using gas chromatography laboratory equipment and the PMI calculation requires the exact list of compounds and correct naming conventions to work properly. The analytical methodology can be cumbersome, when the gas chromatography methodology has to be adjusted for new compounds that are not in the method, or if the compounds are not matching the list for quantification. Also, the method itself is relatively expensive, and not easily transferrable between labs.